Coordination Chemistry
Coordination Chemistry
Coordination Chemistry
2. The optical absorption spectrum of [Ti(H2O)6 ]3 has its absorption maximum at 20300 c.m.1 The
magnitude of crystal field stabilization energy in K.J./mol is :
(a) 97.0 (b) 980 (c) 970 (d) 98.0
3. The octahedral crystal field splitting ( 0 ) of d orbital energies of the following metal ions decreases in
the order :
(a) Co2 Co3 Rh3 (b) Rh3 Co3 Co2 (c) Rh3 Co2 Co3 (d) Co3 Co2 Rh3
7. Hydrated cadmium ion. [Cd(H2O)4 ]2 forms three complex with methyl amine (CH3NH2 ) , ethylene
diamine(en), and triethylene tetramine(trien) G1o , Go2 and Go3 are the standard free energy of the
complexes respectively. Which one is the correct order for their G value? (value of H is negative
and same for all complexes)
(a) Go2 G1o Go3 (b) G1o Go2 G3o (c) Go3 Go2 G1o (d) G1o Go3 Go2
8. Cis platin is used as antitumor agent in the treatment of cancer. Cis platin is :
(a) Cis - [Pt(NH3 )3 Cl] (b) Cis - [Pt(NH3 )2 Cl2 ] (c) Cis - [Pt(CH3 )4 ] (d) Cis - [Pt(NH3 )Cl3 ]
9. Molar conductance of the complex, M(CH3 )5 X4 (X = monodentate ligand and M has C.N. =6) is ~ 400
Ohm-1. The structure of the complex will be :
(a) [M(NH3 )5 ]X4 (b) [M(NH3 )5 X]X3 (c) [M(NH3 )5 X2 ]X2 (d) [M(NH3 )5 X4 ]
10. On the basis of EAN rule which one has high value of magnetic moment ?
(a) [Cu(NH3 )6 ]2 (b) [Cr(NH3 )6 ]Cl3
3
(c) [Co(NH3 )6 ] (d) All of these have same value of
16. N2 is isoelectronic with CO, NO But it does not form any complex compound. It is due to :
(a) Lack of polarity of N2 (b) Inability to behave as a acceptor
(c) Strong acceptor (d) All of these
19. According to VBT (at the time of early use), which is(are) correctly matched ?
(a) High spin ≡ ionic compound
(b) High spin ≡ outer orbital complexes
(c) Low spin ≡ covalent compound
(d) Low spin ≡ Inner orbital complexes
20. Which statement(s) is(are) correct for any coordination compound [ML x ] ?
Where M → Metal atom L = Ligand x=no. of ligand
(a) In coordination compound [M(RS )x ] , p d bonding takes place.
(b) In coordination compound [M(R3P)x ] , d d bonding takes place.
(c) In coordination compound [M(Co)x ], d * bonding takes place.
(d) In coordination compound [M(Alkanes)x ] , d * bonding takes place.
Matrix Match Type Question
21. In the reaction sequence given below A is an anionic Fe(II) complex
2
aq.NO2
A B
aq.S
C
brown (Purple)
SO32
OH
D(Red color)
A
Match the A,B, C and D with correct option.
COLUMN – I COLUMN-II
(1) A (p) Na2 [Fe(CN)5 NO]
COLUMN – I COLUMN-II
(1) A (p) K 2Cr2O7
(v) CrO3
24. Match the following :
COLUMN – I COLUMN-II
(1) Glycine (p) An organo metallic complex
(2) Zeise’s salt (q) Bidentate
(3) Neutral Molecule (r) K 4 [Fe(CN)6 ]
(t) complex
26. The magnetic moment of [Mn(H2O)6 ](NO3 )2 is approximately 6.0 B . The no. of unpaired electrons will
be :
27. The number of geometrical isomers possible for complex [Pt Cl Br I (NH3 )] would be :
28. Magnetic moment value of [Fe(H2O)5 (NO)]2 ion is 3.89 B.M. Find out oxidation state.
29. A solution containing 2.665 gm of CrCl3 .6H2O is passed through AgNO3 solution and gives 2.87 gm of
AgCl ppt. Determine the number of ions in aqueous solution.
30. Total number of isomers having formula [Co(en)2 (NH3 )Cl]2 are :
31. Total number of rings formed in a bis- (dimethyl glyoximato) nickel (II) complex are :
32. How many ketonic groups are present in a complex Fe2 (CO)9 ?
34. The enthalpy of hydration of Cr 2 ions is -460 K cal/mol. In the absence of crystal field stabilisation
energy. The value of enthalpy of hydration is 459.988 K cal/mol. Calculate the value of 0 (in cm-1) for
[Cr(H2O)6 ]2 ion.