Rum Flavour - (SF) - 50% PG

001541 RUM FLAVOUR
The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 1
Version No: 2.2 Issue Date: 26/09/2017
Safety Data Sheet according to WHS and ADG requirements Print Date: 26/09/2017
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name: 001541 RUM FLAVOUR
Other means of identification: Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Use according to manufacturer's directions.
Details of the supplier of the safety data sheet Emergency telephone number
Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation Not Available
Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300
Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available
Fax 61 3 9771 0301
Website www.theproductmakers.com
Email Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only
ChemWatch Hazard Ratings

Flammability 1
Toxicity 1 0 = Minimum
1 = Low
Body Contact 1 2 = Moderate
Reactivity 1 3 = High
Chronic 0 4 = Extreme
Poisons Schedule Not Applicable

[1] Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Flammable Liquid Category 4
Classification
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
Hazard pictogram(s)
SIGNAL WORD : WARNING
Hazard statement(s)
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H227: Combustible liquid
Precautionary statement(s) Prevention

P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Continued...
Chemwatch: 9-310435 Page 2 of 12 Issue Date: 26/09/2017
Version No: 2.2 Print Date: 26/09/2017
001541 RUM FLAVOUR
Precautionary statement(s) Response

P362: Take off contaminated clothing and wash before reuse.
P370+P378: In case of fire: Use alcohol resistant foam or normal protein foam for extinction.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P332+P313: If skin irritation occurs: Get medical advice/attention.
Precautionary statement(s) Storage

P403+P235: Store in a well-ventilated place. Keep cool.
Precautionary statement(s) Disposal

P501: Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
765-70-8 <1 3-methyl-1,2-cyclopentanedione
121-33-5 <1 vanillin
7732-18-5 10-30 water
105-54-4 1-10 ethyl butyrate
57-55-6 30-60 propylene glycol
141-78-6 1-10 ethyl acetate
105-57-7 <1 acetal
56-81-5 1-10 glycerol
8028-89-5 <1 caramel
SECTION 4 FIRST AID MEASURES
Description of first aid measures

Eye Contact
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Seek medical attention without delay; if pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
Inhalation
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
Ingestion
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
- Seek medical advice.
Indication of any immediate medical attention and special treatment needed

Treat symptomatically.
- Polyethylene glycols are generally poorly absorbed orally and are mostly unchanged by the kidney.
- Dermal absorption can occur across damaged skin (e.g. through burns) leading to increased osmolality, anion gap metabolic acidosis, elevated calcium, low ionised calcium, CNS depression
and renal failure.
- Treatment consists of supportive care.
[Ellenhorn and Barceloux: Medical Toxicology]
Propylene glycol is primarily a CNS depressant in large doses and may cause hypoglycaemia, lactic acidosis and seizures.
- The usual measures are supportive care and decontamination (Ipecac/ lavage/ activated charcoal/ cathartics), within 2 hours of exposure should suffice.
- Check the anion gap, arterial pH, renal function and glucose levels.
Ellenhorn and Barceloux: Medical Toxicology
Continued...
001541 RUM FLAVOUR
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
- Alcohol stable foam.
Special hazards arising from the substrate or mixture

Fire Incompatibility
- Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters

Fire Fighting
- Alert Fire Brigade and tell them location and nature of hazard.
Fire/Explosion Hazard
- Combustible.
Combustion products include:
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
HAZCHEM
Not Applicable
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures

See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up

Minor Spills
- Remove all ignition sources.
Major Spills
Moderate hazard.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling

Safe handling
- Avoid all personal contact, including inhalation.
- DO NOT allow clothing wet with material to stay in contact with skin
Other information
Store under refrigerated conditionsand out of direct sunlight.
Shelf-life: 12 months according to the specified storage conditions.
Consider storage under inert gas.
- Store in original containers.
Conditions for safe storage, including any incompatibilities

