XII CHEMISTRY

(Date: 11/10/2022)
Assignment Sheet
1.Solid State
Marks-3 with option 5
Q.1) Differentiate between crystalline and amorphous solids. (2M)
Q.2) Explain the terms: a) Isomorphism b) Polymorphism with examples. (2M)
Q.3) Define: a) Unit cell b) Bravais lattices
c) Diamagnetic solids d) Paramagnetic solids (Each 1 Mark)
Q.4) When gold crystallizes,it forms fcc unit cells.The unit cell edge length is 408 pm. Calculate
the density of gold.Molar mass of gold is 197 g/mol. (Ans: 19.27g/cm3 ) (2M)
Q.5) A compound forms hcp structure. What is the number of a) Octahedral voids b) tetrahedral voids c)
total voids formed in 0.4 mol of it. (3M)
Q.6) What is Schottky defect. Write consequences of Schottky defect. (3M) .
Q.7) What is Frenkel defect.Write consequences of the Frenkel defect. 3M)
Q.8) Explain the following terms:
Substitutional impurity defect b) Interstitial impurity defect.
Q.9) An element with molar mass 27g/mol forms a cubic unit cell with an edge length of 405pm. If the
density of the element is 2.7 g/cm3.What is the nature of a cubic unit cell.(Ans: 4 fcc/ccp)
Q.10) An element has a bcc structure with unit cell edge length of 288 pm and has density 7.21 g/cm3 How
many unit cells and number of atoms are present in 200 g of the element? (Ans: 1.16 x1024, 2.32x1024)
(3M)
Q.2) Niobium forms bcc structure.The density of niobium is 8.55 g/cm3 and edge length of unit cell is 330.6
pm.How many atoms and unit cells are present in 0.5 g of niobium?
Q.11) Write the number of particles present in each of scc, bcc and fcc, unit cells.
Q.12) Write the formula showing relationship between molar mass,density and edge length of a unit cell.
Q.13) The unit cell of metallic silver is fcc.If radius of Ag atom is 144 pm. Calculate Edge length of unit cell
b) Volume of Ag atom c) The Percentage volume of unit cell d) % empty space
Q.14) Write the relationship between ‘a’ and ‘r’ for sc,bcc and fcc unit cells.
Q.15) Write the space occupied and empty space in sc,bcc and fcc crystal lattice.
Q.16) Which among the following solid does not show Schottky defect.
a) NaCl b) CaF2 c) NiO d) K2SO4
Q.17) Write the Coordination number of atoms in sc,bcc and fcc crystal lattice.
Q.18) Write the name of the colour of NaCl crystal formed due to formation of F-centre.

2.Solutions
Marks-4 with option 6
Q.1) The Henry's law constant of methyl( CH3Br),is 0.159 mol L-1 bar -1 at 250 0C.What is the solubility of
methyl bromide in water at 2500C and at pressure of 130 mmHg?
Q.2) The solubility of N2 gas in water at 250C and 1 bar is 6.85x10-4mol L-1. Calculate Henry’s law
constant.
Q.3) Write Henry’s law.Write SI unit of Henry’s law constant.
Q.4) Write the name of any one solution which shows a positive deviation from Raoult's law.
Q.5) Mention colligative properties. (2M)
Q.6) Explain the relationship between molar mass of a solute from vapour pressure lowering.
Q.7) The vapour pressure of pure benzene (Molar mass 78 g/mol) at a certain temperature is 640 mm Hg.A
nonvolatile solute of mass 2.315 g is added to 49 g of benzene.The vapour pressure of the solution is 600
mm Hg.What is the molar mass of the solute?
Q.8) Define ebullioscopic constant. Write its SI Unit.
Q.9) Explain the relationship between Molar mass of solute and boiling point elevation.
Q.10) The normal boiling point of ethyl acetate is 77.06 0C.A solution of 50 g of a non volatile solute in 150
g of ethyl acetate boils at 84.27 0C.Calcuate the molar mass of solute if Kb for ethyl acetate is 2.77 oC Kg
mol-1 (Ans: 128 g/mol)
Q.11) Define: a) Osmosis b) Osmotic pressure c) Isotonic solution
d) Hypertonic solution e) Colligative properties f) Boiling point elevation
Q.12) Write the condition when reverse osmosis takes place.
Q.13) Explain the relationship between van’t Hoff factor and degree of dissociation. 15.Define Cryoscopic
constant. Write its SI Unit.
Q.14) Explain the relationship between Molar mass of solute and freezing point elevation.(2M)
Q.15) Write the relation between molar mass of solute and osmotic pressure.(1M)
Q.16) Derive Raoult’s law for solutions of non volatile solutes.
Q.17) Write the name and molecular formula of ionic solid whose solubility decreases with increase in
temperature.
Q.18) Write the relationship between Osmotic pressure and Concentration of solution.
3.4 g of CaCl2 is dissolved in 2.5 L of water at 300 K.What is the osmotic pressure of the solution? (Van’t
Hoff factor for CaCl2 is 2.47 (Ans: 0.745 atm)
Q.19) A mixture of benzene and toluene contains 30% by mass of toluene.At 300C,vapour pressure of pure
toluence is 36.7mmHg and that of pure benzene is 118.2 mmHg.Assuming that the two liquid form ideal
solutions,calculate the total pressure and partial pressure of each constituent above the solution at300C. (86.7
mm, P=96.5 mm)

