(0999DJA161103230026) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

MAJOR TEST
(Academic Session : 2023 - 2024)
28-04-2024

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY PAPER-1
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. A D D D
Q. 5 6 7
SECTION-I (ii)
A. A,B,C,D A,B,C B,D
Q. 8 9 10 11
SECTION-I (iii)
A. D B B A
Q. 1 2 3 4 5 6
SECTION-II
A. 1 1 1000 5 8 5

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. C B B C
Q. 5 6 7
SECTION-I (ii)
A. A,B,C,D A,B,C,D B,C,D
Q. 8 9 10 11
SECTION-I (iii)
A. D A A B
Q. 1 2 3 4 5 6
SECTION-II
A. 527 4 7 2 3 12

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. D C C B
Q. 5 6 7
SECTION-I (ii)
A. B,C,D C,D A,C
Q. 8 9 10 11
SECTION-I (iii)
A. B A A D
Q. 1 2 3 4 5 6
SECTION-II
A. 32 1 4 9 2 7

HINT – SHEET
PART-1 : PHYSICS →a ⋅ →b →
= ×b
SECTION-I (i) b2

1. Ans ( A ) P 2 − Q2 → +Q
→)
⇒ ( P
Let P→ + Q
→ = →a P2 + Q2

→ −Q
P → = →b 2. Ans ( D )
2uR
v=
Component of →a along →b = a cos θ × b^ u+R
For real object u is negative and R is negative.
∴ v is negative

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3. Ans ( D ) So, power
e2 E02 d e2 (4m2 a2 v4 ) d 4ma2 v3
= = = ...(ii)
mv e2 d 4 mv d3
→ At A
Since, vx = 0
dW
θ + 37∘ + 53∘
So, rate of work done = =0 ....(iii)
53° = ⇒θ = 16° dt
2 Velocity at B
4. Ans ( D ) eE0 d 2mav2 d
vx = − = e( )
mv ed 2 mv
2av
vx = & vy = v
d
2av ^
⇒ so, vnet = i + vj^ ....(iv)
d
6. Ans ( A,B,C )
Range with respect to ground 10 a = 10 g – T2
2ux uy 2(4 + 4 cos θ)(4 sin θ)
R= = 2 a = T1 – fK
g g
32 sin θ(1 + cos θ) 32 3a = T2 – T1 – fK
R= (sin θ + sin θ cos θ )
=
g g
Rmax = when sin θ + sin θ cos θ will be max
d
⇒ (sin θ
+ sin θ cos θ ) = 0
dθ
⇒ cos θ + 2cos2q – 1 = 0
1
⇒ cos θ =
2
⇒ θ = 60°
⇒ 15a = 10g ⇒ a = 5.86;
PART-1 : PHYSICS T1 = 17.7 N and T2 = 41.4 N
SECTION-I (ii) 7. Ans ( B,D )
5. Ans ( A,B,C,D )
Clearly when particle leaves at B, from graph,
velocity along y axis remains unchanged.
Hence, E→ is along x axis
Let E→ = E0 ^i
eE0 Angular momentum remains conserved about
a′ = − centre of earth.
m
Also, d = vt ⇒ t = d mv0 cos30°R = mv2R
v
d2
√ 3V0
and x = (2a-a) = a t = − eE0 2
1 ′2 V =
4
2 2m v
2mav2 ^ Path will not be parabolic because acceleration
⇒ E0 = − i ...(i) due to gravity does not remain constant.
ed 2
Power = dW = F vx = − eE0 vx
dt
and vx = a't = – eE0 d
m v
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PART-1 : PHYSICS (D) v > √
c
ma
SECTION-I (iii) To escape to + ∞ , the particle must pass through
8. Ans ( D ) the point x2 = +a at which the potential energy is
The initial charge on capacitor maximum. Hence we require E > U(a) = c ,
2a
= CVi = 1 × 2 µC = 2 µC i.e.,
The final charge on capacitor 2c
(C) v > √