Suitable container
- Metal can or drum
- Packaging as recommended by manufacturer.
Storage incompatibility
For furfural:
- Strong acids or bases may cause polymerisation.
Glycerol:
- reacts violently with strong oxidisers, acetic anhydride, alkali metal hydrides, calcium hypochlorite, calcium oxychloride, chlorine, chromic anhydride, chromium oxides, ethylene oxide, hydrogen
peroxide, phosphorous triiodide, potassium chlorate, potassium permanganate, potassium peroxide, silver perchlorate, sodium hydride, sodium peroxide, sodium triiodide, sodium
tetrahydroborate,is incompatible with strong acids, caustics, aliphatic amines, isocyanates, uranium fluoride
- is able to polymerise above 145 C
- Glycols and their ethers undergo violent decomposition in contact with 70% perchloric acid.
Acetic acid:
- vapours forms explosive mixtures with air (above 39 C.)
- reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide
- reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine
pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus
isocyanate, phosphorus trichloride, sodium peroxide, xylene
- attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas
- attacks many forms of rubber, plastics and coatings
Alcohols
- are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents.
Continued...
001541 RUM FLAVOUR
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
Occupational Exposure Limits (OEL)

INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standards acetic acid glacial Acetic acid 25 mg/m3 / 10 ppm 37 mg/m3 / 15 ppm Not Available Not Available
Australia Exposure Standards acetaldehyde Acetaldehyde 36 mg/m3 / 20 ppm 91 mg/m3 / 50 ppm Not Available Not Available
Australia Exposure Standards propylene glycol Propane-1,2-diol total: (vapour & particulates) 474 mg/m3 / 150 ppm Not Available Not Available Not Available
Australia Exposure Standards propylene glycol Propane-1,2-diol: particulates only 10 mg/m3 Not Available Not Available Not Available
Australia Exposure Standards ethyl acetate Ethyl acetate 720 mg/m3 / 200 ppm 1440 mg/m3 / 400 ppm Not Available Not Available
Australia Exposure Standards glycerol Glycerin mist 10 mg/m3 Not Available Not Available Not Available
Exposure controls
Appropriate engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Personal protection
Eye and face protection

- Safety glasses with side shields.
Skin protection
See Hand protection below
Hands/feet protection
- Wear chemical protective gloves, e.g. PVC.
NOTE:
- The material may produce skin sensitisation in predisposed individuals.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.
Body protection
See Other protection below
Other protection
- Overalls.
Thermal hazards
Not Available
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties

Appearance: Opaque dark brown liquid
Physical state Liquid Relative density (Water = 1) 1.042

Odour Characteristic Partition coefficient n-octanol / water Not Available
Odour threshold Characteristic of rum. Auto-ignition temperature (°C) Not Available
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available
Flash point (°C) >60 Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Combustible. Oxidising properties Not Available
Refractive Index 1.41 Surface Tension (dyn/cm or mN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Not Available pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY

Reactivity:
See section 7
Chemical stability:
- Unstable in the presence of incompatible materials.
Possibility of hazardous reactions:
See section 7
Continued...
001541 RUM FLAVOUR
Conditions to avoid:
See section 7
Incompatible materials:
See section 7
Hazardous decomposition products:
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects

Inhaled
The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models).
Inhalation of vapours may cause drowsiness and dizziness.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual.
Furfural vapours irritate the nose and throat.
Aliphatic alcohols with more than 3-carbons cause headache, dizziness, drowsiness, muscle weakness and delirium, central depression, coma, seizures and behavioural changes.
Inhalation hazard is increased at higher temperatures.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Swallowing furfural (2-furaldehyde) may cause numbness of the tongue and mucous membranes of the mouth, loss of taste sense, difficulty in breathing, nausea, vomiting and severe headache.
Ingestion of propylene glycol produced reversible central nervous system depression in humans following ingestion of 60 ml.
If swallowed, the toxic effects of glycols (dihydric alcohols) are similar to those of alcohol, with depression of the central nervous system, nausea, vomiting, and degenerative changes in the liver
and kidney.
Overexposure to non-ring alcohols causes nervous system symptoms.
Skin Contact
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
A single prolonged exposure is not likely to result in the material causing harm.
Most liquid alcohols appear to act as primary skin irritants in humans.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.
Eye
Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
Limited evidence or practical experience suggests, that the material may cause eye irritation in a substantial number of individuals.
Chronic
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
Chronic effects of furfural include eczema, allergic sensitisation and photosensitisation in certain individuals.
Propylene glycol is thought to be sensitizing following the regular use of topical creams by eczema patients.
TOXICITY IRRITATION
001541 RUM FLAVOUR
Not Available Not Available
TOXICITY IRRITATION
3-methyl-1,2-cyclopentanedione
[2] Not Available
Oral (guinea pig) LD50: 1400 mg/kg
TOXICITY IRRITATION
[1] Not Available
vanillin dermal (rat) LD50: >2000 mg/kg
Oral (rat) LD50: 1580 mg/kg [2]
TOXICITY IRRITATION
Dermal (rabbit) LD50: 1060 mg/kg [2] Eye (rabbit): 0.05mg (open)-SEVERE
acetic acid glacial
Inhalation (mammal) LC50: 11.4 mg/L/4H[2] Skin (human):50mg/24hr - mild
[2] Skin (rabbit):525mg (open)-SEVERE
Oral (rat) LD50: 3310 mg/kg
TOXICITY IRRITATION
[2] Eye (human): 50 ppm/15min
Dermal (rabbit) LD50: 3540 mg/kg
acetaldehyde
Inhalation (rat) LC50: 13269.6667150173 mg/L/4H[2] Eye (rabbit): 40 mg SEVERE
[2] Skin (rabbit): 500 mg open mild
TOXICITY IRRITATION
water
Continued...
001541 RUM FLAVOUR
TOXICITY IRRITATION
ethyl butyrate
[2] Not Available
TOXICITY IRRITATION
[2] Skin (g.pig): 1%/48h - mod
dihydrocoumarin Dermal (rabbit) LD50: >5000 mg/kg
[2] Skin (rabbit): 500 mg/24h - mod
TOXICITY IRRITATION
lemon oil
[2] Skin (rabbit): 500 mg/24h mod
TOXICITY IRRITATION
[2] Eye (rabbit): 100 mg - mild
Dermal (rabbit) LD50: 11890 mg/kg
propylene glycol Oral (rat) LD50: 20000 mg/kg [2] Eye (rabbit): 500 mg/24h - mild
Skin(human):104 mg/3d Intermit Mod

Skin(human):500 mg/7days mild
TOXICITY IRRITATION
pyroligneous acid
TOXICITY IRRITATION
maltol
[2] Skin (rabbit): 500 mg/24h moderate
TOXICITY IRRITATION
ethyl propionate
[2] Skin (rabbit):500 mg/24h-moderate
TOXICITY IRRITATION
[2] Skin (human): 100%
piperonal dermal (rat) LD50: >5 mg/kg
[2]
TOXICITY IRRITATION
[2] Eye (rabbit): 1.0/110.0 *
ethyl vanillin Dermal (rabbit) LD50: >7940 mg/kg
Oral (rat) LD50: 1590 mg/kg [2] Skin (rabbit): 0.3/8.0 slight *
TOXICITY IRRITATION
ethyl acetate Inhalation (rat) LC50: 50 mg/l1 h[1] Eye (human): 400 ppm
Oral (rat) LD50: 5620 mg/kg [2]
TOXICITY IRRITATION
[2] Eye (rabbit): 500 mg (open)
acetal Eye (rabbit): 500 mg/24h - mild
Skin (rabbit): 10mg/24h(open)mild
Skin (rabbit): 500 mg/24h - mild
TOXICITY IRRITATION
caramel furanone
TOXICITY IRRITATION
glycerol
[2] Not Available
TOXICITY IRRITATION
caramel
Continued...
001541 RUM FLAVOUR
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS -
Register of Toxic Effect of chemical Substances
VANILLIN
For certain benzyl derivatives:
The members of this group are rapidly absorbed through the gastrointestinal tract, metabolised primarily in the liver, and excreted primarily in the urine either unchanged or as conjugates of
benzoic acid derivatives.
Miosis, somnolence, muscle weakness, coma, respiratory stimulation, maternal effects involving ovaries, fallopian tubes, uterus, cervix and vagina recorded.
ACETIC ACID GLACIAL