3. Ionic Equilibria
Marks-4 with option 6
Q.1) Explain acids and bases with examples according to lowery-bronsted theory. (2M)
Q.2) Explain Ostwald’s dilution law for weak acids. (2M)
Q.3) Explain Ostwald’s dilution law for weak bases. (2M)
Q.4) The dissociation constant of NH4OH is 1.8 x10-5.Calculate its degree of dissociation in
0.001 M Solution.
Q.5) A weak monobasic acid is 12% dissociated in 0.05M solution. What is percent dissociation in 0.15 M
solution.(Ans: 6.93 %)
Q.6) A weak monobasic acid is 0.05% dissociated in 0.02 M solution. Calculate dissociation constant of the
acid.(Ans: 5x10-9)
Q.7) Write the relation between PH and POH.(2M)
Q.8) The PH of monobasic weak acid is 11.2.Calculate OH- ion concentration.
Q.9) Define: a)Hydrolysis of salt b) Conjugate acid-base pair
c) Solubility product d) Common ion effect
Q.10) Define: Buffer solution. Explain acidic buffer solution. (1+2)
Q.11) Explain basic buffer solution.
Q.12) Write any four applications of buffer solution.
Q.13) Write the relation between solubility and solubility product with respect to
a) AgBr b) PbI2
Q.14) Calculate PH and POH of 0.01M HCl solution.

Q.15) Calculate the pH of buffer solution composed of 0.1 M weak base BOH and 0.2 M of its salt BA.
(Kb=1.8x10-5 for the weak base) (Ans: 13.95)
Q.16) The solubility product of AgBr is 5.2x10-13. Calculate its solubility in mol dm-3 and
g dm-3(Molar mass of AgBr=187.8 gmol-1)
Q.17) Write the name of buffer solution used in preparation of penicillin drug stabilization.
Q.18) Write PH of human blood.
Q.19) Write the PH range required for precipitation of cataions III A group during qualitative analysis