= CVf = 1 × 4 µC = 4 µC ma
∴ Net charge crossing the cell of emf 4V is 10. Ans ( B )
qf – qi = 4 – 2 = 2 µC
3×2 2
The magnitude of work done by cell of emf 4V is vCM = =
9 3
W = (qf – qi) 4 = 8 µJ
The gain in potential energy of capacitor is
1 1 (A)
ΔU = C (Vf 2 − Vi 2 ) = × [42 – 22] µJ = 6 µJ
2 2
Net heat produced in circuit is
Δ H = W – Δ U = 8 – 6 = 2 µJ
9. Ans ( B )
−dU
(A) At the equilibrium position, F = = 0,
dx
i.e.
(B)
dU c(a2 − x2 )
= =0
dx (x2 + a2 )2
Thus there are two equilibrium positions,
x1 = a, x2 = – a. Consider
d2U 2cx(x2 − 3a2 )
=
dx2 (x2 + a2 )3
d2U ∣ d2U ∣
We have ∣ <0, ∣ >0 (C)
dx2 ∣
x1 dx2 ∣
x2
It follows that x1 is a position of unstable
equilibrium and x2 is a position of stable
equilibrium.
The total energy of the particle is
mv2 mv2
c
E= + U( – a) = –
2 2 2a
For the particle to be confined in a region, we (D)
require E < 0, i.e.
c
(B) v < √
ma
mx2
As E = + U(x), for the particle to reach x
2
= – ∞ , we require E > U( – ∞ ) = 0, i.e.

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PART-1 : PHYSICS 6. Ans ( 5 )
SECTION-II
By phasor diagram

1. Ans ( 1 )

(
→ ) = (L
L → ) Angle traced= 53° + 37° = 90°
i f
0 0 90∘ T
mv0R – I ω 0 = mvfR + I ω f ....(i) ∴ Time taken = ×T = =5s
360∘ 4
vf = ω fR ....(ii)
PART-2 : CHEMISTRY
2. Ans ( 1 ) SECTION-I (i)
(Bvℓ)2 B2 v 2 ℓ 2
P= = = 100 1. Ans ( C )
R R
B2 ℓ 2 v Most effective coagulating agent for Sb2S3 is
& Fm = iB ℓ = ( e ) Bℓ =
R R Al2(SO4)3 because of high charge.
B2 ℓ 2 v 2 100
Fm = = = 10 2. Ans ( B )
vR 10
Fm = T = mg 10 = m × 10 ⇒ m = 1kg Decreasing order of reactivity with NaOH +
3. Ans ( 1000 ) CaO, Δ
* Check stability of Carbanion
P = irms Vrms cos ϕ
Vrms = 260 volt
vrms 260
irms = = = 10
z 26
P.F. = cos ϕ = R = 10
z 26
2
1
∵ z = √R2 + (ωL − ) = 26
ωc
10
∴ P = (10) (260) ( ) = 1000 W
26 Stability of carbanion → III > II > I
4. Ans ( 5 ) Decreasing order of Reactivity → III > II > I
T /A 3. Ans ( B )
=Y
dr/r Kjeldahl method is not applicable to compounds
dr 0.025
T = AY = 1 × 10−6 × 400 × 109 × = 500N containing nitrogen in nitrogroup, Azo groups
r 20
and nitrogen present in the ring (e.g Pyridine) as
nitrogen of these compounds does not change to
5. Ans ( 8 )
dQ
Ammonium sulphate under these conditions.
dm dT
H= =( ) Lf = mc
dt dt dt 4. Ans ( C )
dT −1
(0.1) × 80 = 10 × 1 × For endothermic reaction Keq. ∝ (
1
)
dt temperature
dT
x= = 0.8°C/s
dt
10x = 8
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PART-2 : CHEMISTRY PART-2 : CHEMISTRY
SECTION-I (ii) SECTION-II
5. Ans ( A,B,C,D ) 1. Ans ( 527 )
Heat of formation = Heat of reaction in which
Absorbed energy × 47% = Emitted energy
one mole compound is formed by combination
of its constituent element in standard state.
6. Ans ( A,B,C,D ) Nemitted
1 = 0.527
Cell constant = , so it is independent of Nabs.
A
solution. 2. Ans ( 4 )
7. Ans ( B,C,D ) Δ Hneut. for HCl + NaOH = 13.7 Kcal.
(A) False : ∴ for HCN (weak acid) Enthalpy of dissociation
= 13.7 – 9.7 = 4 kcal mol – 1.
3. Ans ( 7 )
T2 V
ΔS = nCv ℓn + nRℓn 2
T1 V1

3 1000 3
= R ln + R ln 100 = ( R + 2R) × 2.303
2 100 2
(B) True : Six member hemiacetal on anomeric
carbon gives α -D glucose & β -D glucose. 7
= ( R) × 2.303
(C) True : 2