For acid mists, aerosols, vapours
Test results suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the
skin.
Prolonged or repeated exposure to acetic acid may produce irritation and/ or corrosion at the site of contact as well as systemic toxicity.
ACETALDEHYDE
WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.
Tenth Annual Report on Carcinogens: Substance anticipated to be Carcinogen
[National Toxicology Program: U.S. Dep.
DIHYDROCOUMARIN
Somnolence recorded.
LEMON OIL
The essential oils, oleoresins (solvent-free), and natural extractives (including distillates) derived from citrus fruits are generally recognized as safe (GRAS) for their intended use in foods for
human consumption.
Cross-reactivity is also expected between ester derivatives and their parent alcohols, as the esters will be broken down by esterases in the skin.
A member or analogue of a group of of aliphatic and aromatic terpene hydrocarbons generally considered as safe (GRAS) based, in part, on their self-limiting properties as flavouring substances
in food; their rapid absorption, metabolic detoxication, and excretion in humans and other animals; their low level of flavour use; the wide margins of safety between the conservative estimates of
intake and the no-observed-adverse effect levels determined from subchronic and chronic studies and the lack of significant genotoxic potential.
Fragrance allergens act as haptens, which are small molecules that cause an immune reaction only when attached to a carrier protein.
Bicyclic terpenes are very low in acute toxicity.
d-Limonene is readily absorbed by inhalation and swallowing.
PROPYLENE GLYCOL
The acute oral toxicity of propylene glycol is very low; large amounts are needed to cause perceptible health damage in humans.
MALTOL
Oral (rat) TDLo: 90000 mg/kg/90d-I Eye : Mild Maltol at 10% in petroleum produced no sensitisation reactions in a maximisation test. There were no compound-related effects in a three
generation reproduction in the rat.* FAO/ WHO evaluated that the level causing no toxicological effect is 100 mg/kg bw in rat* FAO/WHO estimated in 1974 that acceptable daily intake (ADI) for
man is 1mg/kg bw. The Council of Europe (1974) listed Maltol, giving an ADI of 1 mg/kg 6)* Beijing TianLiHai Chemical Company Co.
ETHYL PROPIONATE
The material may produce moderate eye irritation leading to inflammation.
GLYCEROL
At very high concentrations, evidence predicts that glycerol may cause tremor, irritation of the skin, eyes, digestive tract and airway.
3-METHYL-1,2-CYCLOPENTANEDIONE & VANILLIN & DIHYDROCOUMARIN & LEMON OIL & PIPERONAL & ETHYL VANILLIN & CARAMEL FURANONE
The following information refers to contact allergens as a group and may not be specific to this product.
3-METHYL-1,2-CYCLOPENTANEDIONE & ACETIC ACID GLACIAL & ACETALDEHYDE & ETHYL BUTYRATE & DIHYDROCOUMARIN & LEMON OIL & PYROLIGNEOUS ACID &
MALTOL & ETHYL PROPIONATE & PIPERONAL & ETHYL VANILLIN & GLYCEROL
Asthma-like symptoms may continue for months or even years after exposure to the material ends.
3-METHYL-1,2-CYCLOPENTANEDIONE & WATER & LEMON OIL & PYROLIGNEOUS ACID & CARAMEL FURANONE & CARAMEL
No significant acute toxicological data identified in literature search.
VANILLIN & LEMON OIL & PIPERONAL & ETHYL VANILLIN

Adverse reactions to fragrances in perfumes and fragranced cosmetic products include allergic contact dermatitis, irritant contact dermatitis, sensitivity to light, immediate contact reactions, and
pigmented contact dermatitis.
VANILLIN & PIPERONAL & ETHYL VANILLIN