Chemical Thermodynamics
Marks-6 with option 8
Q.1) Define: a) Extensive property b) Intensive property with examples.
Q.2)Define: Isothermal,Isobaric,Isochoric and adiabatic processes.
Q.3) Write sign conventions of W and Q.
Q.4) Derive the expression for pressure -volume work.
Q.5) What is free expansion?
Q.6) Three moles of an ideal gas are expanded isothermally from 10 dm3 to 20 dm3 at constant external
pressure of 1.2 bar.Calculate the work done in dm3 bar and J.
Q.7) Derive expression for maximum work.
Q.8) 2 moles of an ideal gas are expanded isothermally and reversibly form 20L to 30L at 300K.Calculate
the work done (R=8.314 JK-1 mol-1)
Q.9) Write the first law of thermodynamics in different ways.
Q.10) Write mathematical statement of first law of thermodynamics for
a) Isothermal process b) adiabatic process.
Q.11) Write a relationship between ΔH and ΔU for gaseous chemical reactions.
Q.12) Calculate the standard enthalpy of combustion of CH4 (g) if ΔfH0(CH4) = -74.8 kJ mol-1, ΔfH0CO2) = -
393.5 kJ mol-1 , ΔfH0 (H2O) = -285.8 kJ mol-1
Q.13) State Hess’s law of constant heat summation.
Q.14) Calculate the standard enthalpy of the reaction
SiO2(s) + 3C (graphite) → SiC(s) + 2CO(g) from the following reactions
i) Si(s) +O2(g) → SiO2 (s), ΔrH0 = -911 kJ
2C(graphite) +O2(g) → 2CO(g), ΔrH0 = -221 kJ
Si (s)+ C (graphite) → SiC(s) , ΔrH0 = -65.3 kJ
Q.15) Write the Statement of the second law of thermodynamics.
Q.16) Write relationship between ΔG and ΔS total For Spontaneous reaction, write the condition of ΔG
Q.17) 3 moles of an ideal gas are expanded isothermally from 15 dm3 to 20 dm3 at constant external
pressure of 1.2 bar.Calculate the amount of work in dm3 bar and J. (1 dm3 bar = 100J)
(Ans:-6dm3 bar and -600 J)
Q.18) Calculate the constant external pressure required to compress 2 moles of an ideal gas from volume of
25 dm3 to 13 dm3 when the work is 4862.4J (Ans:4.052 Bar)
Q.19) 22 g of CO2 are compressed isothermally and reversibly at 298 K form initial pressure of 100kPa
when the work obtained is 1.2 kJ.Find the final pressure. (Ans:263.4kpa)
ΔH for a reaction 2C(s) + 3H2(g) C2H6(g) is -84.4 kJ at 250C.Calculate
ΔU for the reaction at250C.(R=8.314J/K/mol) (Ans: -79.44kJ)
Q.20) Define: a) Enthalpy of fusion b) Enthalpy of atomization
c) Enthalpy of ionization d) Enthalpy of vaporization
Q.21) State whether following reactions are spontaneous or not.Further state whether they are exothermic or
endothermic.
ΔH=- 110 kJ and ΔS = + 40 JK-1 at 400K
ΔH=+ 50 kJ and ΔS = -130 JK-1 at 250K

Electrochemistry
Marks-5 with option 7
Q.1) Write the SI unit of conductivity.
Q.2) Write the relationship between k and ( Lambda)
Q.3) The molar conductivity of 0.005 M Barium chloride solution at 250 C is 223 Ω -1 cm2 mol-1 What is
its conductivity? (Ans: 0.01115. Ω -1 cm-1)
Q.4) The conductivity of 0.01 M acetic acid at 250 C is 16.5 Ω -1 cm2 mol-1. Calculate its degree of
dissociation in 0.001 M solution and dissociation constant if molar conductivity of acetic acid at zero
concentration is 390.7Ω -1 cm2 mol-1 . (Ans: 1.85 x 10-5)
Q.5) Define cell constant. Write SI unit of cell constant.
Q.6) Write the formula to calculate molar conductivity of the given solution.
Q.7) Define: a) Cathode b) Anode
Q.8) What is the mass of Cu metal produced at the cathode during passage of 5 ampere current through
CuSO4 solution for 100 minutes.Molar mass of Cu is 63.5 g/mol) (Ans: 9.87g)
Q.9) Write functions of salt bridge.
Q.10) How many moles of electrons are required for reduction of 3 moles of Zn2+ to Zn? How many
Faradays of electricity will be required?
Q.11) In a certain electrolysis experiment 4.36 g of Zn are deposited in one cell containing ZnSO4
solution.Calculate the mass of Al deposited in another cell containing AlCl3 solution connected in series
with ZnSO4 cell.Molar masses of Zn and Al are 65.4 g/mol and 27 g/mol
respectively. (Ans: 1.2 g)
Q.12) Write the value of, 2.303RT/F at 250C.
The standard potential of the electrode,Zn2+(0.02M)| Zn(s) is -0.76 V.Calculate its potential.
(Ans: 0.81 V)
Q.13) Calculate standard Gibbs energy change and equilibrium constant at 250C for the cell reaction,
Cs(s) + Sn2+ (aq) → Cd2+ (aq) + Sn(s)
Given: E0 Cd= - 0.403V and E0 Sn=- 0.136V. Write formula of the cell.
(Ans: ΔG0= -51.53, K= 1.05 x109)
Q.14) Define:Reference electrode.
Q.15) Explain,Construction of Standard Hydrogen electrode(SHE) with diagram, write its applications and
difficulties in setting.
Q.16) Draw labeled diagram of Leclanche cell(Dry Cell)
Q.17) Draw labeled diagram of H2-O2 fuel cell.
Q.18) Explain construction and write advantages of H2-O2 fuel cell.
Q.19) Write applications of H2-O2 fuel cell.
Q.20) Define:Electrochemical series. Write applications of electrochemical series.
Q.21) Draw labeled diagram of Lead accumulator.
Q.22) Write formulation of Standard Hydrogen electrode.
Q.23) Write net cell reaction during discharge of Lead storage battery.

