Contents

Deloro Stellite
PROCESS OVERVIEW

HARDFACING ALLOYS DIVISION

TIG & OXY-ACETYLENE WELDING MMA WELD DEPOSITION MIG WELD DEPOSITION PTA & LASER WELD DEPOSITION HVOF & PLASMA SPRAY DEPOSITION SPRAY AND FUSE & POWDER WELDING

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

Deloro Stellite Worldwide

Deloro Stellite is a global provider of solutions to wear, heat and corrosion problems and is a world class manufacturer of alloy-based materials and components. Deloro Stellite was originally founded in 1917 in the small Canadian town of Deloro, Ontario and today has grown to operate in 10 locations worldwide. The combination of experience, product innovation, and worldwide reach makes Deloro Stellite the number one choice in providing answers to the toughest of problems.

Hardfacing Alloys Division and Coating Services Division

The manufacturing of Deloro Stellite welding consumables spans the globe with strategic locations in the UK, USA and in Shanghai, China. These consumables come in the form of rod, wire, powder and electrode and can be custom engineered to meet individual customer needs. At Deloro Stellite, we do not just produce products, we produce customer solutions.

Shanghai, PRC

Swindon, UK Goshen, Indiana, USA

Contents

In addition to welding consumables, Deloro Stellite also offers its expertise and experience in coating services in the form of HVOF (High Velocity Oxy Fuel) coatings and weld hardfacings. In the UK and in Shanghai, hardfaced components can be manufactured complete to drawing by in-house machine shops.

4-5 6-7 8-9

AT A GLANCE

TIG & OXY-ACETYLENE WELDING

MMA WELD DEPOSITION

Industries Served
Deloro Stellite offers its proven heat, wear and corrosion experience and customized solutions to a broad range of industries, including: Aerospace Oil & Gas Automotive Power Generation Steel Timber Glass Forging Dental

10-11 12-15 16-19 20-22

MIG WELD DEPOSITION

PTA & LASER WELD DEPOSITION

HVOF & PLASMA SPRAY DEPOSITION

SPRAY AND FUSE & POWDER WELDING

For more information visit: www.stellite.com

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

Deloro Alloys
The Deloro alloys are nickel based with additions of typically Cr, C, B, Fe and Si. They cover a very wide range of hardness from soft, tough, build-up alloys that are easily machined or hand finished to exceptionally hard, wear resistant alloys. They can be selected for hardnesses of between 20 and 62 HRC depending on the application. Their low melting point makes these powders ideal for spray/fuse or powder welding applications. The lower hardness Deloro alloys are typically used for glass forming molds. The higher hardness Deloro alloys are used in severe wear applications such as rebuilding the flights of feeder screws, and they can be blended with carbides for an even harder deposit. They maintain their properties up to temperatures of about 315C (600F) and also offer good oxidation resistance.

Stellite Alloys
The cobalt-based Stellite alloys are our most well-known and successful alloys, with the best all-round properties. They combine excellent mechanical wear resistance, especially at high temperatures, with very good corrosion resistance. The Stellite alloys are mostly cobalt based with additions of Cr, C, W and/or Mo. They are resistant to cavitation, corrosion, erosion, abrasion and galling. The lower carbon alloys are generally recommended for cavitation, sliding wear or moderate galling. The higher carbon alloys are usually selected for abrasion, severe galling, or low angle erosion. Stellite 6 is our most popular alloy as it provides a good balance of all of these properties. The Stellite alloys retain their properties at high temperatures where they also have excellent oxidation resistance. They are typically used in the temperature range 315-600C (600-1112F). They can be finished to exceptional levels of surface finish with a low coefficient of friction to give good sliding wear.

Tribaloy Alloys
Tribaloy alloys, with either a nickel or cobalt base, were developed for applications in which extreme wear is combined with high temperatures and corrosive media. Their high molybdenum content accounts for the excellent dry-running properties of Tribaloy alloys and makes them very suitable for use in adhesive (metal-to-metal) wear situations. Tribaloy alloys can be used up to 800-1000C (1472-1832F).

AT A GLANCE

Nistelle Alloys
Nistelle alloys are designed for corrosion resistance rather than wear resistance, particularly in aggressive chemical environments where their high chromium and molybdenum contents provide excellent pitting resistance. As a class, they are also generally resistant to high temperature oxidation and hot gas corrosion. Care should be taken to select the correct alloy for any given corrosive environment.

Jet Kote Powder

Jet Kote powders are used for thermal spraying and they usually consist of either a carbide-metal combination (e.g., WC-Co or Cr3Cr2-NiCr) or a Stellite alloy.

Delcrome Alloys
These iron-based alloys were developed to resist abrasive wear at lower temperatures, typically up to 200C. When compared with our cobalt- and nickel-base alloys, their corrosion resistance is also comparatively low.

Stelcar Alloys
Stelcar alloys are mixtures of carbide particles and nickel- or cobalt-based powders. Due to their construction, Stelcar materials are available only in powder form, for application by thermal spraying or weld hardfacing.

