pocket_colorimeter_ii
pocket_colorimeter_ii
POCKET COLORIMETER™ II
ANALYSIS SYSTEMS
INSTRUCTION MANUAL
Chlorine (Cl2)
© Hach Company, 2006. All rights reserved. Printed in the U.S.A. te/dk 09/06 3ed
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Laboratory Safety
As part of good laboratory practice, please familiarize yourself with the reagents
used in these procedures. Read all product labels and the material safety data
sheets (MSDS) before using them. It is always good practice to wear safety glasses
when handling chemicals. Follow instructions carefully. Rinse thoroughly if
contact occurs. If you have questions about reagents or procedures, please contact
the manufacturer or distributor.
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Precautionary Labels
Please pay particular attention to labels and tags attached to the instrument.
Personal injury or damage to the instrument could occur if not observed.
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Measuring Hints
• Analyze samples immediately. Do not use plastic containers to collect samples.
• For best results, dedicate a set of cells to each free chlorine and total chlorine test.
Note: The Pocket Colorimeter II is designed to measure solutions contained in sample cells.
DO NOT dip the meter in the sample or pour the sample directly into the cell holder.
* Adapted from Standard Methods for the Examination of Water and Wastewater.
** Procedure is equivalent to USEPA method 330.5 for wastewater and Standard Method
4500-Cl G for drinking water.
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1. Fill a 10-mL cell with 2. Press the POWER key to 3. Remove the meter cap.
sample (the blank). Cap. turn the meter on. Place the blank in the cell
Note: Samples must be The arrow should indicate holder with the diamond
analyzed immediately and the low range channel (LR). mark facing the keypad.
cannot be preserved for Note: See page 2—4 for Fit the meter cap over the
later analysis. information on selecting cell compartment to cover
the correct range channel. the cell.
Note: Wipe excess liquid
and finger prints off
sample cells.
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4. Press ZERO/SCROLL. 5. Fill a second 10-mL cell 6. Add the contents of one
The display will show to the 10-mL line with DPD Free Chlorine Powder
“- - - -” then “0.00”. sample. Pillow or one DPD Total
Note: Do not use the same Chlorine Powder Pillow to
Remove the blank from the
sample cells for free and the sample cell (the prepared
cell holder.
total chlorine analysis sample).
without thoroughly rinsing Note: SwifTest™
the cells with sample Dispensers for Free or Total
between free and total Chlorine can be used in
tests. place of powder pillows.
See Using the SwifTest™
Dispenser (USEPA accepted
for reporting) on page 1—
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7. Cap and shake gently for 8. For free chlorine, place 9. For total chlorine, place
20 seconds. the prepared sample cell in the prepared sample in the
Note: Shaking dissipates the cell holder. Cover with cell holder and cover the cell
bubbles that may form in the instrument cap and with the instrument cap.
samples with dissolved proceed to step 10 within Wait three to six minutes
gases. one minute after adding the after adding the DPD Total
DPD Free Pillow. Pillow.
Note: A pink color will
develop if chlorine is Note: Accuracy is not Proceed to step 10.
present. affected by undissolved
powder.
Note: Wipe off sample
cells.
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10. Press READ/ENTER. Note: If the sample temporarily turns yellow after reagent
The instrument will show addition, or if the display shows overrange (page 2—12) dilute
“- - - -” followed by the a fresh sample and repeat the test. A slight loss of chlorine
results in mg/L chlorine. may occur because of the dilution. Multiply the result by the
appropriate dilution factor.
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1. Fill a 10-mL sample cell 2. Press the POWER key to 3. Remove the instrument
with sample (the blank). turn on the meter. cap. Place the blank in the
Cap. Collect at least 40 mL The arrow in the display cell holder, with the diamond
of sample in a 50-mL should indicate the low mark facing the keypad.
beaker. range channel (LR). Cover the cell with the
Note: Empty AccuVac instrument cap.
See page 2—4 for
Ampuls are available for information on selecting the Note: Wipe liquid and
use as blanks. See correct range channel. finger prints off sample
OPTIONAL REAGENTS on cells.
page 1—47.
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4. Press ZERO/SCROLL. 5. Fill a DPD Free Chlorine 6. Quickly invert the ampule
The display will show Reagent AccuVac® Ampul or several times to mix. Wipe
“- - - -” then “0.00”. a DPD Total Chlorine off any liquid or fingerprints.
Remove the blank. Reagent AccuVac Ampul Note: A pink color will
with sample. form if chlorine is present.
Note: Keep the tip Note: Accuracy is not
immersed until the ampule affected by undissolved
fills completely. powder.
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7. For free chlorine, place 8. For total chlorine, insert 9. Press READ/ENTER. The
the prepared sample in the the ampule into the cell instrument will show
cell holder. Cover the ampule holder, then cover with the - - - - followed by the results
with the instrument cap and instrument cap. Wait three in mg/L chlorine.
proceed to step 9 within one to six minutes after filling
minute after filling the the AccuVac Ampul. Proceed
AccuVac Ampul. to step 9.
Note: Wipe liquid off the Note: Wipe liquid off the
AccuVac Ampul. AccuVac Ampul.
Note: If the sample temporarily turns yellow after reagent addition, or if the display shows
overrange (page 2—12) dilute a fresh sample and repeat the test. A slight loss of chlorine may
occur because of the dilution. Multiply the result by the appropriate dilution factor.
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1. Fill a 10-mL cell with 2. Press the POWER key to 3. Remove the meter cap.
sample (the blank). Cap. turn the meter on. Place the blank in the cell
Note: Samples must be The arrow should indicate holder with the diamond
analyzed immediately and the low range channel (LR). mark facing the keypad.
cannot be preserved for Note: See page 2—4 for Fit the meter cap over the
later analysis. information on selecting cell compartment to cover
the correct range channel. the cell.