Chemical Kinetics
Marks-3 with option 5
Q.1) Consider,A+B →Product.If the concentration of A is doubled with concentration of B being
constant,the rate of the reaction doubles.If the [A] is tripled and that of [B] is doubled,the rate increases by a
factor 6. What is the order of the reaction with respect to each reactant? Determine the overall order of the
reaction?
Q.2) For the reaction, 2NOBr(g)→ 2NO(g)+ Br2(g), the rate law is, rate=k [NOBr]2 . If the rate of the
reaction is 6.5 x 10-6 mol L-1 s-1 when the concentration of NOBr is 2x10-3 mol L-1.What would be the
rate constant for the reaction? (Ans: 1.625 mol L-1s-1)
Q.3) Distinguish between order and molecularity of a reaction.
reaction occurs in the following steps
NO2(g) +F2(g)→NO2F(g)+F(g) (slow) ii) F(g) + NO2(g)→NO2F(g) (Fast)
a.Write the equation of overall reaction.
b.Write rate law for the reaction.
c.Write the reaction intermediate.
Q.4) Explain integrated rate law for the first order reactions in solutions.
Q.5) Write only the equation of integrated rate law for the first order reaction in solutions. 7.Write the unit of
rate constant for the first order reaction.
Q.6) Explain the equation for half life and rate constant of the first order reaction. 9.Explain integrated rate
law for gas phase reactions.
Q.7) Write only the equation of integrated rate law for gas phase reactions.
Q.8) In a first order reaction 60% of the reactant decomposes in 45 minutes.Calculate the half life for the
reaction.(Ans: k= 0.0204 min-1,t1/2=34 min.)
Q.9) Explain the integrated rate law for zero order reactions.
Q.10) Write a unit of rate constant of zero order reaction. 14.Define: Pseudo first order reaction.
Q.11) Write Arrhenius equation and write terms involved in it. 15.Explain the equation of determination of
activation energy.
Q.12) The energy of activation for a first order reaction is 104 kJ/mol.The rate constant at 250C is
3.7 x10-5 s-1. What is the rate constant 300C ?(R=8.314J/K mol) (Ans:7.4x10-5 s-1)
Q.13) Show that time required for 99.9% completion of a first order reaction is three times the time required
for 90% completion.
Q.14) A reaction occurs in two steps
NO(g) +Cl2(g)→NOCl2(g)
NOCl2(g) + NO(g)→2NOCl(g)
a.Write the equation of overall reaction. b.Write the reaction intermediate.

Elements of Groups 16,17 and 18

Marks-6 with option 8
Q.1) Write the name of an element, which is a radioactive decay product of thorium and uranium.
Q.2) Write chemical composition of cryolite, fluorapatite, carnallite,copper pyrites.
Q.3) Explain the periodic trends of group 16 elements with respect to following
Atomic and ionic radii ii) Ionisation enthalpy
iii) Electronegativity iv) Electron gain enthalpy.
Q.4) Explain the anomalous behavior of Oxygen with respect to
Atomicity ii) Magnetic property iii) Oxidation state iv) Nature of hydrides
Q.5) Explain anomalous behavior of fluorine.
Q.6) Write anomalous properties of fluorine with respect to
i) Electronegativity ii) Oxoacid iii) Nature of hydride iv) Ionic radii
Q.7) Write in decreasing order, thermal stability of hydrogen halides.
Q.8) Write acidic strength of hydrogen halides in increasing order.
Q.9) Distinguish between rhombic and monoclinic sulfur.
Q.10) Write the structures of following oxoacids of sulfur
i) Sulphuric acid ii) Peroxy monosulphuric acid iii) Peroxy disulphuric acid
iv) Thiosulphuric acid. vi) Pyrosulphuric acid
Q.11) Write the structures and oxidation states of following oxoacids of chlorine.
i) Chloric acid ii) Hypochlorous acid iii) Chlorous acid iv) Perchloric acid.
Q.12) Write uses of dioxygen.
Q.13) Define: Dry Bleach.
Q.14) Write canonical structure of ozone and sulfur dioxide
Q.15) Write the following chemical equations involved in the proportion of sulphuric acid by Contact
process.
Sulphide ore to sulfur dioxide
sulfur dioxide to sulfur trioxide
Sulphur trioxide to oleum
Q.16) Write uses of Sulphuric acid
Q.17) Write the chemical reaction of chlorine and slaked lime.
Q.18) Write the bleaching property of chlorine with chemical reactions.
Q.19) Write uses of Chlorine.
Q.20) Write the ratio of acids used to prepare aqua regia.
Q.21) Define: Interhalogen compounds.Write general characteristics of interhalogen compounds.
Q.22) Write uses of Sulphur dioxide.
Q.23) Draw the structure and write shape of Chlorine pentafluoride and Bromine trifluoride.
Q.24) Write chemical reaction of hydrolysis of XeF2.
Q.25) Draw the structures and write oxidation state of
i) XeF2 ii) XeF4 iii) XeF6 iv) XeOF4 v) XeO3
Q.26) Write uses of Neon and Helium.
Q.27) What is ozone depletion?
Q.28) Write following chemical reactions-
a) Chlorine reacts with excess of ammonia
b) ammonia with excess of chlorine
c) chlorine with excess of fluorine
Q.29) Explain why fluorine shows anomalous behavior of fluorine.