Selection Table

Alloy Stellite Deloro Tribaloy Nistelle

Mechanical Wear

Corrosion

High Operating Temperature

Low resistance Satisfactory resistance Very good resistance Excellent resistance

Delcrome Stelcar Jet Kote

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

Shielding Gas Nozzle

Tungsten Electrode Contact Tube

TIG and Oxy-Acetylene Welding

In TIG (Tungsten Inert Gas) aka Gas Tungsten Arc Welding (GTAW), an arc is drawn between a non-consumable tungsten electrode and the workpiece. The electrode, the arc and the weld-pool are protected from the atmosphere with an inert shielding gas. The hardfacing material is in the form of a rod. Advantages of the TIG process include simple manual operation and good control of the welding arc. The process can also be mechanised, in which case a manipulator is used to move the workpiece in relation to the welding torch and the hardfacing rod or wire. Welding rods used for TIG Welding are also used for hardfacing with the oxy-acetylene welding process. With the correct operation, a very low level of iron dilution can be achieved in the overlay. Rod is available in these standard diameters: 2.6 mm (3/32) (special order) 3.2 mm (1/8) 4.0 mm (5/32) 5.0 mm (3/16) 6.4 mm (1/4) 8.0 mm (5/16) Shielding Gas

Arc

Consumable

Rod inventory held in North America is typically in 36 lengths. In other countries (also available to Special Order in the USA and Canada) rod is available in these standard lengths: 350mm (14) 500mm (20) 970-1000 mm (38-40 or 3.2-3.3 ft) 1.2 metres (approx. 4 ft or 47) 1.5 metres (approx. 5 ft or 60) 2 metres (approx. 6.5 ft) 4 metres (approx. 13 ft). Rod inventory held in North America is typically packaged in 20lb bundles. Elsewhere, rod is packaged in 10kg (22lb) bundles for the shorter lengths, while longer lengths or larger diameters may be bundled in 25kg (55lb) bundles. Rod can also be bundled to customer requirement.

TIG AND OXY-ACETYLENE WELDING

ALLOY NOMINAL ANALYSIS OF WELDING ROD1 Co
Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. <1.5 Bal. Bal.

Cr
32 30 30 33 28 28 20 26 26 31 27 28 28 31 31 26 17 21 12 12 12 13 8.5 14 17 16 18 18

W
12 4-5 8 16 14 7.5 12 4 13.5 19 2 5

C
2.45 1.2 1.55 2.45 0.25 0.30 0.1 0.5 1.7 2 3.2 0.1 1 1.2 1.55 0.06 0.1 <0.10 0.4 0.5 0.6 0.7 <0.08 <0.08 0.2 <0.08 <0.08 <0.08

Ni
<3.0 <3.0 <3.0 <3.0 3 1.5 10 10 22 24 <1 5 <3.0 <3.0 9 Bal. Bal. Bal. Bal. Bal. Bal. <1.5 <1.5 <1.5 Bal. <1.5 16

Mo
<1.0 <1.0 <1.0 <1.0 5.2 12 <1.0 <1.0 <1.0 4 8 5 17 8.5 28 27 22 32 28 22

Fe
<3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <2.0 <3.0 <2.0 <3.0 21 <3.0 <3.0 <3.0 3 6 <5 2-3 3-5 3-5 3-5 <1.5 <1.5 <1.5 <1.5 <1.5

Si
<2.0 <2.0 <2.0 <2.0 <1.5 <2.0 <1.0 <1.0 <2.0 <3.0 1.0 <1.0 1 <1.0 <2.0 2.9 3.5 4.0 4.3 2.5 2.6 1.3 3.4 3.4 2.7

Others

UNS

ASME/ AWS2
(SF)A 5.21 ERCoCr-C (SF)A 5.21 ERCoCr-A (SF)A 5.21 ERCoCr-B (SF)A 5.21 ERCoCr-E (SF)A 5.21 ERCoCr-F (SF)A 5.21 ERCoCr-G

Hardness (HRC)3
51-56 40-45 46-51 53-59 28-40 * 41-49 * 20-45 * 20-35 * 40-45 38-47 54-59 20-28 48-54 39-44 46-51 28-45 * 17-27 *

COBALT BASE ALLOY BARE WELDING RODS

Stellite alloy 1 Stellite alloy 6 Stellite alloy 12 Stellite alloy 20

<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1%V <1.0 <1.0 <1.0 0.3% V 3.3% 1.6% B 2.2% B 2.3% B 3.0% B

R30001 R30006 R30012 R30021 R30031 R30002 R30014 R31233 N30002 N06625 N99644 N99645 N99646 R30400

Stellite alloy 21 Stellite alloy 22 Stellite alloy 25

Stellite alloy 31 Stellite alloy F

Stellite alloy 107 Stellite alloy 190 Stellite alloy 250 Stellite alloy 694 Stellite alloy 706 Stellite alloy 712 ULTIMET ** Nistelle alloy C Nistelle alloy 625

NICKEL BASE ALLOY BARE WELDING RODS

(SF)A 5.14 ERNiCrMo-3 (SF)A 5.21 36-42 ERNiCr-A (SF)A 5.21 48-55 ERNiCr-B (SF)A 5.21 ERNiCr-C 52-57 57-62 54-58 54-59 47-53 50-58 55-60 52-57

Deloro alloy 40 Deloro alloy 50 Deloro alloy 55

Deloro alloy 60 Tribaloy alloy T-400 Tribaloy alloy T-400C

INTER-METALLIC LAVES PHASE ALLOY WELDING RODS (TRIBALOY ALLOYS)

<1.0 <1.0 <1.0 <1.0 <1.0 <1.0

Tribaloy alloy T-401 Tribaloy alloy T-700 (Ni based) Tribaloy alloy T-800

Tribaloy alloy T-900

Nominal analysis is a guideline only for standard product, does not include all incidental elements and may differ depending on the exact specification/standard used when ordering. When written certification to a standard is required, please specify this when ordering. Certain products can also be certified to AMS, SAE and other standards. Please contact us for more details. Undiluted weld metal

* depending upon the degree of work hardening ** ULTIMET is a registered trademark of Haynes International.

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

Manual Metal Arc (MMA) Weld Deposition

In this process an arc is drawn between a coated consumable electrode and the workpiece. The metallic core is melted by the arc and is transferred to the weld pool as molten droplets. The electrode coating also melts to form a gas shield around the arc and the weld pool as well as a slag on the surface of the weld pool, thus protecting the cooling weld-pool from the atmosphere. The slag must be removed after each layer. Manual Metal Arc welding is still a widely used hardfacing process. Due to the low cost of the equipment, the low operating costs of the process and the ease of transporting the equipment, this flexible process is ideally suited to repair work.

