SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Name of the substance Aluminum sulfide (Al2S3) powder and pieces
Identification number 215-109-0 (EC number)
Synonyms Aluminum sulfide (Al2S3) * Dialuminium trisulphide * Dialuminium trisulfide
Document number 1AS
Materion Code 1AS
Issue date 31-August-2018
Version number 01
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Not available.
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
Supplier
Company name Materion Advanced Chemicals Inc.
Address 407 N. 13th Street
1316 W. St. Paul Avenue
Milwaukee, WI 53233
United States
Division Milwaukee
Telephone 414.212.0257
e-mail advancedmaterials@materion.com
Contact person Noreen Atkinson
1.4. Emergency telephone
number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
Physical hazards
Substances and mixtures which, in contact Category 1 H260 - In contact with water
with water, emit flammable gases releases flammable gases which
may ignite spontaneously.

Hazard summary DANGER

Flammable Solid. In contact with water releases flammable gases which may ignite spontaneously.
May cause skin and eye irritation. May cause irritation to the respiratory system.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Aluminum sulfide
Hazard pictograms

Signal word Danger

Hazard statements
H260 In contact with water releases flammable gases which may ignite spontaneously.
H315 + H320 Causes skin and eye irritation.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
Precautionary statements
Prevention

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 P231 + P232 Handle and store contents under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P260 Do not breathe fume/gas/vapours/spray.
Response
IF IN EYES: Rinse cautiously with water for several minuts. Remove contact lenses, if present and
easy to do. Continue rinsing.
P302 + P335 + P334 IF ON SKIN: Brush off loose particles from skin and immerse in cool water.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P314 Get medical advice/attention if you feel unwell.
Storage
P402 + P404 Store in a dry place. Store in a closed container.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Supplemental label None.
information
2.3. Other hazards None known.

SECTION 3: Composition/information on ingredients

3.1. Substances
General information
Chemical name % CAS-No. / EC REACH Registration No. INDEX No. Notes
No.
Aluminum sulfide 100 1302-81-4 - -
215-109-0
Classification: Water-React. 1;H260, Skin Irrit. 2;H315, STOT SE 3;H335

List of abbreviations and symbols that may be used above

DSD: Directive 67/548/EEC.
CLP: Regulation No. 1272/2008.
#: This substance has been assigned Union workplace exposure limit(s).
#: This substance has been assigned Community workplace exposure limit(s).
M: M-factor
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

SECTION 4: First aid measures

General information If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet
to the doctor in attendance.
4.1. Description of first aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician
if symptoms develop or persist.
Skin contact Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash with plenty
of soap and water. Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact
lenses. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical advice/attention if you feel unwell.
4.2. Most important Irritant effects. Conjunctivitis. Discomfort in the chest. Coughing.
symptoms and effects, both
acute and delayed
4.3. Indication of any Not available.
immediate medical attention
and special treatment
needed

SECTION 5: Firefighting measures

General fire hazards In contact with water releases flammable gases.
5.1. Extinguishing media
Suitable extinguishing Foam. Dry chemical powder. Carbon dioxide (CO2).
media

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 Unsuitable extinguishing Water.
media
5.2. Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or
mixture
5.3. Advice for firefighters
Special protective Firefighters should wear full protective clothing including self contained breathing apparatus.
equipment for
firefighters
Special firefighting Move containers from fire area if you can do so without risk. In case of fire and/or explosion do not
procedures breathe fumes. Firefighters must use standard protective equipment including flame retardant coat,
helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. In the
event of fire and/or explosion do not breathe fumes.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
personnel clean-up.
For emergency Not available.
responders
6.2. Environmental Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
precautions
6.3. Methods and material for Stop the flow of material, if this is without risk. Do not get water on spilled substance or inside
containment and cleaning up containers.
6.4. Reference to other Not available.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Keep away from any possible contact with water, because of violent reaction and possible flash fire.
handling Handle under inert gas. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate
personal protective equipment. Observe good industrial hygiene practices.
7.2. Conditions for safe Keep container tightly closed in a cool, well-ventilated place. Never allow product to get in contact
storage, including any with water during storage. Store away from incompatible materials (see Section 10 of the SDS).
incompatibilities
7.3. Specific end use(s) Not available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
Bulgaria. OELs. Regulation No 13 on protection of workers against risks of exposure to chemical agents at work
Material Type Value

Aluminum sulfide (CAS TWA 2 mg/m3

1302-81-4)
Estonia. OELs. Occupational Exposure Limits of Hazardous Substances. (Annex of Regulation No. 293 of 18
September 2001)
Material Type Value
Aluminum sulfide (CAS TWA 2 mg/m3
1302-81-4)
Finland. Workplace Exposure Limits
Material Type Value

Aluminum sulfide (CAS TWA 2 mg/m3

1302-81-4)
Iceland. OELs. Regulation 154/1999 on occupational exposure limits
Material Type Value

Aluminum sulfide (CAS TWA 2 mg/m3

1302-81-4)
Italy. Occupational Exposure Limits
Material Type Value Form

Aluminum sulfide (CAS TWA 1 mg/m3 Respirable fraction.

1302-81-4)

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 Lithuania. OELs. Limit Values for Chemical Substances, General Requirements
Material Type Value

Aluminum sulfide (CAS TWA 1 mg/m3

1302-81-4)
Sweden. OELs. Work Environment Authority (AV), Occupational Exposure Limit Values (AFS 2015:7)
Material Type Value Form

Aluminum sulfide (CAS TWA 1 mg/m3 Total dust.

