Coordination Chemistry

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Single Choice Questions

1. The IUPAC name of [Ru(HSO3 )2 (NH3 )4 ] is :


(a) Tetraammine bi(hydrogen sulfato) ruthenium(III)
(b) Tetraammine bis(hydrogen sulfato) ruthenium(II)
(c) Tetraammine bis(hydrogen sulfito) ruthenium(I)
(d) Tetraammine bi(hydrogen sulfito) ruthenium(I)

2. The optical absorption spectrum of [Ti(H2O)6 ]3  has its absorption maximum at 20300 c.m.1 The
magnitude of crystal field stabilization energy in K.J./mol is :
(a) 97.0 (b) 980 (c) 970 (d) 98.0

3. The octahedral crystal field splitting ( 0 ) of d orbital energies of the following metal ions decreases in
the order :
(a) Co2  Co3  Rh3 (b) Rh3  Co3  Co2 (c) Rh3  Co2  Co3 (d) Co3  Co2  Rh3

4. The colour of potassium dichromate is due to :


(a) d-d transition (b) transition in K  ion
(c) ligand-to-metal charge transfer (d) metal to ligand charge transfer

5. The crystal field stabilization energy of high spin d7 octahedral complex is :


4 4 9 9
(a) 0  2P (b) 0  3P (c) 0  2P (d) 0  3P
5 5 5 5

6. Among the following complex


(i) [Ru(bipyridyl)3 ] (ii) [Cr(EDTA)]
(iii) Trans – [CrCl2 (oxalate)2 ]3 (iv) Cis - [CrCl2 (oxalate)2 ]3
The ones that show chirality are :
(a) (i), (ii), (iv) (b) (i), (ii), (iii) (c) (ii), (iii), (iv) (d) (i), (iii), (iv)

7. Hydrated cadmium ion. [Cd(H2O)4 ]2 forms three complex with methyl amine (CH3NH2 ) , ethylene
diamine(en), and triethylene tetramine(trien) G1o , Go2 and Go3 are the standard free energy of the
complexes respectively. Which one is the correct order for their G value? (value of H is negative
and same for all complexes)
(a) Go2  G1o  Go3 (b) G1o  Go2  G3o (c) Go3  Go2  G1o (d) G1o  Go3  Go2

8. Cis platin is used as antitumor agent in the treatment of cancer. Cis platin is :
(a) Cis - [Pt(NH3 )3 Cl] (b) Cis - [Pt(NH3 )2 Cl2 ] (c) Cis - [Pt(CH3 )4 ] (d) Cis - [Pt(NH3 )Cl3 ]

9. Molar conductance of the complex, M(CH3 )5 X4 (X = monodentate ligand and M has C.N. =6) is ~ 400
Ohm-1. The structure of the complex will be :
(a) [M(NH3 )5 ]X4 (b) [M(NH3 )5 X]X3 (c) [M(NH3 )5 X2 ]X2 (d) [M(NH3 )5 X4 ]

10. On the basis of EAN rule which one has high value of magnetic moment ?
(a) [Cu(NH3 )6 ]2 (b) [Cr(NH3 )6 ]Cl3
3
(c) [Co(NH3 )6 ] (d) All of these have same value of 

One or More than One Choice Questions

11. Which one is not organometallic compound :


(a) R  Mg  X (b) (C2H5 )4 Pb (c) (CH3 )4 Sn (d) C2H5ONa
12. Theoretically the no. of geometrical isomers expected for octahedral complex [Mabcdef] will be :
(a) 0 (b) 15 (c) 12 (d) 30

13. The E.A.N of cobalt in complex ion [Co(ln)2 Cl2 ] is :


(a) 27 (b) 36 (c) 33 (d) 35

14. The complex that violet the EAN rule is :


(a) potassium ferrocyanide (b) potassium ferricyanide
(c) Tetracarbonyl nickel (d) Hexaammine cobalt (III) chloride

15. In a reaction [Co(NH3 )6 ]2 


bubble in
air
[Co(NH3 )6 ]3 , Co3  complex is more stable, because of :
(a) d-d transition
(b) Charge transfer spectera
(c) oxidation by air
(d) Co3  has high crystal field stabilization energy than Co2 .

16. N2 is isoelectronic with CO, NO But it does not form any complex compound. It is due to :
(a) Lack of polarity of N2 (b) Inability to behave as a  acceptor
(c) Strong  acceptor (d) All of these

17. Which is (are) correct statement(s) ?


(a) The higher the value of stability constant for a complex ion, the greater will be its stability.
(b) The terms inert and labile represent kinetic stability of complex.
(c) The terms inert and labile represent thermodynamic stability of complex.
(d) There is no correlation between thermodynamic stability and kinetic stability.