Core Wire Electrode Holder

Coated Electrode

Arc

MMA WELD DEPOSITION

ALLOY

NOMINAL ANALYSIS OF UNDILUTED WELD METAL4 Co Cr W C Ni Mo Fe Si

Others

UNS

ASME/ AWS5

Hardness (HRC)6

COBALT BASE ALLOY ELECTRODES

Stellite alloy 1

Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal.

31 29 30 32 28 20 28 30 30 26

12 4 8 16 14 2

2.45 1.2 1.55 2.45 0.25 0.1 0.1 1.2 1.55 0.06

<3.0 <3.0 <3.0 <3.0 3 10 <3.0 <3.0 9

<1.0 <1.0 <1.0 <1.0 5.5 <1.0 4 8 5

<3.0 <3.0 <3.0 <3.0 <3.0 <3.0 21 <3.0 <3.0 3

<2.0 <2.0 <2.0 <2.0 <1.5 <1.0 <1.0 <1.0 <2.0

<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0

W73001 W73006 W73012 W73021

Stellite alloy 6 Stellite alloy 12 Stellite alloy 20 Stellite alloy 21 Stellite alloy 25 Stellite alloy 250 Stellite alloy 706 Stellite alloy 712 ULTIMET **

(SF)A 5.13 ECoCr-C (SF)A 5.13 ECoCr-A (SF)A 5.13 ECoCr-B (SF)A 5.13 ECoCr-E

51-56 39-43 45-50 53-57 28-40 * 20-45 * 20-28 * 39-44 46-51 28-45 *

NICKEL BASE ALLOY ELECTRODES

Nistelle alloy C 17 5 0.1 Bal. 17 6 0.3%V W80002 17-27*

Nominal analysis is a guideline only for standard product, does not include all incidental elements and may differ depending on the exact specification/standard used when ordering. When written certification to a standard is required, please specify this when ordering. Certain products can also be certified to AMS, SAE and other standards. Please contact us for more details. Undiluted weld metal

Electrodes are available in these standard diameters: 2.6 mm (3/32) (special order) 3.2 mm (1/8) 4.0 mm (5/32) 5.0 mm (3/16) 6.4 mm (1/4) Electrodes are supplied in lengths of 350mm (14) and are boxed in 5.0kg (11 lb) boxes. Depending upon the process parameters, the hardness of the welded deposit can vary from the values provided in the above table. * depending upon the degree of cold-working ** ULTIMET is a registered trademark of Haynes International.

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

MIG Weld Deposition, Submerged Arc Welding

In these arc welding processes, consumable hardfacing wire is fed continuously from a spool through the welding torch into the arc, where it is melted and transferred to the workpiece. In the case of MIG welding, also known as Gas Metal Arc Welding (GMAW) the weld pool is protected from the atmosphere by a stream of shielding gas. The MIG process is very flexible, i.e. it can be partially or fully mechanised and is suitable for a wide range of applications. Wire is also used as the hardfacing consumable in the Submerged Arc Welding (SAW) process. In this process, a mineral-based fluxing powder flows around the consumable wire and is melted by the arc. It forms a gaseous shield around the arc and also forms a slag on top of the weld pool, shielding the cooling weld pool from the atmosphere.

Wire-Feed Mechanism Hardfacing Wire

Shielding Gas Nozzle

Contact Tube

Arc

Shielding Gas

10

MIG WELD DEPOSITION

ALLOY Co NOMINAL ANALYSIS OF UNDILUTED WELD METAL7 Cr W C Ni Mo Fe Si Others UNS ASME/ AWS8 Hardness (HRC)9

COBALT BASE ALLOY CORED WIRE

Stellite alloy 1 Stellite alloy 6 Stellite alloy 12 Stellite alloy 21 Bal. Bal. Bal. Bal. 28 30 29 28 11.5 4.5 8 2.45 1.2 1.55 0.25 <3.0 <3.0 <3.0 3 <1.0 <1.0 <1.0 5.2 <5.0 <5.0 <5.0 <5.0 <2.0 <2.0 <2.0 <1.5 <1.0 <1.0 <1.0 <1.0 W73031 W73036 W73042 W73041 (SF)A 5.21 ERCCoCr-C (SF)A 5.21 ERCCoCr-A (SF)A 5.21 ERCCoCr-B (SF)A 5.21 ERCCoCr-E 50-55 38-44 45-50 28-40 *

Stellite alloy 21 LC

Bal.

26

0.1

6.0

<5.0

<1.5

<1.5

Proprietary crack resistant alloy specially developed for hardfacing of forging dies R31233

25-40 *

Stellite alloy 25 Stellite alloy 250

Bal. Bal. Bal. Bal. Bal.

20 28 31 31 26

14 2

0.1 0.1 1.2 1.55 0.06

10 <3.0 <3.0 9

<1.0 4 8 5

<3.0 21 <3.0 <3.0 3

<1.0 <1.0 <1.0 <2.0

<1.0 <1.0 <1.0 <1.0 <1.0

20-45 * 20-28 39-44 46-51 28-45 *

Stellite alloy 706 Stellite alloy 712 ULTIMET **

NICKEL BASE ALLOY CORED WIRE

Nistelle alloy C

17 10 12 13

0.1 0.4 0.5 0.7

Bal. Bal. Bal. Bal.

17

6 2-3 3-5 3-5

2.9 3.5 4.3

0.3%V 1.6% B 2.2% B 3.0% B

N30002 W89634 W89635 W89636

(SF)A 5.21 ERNiCr-A (SF)A 5.21 ERNiCr-B (SF)A 5.21 ERNiCr-C

17-27* 35-40

Deloro alloy 40 Deloro alloy 50 Deloro alloy 60

47-52 56-61

INTER-METALLIC LAVES PHASE ALLOY CORED WIRE (TRIBALOY ALLOYS)

Tribaloy alloy T-401
7

Bal.