Transition and Inner transition elements

Marks-6 with option
Q.1) Write general electronic configuration of 3d series of d-block elements
Q.2) Write different oxidation states of Mn. Why +2 oxidation state of Mn is most stable.
Q.3) Write the spin only formula for magnetic moment.
Q.4) Calculate the spin only magnetic moment of divalent cation of a transition metal Z=26.
Q.5) Calculate value of the magnetic moment of Cr2+ and V3+ion.
Q.6) Write the conditions of color of transition metal ion.
Q.7) Why Ti4+is colorless Ti3+is colored.
Q.8) Write the name(formula) of the alloy used in Fischer Tropsch process in the synthesis of Gasoline.
Q.9) Define: Interstitial compounds. Write properties of interstitial compounds.
Q.10) Explain Ferrous and non ferrous alloys with examples.
Q.11) Write the combination of metals in the following alloys.
i) Bronze ii) Stainless steel iii) Nichrome iv) Cupro-nickel v)Brass
Q.11) Write preparation of Potassium dichromate by using Chromite ore( FeOCr2O3). (3M)
Q.12) Write the chemical composition of the following .
i) Haematite ii) Chalcopyrite iii) Calamine iv) Zinc blende
Q.13) Define: a) Pyrometallurgy b) Hydrometallurgy c) Electrometallurgy 15. Define: a) Ore b) Mineral
c) Gangue d) Lanthanoid contraction e) Actinoid contraction
f)Transuranic elements g) Postactinoid elements
Q.14) Write electronic configuration of Gd (Z=64), Ce (Z=58) Sc( Z=21) Cu (Z= 29) Cr (Z=24)
Q.15) Write the general electronic configuration of lanthanoids.
Q.16) Write difference between Lanthanoids and actinoids.
Q.17) Write similarities between Lanthanoids and actinoids.
Q.18) Write the name of reducing agents used in the extraction of iron from haematite ore by using a blast
furnace.
Coordination Compounds
Marks-5 with option 7
Q.1) Define:Ligand.
Q.2) Write one example of each, Bidentate,Hexadentate and Ambidentate ligands.
Q.3) Write the coordination number of the complexes [Fe(C2O4)3]3- and [Co(en)3]3+
Q.4) Write the name and molecular formula of one example of double salt.
Q.5) Write four postulates of Werner theory of coordination complexes.
Q.6) Explain the terms:
Q.7) Homoleptic complexes ii) Heteroleptic complexes
Q.8) Write the classification of coordination complexes on the basis of charge on the complex.
Q.9) Write the IUPAC name of the following complexes
[Fe(CN)6]4- ii) Na3[AlF6] iii) [PtBr2(NH3)4]Br2 iv) [Co(NO2)3 (NH3)3] iv) Fe[CO)5]
Q.10) State EAN rule. Write the formula to calculate EAN.
Q.11) What is EAN? Calculate EAN of the complex [Co(NH3)6]3+ and [Fe(CN)6]3-
Q.12) Define: Diastereomers. Write the structures of cis and trans isomers of the complex
i)[Co(NH3)4Cl2]+ ii) [Pt(NH3)4ClBr]2+
Q.13) Explain the following terms:
i) Linkage isomers ii) Ionization isomers
iii) Coordination isomers iv) Hydrate isomers
Q.14) Explain the formation of following complexes according to VBT (3M Each) i) [Co(NH3)6]3+
ii)[CoF6]3- iii)[Ni(Cl)4]2- iv) [Ni(CN)4]2-
Q.15) Write the name of the Pt complex which is used in the treatment of cancer.
Q.16) Write the name of the complex which is used for treatment of lead poisoning.
Q.17) Write the name of the element, by which the hemoglobin complex is formed.