4. Ans ( 2 )
w = – pext. Δ V = – 1atm × (22 – 2) litre = – 20
lit-atm
(D) True : Monosaccharide cannot be
= – 2000 J = – 2 kJ.
hydrolysed to give polyhydroxy aldehydes and
ketones. 5. Ans ( 3 )
PART-2 : CHEMISTRY
SECTION-I (iii)

11. Ans ( B ) 6. Ans ( 12 )

V ol. of atoms in unit cell
PF =
V ol. of unit cell
4 × 43 πR3 π
(P) a = 4R, z = 4, P.E. = 3
=
(4R) 12
π 2π
√
(Q) FCC, P.E. = =
3 2
√ 6
8πR3 √ 3π (4 σ + 2 π ) (8 σ + 4 π )
(R) BCC, P.E. = 3
=
8 Total number of bonds( σ ) between chromium
3 × ( 4R )
√ 3 and oxygen in both structures are 12.
4
3
πR3 π
(S) SC, P.E. = =
8R3 6

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PART-3 : MATHEMATICS PART-3 : MATHEMATICS
SECTION-I (i) SECTION-I (ii)

1. Ans ( D ) 5. Ans ( B,C,D )

100 100 100 100 100 100
2B + A = I ...(1)
C36 C68 C84 C92 C96 C98
+ + + + + T
⇒ 2B + A = I T
99 C 99 C 99 C 99 C 99 C 99 C
36 68 84 92 96 98
⇒ – 2B + A = I ...(2)
1 1 1 1 1 1 adding (1) and (2) we get
= 100 [ + + + + + ]
64 32 16 8 4 2 A = I, B = O (Null matrix)
5 B + A = I ⇒ |B + A| = 1∀n
100 25 r ⇒ {
= [1 + 2 + 4 + 8 + 16 + 32] = ∑ 2 B − A = −I ⇒ |B − A| = 1or − 1
64 16 r=0 according as n is even or odd respectively.
2. Ans ( C ) 6. Ans ( C,D )
a log3log2(x) – 2 = 0 & log2 log2 3 y = 1
y = mx + √

m
∣3m + 1 ∣ ⇒ log3log2(x) = 2 log2 3 y = 2 √

∣ m∣ 1 log2x = 9 y = 12
3= ⇒m=±
√ 1 + m2 √3

x = 29 = 512
m>0
7. Ans ( A,C )
1
y= x + √3 Clearly f(a) ≠ 0
√ 3 g(a + h) − g(a)
3. Ans ( C ) g ′ (a+ ) = lim+
h→0 h
a+h
First five tosses must contain either 4H+1T or 5H ∫ f(t) dt − 0
a
= lim+
h→0 h
⇒ Required probability = P(4H + 1T) + P(5H) f(a + h) − 0
= lim+
4 5 h→0 1
= 5C4 × ( 1 ) × 1 + ( 1 ) = 5
+
1
= 3
= f(a) ≠ 0
2 2 2 32 32 16
g(a − h) − g(a)
4. Ans ( B ) g ′ (a− ) = lim+
h→0 −h
x12 + x6 + 1 x12 + 2x6 + 1 − x6 0−0
y= = = lim+ =0
x6 + x3 + 1 x6 + x3 + 1 h→0 −h
2 2 hence non-differentiable at x = a but continuous
(x6 + 1) − (x3 )
= ⇒ y = x6 – x3 + 1 as limits are finite
x6 + x3 + 1
g(b + h) − g(b)
dy g ′ (b+ ) = lim+
⇒ = 6x5 − 3x2 h→0 h
dx b b
∫ f(t) dt − ∫ f(t) dt
a a
∴ a = 6, b = – 3 = lim+ =0
h→0 h
b −h b

a+b=6–3=3 ∫ f(t) dt − ∫ f(t) dt

a a
g ′ (b− ) = lim+
h→0 −h
−f(b − h) − 0
= lim+ = f(b) ≠ 0
h→0 −1
Hence non-differentiable at x = b but continuous
as limits are finite. correct options → A, C.
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PART-3 : MATHEMATICS 10. Ans ( A )
1
SECTION-I (iii)
I = ∫ (−ℓnt)n dt
8. Ans ( B ) e−x