1302-81-4)
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Follow standard monitoring procedures.
procedures
Derived no effect levels Not available.
(DNELs)

Predicted no effect Not available.

concentrations (PNECs)

8.2. Exposure controls

Appropriate engineering General ventilation normally adequate.
controls
Individual protection measures, such as personal protective equipment
General information Use personal protective equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the personal protective
equipment.
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
- Hand protection Wear appropriate chemical resistant gloves.
- Other Wear protective gloves. Wear suitable protective clothing. Personal protection equipment should be
chosen according to the CEN standards and in discussion with the supplier of the personal
protective equipment.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Not available.
Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material and
before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants.
Environmental exposure Not available.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Solid.
Form Solid.
Colour Not available.
Odour Not available.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and Not available.
boiling range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - Not available.
upper (%)
Vapour pressure Not available.
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Vapour density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information
Molecular formula Al2S3

SECTION 10: Stability and reactivity

10.1. Reactivity Water, moisture. Strong oxidising agents. Acids.
10.2. Chemical stability Risk of explosion. Risk of ignition.
10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
10.4. Conditions to avoid Exposure to moisture. Contact with water liberates flammable gas. Contact with incompatible
materials.
10.5. Incompatible materials Strong oxidising agents. Strong acids. Water.
10.6. Hazardous Sulphur oxides.
decomposition products

SECTION 11: Toxicological information

General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact May be irritating to eyes.
Ingestion Due to lack of data the classification is not possible.
Symptoms Irritating to eyes, respiratory system and skin.
11.1. Information on toxicological effects

Acute toxicity Causes eye irritation. Causes skin irritation. May cause irritation to the respiratory system.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye May be irritating to eyes.
irritation
Respiratory sensitisation Due to lack of data the classification is not possible.
Skin sensitisation May be irritating to the skin.
Germ cell mutagenicity Due to lack of data the classification is not possible.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Hungary. 26/2000 EüM Ordinance on protection against and preventing risk relating to exposure to carcinogens
at work (as amended)
Not listed.
Reproductive toxicity Due to lack of data the classification is not possible.
Specific target organ toxicity Respiratory tract irritation.
- single exposure
Specific target organ toxicity Due to lack of data the classification is not possible.
- repeated exposure
Aspiration hazard Due to lack of data the classification is not possible.
Mixture versus substance No information available.
information
Other information Not available.

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SECTION 12: Ecological information
12.1. Toxicity Due to partial or complete lack of data the classification for hazardous to the aquatic environment,
is not possible.
12.2. Persistence and No data is available on the degradability of this product.
degradability
12.3. Bioaccumulative No data available.
potential
Partition coefficient Not available.
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil No data available.
12.5. Results of PBT Not a PBT or vPvB substance or mixture.
and vPvB
assessment
12.6. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Residual waste Dispose of in accordance with local regulations. Empty containers or liners may retain some product
residues. This material and its container must be disposed of in a safe manner (see: Disposal
instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
methods/information
Special precautions Dispose in accordance with all applicable regulations.

SECTION 14: Transport information

ADR
14.1. UN number UN3134
14.2. UN proper shipping Water-reactive solid, toxic, n.o.s.
name
14.3. Transport hazard class(es)
Class 4.3
Subsidiary risk 6.1(PGI, II)
Label(s) 4.3, 6.1
Hazard No. (ADR) Not available.
Tunnel restriction Not available.
code
14.4. Packing group I
14.5. Environmental No.
hazards
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
RID
14.1. UN number UN3134
14.2. UN proper shipping Water-reactive solid, toxic, n.o.s.
name
14.3. Transport hazard class(es)
Class 4.3
Subsidiary risk -
Label(s) 4.3+6.1
14.4. Packing group I
14.5. Environmental No.
hazards
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
ADN
14.1. UN number UN3134

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 14.2. UN proper shipping Water-reactive solid, toxic, n.o.s.
name
14.3. Transport hazard class(es)
Class 4.3
Subsidiary risk 6.1(PGI, II)
Label(s) 4.3, 6.1
14.4. Packing group I
14.5. Environmental No.
hazards
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
IATA
14.1. UN number UN3134
14.2. UN proper shipping Water-reactive solid, toxic, n.o.s.
name
14.3. Transport hazard class(es)
Class 4.3
Subsidiary risk 6.1(PGI, II)
14.4. Packing group I
14.5. Environmental No.
hazards
ERG Code 4PW
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
Other information
Passenger and cargo Forbidden
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
14.1. UN number UN3134
14.2. UN proper shipping WATER-REACTIVE SOLID, TOXIC, N.O.S.
name
14.3. Transport hazard class(es)
Class 4.3
Subsidiary risk 6.1(PGI, II)
14.4. Packing group I
14.5. Environmental hazards
Marine pollutant No.
EmS F-G, S-N
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
ADN; ADR; IATA; IMDG

RID

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SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as
amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as
amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as
amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as
amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and
mutagens at work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
Other regulations The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP
Regulation) as amended. This Safety Data Sheet complies with the requirements of Regulation (EC)
No 1907/2006, as amended. Additional information is given in the Safety Data Sheet.
National regulations Follow national regulation for work with chemical agents.

15.2. Chemical safety No Chemical Safety Assessment has been carried out.
assessment

SECTION 16: Other information

List of abbreviations Not available.
Information on evaluation Not applicable.
method leading to the
classification of mixture
Disclaimer Materion Advanced Chemicals Inc. cannot anticipate all conditions under which this information and
its product, or the products of other manufacturers in combination with its product, may be used.
It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use.
This document has been prepared using data from sources considered to be technically reliable and
the information is believed to be correct. Materion makes no warranties, expressed or implied, as to
the accuracy of the information contained herein. Materion cannot anticipate all conditions under
which this information and its products may be used and the actual conditions of use are beyond its
control. The user is responsible to evaluate all available information when using this product for any
particular use and to comply with all Federal, State, Provincial and Local laws, statutes and
regulations.

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