Fragrance allergens act as haptens, low molecular weight chemicals that cause an immune response only when attached to a carrier protein.
VANILLIN & ETHYL VANILLIN

For vanillin:
Vanillin generally does not cause irritation or sensitisation of the skin but sometimes does cause inflammation.
VANILLIN & PIPERONAL & ETHYL VANILLIN

A member or analogue of a group of hydroxy and alkoxy-substituted benzyl derivatives generally regarded as safe (GRAS) based in part on their self-limiting properties as flavouring substances in
food; their rapid absorption.
ACETIC ACID GLACIAL & LEMON OIL

The material may produce severe irritation to the eye causing pronounced inflammation.
ACETALDEHYDE & ETHYL BUTYRATE & DIHYDROCOUMARIN & LEMON OIL & PROPYLENE GLYCOL & MALTOL & ETHYL PROPIONATE & ETHYL VANILLIN & ACETAL
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.
DIHYDROCOUMARIN & CARAMEL FURANONE

This is a member or analogue of a group of lactones generally considered as safe (GRAS).
Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin sensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
Continued...
001541 RUM FLAVOUR
Legend: – Data available but does not fill the criteria for classification
– Data available to make classification
– Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

001541 RUM FLAVOUR
Not Available Not Available Not Available Not Available Not Available

3-methyl-1,2-cyclopentanedione

LC50 96 Fish 57mg/L 4
vanillin EC50 48 Crustacea 36.79mg/L 2
EC50 72 Algae or other aquatic plants 120mg/L 2
NOEC 72 Algae or other aquatic plants >2mg/L 1

LC50 96 Fish 31.3-67.6mg/L 2
acetic acid glacial EC50 48 Crustacea 18.9mg/L 2
EC50 72 Algae or other aquatic plants 29.23mg/L 2
NOEC 48 Crustacea 21.5mg/L 2

LC50 96 Fish 2.1mg/L 4
acetaldehyde
EC50 48 Crustacea 4.7mg/L 4

water

ethyl butyrate

dihydrocoumarin

lemon oil

LC50 96 Fish 710mg/L 4
propylene glycol EC50 48 Crustacea >1000mg/L 4
NOEC 168 Fish 98mg/L 4

pyroligneous acid

maltol

ethyl propionate
Continued...
001541 RUM FLAVOUR

LC50 96 Fish 2.5mg/L 2
piperonal
NOEC 72 Algae or other aquatic plants <0.38mg/L 2

LC50 96 Fish 87.6mg/L 4
ethyl vanillin EC50 48 Crustacea 36.79mg/L 2

LC50 96 Fish 212.5mg/L 4
EC50 48 Crustacea =164mg/L 1
ethyl acetate
BCF 24 Algae or other aquatic plants 0.05mg/L 4