17

0.2

<1.5

22

<1.5

1.3

46-52

Nominal analysis is a guideline only for standard product, does not include all incidental elements and may differ depending on the exact specification/standard used when ordering. When written certification to a standard is required, please specify this when ordering. Certain products can also be certified to AMS, SAE and other standards. Please contact us for more details. Undiluted weld metal. Please note that the hardness of the Deloro Ni-based alloys is very sensitive to dilution.

Wire is available in the following standard diameters: 1.2 mm (0.045) supplied in 15kg (33lb) spools 1.6 mm (0.062) supplied in 15kg (33lb) spools 2.4 mm (0.093) typically supplied in 25kg (55lb) spools (optionally in 15kg spools) 3.2 mm (0.126) (special order) supplied in 25kg (55lb) spools Depending upon the process parameters, the hardness of the welded deposit can vary from the values provided in the above table. ** ULTIMET is a registered trademark of Haynes International.
11

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

PTA Weld Deposition

The Plasma Transferred Arc process is easily automated, providing a high degree of reproducibility of the weld overlays. In addition, because of the highly concentrated heat source, this process benefits from high powder utilisation and can achieve a very low level of iron dilution in the overlay. Because the hardfacing materials are in powder form, it is possible to produce overlays from many different materials and combinations of materials with a wide range of hardness and other properties.

Tungsten Electrode

Plasma Gas Nozzle Powder Nozzle Shielding Gas Nozzle

Water Cooling Arc Shielding Gas

Powder

12

PTA & LASER WELD DEPOSITION

Laser Weld Deposition

When overlaying with a laser an optical arrangement is used to focus the laser beam on the workpiece and heat it. Simultaneously, hardfacing material in the form of powder or wire is introduced into the laser beam and melted. Due to the narrow heat-affected zone and the fast cooling rate, the heat input is low, thereby producing an almost stress free overlay. Compared with other welding processes, for a given hardfacing alloy, the fast cooling rate of the laser process produces an overlay with a significantly higher hardness and finer microstructure. Laser Head Shielding Gas Nozzle

Shielding Gas Nozzle Laser Light Shielding Gas Powder Powder Nozzle

13

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N
ALLOY NOMINAL ANALYSIS OF POWDER1 Co
Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. <2.0 1.5 <2.0

Cr
30 30 28.5 29 28.5 28 30 32.5 27.5 28 20 26 26 26 28 28.5 29 29 26 8.5 14 17 17 18 23 17 16 21.5 15.5 22 42 20 15.5 21.5 21.5

W C Ni Mo Fe Si COBALT BASE ALLOY (GAS ATOMIZED POWDERS)

13 13.5 4.6 4.5 4.6 4 8.5 17.5 15 7.5 12.5 14 <1.0 19.5 2 4.5 3 3.7 <1.0 3 2.5 0.7 1.2 1.1 1.35 1.7 1.45 2.55 0.25 0.30 0.1 0.5 1.8 3.4 0.1 0.9 1.25 2.0 0.07 <0.08 <0.08 0.2 <0.08 <0.08 0.1 0.1 0.15 <1.0 <2.0 <2.5 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.6 1.5 10 10.5 22 <2.0 <1.0 5 <2.0 <2.0 9.4 <1.5 <1.5 <1.5 <1.5 16 Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 5.4 12 <1.0 <1.0 <1.0 <1.0 <1.0 4.5 8.5 5 29 27 22 29 23 18 17 16 13.5 16 9.1 9 13.5 <2.0 <2.5 <2.0 <2.0 <2.0 <0.5 <2.0 <2.0 <2.0 <3.0 2 <2.0 <2.0 <2.0 20 <3.0 <2.0 <2.0 3 <1.5 <1.5 <1.5 <1.5 <1.5 <1.0 6 <1.0 4 5.5 18.5 8 <1.0 4 <2.0 <1.0 <2.0 <2.0 <2.0 <2.0 <2.0 <1.0 <2.0 <2.0 <1.0 <1.0 1.1 <1.0 <1.5 <1.0 <1.0 <1.0 <1.0 2.8 2.6 1.3 3.7 2.8 <1.0 <1.0 <1.0 <1.0 <1.0 0.5 <1.0 <0.5 <0.5

Others

UNS

Hardness (HRC)2
51-60 40-50 40-46 38-44 43-53 46-54 43-53 52-62 27-40 * 41-49 * 20-45 * 20-35 * 40-45 55-60 20-28 46-52 39-44 46-53 20-45 * 51-57 51-57 45-50 53-61 48-55 15-25 * 17-27 *

Stellite alloy 1 Stellite alloy 4

<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <0.5 1.9%Mn <0.5 <0.5 <1.0 <1.0 1% V <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 0.3% V 0.15% V 0.15% V <1.0% <1.0% <1.0% <1.0% 3.5% Nb 0.15%V

R30001 R30404 R30106 R30012 R30021 R30031 R30002 R30014 R31233 R30400 N06455 N06002 N06600 N06625 N07718

Stellite alloy 6 Stellite alloy 6LC Stellite alloy 6HC

Stellite alloy 156 Stellite alloy 12 Stellite alloy 20

Stellite alloy 21 Stellite alloy 22 Stellite alloy 25

Stellite alloy 31 Stellite alloy F

3

Stellite alloy 190 Stellite alloy 250 Stellite alloy 694 Stellite alloy 706

Stellite alloy 712 ULTIMET ** Tribaloy alloy T-400

COBALT BASE TRIBALOY ALLOYS (GAS ATOMIZED POWDERS)

