SAFETY DATA SHEET

1. Identification
Product identifier HumiSeal 1B31
Other means of identification
Product code AR0000-4135
Synonyms HUM 1B31
Recommended use Protective coating for printed circuit boards. Industrial use.
Recommended restrictions No other uses are advised.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name CHASE CORPORATION Zeta Drive Plant
Address 201 Zeta Drive
Pittsburgh, Pennsylvania 15238
United States
Telephone 1-866-932-0800
E-mail techsupport@humiseal.com
Emergency phone number 1-800-424-9300 Chemtrec, US
(+1)703-527-3887 Chemtrec, outside of US

2. Hazard(s) identification
Physical hazards Flammable liquids Category 3
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Reproductive toxicity Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Specific target organ toxicity, repeated Category 2
exposure
Aspiration hazard Category 1
Environmental hazards Hazardous to the aquatic environment, acute Category 2
hazard
Hazardous to the aquatic environment, Category 2
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

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 H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist/vapors.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P310 If swallowed: Immediately call a poison center/doctor.
P331 Do NOT induce vomiting.
P303 + P361 +
P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 +
P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 If exposed or concerned: Get medical advice/attention.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use appropriate media to extinguish.
P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information % of the mixture consists of component(s) of unknown acute dermal toxicity.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Toluene 108-88-3 50 - < 60
Butanone 78-93-3 10 - < 20

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

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Most important Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness or dizziness.
symptoms/effects, acute and Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
delayed redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged
exposure may cause chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing
before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Flammable liquid and vapor.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
protective equipment and ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
emergency procedures protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. Prevent product from entering drains.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general
and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Do not breathe mist/vapors. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible. Wear
appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release
to the environment. Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).

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8. Exposure controls/personal protection
Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Butanone (CAS 78-93-3) PEL 590 mg/m3
200 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
Components Type Value
Toluene (CAS 108-88-3) Ceiling 300 ppm
TWA 200 ppm

US. ACGIH Threshold Limit Values

Components Type Value
Butanone (CAS 78-93-3) STEL 300 ppm
TWA 200 ppm
Toluene (CAS 108-88-3) TWA 20 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value
Butanone (CAS 78-93-3) STEL 885 mg/m3
300 ppm
TWA 590 mg/m3
200 ppm
Toluene (CAS 108-88-3) STEL 560 mg/m3
150 ppm
TWA 375 mg/m3
100 ppm

Biological limit values

ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Butanone (CAS 78-93-3) 2 mg/l MEK Urine *
Toluene (CAS 108-88-3) 0.3 mg/g o-Cresol, with Creatinine in *
hydrolysis urine
0.03 mg/l Toluene Urine *
0.02 mg/l Toluene Blood *
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Toluene (CAS 108-88-3) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Toluene (CAS 108-88-3) Skin designation applies.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
controls Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide eyewash station and safety shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
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 Thermal hazards Not applicable.
General hygiene Observe any medical surveillance requirements. When using do not smoke. Always observe good
considerations personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Not available.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point -138.82 °F (-94.9 °C) estimated
Initial boiling point and boiling 175.26 °F (79.59 °C) estimated
range
Flash point 84.2 °F (29.0 °C) Closed Cup
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Explosive limit - lower (%) 1.27 % estimated
Explosive limit - upper (%) 11.4 % estimated
Vapor pressure 5.62 kPa estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 896 °F (480 °C) estimated
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 0.89 - 0.93 g/cm³
Explosive properties Not explosive.
Kinematic viscosity 195 - 245 mm²/s
Kinematic viscosity 73.4 °F (23 °C)
temperature
Oxidizing properties Not oxidizing.

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents. Amines. Ammonia. Caustics. Isocyanates.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May cause drowsiness or dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.

