DISTRICT LEVEL II PUC MID-TERM EXAM, OCT INOV: 2024

Time: 3 Hours Sub: CHEMISTRY (34) Max. Marks: 70

General Instructtons:
1
The question paper has FIVE parts All the FIVE parts are compulsory.
(a) Part -A caries 6
20m
marks,
qe s I o n carries 1 mak
each
(b) Part-Bcames
(C) Part-Ceamies 15
(d) Part-De
Emads eBchquesbon
quesb cames
09 m deach
arke n qUestion maks
(e) Part-Ee
3
manks, each question (pro em) arries 3 marks.
be considered for awarding marks
In Part -A question, first attempled answer ml D
4 Wrte balan cod Cnemical equations and draw neat labelled odisorams and oraohs wherever necessary
Direct
5 teoe snd sneciße unit for final answer wll not carry any marks
detaiiod eton
answers to the numenca prooea tee aof seentifc calculator is not allowed)
6 table imple calcuators if necessary (Use
PART-A
I Select the correct option from the given cholces: 15 x1= 1$
1 Which of the following is depending on temperature?
(A) Molarity (B) Mole fraction (C) Weight percentage (D) Moialty
2 An unripe mango placed ina concentrated salt solution to prepare pickle, shrivels because
(A) It gains water due to osmosis (B) It loses water due to reverse osmosis
(C) It gains water due to reverse osmosis (D) It loses water due to osmosis
3 The values of Van't Hoff factors for KCI, NaCl and K;SO, respectively are
(A) 2, 2. and 2 (B) 2. 2 and 3 (C) 1, 1 and 2 (D) 1. 1and 1
4 The SI unit of conductivity
(A) Sm (B) S/m (C)Sm (D) Sm'mol

5 The quantity of eleciric charge required to reduce one mole of MnO, to Mn

(A) 1 F (B) 2 F (C) 5 F (D) 3 F

6. Electronic configuration ofa transition element Xin +3 oxidation state is Ar|3d. What is its
atomic nunber?
(A) 25 (B) 26 (C) 27 (D) 24
7 Bronze is an alloy of
(A) Pb Sn + Zn (B) Cu Zn (C) Cu + Sn (D) Pb + Zn
8 The almost identical radii of Zr and Hf is a consequence of
(A) Shielding effect (B) Actinoid contracion
(C) Lanthanoid contraction (D) None of these

9 The correct IUPAC name of Pr(NH, ), CI, is

(A) Diamminedichloridoplatinum (1) (B) Diamminedichloridoplatinum (IV)
(C) Diamminedichloridoplatinum (0) (D) Dichloidodiammineplatinum (IV)
10 The oxidation state of metal in metal carbonyl complexes is
(A) 1 (B) 2 (C) 3 (D) 0

11.The secondary valency of central metal ion in the complex| Co(en),

(A) 6 (B) 3 (C) 2 (D) 4

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 12.Stater Enantiomers are non-superiposable miror images on each other
Stalament -lt Arecemic mixture shows zero opticalrotation.
ldentily the corect statement
(A) Both Statementsi and l are corect
(B) Both Slatements I and l are tncoea
l is incorect
n Stalement is incorrect and Slatement l is correct
13.Chiorobenzene reacts with magnesium in dry ether to glve a compound A, AIS
(B) CH,MgCI
(A) C,H,OH
(C) C,H,CH, MgCI (D) MgC,

14.Tertiary alcohols can be prepared Grignard reagent wth (D) R-CO00

(A) H-CH CuO (B) R-CHO (C) R-CO- R
15.Consider the following phenols arange in decreasing order of their acidic nature

NO,
NO

(A) lIl >V> |>| (8) i>>V> ll (C)|> IV > l> 1 (D) ll>1V>|>
IL Fill in the blanks choosing the appropriate word from those glven in the brackets: 515
(5, Infinite dilutlon, Methoayethane, +7, C,F isotonic solutions)
16. Two solutons have same osmoic pressure at the same temperature is called
17. Kohlrausch's law is applicable for weak elecirolyles at
18. The oxddation number of Mn in potassium permanganate is
19. One of the most common Freon's in industrial use is
20. The IUPAC name of ethylmethylether is
PART- B
. Answer any THREE of the following questions. Each question carries two marks:
32-6
21. What is Van't Holrs factor and write its significaance.
22 Wite anodic and cathodic reacions takes place in
Daniel cell.
23. Calculate the spin only magnetic moment of Fe ions (atomic number
of Fe is 26)
24. Draw the Cis and trans orn ofFe(NH, ), (CN ),
25. Complete the following reaction and mention the name of the
reaction
Ethyl alcothol0c
pyrine