Tribaloy alloy T-400C Tribaloy alloy T-401 Tribaloy alloy T-800 Tribaloy alloy T-900 Nistelle alloy Super C Nistelle alloy C

NICKEL BASE SUPERALLOYS (GAS ATOMIZED POWDERS)

Nistelle alloy C4C Nistelle alloy C22 Nistelle alloy C276

Nistelle alloy X Nistelle alloy 305 Nistelle alloy 2315

Nistelle alloy 600 Nistelle alloy 625 Nistelle alloy 718

Nominal analysis is a guideline only for standard product, does not include all incidental elements and may differ depending on the exact specification/standard used when ordering. Undiluted weld metal Stellite Alloy F usually made to customer specification

2 3

* depending on the degree of work hardening ** ULTIMET is a registered trademark of Haynes International.
14

PTA & LASER WELD DEPOSITION

ALLOY Co
Deloro alloy 22

NOMINAL ANALYSIS OF POWDER1 Cr

9 7.5 9 11 12 15 21

Others Fe
<1.0 2.3 0.5 2.5 2.5 3.3 4.0 4.0 <1.0

UNS

C
<0.05 0.2 0.05 0.3 0.35 0.05 0.45 0.6 0.7 1.3

Ni
Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal.

Mo
6

Si
2.5 3.2 3.0 3.5 3.7 3.7 3.9 4.0 4.4 3.0 1.4%B 1.2%B 2.1%B 1.7%B 1.9%B 1.9%B 2.3%B 2.7%B 3.1%B 2.3%B N99644 N99645 N99646

Hardness (HRC)2

NICKEL BASE HARDFACING ALLOYS (GAS ATOMIZED POWDERS)

15 20-22 27-31 35-39 38-42 44-47 32-40 48-52 52-57 57-62

Deloro alloy 30 Deloro alloy 38 Deloro alloy 40 Deloro alloy 45 Deloro alloy 46 Deloro alloy 50 Deloro alloy 55

Deloro alloy 60 Extrudalloy 50

NICKEL BASE TRIBALOY ALLOYS (GAS ATOMIZED POWDERS)

Tribaloy alloy T-700

<1.5

16

0.08

Bal.

32

<1.5

3.4

<1.0

45-52 Depends on heat treatment 55-63 <180 DPH <180 DPH 47-51

IRON BASE HARDFACING ALLOYS (GAS ATOMIZED POWDERS)

Delcrome 90 Delcrome 92 Delcrome 253

<0.5 <0.5 <0.5 <0.5 12 <0.5

27 <1.0 28 17 18 35 25

2.9 3.8 1.9 0.05 <0.03 3.1 2.5

<1.0 16.5 11 13 10 14

10 4.5 2.6 2.6 7

Bal. Bal. Bal. Bal. Bal. Bal. Bal.

<1.0 <1.0 1.3 2.5 1.8 4.8 1.8

0.5%Mn <1%Mn 0.8%Mn 0.4%Mn 0.7%Mn 0.3%Mn <1.0%

Delcrome 316 Delcrome 316L Delcrome 317

Tristelle TS-3 Delcrome 6272

CARBIDES IN A CORROSION RESISTANT HARD ALLOY MATRIX

Super Stelcar alloy 9365 Super Stelcar alloy 50 plus

WC in an alloy matrix WC in a Deloro 50 alloy matrix WC in a Deloro 60 alloy matrix

Super Stelcar alloy 60 plus

PTA and laser hardfacing powders are available in these standard powder particle size ranges and custom sizes upon request. WM WE E G HK
2

53-180m 63-180m 53-150m 38-125m 63-210m

Undiluted weld metal Depending upon the process parameters and extent of dilution, the hardness of the weld deposit may vary from that provided in the above table.

15

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

Plasma Spraying
In the Plasma Spraying process powder is softened or melted in the plasma gas stream, which also transfers the particles to the workpiece. The plasma arc is not transferred to the workpiece, it is contained within the plasma torch between an axial electrode and a water-cooled nozzle. The process is operated in normal atmosphere, in a shielding gas stream (e.g., argon), in a vacuum or under water. Due to the high temperature of the plasma gas stream the Plasma Spray process is especially suitable for spraying high melting-point metals as well as their oxides. Powder Delivery Powder Flame

Plasma Gas Delivery

Electrode Water Cooling

16

HVOF & PLASMA SPRAY DEPOSITION

High Velocity Oxy-Fuel Spray (HVOF)

In the High Velocity Oxy-Fuel process, powder is introduced axially into a chamber in which a gas flame is constantly burning under high pressure. The exhaust gas exits through an expansion nozzle which produces a high velocity gas stream. The powder particles are heated in this gas stream and transferred by it with high kinetic energy to the surface of the workpiece, forming a dense coating with excellent bonding properties. Due to the moderate transfer of heat to the powder particles and to the workpiece, which remains relatively cool, there is little metallurgical change to the sprayed material and the workpiece.

Powder Delivery Spray Nozzle

Flame

Water Cooling Fuel Gas Delivery

17

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N
TUNGSTEN CARBIDE HVOF POWDERS PRODUCT JK112H JK112P POWDER TYPE WC-12Co
NOMINAL COMPOSITION (mass %)

Co 12 12

Ni

Cr

W Bal. Bal.

C 5.5 5.5

(depends on deposition method & parameters)

HARDNESS

Nominal size (m) and manufacturing method 53/10 Agglomerated, sintered & densified. 45/10 Agglomerated, sintered & densified. 45/10 Agglomerated, sintered & crushed. 53/15 Agglomerated & sintered. 45/5 Sintered and crushed, blocky. 45/5 Agglomerated, sintered & densified. 53/10 Agglomerated, sintered & densified. 53/10 Agglomerated sintered & densified. 53/10 Sintered and crushed. Nominal size (m) and manufacturing method 53/10 Agglomerated, sintered & densified.

with fine carbides

1140-1296 DPH 92.7-94.6 R15N 960-1150 DPH 89-93 R15N

(Also sold as JK7112)

WC-12Co

with fine carbides

(equiv. to HRC: ~67-71)

JK114

(Also sold as JK7114)

WC-12Co WC-17Co

with coarse carbides

12

Bal.

1000-1150 DPH 87-94 R15N 960-1240 DPH 90-95 R15N 860-1170 DPH 89-94 R15N

(equiv. to HRC: ~68-71)

JK117

(Also sold as JK7117)

with intermediate sized carbides

17

Bal.

5.2

(equiv. to HRC: ~67-72)

JK119

WC-9Co

with coarse carbides

Bal.

4.2

(equiv. to HRC: ~65-71)

JK120H

(Also sold as JK7109)

WC-10Co-4Cr

10

Bal.

5.4

1160-1370 DPH 93-95 R15N 825-1030 DPH 89-91 R15N 900-1100DPH 89-92 R15N

(equiv. to HRC: ~71-73)

JK120P JK125

(Also sold as JK7109)

WC-10Co-4Cr nickel 70%(W, Cr)xCy 25%WC 6%Ni WC 10Ni

with large carbides

10 6 10

4 20

Bal. Bal. Bal.

5.4 5 3.7

(equiv. to HRC: ~65-71)

A mixed carbide with

(Also sold as JK7175, 7176)

(equiv. to HRC: ~66-70)

JK6189

Not available

CHROMIUM CARBIDE HVOF POWDERS PRODUCT JK135 POWDER TYPE 75% Cr3C2 25% NiCr
NOMINAL COMPOSITION (mass %)

Ni 20

Cr Bal.

C 9.7

(depends on deposition method & parameters)

HARDNESS

(Also sold as JK7184)

(equiv. to HRC: ~58-65) (varies srongly depending on spray parameters)

610-910 DPH 87.5-91.5 R15N

GAS ATOMIZED STELLITE COBALT BASED HVOF POWDERS PRODUCT JK571 STELLITE ALLOY NO. 21 12 31 1 6 SF6 25
NOMINAL COMPOSITION (mass %)
(depends on deposition method & parameters)

HARDNESS

Co Bal. Bal. Bal. Bal. Bal. Bal. Bal.

Ni 2.5

Cr 28 29.5

Mo 5.5

C 0.25 1.4 0.5 2.5 1.1 0.7

Others Si 2 Si 1.5

Nominal size (m) 53/10 53/10 45/10 53/10 53/10 53/10 53/10

(Also sold as JK7221) (Also sold as JK7212)

400-520 DPH 80.5-84.5 R15N (equiv. to HRC: ~40-50) 680-675 DPH 88.1-89.5 R15N 32 HRC Not available

JK572

8 7.5 12 4.5 7.5 15 1

JK573

(Also sold as JK7231) (Also sold as JK7201) (Also sold as JK7206)

10.5

25.5 30 28

JK575

JK576

Si 1.1 Si 2.5 B 1.6 Si 1 Mn 1.5

495-580 DPH 81.5-86.5 R15N (equiv. to HRC: ~43-54)

(equiv. to HRC: ~50-51)

JK577 JK579

14.5 10

19 20

635-790 DPH (505-525 when fused) ~ 85.5 R15N

(Also sold as JK7225)

0.1

82-85.5 R15N (equiv. to HRC: ~43-50) (varies strongly depending on spray parameters)

450-490 DPH

GAS ATOMIZED TRIBALOY COBALT BASED HVOF POWDERS PRODUCT JK554 TRIBALOY ALLOY NO. T-400 T-800 T-800 T-900 T-900 UlTiMeT
NOMINAL COMPOSITION (mass %)
(depends on deposition method & parameters)

HARDNESS

Co Bal. Bal. Bal. Bal. Bal. Bal.

Ni

Cr 8.5 18 18

Mo 29 28 28 23 23

C <0.08 <0.08 <0.08 <0.08 <0.08 0.06

Others Si 2.6 Si 3.4 Si 3.4 Si 2.7 Si 2.7 Si 0.3

Nominal size (m) 53/10 45/5 53/10 45/5 53/10 53/20

(Also sold as JK7221) Typically used with hydrogen fuel Typically used with carbon fuel (Also sold as JK7580)

450-600 DPH 86-87.5 R15N (equiv. to HRC: ~52-55) 670-780 DPH 89-92 R15N (equiv. to HRC: ~58-64) 455-620 DPH 83.5-88.5 R15N (equiv. to HRC: ~46-56) ~ 700 DPH ~ 500 DPH ~ 500 DPH

JK558H JK558P

JK559H (Special order) JK559P (Special order) UlTiMeT for JK and Plasma Spray

16 16 9

18 18 26 2

18

*ULTIMET is a registered trademark of Haynes International.

HVOF & PLASMA SPRAY DEPOSITION

GAS ATOMIZED NICKEL BASED POWDERS PRODUCT JK347
(Also sold as JK7301) (Also sold as JK7570) (Also sold as JK7640) (Also sold as JK7650) (Also sold as JK7660)

ALLOY NAME Nistelle 2347 Nistelle 2350 Tribaloy T-700 Deloro 40 Deloro 50 Deloro 60 Nistelle C Nistelle C Nistelle Super C

NOMINAL COMPOSITION (mass %)

Ni Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal.

Fe

Cr

Mo 5

Others Ai 6 Ai 5

(depends on deposition method & parameters)

HARDNESS

Nominal size (m) 63/15 63/15 45/10 53/10 53/10 53/10 45/5 63/15 P: 53/15 H: 45/10 53/15 53/20 45/15

332-336 DPH 75.3-78.1 R15N 285-335 DPH 71-76 R15N ~ 700 DPH ~ 40 HRC ~ 50 HRC ~ 60 HRC 400-440 DPH ~ 83 R15N (equiv. to HRC: ~44-45) 375-390 DPH ~ 80 R15N (equiv. to HRC: ~39-41)
(equiv. to HRC: ~ 41)

JK350

JK557

15.5 2.5 2.9 4 5.5 5.5 7.5 11 15 16.5 16.5 23 16 <5 18 21.5 19 4.5 4.5

32.5

<0.08 0.25 0.45 0.7

Si 3.4 Si 3.5 B 1.7 Si 4 B 2.3 Si 4.4 B 3.1

JK584

JK585 JK586

JK591H
(Also sold as JK7391)

17 17 18 16.5 9 3 0.06 (Nb+Ta) 3.7 (Nb+Ta) 5 Ai 0.5, Ti 1

JK591P

Nistelle Super C (Jet Kote)

410 DPH

(Also sold as JK7392) (Also sold as JK7342) (Also sold as JK7341)

JK594 JK625 JK718

Nistelle C-4C Nistelle 625 Nistelle 718

380-440 DPH ~ 81-83 R15N (equiv. to HRC: ~40-44) 385-460 DPH ~ 79-83 R15N (equiv. to HRC: ~37-46) 275-470 DPH 72.5-81.5 R15N (equiv. to HRC: ~25-45) HARDNESS

GAS ATOMIZED IRON BASED HVOF POWDERS PRODUCT JK513 POWDER TYPE 316 Stainless Steel
NOMINAL COMPOSITION (mass %)

Co

Ni

Others Mo 2.5 13 Bal. 17 0.1 Si 1 COBALT BASED PLASMA SPRAY POWDERS

NOMINAL COMPOSITION (mass %)

Fe

Cr

(depends on deposition method & parameters)

Nominal size (m) 53/10

260-315 DPH 69-75 R15N HARDNESS

PRODUCT Stellite 157 Tribaloy T-400 Tribaloy T-900

POWDER TYPE T-400 T-900

Co Bal. Bal. Bal.

Ni

Cr 21 8.5

W 4.5

Mo

C <0.2

29 23

<0.08 <0.08

Others B 2.4 Si 1.5 Si 2.6 Si 2.7

(depends on deposition method & parameters)

Nominal size (m) 45/5 45/5 75/D 53/10

Not available 52 HRC 52 HRC HARDNESS

16

18

NICKEL BASED PLASMA SPRAY POWDERS PRODUCT Deloro 55 Deloro 60 Nistelle C276 Nistelle 625 Nistelle 2315 Nistelle 2350 ALLOY NAME Deloro 55 Deloro 60 Nistelle C276 Nistelle 625 Nistelle 2315 Nistelle 2350
NOMINAL COMPOSITION (mass %)

Ni Bal. Bal. Bal. Bal. Bal. Bal.

Fe 4 4 5 <5

Cr 12 15 15.5 21.5 20

Mo

C 0.6 0.7

Others Si 4.0 B 2.7 Si 4.4 B 3.1

(depends on deposition method & parameters)

Nominal size (m) various various 106/D 45/5 various 106/D 75/45 45/5 75/45

52-57 HRC 58-62 HRC Not Available

3.8

16 9 (Nb+Ta) 3.7

(equiv. to HRC: ~37-46)

385-460 DPH 79-83 R15N

Not Available Ai 5 ~ 70 HRB HARDNESS

GAS ATMOZED IRON BASED PLASMA SPRAY POWDERS PRODUCT Delcrome 90 Delcrome 92 Delcrome 316l/317 Tristelle TS-3 ALLOY NAME Delcrome 90 Delcrome 92 316l Stainless Steel Tristelle TS-3 12 13 10
NOMINAL COMPOSITION (mass %)

Co

Ni

Fe Bal. Bal. Bal. Bal.

Cr 27

C 2.8 3.7

Others Si 0.5 Mo 10 Mo 2.5 Si 1 Si 5

(depends on deposition method & parameters)

Nominal size (m) 53/10 45/D 106/38 106/D 45/5 45/5

Not Available Not Available ~ 180 DPH >55 HRC

17 35

0.03 3

Powders labelled JK are intended primarily for HVOF spraying with the Jet Kote or Diamond Jet* torches but can also be used for plasma spraying. Some of these powders may be listed below in different nominal size ranges for other thermal spray processes. * Diamond Jet is a registered trademark of Sulzer Metco.

19

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

The bonding of the sprayed coating to the workpiece is significantly increased by the fusing process, which creates metallurgical bonds between the powder particles and also between the coating and the workpiece. The coating becomes liquid and gas tight.

Flame Spraying with subsequent Fusing (Spray and Fuse)

Spray and fuse is a two-stage process, the powder alloy being deposited first by flame spraying and then fused. During fusing the deposit is partially remelted and allowed to resolidify. In flame-spraying, the powder particles are softened or melted in an oxyacetylene flame and transferred to a prepared workpiece by the expanding gases. An additional gas stream can be used to assist with powder particle transfer. The second stage of the process, fusing the sprayed coating to the workpiece, is usually done with an oxyacetylene burner. Alternatively, for mass production, fusing can be carried out by induction heating or in a vacuum furnace.

This process is used for the deposition of relatively thin (0.010 to 0.060 or 0.25 to 1.5 mm) layers, usually on the surface of small cylindrical objects such as pump shafts, packing gland sleeves and pistons, as an alternative to the greater deposit thickness obtained from oxy-acetylene and arc processes. The process can also be used for the facing of flat surfaces, but its possibilities for this type of work are limited. Since the deposit is thinner and more uniform than that obtained by other welding methods and the heat for fusion is applied uniformly and rapidly, shrinkage and distortion of the component is frequently very small. When the fusing operation is carried out correctly, dilution of the deposit by the base metal is negligible.

Powder Hopper

Powder Delivery Flame

Fuel Gas Delivery

20

SPRAY AND FUSE & POWDER WELDING

Powder Welding
A specially-designed oxyacetylene torch is used for powder welding. The workpiece is heated with the torch, powder is introduced into the gas stream from the integral powder hopper and transferred to the workpiece through the flame. The powder-weld process is ideal for the deposition of smooth, thin, well bonded layers on flat surfaces on a wide range of substrates, including cast iron. The hardfacing takes place at lower temperatures, which minimizes oxidation and distortion of the workpiece and enables easy surfacing of edges.

Powder Hopper

Powder Delivery Fuel Gas Delivery

Torch Tip

Flame

21

SPRAY-FUSE & POWDER WELDING

ALLOY Co
Stellite alloy SF1 Stellite alloy SF6 Stellite alloy SF12

NOMINAL ANALYSIS OF POWDER1 Cr

19 19 19 19 21

Others Fe
3 3 3 3 <2

W
13 7.5 9 15 4.5

C
1.3 0.8 1.1 1.6 0.1

Ni
13.5 14 14 14 <2.0

B
2.45 1.7 1.9 2.9 2.5

Si
2.8 2.6 2.8 3.2 1.6 <0.5%Mn <0.5%Mn <0.5%Mn <0.5%Mn <0.5%Mn

Hardness (HRC)2

COBALT BASE ALLOYS (GAS ATOMIZED POWDERS)

Bal. Bal. Bal. Bal. Bal. 50-60 40-48 42-52 55-65 45-55

Stellite alloy SF20 Stellite alloy 157

NICKEL BASE ALLOYS (GAS ATOMIZED POWDERS)

Deloro alloy 15

3 3 9 4.5 4 7 7.5 9 11 12 15 17 15.3

<0.05 <0.05 <0.05 <0.06 <0.05 0.2 0.15 0.4 0.3 0.05 0.3 0.35 0.45 0.6 0.7 0.9 0.03

Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal. Bal.

1.1 0.8 1.4 1.7 0.9 1.2 1.2 1.6 1.2 2.1 1.7 1.9 2.3 2.7 3.1 3.5 4.0

0.5 <0.5 <1.0 <1.0 <0.5 2.3 0.3 1.5 3 0.5 2.5 2.5 3.3 4.0 4.0 4.5

2.0 2.1 2.5 2.7 2.2 3.2 2.8 3.4 3.7 3.0 3.5 3.7 3.9 4.0 4.4 4.5

20%Cu 2.2% 2.2% 2.5%Mo, 2.2% Other 2%Cu, 3%Mo

180-230 DPH 240-280 DPH 18-24 22-28 27-30 29-39 33-37 32-42 34-42 35-42 38-45 42-50 47-53 52-60 57-65 53-63

Deloro alloy 21 Deloro alloy 22 Deloro alloy 25

Deloro alloy 29 Deloro alloy 30 Deloro alloy 34 Deloro alloy 35 Deloro alloy 36 Deloro alloy 38 Deloro alloy 40

Deloro alloy 45 Deloro alloy 50 Deloro alloy 55 Deloro alloy 60

Deloro alloy 75 Deloro alloy 6116

COMPOSITE ALLOYS
Stelcar Powders

Blends of WC, WC/Co and Deloro alloy powders. Size and chemistry to customer requirements Blend of tungsten carbide (40%) and Deloro 50 alloy (60%) Blend of tungsten carbide (50%) and Deloro 50 alloy (50%) Blend of tungsten carbide (60%) and Deloro 50 alloy (40%) Blend of tungsten carbide (70%) and Deloro 50 alloy (30%)

Super Stelcar 40 Super Stelcar 50 Super Stelcar 60 Super Stelcar 70

Other alloy compositions may be available on request.

1

Nominal analysis is a guideline only for standard product, does not include all incidental elements and may differ depending on the exact specification/standard used when ordering. Undiluted weld metal. Rockwell (HRC) units unless otherwise stated.

22

Spray-fuse powders are available in these Powder Welding powders are available in these standard size ranges: standard size ranges: KS 20-63 m M 45-106 m (Metco torch) KX 20-106 m S 38-106 m (Eutectic torch) K 20-75 m Depending upon the process parameters and extent of dilution, the hardness of the weld deposit may vary from that provided in the above table.

Stellite History

The History of Stellite

In the early 1900s, an American scientist named Elwood Haynes searched persistently for a cobalt alloy to be used in cutlery which was extremely hard and resistant to tarnishing so that his wife would not have to polish silverware. Through this search and with much trial and error, Haynes stumbled onto an extremely wear and corrosion resistant cobalt alloy. He aptly named the alloy Stellite, which is derived from the Latin word star. He applied and received the patent for Stellite in April of 1907. In 1917, Haynes joined efforts with M.J. OBrien, a mine owner in the small town of Deloro, Canada, to form the Deloro Smelting & Refining Company Limited. This company later became Deloro Stellite.

23

Deloro Stellite
H A R D FA C I N G A L L O Y S D I V I S I O N

UK SALES OFFICE

US SALES OFFICE

Deloro Stellite Cheney Manor Industrial Estate Swindon SN2 2PW UK Tel: (+44) 1793-498500 Fax: (+44) 1793-498501

Stellite Coatings 1201 Eisenhower Drive North Goshen, Indiana 46526 USA Tel: (+1) 574-534-2585 Fax: (+1) 574-534-3417

Contact Us E-Mail: saleshad@stellite.com www.stellite.com

BR-17608 (SR0608) Copyright 2007 Deloro Stellite Printed in USA