(P) (→a . →c ) →b − →b. →c ) →a = −5→a + 4→b

(
– ℓ n t = u ⇒ t = e – u ⇒ dt = – e – u du
x
→b. →c = 5, →a . →c = 4 & →a . →b = 3
I = ∫ un e−u du
→a × (→b × →c ) = (→a . →c )→b − (→a . →b)→c = 4→b − 3→c 0
∞
(Q) Total number of squares
Hence In = ∫ un e−u du
 
= (8 × 8) + (7 × 7) + (6 × 6) + (5 × 5) + (4 I II
0
× 4) + (3 × 3) + (2 × 2) + (1 × 1) ∞
∣ ∣∞
= 204 In = ∣−un e−u ∣0 + ∫ n . un−1 e−u du
sum of digits = 2 + 0 + 4 ⇒ k = 6 0

then k – 1 = 5 ⇒ In = 0 + n . In – 1 ⇒ In = n . (n – 1) . In – 2
(R) Point is (4, 2, k) ∴ In = n.(n – 1).(n – 2). ... 2.I1
∞
8–8+k=9 ⇒ I1 = ∫ u . e−u du = 1
k=9 0
π π
4 4 ⇒ In = n!
1 π/4
(S) ∫ dx = ∫ sec2 xdx = 2[tan x]0 = 2 1/ 2
4
1/ 2
2 4
cos2 x 1 1 1
− π4 π
−4 Let J = ∫ ( − x2 ) dx = ∫ ( − ( − x) ) dx
4 4 2
0 0
9. Ans ( A ) (Using King Property)
(P) 1/ 2 1/ 2
2 4 4
∴ J=∫ ( x−x ) dx = ∫ x4 . (1 − x) dx .... (i)
0 0
⇒ J = K so J – K = 0
put x = 1 – y
1/ 2
4
Also, J = − ∫ (1 − y) y 4 dy
1
1
4
⇒ J = ∫ (1 − x) x4 dx .... (ii)
1/2

(Q) ∴ (i) + (ii)

1
1 4
⇒J= ∫ x4 (1 − x) dx
2
0
using Queen property
At x = 2 put x = sin2 θ
one solution for k = 2 π /2

J = ∫ sin9 θcos9 θ dθ
(R) sgn(g(x)) = 1 only one solution 0
(8 × 6 × 4 × 2) (8 × 6 × 4 × 2) 1
ƒ(x) = ℓ nx J=
(18 × 16 × 14 × 12 × 10 × 8 × 6 × 4 × 2)
=
1260
(S) For function to be bounded a = 7 ; b = 2

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11. Ans ( D ) 5. Ans ( 2 )
D = ( λ – 2) (µ – 3) y y y
x cos d(xy) = y sin d ( ) ⋅ x2
x x x
D1 = ( λ – 2) (4µ – 15) y y y
cos( )d (xy) = xy sin( )d ( )
D2 = 0 x x x
d(xy) y y
D3 = ( λ – 2) ∫ = ∫ tan( )d ( )
xy x x
D1 D D
x= ,y = 2 ,z = 3 y∣
D D D ln(xy) = ln∣∣sec + ln C
x∣
for no solution → λ ≠ 2, µ = 3 y
xy = sec( )C
for unique solution → λ ≠ 2, µ ≠ 3 x
y
for infinite many solution → λ = 2, µ ∈ R cos(
x
)xy = C

Exactly three solution is not possible

Put x = 1, y(1) = 2 π
∴ correct combination
2π cos(2π) = C
PART-3 : MATHEMATICS
SECTION-II c = 2π
1. Ans ( 32 ) y
cos( )xy = 2π
ƒ(x) = x3 + x x
∑( 8r3 + 2r) put x = 4
lim
n→∞ 2
=8
∑ r(r + 1) y(4)
cos( ) ⋅ 4 ⋅ y(4) = 2π
2. Ans ( 1 ) 4
1/3 y(4) π
Let I = ∫ ( x5 + x6 ) ( 5x4 + 6x5 ) dx y(4) cos( ) =
4 2
Let x5 + x6 = t3 6. Ans ( 7 )
( 5x4 + 6x5 ) dx = 3t2 dt ⇒ I = ∫ t (3t2 ) dt
3 4 3 4/3 3
= t + c = (x5 + x6 ) + C = x20/3 (1 + x)4/3 + C ⇒ km = 1
4 4 4

