D & F Block Chem

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Periodic table with atomic number, symbol, and electron configuration

Alkali metals Halogens


group Alkaline-earth metalsNoble gases
1* 18
Transition metals Rare-earth elements (21, 39, 57-71)
1 2
1 H Other metals
and lanthanoid elements (57-71 only) He
1s!
2 13 14 15 16 17 182

3 Other nonmetals Actinoid elements 5 6 7 8 10


2 Li Be B C N F Ne
[Hel2s 282 2s?2p' 2s?202 2s°2p3 2s22p4 28?2p5 2s2p
11 12 13 14 15 16 17 18
3 Na Mg 3 4 5 6 7 8 9 10 11 12
Al Si P S CI Ar
[Nej3s 3s?3p1 3s23p2 3s23p3 3s23p4 3s235 3s23p6

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
(Ar4s 3d'482 3d2482 3d482 3d54s' 3d54s2 3d®482 3d'462 3d104s1 3d104s2 3d 104s?4p1 3d 104s24p2 3d104s4p3 3d1048 4p4 3d 104s²4p5 3d104824p6
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te Xe
(Kij5s! 5s 4d'5s2 4d2582 4d45s1 4d5s! 4d5%s? 4d75s 4dB5s1 4d10 4d105s1 4d105s2 4d 105s5p' 4d 105s?5p2 4d105s25p3 4d105s25p4 4d 105s5p5 4d 105s?5p6
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Pt Au Hg TI Pb Bi Po At Rn
Kej6s 5d'6s 4f145d 6s? 4f145d6s? 4f145d4e2 4f145d 6s2 4fl45d6s? 4f145dT6s2 4f145d
6s! 4f145g 10gs1 4f145d106s2 4f l45d108s?6p14145o 106s2624f145d108s?6p3 4/145d 108s26p44145108s?6p54f145sa108s26p6
87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Nh FI Mc Lv Ts Og
[Rn]7s1 782 5rl46d27s2 5rl46097s2 5rl46d47s2 5r46d97s2 5rt46d67s2 5rt46d77s2 5/46d7s 5rl46d107s! 5rl46d107s2 5rl46d107s7p'5/l46d 107s 7p²5/l46d 107s7psrl46d t07s?7p5/146d 107s?7p55/14sd 107s?7p6

58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoid series 6 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Ke<4f°6s? 4f6s2 4f662 4f6S 4f662 4f 6s2 4f75d'6s? 4fP6s2 4f106s2 4f116s2 4f126s2 4f136s2 4f14662 4f145d'6s2

90 91 92 93 94 95 96 97 98 99 100 101 102 103


actinoid series 7 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
(Rn]6d²7s? 5r26d7s2 5F6d'7s2 5rt6d17s2 5/7s2 5f77s2 5/76d792 5r7s2 5r10752 5r117s? 5r127s2 5r187s2 5f147s2 5/146d7s2

"Numbering system adopted by the International Union of Pure and Applied Chemistry (IUPAC). OEncyclopædia Britannica, Inc.
3
2nd Series

4th Series

NR
Lattice Structures of Transition Metals

Ti V Mn Fe Co Ni Cu Zn

hcp hep bcc bcc X bcc Ccp ccp ccp X


(bcc) (bcc) (bcc, ccp) (hep) (hep) (hep)
Zr Nb Mo Te Ru Rh Pd Ag Cd

hcp hcp bcc bcc hep hcp ccp ccp Ccp X


(bcc) (bcc) (hep)
La Hf Ta W Re Os Pt Au Hg
hcp hcp bcc bcc hep hcp Ccp ccp Ccp X
(ccp.bec) (bec)
Element Sc Ti Cr Mn Fe Co Ni Cu Za

Atomic number 21 22 23 24 25 26 27 28 29 30

Electronic configuration
3d'4 3d4s' 3d'4s 3d4s' 3d4s 3d4s 3d'4s 3d'4s 3d°4s' 3d'4s
M 3d'4s' 3d'4s' 3d'4s 3d 3d'4s' 3d4s' 3d'4s' 3d'4s' 3do 3d"4s'
M 3d 3d 3d 3d 3d 3d 3d 3d 3dlo
M |Ar 3d 3d 3d 3d 3d 3d 3d

Enthalpy of atomisation, A,/kd mol


326 473 515 397 281 116 425 130 339 126

Ionisation enthalpy/A,H°/kJ mol!