Halogen Derivatives
Marks-5 with option 7
Q.1) Write the structure of one example of allylic halide.
Q.2) Write the structure of one example of Vinylic halide.
Q.3) Write the following chemical reaction:
a) Action of red phosphorus and bromine on ethyl alcohol
b) Ethylalcohol and mix of NaBr,H2SO4
Q.3) Write the preparation of ethyl chloride by using Grooves process.
Q.4) Write Swartz reaction with an example.
Q.5) Explain optical activity 2-chlorobutane.
Q.6) Define: a) Optical activity b) Enantiomorphs c) Racemic mixture d) Chiral carbon
Q.7) Write the following chemical reactions:
a) Ethyl chloride with aqueous caustic potash
b) Ethyl bromide with sodium methoxide
c) Methyl iodide with silver acetate
d) Ethyl chloride with potassium nitrite
e) Ethyl bromide with silver nitrite.
f) Thionyl chloride with straight chain primary alcohols.
g) Propene with hydrogen bromide in presence of peroxide
Q.8) Write salient features of SN2 mechanism. (Any 4 points)
Q.9) Write salient features of SN1 mechanism. (Any 4 points)
Q.10) Define dehydrogenation reaction. Write the dehydrogenation reaction of 2-bromobutane with
alcoholic KOH. Mention major and minor products.
Q.11) What is Grignard reagent. How it is prepared, write chemical reaction.
Q.12) Write the chemical reaction of methyl magnesium iodide with ammonia.
Q.13) Write the name of hydrocarbon prepared, when ethyl magnesium bromide reacts with methanol in
presence of dry ether.
Q.14) Write the chemical reaction, when bromobenzene and methyl bromide reacts with sodium metal in
presence of dry ether.
Q.15) Write the structure of the product formed,when chlorobenzene reacts with sodium metal in presence
of dry ether.
Q.16) Write the chemical reaction,when chlorobenzene reacts with fuming sulphuric acid,
Q.17) What is the action of nitrating mixture on chlorobenzene? Write the chemical reaction.
Q.18) Write uses and environmental effects of Dichloromethane and CFC’s ( Freons)
Q.19) Define: a) Dextrorotatory compounds b) Laevorotatory compounds
Q.20) Write the chemical reaction of chlorobenzene with acetyl chloride in presence of anhydrous AlCl3.
Q.21) Write chemical reaction, When propene reacts with hydrogen chloride gives product ‘A’. Further
reacts with the Alcoholic solution of Potassium cyanide give product ‘B’.
Q.22) Write structure and full form of DDT. Write a full form of DDT.