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 PART -C
IV. Answer any THREE of the following. Each question carries three marks: 3 x3= 9

26. Write the balanced equations involved in the manufacture of potassium dichromate from
chromite ore.
27. What is Lanthanoid contraction? Mention two of its consequences.
28. On the basis of valence bond theory (VBT) explain the hybridization, geometrical shape
and magnetic property of hexaammine cobalt (ll) ion.
29. Write any three postulates of Werner's theory of complexes.

30. (a) Givethe facial (fac) and meridional (mer) isomeric structure of Co( NH,), ( NO,),
(b) Wite the IUPCA name of
[Co(NH,), (H,0)ci]c, [1M)

V. Answer any TWO of the following. Each question carries THREE marks: 2 x 3 =6

31. (a) State and explain Raoult's law of liquid - liquid solution. (2M
(b) Based on inter molecular interaction give the reason for a solution of Aand B to
show positive deviation from Raoull's law. [1M)
32 Define the following terms: (a) Hypotonic solutions (b) Molality (c) Osmotic pressure.
33. Draw a neat labelled diagram of SHE and write half - cell reacion. Give its E value.
34. (a) State Faradays first law of electrolysis. (1M]
(b) How molar conducivity varies with dilution? (1M)
(c) Wite the relation between Molar conductivity and concentration of electrolytic
solution. [1M]
PART -D
VI. Answer any FOUR of the following. Each question carries FIVE marks: 4x 5=20

35. (a) How do you convert an aryl halide to dipheny!? Wite the equation and name the
reaction? (3M)
(b) Wite SN, mechanism for the conversation of methyl chloride to methyl alcohol. (2M)
36 (a) Explain () Finkelstein reacion (ii) Swart's reaction with an example for each (2+2]
(b) Which one of the following is more reactive towards SNzreaction?
CH,Br, (CHy)}CHBr. (CHs),CBr (1M)
37 (a) Aryl halides are less reactive towards nucleophilic substitution compared to alkyl
halides Give two reasons. (2M)
(b) Name the product formed when chloromethane reacts with
|2M
() aqueous KOH () Alcoholic AgCN
(c) Give an example of polyhalogen compound. (1M]

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 38. (a) Write the mechanism involved in the conversion of ethanol to ethene. [3M)
(b) Complete the following reacion: (2M)
akall KMnO,
CH,CH,0H
Cu/573K
(CH,), C-OH
39. (a) Explain the preparation of phenol from Cumene process. [3M]
(b) What is the effect of electron releasing group and electron withdrawing group on
acidity of phenols? [1M)
(c) Complete the following reacion: [1M)
OH

Conc. H,SO,
+conc. HNO,

40. (a) Name the products formed when phenol is reacts with
() Zinc dust (ü) aidified Chromic acid (ii) Bromine water [3M
(b) Explain Kolbe's reacion with example.
[2M]
PART- E
VII. Answer any THREE of the following. Each question carries THREE marks: 3 x 3 =9
41. Calculate the mole fracion of ethylene glycol (C,H,0,) in a solution containing 20% of
C,H0, by mass.
42. 200cm' of aqueous soluion of a protein contains 1.26 g of protein. The osmotic pressure of a
solution at 300 Kis found to be 2.57 x10°bar. Calculate the molar mass of the protein.
(R= 0.0821 L atm mol).

43. Asolution containing 2.56 g of Sulphur in 100 g CS, gave a freezing point lowering of0.383 K.
calculate the molar mass of sulphur molecules. Given (K, of CS, = 3.83 Kkg molr)
44. Calculate the emf of the cell in which the following reacion takes place:
N + 2AS(ao02M) NioisoMye) t 2A8-Given that E =1.05V
45. Standard EMF of the cell: Cu/ CuM l/Ag lAg is 0.46V at 25° C. Find the value of
standard free energy change for the reacion that occurs in the cll.
46. Calculate the equilibium constant of the reaction: Cu +2Ag Cut 2Ag,.:
Given that E =0.46V