A,H 631 656 650 653 717 762 758 736 745 906
1235 1309 1414 1592 1509 1561 1644 1752 1958 1734
A,H 2393 2657 2833 2990 3260 2962 3243 3402 3556 3837
Metallic/ionie M 164 147 135 129 137 126 125 125 128 137

radii/pm 79 82 82 77 74 70 73 75
M 73 67 64 62 65 65 61 60

Standard
electrode M"/M -1.63 -1.18 -0.90 -1.18 -0.44 -0.28 -0.25 +0.34 -0.76
potential E /V M/M* -0.37 -0.26 -0.41 +1.57 +0.77 +1.97

Density/g cm 3.43 4.1 6.07 7.19 7.21 7.8 8.7 8.9 8.9 7.1
Sc Ti V Cr Mn Fe Co Ni Cu Zn

+2 +2 +2 +2 +2 +2 +2 +1 +2
+3 +3 +3 +3 +3 +3 +3 +3 +2
+4 +4 +4 +4 +4 +4 +4
+5 +5 +5
+6 +6 +6
+7
Table 8.9: Electronic Configurations and Radii of Lanthanum and Lanthanoids

Electronic configurations" Radii/pm


Atomic Name Symbol Ln Ln Ln" Ln" Ln Ln
Number
57 Lanthanum La 5d'6s 5d' 4f 187 106
58 Ceriumn Ce 4f5d'6s 4f2 4f" 183 103
59 Praseodymium Pr 4f'6s 4f 4f 182 101
60 Neodymium Nd 4f "6s 4f? 181 99
61 Promethium Pm 4f"6s 4f5 181 98
62 Samarium Sm 4f°6s 4f 180 96
63 Europium Eu 4f '6s 4f 199 95
64 Gadolinium Gd 4f'5d'6s 4f'5d' 180 94
65 Terbium Tb 4f°6s 4f" 178 92
66 Dysprosium Dy 4f"6s 4f 177 91
67 Holmium Ho 4f"6s 4f" 176 89
68 Erbium Er 4f"6s 4f 12 4f" 175 88

69 Thulium Tm 4f"6s 4f1a 4f2 174 87


70 Yterbium Yb 4f"6s 4fl4 4fl 173 86
71 Lutetium Lu 4f"5d'6s 4f"5d' 4f4
Table 8. 10: Some Properties of Actinium and Actinoids
Electronic conifigurations Radii/pm
Atomic Name Symbol M M M M M
Number

89 Actinium Ac 6d'7s 5f° 111


90 Thorium Th 6d7s 5f 5f° 99
91 Protactinium Pa 5f '6d'7s 5f? 5f! 96
92 Uranium U 5f°6d'7s 5f 5f 103 93
93 Neptunium Np 5f'6d'7s 5f 5/ 101 92
94 Plutonium Pu 5f"7s 5f 5/ 100 90
95 Americium Am 5f"7s 5f 5f 99 89

96 Curium Cm 5f'6d'7s 5f 5f 99 88

97 Berkelium Bk 5f"7s 5f 5f 98 87
98 Californium C! 5f °7s 5f 5f 98 86
99 Einstenium Es 5f"7s 5f0 5f
100 Fermium Fm 5f "7s 5f 5f0
101 Mendelevium Md 5f "7s 5f 5f
102 Nobelium No 5f "7s 5f13 5f2
103 Lawrencium Lr 5f"6d'7s 5fl4 5f43

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