3. Ans ( 4 )
(sin6°sin54°sin66)(sin14sin46sin74)
(sin26sin34sin86)
1 1 1
⇒ (sin 18). (sin 42). sin 78
4 4 4
1 1 1
⇒ (sin 18). (sin 42). sin 78 = . sin 54∘
64 64 4
Allowed integral values of 'a' are
Hence a = 4 a = 1, 2, 3, 4, 5, 6, 7
4. Ans ( 9 )
N = 9 C4 × 5 C4 = 630
N 630
= =9
70 70

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 (0999DJA161103230027) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

MAJOR TEST
(Academic Session : 2023 - 2024)
28-04-2024

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. C B C B
Q. 5 6 7
SECTION-I (ii)
A. B,C,D B,C B,D
Q. 1 2 3 4
SECTION-II (i)
A. 16.00 2.00 4.00 2.00
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 40 3 2 2 3 1

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. C C B B
Q. 5 6 7
SECTION-I (ii)
A. B,C A,D A,C,D
Q. 1 2 3 4
SECTION-II (i)
A. 4.00 3.00 100.10 2.50
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 1435 7 7 7 2 19

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. A B B B
Q. 5 6 7
SECTION-I (ii)
A. A,B,C,D A,C A,C
Q. 1 2 3 4
SECTION-II (i)
A. 7.00 24.00 3360.00 60.00
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 3 27 25 9 5 2

HINT – SHEET
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (i) SECTION-I (ii)
4. Ans ( B ) 5. Ans ( B,C,D )
2I U = 5x(x – 4)
Pressure =
C dU
2IA ⇒F= – = – 10x + 20
Force = dx
C when a = 0 ⇒ x = 2m velocity is maximum
2IA
= Rxeq F = – 10x + 20 → SHM eqm
C
2IA 2IA m 0.1
xeq = Amplitude = T = 2π √ = 2π √ = π /5 sec
KC KC k 10
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6. Ans ( B,C ) 2. Ans ( 2.00 )
1 1
W = (0.9 × ρ ω ) × π (10 tan θ )2 × 10 w = w12 + w23 + w31 = (4P0 ) (2V0 ) + nRT ℓn (3) − P0 (8V0 )
3 2
1
B = ρω × π(9 tan θ)2 × 10
3 = −4P0 V0 + 9P0 V0 ℓn3 = (9ℓn3 − 4) P0 V0

n ( 3R . ΔT ) + Δw
ΔQ 2
C= =
nΔT nΔT
3R 4P0 V0
= +
2 nΔT
3R P V 3R R
⇒W>B&W=B+N&N=W–B = + 0 0 = + = 2R
2 n (2T0 ) 2 2
7. Ans ( B,D ) ΔQ123 = n (2R) (ΔT12 ) + (w23 )
dsin θ = x λ
xλ y = n (2R) (8T0 ) + nR (9T0 ) ℓn (3)
sin θ = =
d √y 2 + D2
x 2 λ2 y 2 x 2 λ 2 D2 = nRT0 (16 + 9ℓn3)
y2 = +
d2 d2 w 9ℓn3 − 4
xλD η= =( )
d ΔQ123 9ℓn3 + 16
y=
x 2 λ2
√ 1−
d2
PART-1 : PHYSICS
y
yact = SECTION-II (ii)
x 2 λ2
√ 1−
d2
5. Ans ( 40 )
⎛ ⎞
1 Δℓ1 ℓ1 ΔQ1 α
yact − y = y ⎜
⎜
− 1⎟
⎟ = × × 1
x 2 λ2 Δℓ2 ℓ2 ΔQ2 α2
⎝ √ 1− ⎠
d2 1 1 2 60
= × ×
PART-1 : PHYSICS 2 2 3 ΔQ

SECTION-II (i) Δ Q = 40°C

1. Ans ( 16.00 ) 6. Ans ( 3 )

w = w12 + w23 + w31 6P0 V0 4P0 V0 9P0 V0 6P0 V0
Q = CV ( − ) + CP ( − )
R R R R
1
= (4P0 ) (2V0 ) + nRT ℓn (3) − P0 (8V0 ) 3R 2P0 V0 5R 3P0 V0
2 Q= ( ) + ( )
2 R 2 R
= −4P0 V0 + 9P0 V0 ℓn3 = (9ℓn3 − 4) P0 V0
21P0 V0
3R
Q=
ΔQ n( . ΔT ) + Δw 2
2 3R 4P0 V0
C= = = +
nΔT nΔT 2 nΔT 7. Ans ( 2 )
3R P V 3R R di1
= + 0 0 = + = 2R E2 = M = 2ktM
2 n (2T0 ) 2 2 dt
ΔQ123 = n (2R) (ΔT12 ) + (w23 ) E 2ktM
i2 = 2 =
R R
T
= n (2R) (8T0 ) + nR (9T0 ) ℓn (3) kMT 2
2Mk
∫ dq = ∫ i2 dt = ∫ tdt =
= nRT0 (16 + 9ℓn3) R R
0