Alcohols,Phenols and Ethers

Marks-4 with option 6
Q.1) Write classification of ethers.
Q.2) Write the structure of vinyl alcohol,vinyl methyl ether
Q.3) Write the IUPAC name of tert-butyl alcohol. 4.Write the structure of Pyrogallol and Phloroglucinol
Q.4) Write IUPAC name and structure of Phenyl n-propyl ether.
Q.5) Write the chemical reactions of methyl magnesium iodide with
i) methanal ii) ethanal iii) propanone
Q.6) Write the structure of the product formed,when pent-3-en-1-al undergoes reduction with LiAlH4
followed by acidic hydrolysis.
Q.7) Write Dow process for the preparation of phenol.
Q.8) Write the chemical reaction for the commercial method of preparation of phenol. (Preparation of
phenol by using cumene/isopropylbenzene)
Q.9) Write the chemical equation for the proportion of phenol by using aminobenzene.
Q.10) Define: Esterification . Write the chemical reaction of acetic acid with
a) Ethyl alcohol b) Phenol
Q.11) Write the following chemical equations/conversions
a) ethyl alcohol with PCC
b) phenol with bromine water
c) phenol with dil.nitric acid
d) phenol with chloroform in aqueous solution of sodium hydroxide
e) ethyl alcohol oxidation with Cu
f) secondary alcohol with Cu
g) Phenol to 2,4,6 tripicric acid
h) Phenol on catalytic hydrogenation
i) Phenol on reduction with Zn dust
Q.12) What is Kolbe reaction.Write chemical equation.
Q.13) Write the chemical reaction of phenol on oxidation with sodium dichromate.
Q.14) Write the chemical reaction of ethyl methyl ether with phosphorus pentachloride
Q.15) Write with chemical reaction,preparation of phenol from anisole.
(Write the chemical reaction, when phenol reacts with Hydrogen iodide)
Q.16) Write the chemical reactions of anisole with following reagents
a) Bromine in acetic acid b) methyl chloride c) nitrating mixture d) acetyl chloride
Q.17) What is the Reimer -Tiemann reaction.Write chemical equation.
Q.18) Write chemical reactions of alkyl halide with sodium alkoxide and sodium phenoxide.
 Aldehydes,Ketones and Carboxylic acids
Marks-6 with option 8
Q.1) Write the classification of aliphatic ketones.
Q.2) Write the chemical reaction of ethene with ozone followed by decomposition with Zn dust and water
Q.3) Write Rosenmund reduction reaction with an example.
Q.4) Write the chemical equation,when ethanoyl chloride reacts with dimethyl cadmium.
Q.5) Write the IUPAC name of acrylic acid.
Q.6) What is Stephen reaction? Write the chemical reaction ,ethanenitrile undergoes stephen
reaction.
Q.7) Write the following chemical conversions.
Ethanenitrile reacts with methyl magnesium bromide followed by acid hydrolysis
Benzonitrile reacts with methyl magnesium iodide followed by acid hydrolysis.
Q.8) What is the Etard reaction? Write one example.
Q.9) Explain Gatterman-Koch formylation reaction with an example.
Q.10) Write the chemical reaction of cyclohexene with KMnO4 in dilute Sulphuric acid.
Q.11) Write the chemical reaction of methyl magnesium bromide with solid CO2 followed by
acid hydrolysis.
Q.12) Write the chemical reaction,when acetaldehyde reacts with a fehling solution.
Q.13) Write the structure of the product formed when propanone reacts with 2,4-dinitrophenyl Hydrazine.
Q.14) What is hemiacetal? Write the chemical reaction when an acetaldehyde reacts with ethyl alcohol in
presence of dry HCl.
Q.15) Write the chemical reaction and structure of the product formed when propanone reacts with ethane
1,2-diol.
Q.16) Write the following conversions/equations
a) aldehyde reacts with hydroxyl anime
b) ketone with hydrazine
c) aldehyde with semicarbazide
d) ketone with hydrazine
Q.17) Explain haloform reaction with one example.
Q.18) Write aldol condensation reaction of ethanal.
Q.19) Write Cannizzaro reaction of methanal with Strong base NaOH.
Q.20) Write cross Cannizzaro reaction between formaldehyde and benzaldehyde.
Q.21) Write the product of cross aldol condensation reaction between ethanal and propanal.
Q.22) Write the chemical reaction of propanone with Ba(OH)2 followed by heating.
Q.23) Explain Clemmensen reduction propanal.
Q.24) Write Wolf-Kishner reduction reaction of ethyl phenyl ketone.
Q.25) Write the following chemical conversions
a) acetic acid to acetamide
b) acetic acid to acetic anhydride
c) acetic acid to acetic anhydride by using thionyl chloride.
d) acetic acid to ethyl alcohol
e) sodium acetate to methane
f) acyl chloride to acid aminde
 Amines
Marks-3 with option 4

Q.1) Write IUPAC name and structure of

p-toluidine,methylphenylamine,trimethylamine,ethyldimethylamine
Q.2) Write the chemical reaction for conversion of nitroalkanes to primary amines.
Q.3) Write the chemical equation for the preparation of ethylamine from acetamide.
Q.4) Write Gabriel phthalimide synthesis reaction with an example.
Q.5) Explain Hofmann bromamide degradation reaction with an example.
Q.6) Why amines are basic in nature? Among,N-Methylmethanamine and N-ethylethanamine,which is more
basic.
Q.7) What is Mendius reduction? Write the chemical equation for the preparation of ethylamine by using
methyl cyanide.
Q.8) Write the chemical reaction of ethylamine with
i) caustic potash(aq.KOH) and Chloroform ii) Nitrous acid
iii) Hinsberg reagent(Benzene sulphonyl chloride) iv) Ethanoyl chloride
Q.9) Write the chemical reaction of benzenamine with nitrous acid.
Q.10) Write the chemical reaction of Benzenediazonium chloride with following reagents
i) phosphinic acid(hypophosphorous acid,H3PO2) ii) Ethanol
iii) Copper powder & HCl iv) CuCN/KCN
v) Carbolic acid v) Fluoroboric acid followed by heat
Q.11) Write the structure of Zwitter ion of sulfanilic acid.

