IONIC EQUILIBRIUM-MPS

1. Ans: (b) 14. Ans: (d) 27. Ans: (d) 40. Ans: (d)
2. Ans: (a) 15. Ans: (d) 28. Ans: (d) 41. Ans: (d)
3. Ans: (b) 16. Ans: (b) 29. Ans: (c) 42. Ans: (c)
4. Ans: (c) 17. Ans: (d) 30. Ans: (a) 43. Ans: (d)
5. Ans: (c) 18. Ans: (c) 31. Ans: (a) 44. Ans: (c)
6. Ans: (c) 19. Ans: (d) 32. Ans: (a) 45. Ans: (b)
7. Ans: (c) 20. Ans: (b) 33. Ans: (b) 46. Ans: (b)
8. Ans: (c) 21. Ans: (a) 34. Ans: (c) 47. Ans: (b)
9. Ans: (d) 22. Ans: (c) 35. Ans: (a) 48. Ans: (c)
10. Ans: (a) 23. Ans: (d) 36. Ans: (d) 49. Ans: (a)
11. Ans: (b) 24. Ans: (d) 37. Ans: (c) 50. Ans: (c)
12. Ans: (b) 25. Ans: (c) 38. Ans: (a)
13. Ans: (c) 26. Ans: (a) 39. Ans: (d)

1. Ans: (b) 6. Ans: (c)

[OH-] = 10-3 M pOH = 14 – pH = 1
pOH = - log10 [OH-] ∴ [OH-] = 0.1 M (10-1M)
=3 Moles of [OH-] = 0.1 M × Volume
pOH + pH = 14 = 0.1 × 0.250
⇒ 3 + pH = 14 = 0.025 moles
pH = 14 – 3 = 11 Mass of NaOH = 0.025 × 40 g/mol
2. Ans: (a) = 1 gm
3. Ans: (b) 7. Ans: (c)
Ka × Kb = 10-14 For 100 mL sol (pH = 3)
10 −6
𝐾𝑏 (𝐴̅) = 𝐾 = 10−8 Moles of H+ = 10-3 × 0.1 L
𝑎
= 10-4 moles
4. Ans: (c)
For 400 mL sol (pH = 4)
Initial conc(c) = 10-3 M
Moles of H+ = 4 × 10-5
∝ = 1% = 0.01
Total H+ = 1.4 × 10-4 moles
[H+] = c ∝ = 10-5 M
Total vol = 0.50 L
pH = - log [H+] = 5
1.4×10−4
5. Ans: (c) [𝐻 + ] =
0.5
Milliequivalent of NaOH = 10 × 0.1 = 1M = 2.8 × 10-4 M
Milliequivalent of H2SO4 = 10 × 0.05 = 0.5 M pH = - log (2.8 × 10-4)
NaOH left = 1 – 0.5 = 0.5 M = 3.55
Total Vol = 20 8. Ans: (c)
5
[𝑂𝐻 − ] = = 2.5 × 60−2 0.01 M HCl
20×10
1×10−14
pOH = - log [OH-] = 1.602 [𝐻 + ] = 0.01𝑀 [𝑂𝐻 − ] = = 1 × 10−12 𝑀
0.01
pH = 14 – 1.602 > 7
 0.01 M HCOOH 20. Ans: (b)
1×10−14 Moles of OH-
[𝐻 + ] = √𝐾𝑎 ⋅ 𝑐 [𝐻 + ] =
0.0013
Ba(OH)2 → 0.1 × 4 × 2 = 0.8
= 0.0013 M (Ka = 1.8 × 10-4 = 7.4 × 10-12 M
NaOH → 0.05 × 6 = 0.3
[H+] = 2 × 0.01 = 0.02M
Total vol = 10 L Total moles = 1.1
1×10−14
[𝑂𝐻 − ] = = 5 × 10−13 𝑀 1.1
0.02 𝑝𝑂𝐻 = −log ( 10 ) = 0.96
0.01 M H2CO3
pH = 14 – 0.96 ≈ 13
[H+] = 6.6 × 10-5 [OH-] = 1.5 × 10-10
21. Ans: (a)
0.01 M H2SO4 has lowest [OH-]
< 7 NaCl is a neutral solution
9. Ans: (d)
22. Ans: (c)
K = 10-5 × 5 × 10-10 = 5 × 10-15 > 7 Sodium acetate is (weak acid + strong base)
10. Ans: (a) Salt
CCl4 23. Ans: (d)
11. Ans: (b) a, b both
[𝑂𝐻 − ] 10−3
∝ = initial conc. = 10−2 = 10% 24. Ans: (d)
12. Ans: (b) Weak acid + strong base
[𝐻 + ] = √𝐾𝑎 𝑐 25. Ans: (c)
26. Ans: (a)
13. Ans: (c)
6.5 weak acid + weak base
[𝐻 + ] = √𝐾𝑎 𝑐 = 10−3 1 𝐾
𝑝𝐻 = −log[𝐻 + ] = 3 𝑝𝐻 = 7 + 2 log (𝐾𝑏)
𝑎