9ℓn3 − 4 λ 1 1
w ∴ =1⇒ λ= ⇒ =2
η= =( )
1−λ 2 λ
ΔQ123 9ℓn3 + 16
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8. Ans ( 2 ) 4. Ans ( B )
τ 1 = RC
L
τ2 =
R
⇒ LC = t1t2 = 0.1 sec
1
⇒ T = 2 π √LC = 2π √ = 2 sec.
10
9. Ans ( 3 )

mg sin θ + F – f1 = ma Due to non-equivalent R.S. have less electron

Q
mg sin θ – F – f2 = ma density between C − O bond
f1r = mr2 α PART-2 : CHEMISTRY
2 2
f2 r = mr α SECTION-I (ii)
5
f1 = ma, f2 = 2ma 5. Ans ( B,C )
5
Solve above equations to get F. 40 × At Q 3
(A) Compound 3 is P3O4 ⇒ =
At P × 60 4
PART-2 : CHEMISTRY At Q 9
∴ =
At P 8
SECTION-I (i) 44.4 × At Q 9 4
∴ Compound 2 ⇒ = ×
1. Ans ( C ) At P × 55.6 8 5

Rb & Cs have nearly same electron gain

∴ A is incorrect
enthalpy electron gain enthalpy = – 46 kj/ml 40 × At Q 3
Ar & Kr have same Δ Heq. Value is + 96 kj/ml. (B) Compound 3 is P3O2 ⇒ =
At P × 60 2
At Q 9
2. Ans ( C ) ∴ =
At P 4
According to Fajan's Rule, 9
∴ At Q = At Q = × 20 = 45
A. KF > KI - False ; LiF > KF - True 4
∴ B is correct
B. KF < KI - True ; LiF > KF - True
44.4 × AtQ 1
C. SnCl4 > SnCl2 ; True; CuCl > NaCl - True (C) Compound 2 is PQ ⇒ =
AtP × 55.6 1
D. LiF > KF - True ; CuCl < NaCl - False AtQ 55.6 5
∴ = ≃
E. KF < KI - True ; CuCl > NaCl - True AtP 44.4 4
50 AtQ 5
3. Ans ( B ) ∴ Compound 1 = P5Q4
AtP × 50 4
Zn = 1s2 2s2 2p6 3s2 3p6 3d10 4s2 'C' is correct.
ℓ = 0 ; 8 e– 50 50
(D) Compound np = nQ =
70 35
m = 0 ; 14 e – ∴ PQ2
n × ℓ × m = 0 ; 14 e –
ℓ×m
= 0 ; 14 e –
n
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6. Ans ( A,D ) 3. Ans ( 100.10 )
ΔTb = 1∘ Kb m
(x – 100) = 2 × 0.5 × 0.1
= 0.1
x = 100.1ºC
4. Ans ( 2.50 )
2AgNO3 + BaCl2 →
2AgCl(s) + Ba(NO3)2
0.1M, V ml 0.1M, V ml.
0.1V
0 ( )
2
0.1V
7. Ans ( A,C,D ) ( )
2
0.1
= M
4
0.1
M
4
0.1 0.1
ΔTb1 + ΔTb2 = 3 × 0.5 × + 3 × 0.5 ×
PART-2 : CHEMISTRY 4 4
= 0.075
SECTION-II (i)
1. Ans ( 4.00 ) New boiling point = 100.075
Overall reaction : Difference in b.p. = 100.1 – 100.075
Ca + 2C + N2 + 3H2O → 2NH3 + CaCO3
= 0.025
x mol 2 mol
1 1
Overall yield = × 1 × × 100 = 25% = 2.5 × 10 – 2
2 2
nNH3 prod. theoritically = 2x Y = 2.5
nNH3 prod. exp. = 2x × 25% = 2
PART-2 : CHEMISTRY
x = 4 mol
SECTION-II (ii)
2. Ans ( 3.00 )
80 5. Ans ( 1435 )
Moles of Ca = =2
40 AgNO3 + NaCl → AgCl + NaNO3
36
Moles of C = =3 1.7 g 5.85
12
170 mol 58.5
'C' is the limiting reagent 10 – 2 mol 10 – 1 mol
3
Moles of CaC2 formed in 1st reaction = × 0.5 L.R.
2
= 0.75 Moles of AgCl product = 10 – 2 mol
1 milligrams of AgCl product
moles of NH3 formed = 0.75 × 2 × = 0.75
2
molarity of NH4OH = 0.75
× 1000 = 3 M = 10 – 2 × 143.5 × 1000 = 1435 mg
250
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7. Ans ( 7 ) 2. Ans ( B )
rmix 32 Given ƒ(2) = 0
=√
r O2 Mmix.
loge (1 + 5f(x)) 0
1/10 32 ℓ = lim ( ) form
=√ x→2 e2f(x) − f(x) − 1 0
2/20 Mmix.
Use : L Hopital rule
Mmix = 32
5f ′ (x)
( )
1+5f(x) 5
Let mol % of butane in mixture = x% ℓ = lim = =5
x→2 2f ′ (x)e2f(x) − f ′ (x) 2−1