acetal

caramel furanone

glycerol
LC50 96 Fish >11mg/L 2

caramel
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity
Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -
Bioconcentration Data 8. Vendor Data
Environmental Fate: Furfural rapidly degrades in four sandy loam soils with 2-furoic acid as the major by-product.
Propylene glycol is known to exert high levels of biochemical oxygen demand (BOD) during degradation in surface waters.
For Glycerol: Log Kow: -2.66 to -2.47, Atmospheric Fate: Glycerol is broken down in the air by hydroxyl radicals the half-life for this process is 6.8 hours.
For Acetic Acid: Acetic acid and its salts (the acetates) can be grouped together because of their close structural relationships, their natural occurrence in plants and animals, and their
fundamental role in cell metabolism.
DO NOT discharge into sewer or waterways.
Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
3-methyl-1,2-cyclopentanedione LOW LOW
vanillin LOW LOW
acetic acid glacial LOW LOW
acetaldehyde LOW LOW
water LOW LOW
ethyl butyrate LOW LOW
dihydrocoumarin LOW LOW
propylene glycol LOW LOW
maltol LOW LOW
ethyl propionate LOW LOW
piperonal LOW LOW
ethyl vanillin LOW LOW
ethyl acetate LOW (Half-life = 14 days) LOW (Half-life = 14.71 days)
acetal HIGH HIGH
caramel furanone LOW LOW
Continued...
001541 RUM FLAVOUR
glycerol LOW LOW
Bioaccumulative potential
Ingredient Bioaccumulation
3-methyl-1,2-cyclopentanedione LOW (LogKOW = 1.288)
vanillin LOW (LogKOW = 1.21)
acetic acid glacial LOW (LogKOW = -0.17)
acetaldehyde LOW (BCF = 1.2)
water LOW (LogKOW = -1.38)
ethyl butyrate LOW (LogKOW = 1.8464)
dihydrocoumarin LOW (LogKOW = 0.967)
propylene glycol LOW (BCF = 1)
maltol LOW (LogKOW = 0.09)
ethyl propionate LOW (LogKOW = 1.21)
piperonal LOW (LogKOW = 1.05)
ethyl vanillin LOW (LogKOW = 1.58)
ethyl acetate HIGH (BCF = 3300)
acetal LOW (LogKOW = 0.84)
caramel furanone LOW (LogKOW = -0.4415)
glycerol LOW (LogKOW = -1.76)
Mobility in soil
Ingredient Mobility
3-methyl-1,2-cyclopentanedione HIGH (KOC = 1)
vanillin LOW (KOC = 38.45)
acetic acid glacial HIGH (KOC = 1)
acetaldehyde HIGH (KOC = 1.498)
water LOW (KOC = 14.3)
ethyl butyrate LOW (KOC = 21.85)
dihydrocoumarin LOW (KOC = 146.1)
propylene glycol HIGH (KOC = 1)
maltol HIGH (KOC = 1)
ethyl propionate LOW (KOC = 11.85)
piperonal LOW (KOC = 10.18)
ethyl vanillin LOW (KOC = 70.92)
ethyl acetate LOW (KOC = 6.131)
acetal HIGH (KOC = 1.317)
caramel furanone HIGH (KOC = 1)
glycerol HIGH (KOC = 1)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods

Product / Packaging disposal
Legislation addressing waste disposal requirements may differ by country, state and/ or territory.
- DO NOT allow wash water from cleaning or process equipment to enter drains.
- Recycle wherever possible or consult manufacturer for recycling options.
SECTION 14 TRANSPORT INFORMATION
Labels Required
COMBUSTIBLE LIQUID, regulated for storage purposes only
Marine Pollutant
NO
HAZCHEM
Not Applicable
Land transport (ADG): NOT Air transport (ICAO-IATA / DGR): NOT Sea transport (IMDG-Code / GGVSee): NOT
REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF REGULATED FOR TRANSPORT OF
DANGEROUS GOODS DANGEROUS GOODS DANGEROUS GOODS
UN number: Not
Applicable
Continued...
001541 RUM FLAVOUR
UN proper shipping
name: Not Applicable
Transport hazard
class(es): Not
Applicable
Subrisk: Not
Applicable
Packing group: Not
Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
3-methyl-1,2-cyclopentanedione(765-70-8) is found on the following regulatory lists

- Australia Inventory of Chemical Substances (AICS)
vanillin(121-33-5) is found on the following regulatory lists

acetic acid glacial(64-19-7) is found on the following regulatory lists

- Australia Exposure Standards - Australia Inventory of Chemical Substances (AICS)
- Australia Hazardous Substances Information System - Consolidated Lists
acetaldehyde(75-07-0) is found on the following regulatory lists