Biomolecules
Marks-3 with option 4

Q.1) Write preparation of glucose from sucrose .

Q.2) Write commercial method of preparation of glucose(from Starch).
Q.3) Write the chemical reaction of glucose with following reagents.
a) HI b) NH4OH c) HNO3 d) Br2 water e) Acetic anhydride
Q.4) Write the structure of β-D-(+) Glucose by Fishcer projection formula.
Q.5) Write the structure of α-D-(+) Glucopyranose.
Q.6) Write the structure of α-D-(-) fructofuranose.
Q.7) Write the glycosidic linkages present in Maltose,lactose, cellulose and sucrose.
Q.8) Write the structure of glycine ( amino acid with no chiral carbon)
Q.9) Write the structure of Zwitter ion of alanine/ Zwitter ion of α-amino acid
Q.10) Explain types of proteins with examples.
Q.11) Define: a) Enzymes b) Peptide bond c) Denaturation of proteins d) Monosaccharides
Q.12) Write the name of sugar components present in DNA and RNA.
Q.13) Write the structure of D-ribose and 2-Deoxy-D-ribose.
Q.14) Write names of pyrimidine bases present in RNA and DNA.
Q.15) Define : Nucleotide
 Introduction to Polymer Chemistry
Marks-3 with option 4
Q.1) Write the classification of polymers based on source.
Q.2) Write the classification of polymers based on structure.
Q.3) Define: a) Elastomers b) Fibers c) Vulcanization d)Homopolymers e) Copolymers
Q.4) Explain the terms a) Thermoplastic polymers b) Thermosetting polymers
Q.5) Write the name and structure of the monomer of natural rubber.
Q.6) Write the name of the catalyst used in preparation of High density polyethylene.
Q.7) Write the chemical reactions for the preparation of following polymers.
i) Teflon ii) Polyacrylonitrile iii) SBR iv) Nylon-6 8.Write the preparation of Nylon 6,6 polymer.
Q.8) Write the name and structure of the monomer used in preparation of Nylon-6 polymer.
Q.9) Write chemical reaction for the preparation of PHBV polymer.
Q.10) Write the chemical reaction for the preparation of copolymer Dacron.
Q.11) Write uses of LDP and HDP
Q.12) Write the applications and name of the monomers used in the preparation of following Polymers
i) Buna N ii) PVC iii) Glyptal iv) Thermocol
Q.13) Write classification of polymers on the basis of intermolecular forces.
Q.14) Write the structure and names of monomers used in SBR .

Green Chemistry and Nano chemistry

Marks-3 with option 4
Q.1) Define : a) Green chemistry b) Atom economy c) Sustainable development
Q.2) Write the formula to calculate atom economy.
Q.3) Write the name of gamma isomer of BHC.
Q.4) Write the name of the insecticide which is effectively used instead of DDT.
Q.5) Write the full form of ZWT and MRAM
Q.6) Write the role of green chemistry.
Q.7) Mention any four principles of green chemistry.
Q.8) Define: a) Nanoscience b) Nanotechnology c) Nanomaterial d) Nanochemistry
Q.9) Write chemical reactions involved in the sol-gel process.
Q.10) Write the name of the technique used to determine the geometry of nanomaterial.
Q.11) Write the name of the nanostructured material that is used to increase the life of a car tyre.
Q.12) Write any two applications of nanomaterials.
Q.13) Write the name of the metal nanoparticle,act as highly effective bacterial disinfectant, remove E.Coli
from water.
Q.14) Write the name of the plant,which acts as self cleaning material.
Q.15) Write advantages and disadvantages of Nanoparticles and nanotechnology.
Q.16) Define: a) Zero dimensional nanostructure b) Two dimensional nanostructure
Q.17) Write the name of nanomaterial synthesis process, which is based on inorganic
Polymerization.
Q.18)Write the name of the technique used to determine the particle size of nanomaterial.
Q.19) Write the name of the technique used to determine morphology of the nanoma terial.