58x + 30 (100 − x) 3. Ans ( B )

32 =
100 ∣ α + α2 + 3 ∣
∣ ∣ = 2 √2
∣ √ 2 ∣
x = 7.14
α + α2 + 3 = 4
9. Ans ( 2 )
−1 + √5 −1 − √5
α2 + α – 1 = 0 ⇒ α = or
2 2

∴ α has only one value in first quadrant.

4. Ans ( B )
Assume (h, k) be the middle point of chord

∴ Its equation is

h k2 − h2
hx – ky = h2 – k2 ⇒ y = x+
k k
a
Now using c = , we get
m
k2 − h2 5
= .k
k h
Reaction have DBE value less than 4 are 2 & 5.
3 2
⇒ x = y (x – 5)
10. Ans ( 19 )
Gas 1, Gas 2, A and B respectively are SO2, ∴a=5
NO2, H2SO4, HNO3
PART-3 : MATHEMATICS
SECTION-I (i)

1. Ans ( A )
log2(4cosx – 4)2 = log2(2cosx)2
⇒ (4cosx – 4)2 = (2cosx)2

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PART-3 : MATHEMATICS 7. Ans ( A,C )
SECTION-I (ii) I + F = 15 + 224 n = nC0(15)n
( √ )

5. Ans ( A,B,C,D ) + nC1(15)n – 1 (√

1
224) +. . . . + n Cn (15)0 (√224)n
n
∣ c ∣ ∣ −b ∣ Let F ′ = (15 − √224)
| z1 z2 | = = 1 , | z1 + z2 | = ∣ ∣ =1
∣
a ∣ ∣ a ∣
= n C0 (15)n − n C1 (15)n−1 (√224)1 +. . . . .
⇒ (z1 + z2) × (z¯1 + ¯z2 ) = 1 ⇒ (z1 + z2) ⇒ I + F + F' = even
1 1 ⇒ 0 < F + F' < 2 ⇒ F + F' = 1
( + ) = 1
z2 z2
⇒ F' = 1 – F
⇒ (z1 + z2)2 = z1 z2 ⇒ I = odd and x(1 – F)
c
2 = (15 + √224)n (15 − √224)n = 1
⇒ ( −b ) = ⇒ b2 = ac
a a

θ
| z1 + z2 | = | z1 | ∣∣ 1 + eiθ ∣∣ = 2 cos =1⇒ θ PART-3 : MATHEMATICS
2
SECTION-II (i)
2π
=
3 1. Ans ( 7.00 )
θ Normal : (Given)
PQ = | z2 − z1 | = | z1 | ∣∣ eiθ − 1 ∣∣ = 2 sin
2

π 4x – 3y = 7 .... (1)
= 2 sin = √ 3.
3
x2 y2
Ellipse : + =1
6. Ans ( A,C ) 32 18

Let P(A) = x let point P : (x1, y1)

a2 x b 2 y
⇒ P(B) = 2x ∴ Normal : − = a2 − b 2
x1 y1
32x 18y
⇒ − = 14
Now P(A ∪ B) = P(A) + P(B) – P(A ∩ B) x1 y1