- Australia Exposure Standards - International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
- Australia Hazardous Substances Information System - Consolidated Lists Monographs
- Australia Inventory of Chemical Substances (AICS) - International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List
Passenger and Cargo Aircraft
water(7732-18-5) is found on the following regulatory lists

ethyl butyrate(105-54-4) is found on the following regulatory lists

dihydrocoumarin(119-84-6) is found on the following regulatory lists

lemon oil(8008-56-8) is found on the following regulatory lists

propylene glycol(57-55-6) is found on the following regulatory lists

pyroligneous acid(8030-97-5) is found on the following regulatory lists

maltol(118-71-8) is found on the following regulatory lists

ethyl propionate(105-37-3) is found on the following regulatory lists

- Australia Hazardous Substances Information System - Consolidated Lists - Australia Inventory of Chemical Substances (AICS)
piperonal(120-57-0) is found on the following regulatory lists

ethyl vanillin(121-32-4) is found on the following regulatory lists

ethyl acetate(141-78-6) is found on the following regulatory lists

acetal(105-57-7) is found on the following regulatory lists

- Australia Hazardous Substances Information System - Consolidated Lists - Australia Inventory of Chemical Substances (AICS)
caramel furanone(28664-35-9) is found on the following regulatory lists

glycerol(56-81-5) is found on the following regulatory lists

caramel(8028-89-5) is found on the following regulatory lists

National Inventory Status

Australia - AICS Y
Canada - DSL N (caramel furanone)
Continued...
001541 RUM FLAVOUR
N (piperonal; propylene glycol; ethyl acetate; glycerol; vanillin; water; dihydrocoumarin; ethyl propionate; ethyl vanillin; caramel; acetic acid glacial; 3-methyl-
Canada - NDSL
1,2-cyclopentanedione; ethyl butyrate; lemon oil; acetal; maltol; pyroligneous acid; acetaldehyde)
China - IECSC Y
Europe - EINEC /
N (lemon oil)
ELINCS / NLP
Japan - ENCS N (vanillin; acetic acid glacial; lemon oil; acetal; caramel furanone)
Korea - KECI N (caramel furanone; pyroligneous acid)
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Y = All ingredients are on the inventory
Legend:
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information
Ingredients with multiple cas numbers

Name CAS No
3-methyl-1,2-cyclopentanedione 765-70-8, 80-71-7
lemon oil 8008-56-8, 68917-33-9
piperonal 120-57-0, 30024-74-9
caramel furanone 28664-35-9, 87021-36-1
glycerol 56-81-5, 29796-42-7, 30049-52-6, 37228-54-9, 75398-78-6, 78630-16-7, 8013-25-0
caramel 8028-89-5, 1343-75-5, 1343-76-6, 1009080-01-6, 1038587-78-8, 1038587-80-2
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.
Powered by AuthorITe, from Chemwatch.
end of SDS

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001541 RUM FLAVOUR

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

ChemWatch Hazard Ratings

Poisons Schedule Not Applicable

SIGNAL WORD : WARNING

Precautionary statement(s) Prevention

Precautionary statement(s) Response

Precautionary statement(s) Storage

Precautionary statement(s) Disposal

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Indication of any immediate medical attention and special treatment needed

Ellenhorn and Barceloux: Medical Toxicology

SECTION 5 FIREFIGHTING MEASURES

Special hazards arising from the substrate or mixture

Advice for firefighters

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Methods and material for containment and cleaning up

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits (OEL)

Source Ingredient Material name TWA STEL Peak Notes

Eye and face protection

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid Relative density (Water = 1) 1.042

SECTION 10 STABILITY AND REACTIVITY

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Oral (rat) LD50: 1580 mg/kg [2]

Skin(human):104 mg/3d Intermit Mod

Oral (rat) LD50: 5620 mg/kg [2]

ACETIC ACID GLACIAL

VANILLIN & LEMON OIL & PIPERONAL & ETHYL VANILLIN

VANILLIN & PIPERONAL & ETHYL VANILLIN

VANILLIN & ETHYL VANILLIN

VANILLIN & PIPERONAL & ETHYL VANILLIN

ACETIC ACID GLACIAL & LEMON OIL

DIHYDROCOUMARIN & CARAMEL FURANONE

Acute Toxicity Carcinogenicity

SECTION 12 ECOLOGICAL INFORMATION

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE