Page 1/7

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

1 Identification of the substance/mixture and of the company/undertaking

· Product identifier
· Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),
· Article number: 301171
· Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
· Product category PC9a Coatings and paints, thinners, paint removers
· Process category
PROC4 Chemical production where opportunity for exposure arises
PROC10 Roller application or brushing
PROC13 Treatment of articles by dipping and pouring
· Environmental release category
ERC5 Use at industrial site leading to inclusion into/onto article
ERC6a Use of intermediate
· Article category AC2 Machinery, mechanical appliances, electrical/electronic articles
· Application of the substance / the mixture Coating material
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Lackwerke Peters GmbH & Co.KG
Hooghe Weg 13
47906 KEMPEN
GERMANY
peters@peters.de
· Further information obtainable from:
Arbeitssicherheit und Umweltschutz (workplace safety / environmental protection)
· Emergency telephone number: During normal office hours (8 - 16h CET): ++49 - 21 52 - 20 09 0

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008


~
d GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms


~
d
GHS07

(Contd. on page 2)
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 Page 2/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 1)
· Signal word Warning
· Hazard-determining components of labelling:
Isocyanato acrylate
Hexane, 1,6-diisocyanato-, homopolymer, 2-hydroxyethyl acrylate-blocked
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 2399-48-6 tetrahydrofurfuryl acrylate 25-50%
 Skin Irrit. 2, H315; Eye Irrit. 2, H319
~
d
Isocyanato acrylate 10-25%

~
d Skin Sens. 1, H317; Aquatic Chronic 3, H412
CAS: 5888-33-5 exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate ≥10-≤12.5%
EINECS: 227-561-6 d  Aquatic Chronic 2, H411; d
~  Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT
~
SE 3, H335
CAS: 264888-31-5 Hexane, 1,6-diisocyanato-, homopolymer, 2-hydroxyethyl acrylate-blocked ≥10-≤12.5%
 Skin Sens. 1, H317; Aquatic Chronic 3, H412
~
d
· Additional information: For the wording of the listed hazard phrases refer to section 16.

4 First aid measures

· Description of first aid measures
· General information: Take affected persons out of danger area and lay down.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
(Contd. on page 3)
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 Page 3/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 2)
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Storage class: 10
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored
at the workplace.
(Contd. on page 4)
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 Page 4/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 3)
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:

S
_ Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

R
_ Tightly sealed goggles

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Colourless
· Odour: Product specific
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 275 °C
· Flash point: >70 °C
· Flammability (solid, gas): Not applicable.
(Contd. on page 5)
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 Page 5/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 4)

· Decomposition temperature: Not determined.

· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1.08 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic at 20 °C: 70 mPas
Kinematic: Not determined.
· Solvent content:
Organic solvents: 0.6 %
VOC (EC) 0.64 %
Solids content: 34.8 %
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation
May cause an allergic skin reaction.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
(Contd. on page 6)
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 Page 6/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 5)
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· ADR, ADN, IMDG, IATA not regulated
· UN proper shipping name
· ADR, ADN, IMDG, IATA not regulated
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class not regulated
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2018 Version number 1 Revision: 22.06.2016

Trade name: Twin-Cure® DSL 1600 E-FLZ/75 (222),

(Contd. of page 6)

· Packing group
· ADR, IMDG, IATA not regulated
· Environmental hazards: Not applicable.
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of Marpol
and the IBC Code Not applicable.
· UN "Model Regulation": not regulated

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
· Department issuing SDS: Abteilung Arbeitssicherheit und Umweltschutz
· Contact: Tilman Sehlen
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Skin Sens. 1: Skin sensitisation – Category 1
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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