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 Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness or dizziness.
physical, chemical and Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,
toxicological characteristics redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways.
Product Species Test Results
HumiSeal 1B31
Acute
Dermal
LD50 Rabbit 8321 mg/kg
Inhalation
LC50 Rat 44 mg/l, 4 hours
Oral
LD50 Rat 6579 mg/kg
Components Species Test Results
Butanone (CAS 78-93-3)
Acute
Dermal
LD50 Rabbit 8054 mg/kg
Inhalation
Vapor
LC50 Rat 34 mg/l, 4 hours
Oral
LD50 Rat 2193 mg/kg
2054 mg/kg
Toluene (CAS 108-88-3)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg
> 5000 mg/kg, 24 Hours
Inhalation
Vapor
LC50 Rat > 20 mg/l, 4 hours
Oral
LD50 Rat > 5000 mg/kg
2.6 - 7.5 g/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

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 US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Suspected of damaging fertility or the unborn child.
Specific target organ toxicity - May cause drowsiness or dizziness.
single exposure
Specific target organ toxicity - May cause damage to organs through prolonged or repeated exposure.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or
repeated exposure.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.
Product Species Test Results
HumiSeal 1B31
Aquatic
Acute
Crustacea EC50 Daphnia 7.6075, 48 hours
Fish LC50 Fish 669.8128, 96 hours
Components Species Test Results
Toluene (CAS 108-88-3)
Aquatic
Acute
Crustacea EC50 Invertebrates (Invertebrates) 3.78, 48 hours
Fish LC50 Fish 5.5, 96 hours
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Butanone (CAS 78-93-3) 0.29
Toluene (CAS 108-88-3) 2.73
Mobility in soil No data available.
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate
ponds, waterways or ditches with chemical or used container. If discarded, this product is
considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
D035: Waste Methyl ethyl ketone
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information

DOT
UN number UN1263
UN proper shipping name PAINT
Transport hazard class(es)
Class 3
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 Subsidiary risk -
Label(s) 3
Packing group III
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions B1, B52, IB3, T2, TP1, TP29
Packaging exceptions 150
Packaging non bulk 173
Packaging bulk 242
IATA
UN number UN1263
UN proper shipping name PAINT
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards No.
ERG Code 3L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
UN number UN1263
UN proper shipping name PAINT
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant No.
EmS F-E, S̲-E̲
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.

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 Toxic Substances Control Act (TSCA) One or more components of the mixture are not on the TSCA 8(b) inventory
or are designated “inactive”.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Butanone (CAS 78-93-3) Listed.
Toluene (CAS 108-88-3) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Flammable (gases, aerosols, liquids, or solids)
categories Skin corrosion or irritation
Serious eye damage or eye irritation
Reproductive toxicity
Specific target organ toxicity (single or repeated exposure)
Aspiration hazard
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Toluene 108-88-3 50 - < 60
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Toluene (CAS 108-88-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Contains component(s) regulated under the Safe Drinking Water Act.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Butanone (CAS 78-93-3) 6714
Toluene (CAS 108-88-3) 6594
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Butanone (CAS 78-93-3) 35 %WV
Toluene (CAS 108-88-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Butanone (CAS 78-93-3) 6714
Toluene (CAS 108-88-3) 594
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Butanone (CAS 78-93-3) Low priority
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Butanone (CAS 78-93-3)
Toluene (CAS 108-88-3)
California Proposition 65
WARNING: This product can expose you to Toluene, which is known to the State of California to cause birth
defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

California Proposition 65 - CRT: Listed date/Developmental toxin

Toluene (CAS 108-88-3) Listed: January 1, 1991
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Industrial Chemicals (AICIS) Yes

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 Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 05-22-2021
Revision date 10-07-2023
Version # 08
HMIS® ratings Health: 3*
Flammability: 3
Physical hazard: 0
NFPA ratings Health: 2
Flammability: 3
Instability: 0

List of abbreviations AICIS: Australian Inventory of Industrial Chemicals.

Disclaimer The information offered in this data sheet is designed only as guidance for the safe use, storage
and handling of the product. This information is correct to the best of our knowledge and belief at
the date of publication, however, no guarantee is made to its accuracy. This information relates
only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any other process. This material is intended for industrial use only.
No warranty, expressed or implied is made.
Revision information Product and Company Identification: Product and Company Identification

Material name: HumiSeal 1B31 SDS US

AR0000-4135 Version #: 08 Revision date: 10-07-2023 Issue date: 05-22-2021 10 / 10