⇒ (32y1)x – (18x1)y = 14x1y1 .... (2)

= P(A) + P(B) – P(A).P(B) = x + 2x – 2x2
compare (1) & (2)
Now 0 ⩽ P(A ∪ B) ⩽ 1
32y1 −18x1 14x1 y1
= =
4 −3 7
⇒ 0 ⩽ 3x – 2x2 ⩽ 1
⇒ 8y1 = 6x1 = 2x1y1
1
⇒ x ∈ [0, ]
2
⇒ (x1, y1) ≡ (4, 3) Ans.
2
⇒ a+ =4
b 2. Ans ( 24.00 )
Area of ellipse = π ab = π √ 32 × 18 = 24 π

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3. Ans ( 3360.00 ) 6. Ans ( 27 )
The order of vowels does not change means, |z1 – i| = |z2 – i| = |z3 – i| = 2 = R
first u occurs, then i and then e must occur. The
8! ⇒ circumcentre is (0,1)
total number of arrangements is (since there
2!
are two l)
In each of these arrangements, vowels may
occur in 3! ways. Therefore the number of
arrangements in which u, i, e occurs in this
order is : z +z +z
8! 1 also 1 2 3 = i
× = 3360 3
2! 3!
4. Ans ( 60.00 ) ⇒ centroid is also (0,1)
Keeping u, i, e in their respective places, the
⇒ triangle is equilateral
number of arrangements is
2
5! R
h2 ( R+ )
(2 + 1)
2
= 60 2
2! Area = = = = 3 √3
√ 3 √ 3 √ 3
PART-3 : MATHEMATICS
7. Ans ( 25 )
SECTION-II (ii)

5. Ans ( 3 )
2 −x
Let (2 + √ 3)x =t

t + 1/t ≥ 14
t2 – 14t + 1 ≥ 0
t≤7–4 √ 3 or t ≥ 7 + 4 √ 3
xy = 2 is rectangular hyperbola & 8(x2 + y2) ≥ 2
⇒ t ≤ (2 + √3) – 2
is exterior of circle; shaded portion is given by
or t ≥ (2 + √ 3) 2
figure.
⇒ x2 – x ≤ – 2
2
2
x2 – x + 2 ≤ 0 Not possible always Area of portion OAB = 2 – ∫ dx = (2 − ℓn 4)
x
1
or x2 – x ≥ 2
Total area = 4 − ( π + 2 − ℓn4)
16
(x – 2)(x + 1) ≥ 0 π
2 + ℓn 4 −
16
x ∈ ( – ∞ , – 1] ∪ [2, ∞ )
a = – 1, b = 2
|a| + |b| = 3

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8. Ans ( 9 ) 9. Ans ( 5 )
Equation of the line through (0, 1, 2)

x−0 y−1 z−2

= = ....(1)
a b c

x−1 y−1 z−0

now given line is, 1
= =
2
= t ....(2)
−1

^
(2) is along the vector V→ = ^i − ^j + 2k.

Since (1) is perpendicular to (2)

hence, a – b + 2c = 0 ....(3) Clearly the domain of g (x) = sin−1 (f (|x|)) is

[– 2, 2]
since (1) and (2) intersect; hence must be coplanar
∣ 1 0 −2 ∣
⇒ g (x) is non-differentiable at x = – 2, – 1, 0,
∣ ∣

hence ∣
∣
1 −1 2 ∣
∣
=0 1, 2.
∣ ∣
∣ a b c ∣
∴ Number of non-derivable points are 5. Ans.
2a + 4b + c = 0 ....(4) 10. Ans ( 2 )
Equation of chord of contact w.r.t. P
solving (3) and (4), a : b : c = – 3 : 1 : 2
hx + ky = 1
x y−1 z−2
required equation is = = =t
−3 1 2

A point on this line is (x0, y0, z0) = (–3t, 1+t, 2 + 2t)

it satisfy the plane 2x + y + z = 6 therefore -6t + (1 + t)

+ (2 + 2t) = 6 Equation of common chord is

( λ – 3) x + (2 λ + 2)y + 3 = 0
Hence we get t = -1 and (x0, y0, z0) = (3, 0, 0)
λ−3 2λ + 2
⇒ = = −3
h k

⇒ Equation of locus is 6x – 3y – 8 = 0
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