Class : XIIth Subject : CHEMISTRY

Date : DPP No. : 1

Topic :- Amines
1. Hofmann bromamide reaction is used to prepare

a) 1° amine b) 2° amine c) 3° amine d)All of these

2. Tertiary amine is obtained in the reaction

a) CH3I CH3I b) CH3I c) Sn/HCl d)None of these

Aniline Aniline Nitrobenzene
3. Which of the following on reduction with LiAlH4 gives a secondary amine?

a) CH NC b) CH CONH c) CH CN d) CH NO
3 3 2 3 3 2

4. Which of the following is most basic in aqueous medium?

a) CH CH CH CH NH b) CH ― CH ― CH ― NH
3 2 2 2 2 3 2 2 2

c) CH3 d) CH3
CH3 N CH3 CH3 CH2 NH CH3
5. The product A and 𝐵 in the reaction are:
C2H5NH2 + CHCl3 + 3KOH ⟶𝐴 + 𝐵 + 3H2O
a) C H NC + 3KCl b) C H CN + 3KCl c) C H CONH + 3KCl d) C H NC + K CO
2 5 2 5 2 5 2 2 5 2 3

6. 𝑝 – amine and 𝑠 – amine are distinguished by:

a) Br /KOH b)HClO c) HNO d) NH

2 2 3

7. Which one of the following compounds will dissolve in an alkali solution after it has undergone
reaction with Hinsberg reagent?
a) CH NH b) (CH3) N c) (C2H5) NH d) C H NHC H
3 2 3 2 6 5 6 5

8. The reaction of chloroform with alcoholic KOH and 𝑝-toluidine from

a) b)
H3C CN H3C N2Cl

c) d)
H3C NH. CHCl2 H3C NC

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 Which one of the following functional groups undergoes hydrolysis with alkali to yield an acid
9. group?
a) ―CN b) ―CHO c) ―COCH d) ―Br
3

10. Ethylamine reacts with nitrosyl chloride (NOCl)to form:

a) Ethyl chloride b)Ethyl alcohol c) Ethyl nitrite d)Nitroethane

11. The product obtained in the reduction

CH3
NO2
H2S, NH3
is

NO2
CH3
NH2
a)

NH2
CH3
NO2
b)

NH2
CH3
NH2
c)

NH2
d)The compound is not reduced

12. The correct order of basic nature of the following compounds is:
NH
CH3CH2NH2
CH3 C (2)
NH2
(1)
O

(CH3)2NH CH3 C NH2

(3)
(4)
a) 2 > 1 > 3 > 4 b) 1 > 3 > 2 > 4

c) 3 > 1 > 2 > 4

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 d)1 > 2 > 3 > 4

13. In reduction of nitrobenzene, which of the following is the intermediate?

O
a) ϕNO b) ϕNHNHϕ c) ϕN = N ― ϕ ↑ d)
ϕN = N ― ϕ
14. Nitration of aniline also gives 𝑚-nitro aniline in strong acidic medium because

a) In electrophilic substitution reaction amino b) Inspite of substituents nitro group always

group is 𝑚𝑒𝑡𝑎 directive goes to 𝑚-position
c) In strong acidic medium aniline aniline d)None of the above
present as anilinium ion
15. Gabriel’s sunthesis is used frequently for the preparation of which of the following?

a) Primary amines b)Primary alcohols c) Tertiary amines d)Tertiary alcohols

16. C6H5NO2Sn/HClC6H5𝑋
‘X ’ is identified as
a) NO b) ―NH c) NHOH d)None of these
2

17. 𝐴H2NOH 𝐵Reduction 𝐶NOCl CH3CH2Cl

In the above sequence 𝐴 and 𝐶 are
a) Methanal, methyl amine b) Acetone, ethaneamine

c) Ethanal, diamethyl amine d)Acetaldehyde, ethyl amine

18. In the following reaction, 𝑋 is

Bromination NaNO2 Boiling
X Y Z Tribromo benzene
+HCl C2H5OH
a) Benzoic acid b)Salicyclic acid c) Phenol d)Aniline

19. Which of the following is not a nitro-derivative?

a) C H NO b) CH CH ONO c) CH3CH N d) C H (OH)NO

6 5 2 3 2 6 5 2
O
CH3
20. Decreasing order of basic nature in aqueous solutions

a) C6H5NH2 > 𝑁H3 > 𝐶H3NH2 > (CH3) NH b) NH3 > C6H5NH2 > 𝐶H3NH2 > (CH3) NH
2 2

c) (CH3) NH > 𝐶H3NH2 > 𝑁H3 > C6H5NH2 d) CH3NH2 > (CH3) NH > 𝑁H3 > C6H5NH2
2 2

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