D & F Block Chem
D & F Block Chem
D & F Block Chem
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
(Ar4s 3d'482 3d2482 3d482 3d54s' 3d54s2 3d®482 3d'462 3d104s1 3d104s2 3d 104s?4p1 3d 104s24p2 3d104s4p3 3d1048 4p4 3d 104s²4p5 3d104824p6
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te Xe
(Kij5s! 5s 4d'5s2 4d2582 4d45s1 4d5s! 4d5%s? 4d75s 4dB5s1 4d10 4d105s1 4d105s2 4d 105s5p' 4d 105s?5p2 4d105s25p3 4d105s25p4 4d 105s5p5 4d 105s?5p6
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Pt Au Hg TI Pb Bi Po At Rn
Kej6s 5d'6s 4f145d 6s? 4f145d6s? 4f145d4e2 4f145d 6s2 4fl45d6s? 4f145dT6s2 4f145d
6s! 4f145g 10gs1 4f145d106s2 4f l45d108s?6p14145o 106s2624f145d108s?6p3 4/145d 108s26p44145108s?6p54f145sa108s26p6
87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Nh FI Mc Lv Ts Og
[Rn]7s1 782 5rl46d27s2 5rl46097s2 5rl46d47s2 5r46d97s2 5rt46d67s2 5rt46d77s2 5/46d7s 5rl46d107s! 5rl46d107s2 5rl46d107s7p'5/l46d 107s 7p²5/l46d 107s7psrl46d t07s?7p5/146d 107s?7p55/14sd 107s?7p6
58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoid series 6 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Ke<4f°6s? 4f6s2 4f662 4f6S 4f662 4f 6s2 4f75d'6s? 4fP6s2 4f106s2 4f116s2 4f126s2 4f136s2 4f14662 4f145d'6s2
"Numbering system adopted by the International Union of Pure and Applied Chemistry (IUPAC). OEncyclopædia Britannica, Inc.
3
2nd Series
4th Series
NR
Lattice Structures of Transition Metals
Ti V Mn Fe Co Ni Cu Zn
Atomic number 21 22 23 24 25 26 27 28 29 30
Electronic configuration
3d'4 3d4s' 3d'4s 3d4s' 3d4s 3d4s 3d'4s 3d'4s 3d°4s' 3d'4s
M 3d'4s' 3d'4s' 3d'4s 3d 3d'4s' 3d4s' 3d'4s' 3d'4s' 3do 3d"4s'
M 3d 3d 3d 3d 3d 3d 3d 3d 3dlo
M |Ar 3d 3d 3d 3d 3d 3d 3d
radii/pm 79 82 82 77 74 70 73 75
M 73 67 64 62 65 65 61 60
Standard
electrode M"/M -1.63 -1.18 -0.90 -1.18 -0.44 -0.28 -0.25 +0.34 -0.76
potential E /V M/M* -0.37 -0.26 -0.41 +1.57 +0.77 +1.97
Density/g cm 3.43 4.1 6.07 7.19 7.21 7.8 8.7 8.9 8.9 7.1
Sc Ti V Cr Mn Fe Co Ni Cu Zn
+2 +2 +2 +2 +2 +2 +2 +1 +2
+3 +3 +3 +3 +3 +3 +3 +3 +2
+4 +4 +4 +4 +4 +4 +4
+5 +5 +5
+6 +6 +6
+7
Table 8.9: Electronic Configurations and Radii of Lanthanum and Lanthanoids
96 Curium Cm 5f'6d'7s 5f 5f 99 88
97 Berkelium Bk 5f"7s 5f 5f 98 87
98 Californium C! 5f °7s 5f 5f 98 86
99 Einstenium Es 5f"7s 5f0 5f
100 Fermium Fm 5f "7s 5f 5f0
101 Mendelevium Md 5f "7s 5f 5f
102 Nobelium No 5f "7s 5f13 5f2
103 Lawrencium Lr 5f"6d'7s 5fl4 5f43