Note: Wipe excess liquid
and finger prints off
sample cells.
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7. Cap and shake gently for 8. For free chlorine, place 9. For total chlorine,
20 seconds. the prepared sample cell in place the prepared sample
Note: Shaking dissipates the cell holder and cover in the cell holder and cover
bubbles that may form in with the instrument cap. with the instrument cap.
samples with dissolved Proceed to step 10 within Wait three to six minutes
gases. one minute after adding the after adding the DPD Total
DPD Free Pillow. Pillow.
Note: A pink color will
develop if chlorine is Note: Accuracy is not Proceed to step 10.
present. affected by undissolved
powder.
Note: Wipe off sample
cells.
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10. Press READ/ENTER. Note: If the sample temporarily turns yellow after reagent
The instrument will show - - addition, or if the display shows overrange (page 2—12) dilute
- - followed by the results in a fresh sample and repeat the test. A slight loss of chlorine
mg/L chlorine. may occur because of the dilution. Multiply the result by the
appropriate dilution factor.
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Method Performance
Estimated Detection Limit (EDL) = 0.02 mg/L
Typical precision (95% confindence interval) = 1.00 ± 0.05 mg/L
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Measuring Hints
• If the chlorine concentration is typically less than 2 mg/L, use the low range
procedure.
• Analyze samples immediately. Do not use plastic containers to collect samples.
For best results, dedicate a set of sample cells to each test (free and total).
• If the sample temporarily turns yellow after reagent addition or shows
overrange (page 2—12), dilute a fresh sample and repeat the test. A slight loss
of chlorine may occur. Multiply the result by the dilution factor.
* Adapted from Standard Methods for the Examination of Water and Wastewater.
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Note: The Pocket Colorimeter II is designed to measure solutions contained in sample cells.
DO NOT dip the meter in the sample or pour the sample directly into the cell holder.
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1. Fill a 1-cm/10-mL cell 2. Press the POWER key to 3. Remove the meter cap.
with sample (the blank). Cap. turn the meter on. Place the blank into the
Note: Samples must be The arrow should indicate the cell holder, with the
analyzed immediately and high range channel (HR). diamond mark facing the
cannot be preserved for later back of the cell holder.
Note: See page 2—4 for
analysis. Cover the cell with the cap.
information on selecting the
correct range channel. Note: Wipe liquid off
sample cells.
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7. For free chlorine, place the 8. For total chlorine, place the 9. Press READ/ENTER.
prepared sample cell in the cell prepared sample in the cell The instrument will
holder and cover with the holder and cover with the show “- - - -” followed by
instrument cap within one instrument cap. Wait three to the results in mg/L chlorine
minute after adding the DPD six minutes after adding the (Cl2).
Free Pillow. DPD Total Pillows. Proceed to
Proceed immediately to step 9.
step 9. Note: Wipe off sample cells.
Note: The SwifTest™ Dispenser
can be used in place of the
powder pillow (see page 1—36).
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1. Fill a 1-cm/10-mL cell 2. Press the POWER key to 3. Remove the meter cap.
with sample (the blank). Cap. turn the meter on. Place the blank into the cell
Note: Samples must be The arrow should indicate the holder, with the diamond
analyzed immediately and high range channel (HR). mark facing the back of the
cannot be preserved for later cell holder. Cover the cell
Note: See page 2—4 for
analysis. with the cap.
information on selecting the
correct range channel. Note: Wipe liquid off sample
cells.
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7. For free chlorine, place the 8. For total chlorine, place the 9. Press READ/ENTER.
prepared sample cell in the cell prepared sample in the cell The instrument will show
holder and cover with the holder and cover with the “- - - -” followed by the
instrument cap within one instrument cap. Wait three to results in mg/L chlorine (Cl2).
minute after adding the DPD six minutes after adding the
Free Pillow. DPD Total Pillows. Proceed to
Proceed immediately to step 9.
step 9. Note: Wipe liquid off sample
Note: Wipe liquid off sample cells.
cells.
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Method Performance
Estimated Detection Limit (EDL) = 0.1 mg/L
Typical precision (95% confidence interval) = 5.0 ± 0.2 mg/L
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Note: Before proceeding, make sure the instrument is in the low (LR) range channel. See
Switching Ranges on page 2—4.
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Menu Selections
Press the MENU key to access the menu selections.
Switching Ranges
1. Press the MENU key. The display will show “SEL”. A flashing arrow indicates
the current range.
2. Press the READ/ENTER key to toggle between ranges.
3. Press MENU again to accept and exit back to the measurement screen.
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Note: The Low Battery icon will appear on the display when the batteries have 10% battery life
remaining. The battery icon will flash when the batteries are too low to complete
measurements. See Instrument Keys and Display on page 1—11.
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Error Messages
1. E-0 No Zero (User mode)
Error occurs when trying to read a standard in the user calibration mode
before setting the meter to zero.
•
Zero the instrument on an appropriate blank.
2. E-1 Ambient Light Error
There is too much light present to take a valid measurement.
• Verify instrument cap is correctly seated.
• If the problem persists, contact a Service Center (page 2—37).
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Note: For meters with factory-calibrated ranges or methods, Standard Calibration Adjust
(SCA) will be disabled when a user-entered method is programmed into the meter. To
turn SCA back on, restore the meter to factory default calibration.
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International Customers
Hach maintains a worldwide network of dealers and distributors. To locate the
representative nearest you, send E-mail to intl@hach. com or call (970) 669-3050.
In Canada
Hach Instrument Service Centre, Winnipeg, Manitoba, Canada
Telephone: (204) 632-5598; (800) 665-7635
FAX: (204) 694-5134
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