14. Ans: (d) 27. Ans: (d)

10-6 28. Ans: (d)
15. Ans: (d) All are strong acid and base
5 29. Ans: (c)
16. Ans: (b) 30. Ans: (a)
Same pH, pH = 3 Degree of hydrolysis
17. Ans: (d) 𝐾𝑤
10×0.1
= √𝐾
− 𝑎 𝐾𝑏
Mole of 𝑂𝐻 = 1000
10−14
= 0.001 = √10−5 10−5 = 10−2
10×0.05
Moles of H+ = ×2 31. Ans: (a)
+
(2𝐻 ) 1000
𝑠𝑎𝑙𝑡
= 0.001 𝑝𝐻 = 𝑝𝐾𝐵 + log (𝐵𝑎𝑠𝑒 )
As no. of moles of H+ and OH- are same – 1
Initial (1 : 1) 𝑝𝐻 = 𝑝𝐾𝐵 + log (1)
neutral solution pH = 7
2
18. Ans: (c) Final (2: 1)(𝑝𝐻)′𝑝𝐾𝐵 + log (1)
[𝐻 + ]initial
[𝐻 + ] = (pH)’ > (pH)
[𝐻 + ]final
32. Ans: (a)
= 103
𝑠𝑎𝑙𝑡
1000 times reduces 𝑝𝐻 = 𝑝𝐾𝑎 + log (𝑎𝑐𝑖𝑑)
19. Ans: (d) 1
= 𝑝𝐾𝑎 + log (10)
pH increases
 = pKa – 1 𝐿𝑖 + = 35 𝑁𝑎+ = 35 𝐴𝑙𝐹63− = 25
33. Ans: (b) S = Solubility 𝐾𝑐𝑝 = (35)3 (35)3 (25)2 = 291658
No change 42. Ans: (c)
Buffer solution will resist the changes in the pH Ksp = [Ag+] [Cl-]
34. Ans: (c) Total no. of ions = 1 + 1 = 2
NH4Cl + HCl [AgCl → Ag+ + Cl-]
35. Ans: (a) 1.43×10−3
Molar solubility = 10−5 𝑚𝑜𝑙/𝐿
4 143
Ksp = (10-5)2
36. Ans: (d)
𝑆𝑎𝑙𝑡 1 = 10-10
log (𝐴𝑐𝑖𝑑) = log (1) = 0
43. Ans: (d)
∴ pOH pKb All have same Ksp
pH = 14 – pOH 44. Ans: (c)
= 14 – 4.74 = 9.26 𝐴𝑔2 𝐶𝑟𝑂4 → 2𝐴𝑔+ + 𝐶𝑟𝑂42−
2𝑥 𝑥
37. Ans: (c)
Given 2x = 1.5 × 10-4
1:1 M CH3COONa 1M HCl
𝐾𝑠𝑝 = [𝐴𝑔+ ]2 [𝐶𝑟𝑂4−2 ]
[𝐻 + ] = √𝐾𝑎⋅𝐶
= (2x)2 (x) = 4x3
[𝐻 + ] = √1.8 × 10−5 × 1
= 1.68 × 10-12
= 4.2 × 10−3
45. Ans: (b)
𝑝𝐻 = 2.38
Ksp is a constant at a given temperature
2:1 M CH3COONa + 1M CH3COOH pH = pKa
46. Ans: (b)
= - log (1.8 × 10-5) = 4.74
0.1 M CaBr2
2.3
≈ 1.2 47. Ans: (b)
4.7
38. Ans: (a) Solubility ∝ Ksp
Buffer capacity PbSO4 – Max. solubility
no. of moles of strong acid
= 48. Ans: (c)
𝛥𝑝𝐻
0.02 s = √S = S1/2
= 5.8−5.75 = 0.4
49. Ans: (a)
39. Ans: (d) 7
Moles of 𝐶𝑎𝐶𝑂3 = 100 = 0.07 𝑚𝑜𝑙𝑒𝑠
I, II, III
Ksp = (0.07)2 = 4.9 × 10-3
40. Ans: (d)
50. Ans: (c)
𝐻2 𝐶𝑂3 /𝐻𝐶𝑂3−
𝐻𝑔2 𝐼2 → 𝐻𝑔22+ + 2𝐼 −
41. Ans: (d)
𝐾𝑠𝑝 = [𝐻𝑔2+2 ][𝐼 − ]2
𝐿𝑖3 𝑁𝑎3 (𝐴𝑙𝐹6 )2 → 3𝐿𝑖 + + 3𝑁𝑎+ + 2(𝐴𝑙𝐹63− )