18. Correct statement(s) for metal carbonyl [M(CO)6 ] is (are) :


(a)  bonding electrons are donated by co group to the metal.
(b) d  p back bonding occurs from the filled metal orbitals.
(c) d  p back bonding is stronger than  bonding.
(d)  bonding is strong from d  p bonding.

19. According to VBT (at the time of early use), which is(are) correctly matched ?
(a) High spin ≡ ionic compound
(b) High spin ≡ outer orbital complexes
(c) Low spin ≡ covalent compound
(d) Low spin ≡ Inner orbital complexes

20. Which statement(s) is(are) correct for any coordination compound [ML x ] ?
Where M → Metal atom L = Ligand x=no. of ligand
(a) In coordination compound [M(RS )x ] , p  d bonding takes place.
(b) In coordination compound [M(R3P)x ] , d  d bonding takes place.
(c) In coordination compound [M(Co)x ], d   * bonding takes place.
(d) In coordination compound [M(Alkanes)x ] , d   * bonding takes place.
Matrix Match Type Question
21. In the reaction sequence given below A is an anionic Fe(II) complex

 2
aq.NO2
A   B 
aq.S
C
brown (Purple)

SO32
OH
D(Red color)
A
Match the A,B, C and D with correct option.

COLUMN – I COLUMN-II
(1) A (p) Na2 [Fe(CN)5 NO]

(2) B (q) Na4 [Fe(CN)6 ]

(3) C (r) Na4 [Fe(CN)5 (NO)(SO3 )]

(4) D (s) Na4 [Fe(CN)5 NOS]

(t) [Fe(NO)(H2O)5 ]SO4


Hybridisation of central metal atom is
(u)
d2 sp3
(v) Sodium penta cyano nitrosyl ferrate (II)
22. Match the following :
Complex Orbitals Hybridised

(1) MnO 4 (p) dxy ,dyz ,dxz ,s

(2) [V(CN)7 ]4  (q) dxy ,dx2  y2 ,dz2 ,s,p3

(3) [Co(NH3 )6 ]3  (r) dz2 ,dx2  y2 ,s,p3

(4) [Ni(CN)5 ]3  (s) dx2  y2 ,s,p3

(t) dz2 ,s,p3

pH 6 dil HCl


23. A   B ‡ˆ ˆˆ ˆˆ ˆˆ ˆ†ˆ C
g Oxide of Cr g Yellow color g Strong oxidizing agent
g Solid g Tetrahedral
g no d-electrons
B  diphenyl carbazinde 
 D(violet color)
C  HCl  E (greenish yellow gas)

Match the A,B, C and E with correct option.

COLUMN – I COLUMN-II
(1) A (p) K 2Cr2O7

(2) B (q) KMnO4

(3) C (r) K 2CrO4

(4) E (s) Cl2


(t) Charge transfer spectra
(u) Cr2O3

(v) CrO3
24. Match the following :
COLUMN – I COLUMN-II
(1) Glycine (p) An organo metallic complex
(2) Zeise’s salt (q) Bidentate
(3) Neutral Molecule (r) K 4 [Fe(CN)6 ]

(4) Low spin complex (s) [Co(NH3 )3 Cl3 ]

(t)   complex

Numerical based questions Question

25. Multiplicity for complex [Fe(H2O)6 ]2 will be :

26. The magnetic moment of [Mn(H2O)6 ](NO3 )2 is approximately 6.0 B . The no. of unpaired electrons will
be :

27. The number of geometrical isomers possible for complex [Pt Cl Br I (NH3 )] would be :

28. Magnetic moment value of [Fe(H2O)5 (NO)]2 ion is 3.89 B.M. Find out oxidation state.

29. A solution containing 2.665 gm of CrCl3 .6H2O is passed through AgNO3 solution and gives 2.87 gm of
AgCl ppt. Determine the number of ions in aqueous solution.

30. Total number of isomers having formula [Co(en)2 (NH3 )Cl]2 are :

31. Total number of rings formed in a bis- (dimethyl glyoximato) nickel (II) complex are :

32. How many ketonic groups are present in a complex Fe2 (CO)9 ?

33. Calculate CFSE value for d5 high spin octahedral.

34. The enthalpy of hydration of Cr 2 ions is -460 K cal/mol. In the absence of crystal field stabilisation
energy. The value of enthalpy of hydration is 459.988 K cal/mol. Calculate the value of  0 (in cm-1) for
[Cr(H2O)6 ]2 ion.

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