PHYSICS MAX.

MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. In a new system of units, if energy (E), velocity (V) and time (T) are chosen as
fundamental quantities, then dimensional formula of force is  E V  T   . The value of
     is

1)2 2)-2 3)0 4)1

2. A bar magnet is held perpendicular to a uniform magnetic field. If the couple acting on
the magnet is to be halved by rotating it, then the angle by which it is to be rotated is
1) 300 2) 450 3) 600 4) 900
3. A block is moving on horizontal rough surface. It has velocity v0 i at x  0.1 m. The
1
coefficient of friction varies with distance (x) from origin as   . The minimum
2x 2
value of v0 so that it never stops is
1) 5 m/s 2) 7 m/s 3) 8.5 m/s 4) 10 m/s
4. A disc (m, R) is doing pure rolling motion on a horizontal surface. Radius of curvature
of trajectory followed by point A at topmost point is
A

1) R 2) 2R 3) 4R 4) 2 2R

5. A pendulum made of a uniform wire of cross-sectional area A has time period T. When
an additional mass M is added to its bob, the time period changes to TM . If the Young’s
1
modulus of the material of the wire is Y, then is equal to (g = gravitational
Y
acceleration)

 TM  2  Mg   TM  2  A   T 2  A  T  2  A
1)    1 2) 1     3) 1     4)  M   1
 T   A   T   Mg   TM   Mg  T   Mg
6. An ideal monatomic gas undergoes isothermal expansion from state A to B. Work done
by the gas from A  B is double of work done by the gas from A  C . Pressure at point
C is

P0 P0 2 P0 2 P0
1) 2) 3) 4)
3 3 3 3

7. One mole of an ideal gas undergoes a process given by, T  T0  V 2 where T is the
temperature and V is the volume of gas. Volume of gas when its pressure is least is
[Where T0 and  are positive constants].

2T0 T0
1) T0 / 2 2) T0 /  3) 4) 2
 

8. Two particle A and B are performing SHM with amplitude A0, and time period T about
A0
the same mean position. At t = 0, A is at mean position and B is at distance from
2
mean position and is going towards mean position. At what time they will be at
maximum separation? (At t = 0, direction of velocities of A and B are same)

T T T T
1) 2) 3) 4)
12 8 30 24

9. Electric field at point ‘P’ due to long rod having uniform charge density,  as shown is

   
1) 2) 3) 4)
4 0 R 2 2 0 R 2 0 R 2 0 R
10. For the circuit shown in figure, dielectric slab of dielectric constant k = 2 is inserted in
space between the plates of capacitor 1. As the dielectric is inserted

1) Potential across capacitor 1 increases

2) Charge on capacitor 3 decreases

3) Charge on capacitor 4 decreases

4) Charge on capacitor 2 decreases

11. For the circuit shown in figure, value of resistance R is adjusted so that power delivered
to resistor, R is maximum and is equal to P0. Value of P0 is

1) 6.0W 2) 3.0W 3) 9.0W 4) 4.5W

12. STATEMENT-1 : Inductance plays same role in the electrical circuits as mass plays in
the mechanical circuits.
STATEMENT-2 : Greater the value of inductance, harder it is to change the current in
the circuit.
(1) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
(2) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation
for Statement-1
(3) Statement-1 is True, Statement-2 is False

(4) Statement- 1 is False, Statement- 2 is True

13. For the RC circuit shown in figure, switch 'S' is closed at time t = 0. Current I at
2 RC
t ln 3 , is
3

V0 2V0 2V0 V0
1) 2) 3) 4)
9R 9R R 4R

14. A sinusoidally varying source voltage is given as a function of time as shown. RMS
value of voltage is

59 7
1) V 2) V 3) 4V 4) 6V
2 2

15. Magnetic field associated with electromagnetic wave whose electric field is given by

E  2.1sin  3  108 t  1.8Z  i N / C , is
^

 
1) B  1.26 108 sin  3 108 t  1.8Z  j T 2) B  1.8 108 sin  3 108 t  1.8Z  j T
^ ^

 
3) B  0.7 108 sin  3 108 t  1.8Z  j T 4) B  1.26 108 sin  3 108 t  1.8Z  j T
^ ^

16. A ray of light travelling from glass to air is incident at angle i. Maximum angle of

deviation suffered for any angle of incidence is , then refractive index of glass is
2

1) 2 2) 3 3) 2 4) 4/3
17. In a standard YDSE, the distance between the slits varies with time
 t  as  dt   d0  a0 sin t  . The difference between the largest fringe width and the smallest
fringe width over time is given as (  is wavelength of monochromatic light used, D is
the screen distance from slits. D >>d)

2 Da0 2 Dd0 D  Da0

1) 2) 3) 4)
d02  a02 d02  a02 d0  a0 d02  a02

18. In a hydrogen atom, electron jumps from 4th excited state to 2nd excited state.
Wavelength of photon emitted is [R : Rydberg constant]

225 225 100 100

1) 2) 3) 4)
16R 4R 21R 4R

19. In the circuit with ideal diodes as shown, current (in A) through battery is

1) 3 2) 5 3) 6 4) 4

20. In a Vernier calipers, one main scale division is 1mm and 9main scale divisions are
equal to 10 vernier scale divisions. When nothing is put between jaws of the calipers,
zero of the Vernier scale lies to the right side of zero of the main scale and the 2nd
division of the Vernier scale coincides with a main scale division. While measuring
inner diameter of a hollow cylinder the zero of Vernier scale lies between 1.7cm and
1.8cm of the main scale. Also, 8th division of Vernier scale coincides with a main scale
division, inner diameter of the cylinder is

1) 17.2mm 2) 17.4mm 3) 17.6mm 4) 17.8mm

 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. Pitch of a screw gauge is 1mm and its cap is divided into 100 divisions. When nothing is
placed between studs of the screw gauge, zero of circular scale is 8 divisions above the
reference line and zero of the main scale is not visible. Now, when a cylindrical wire is
placed between its studs the main scale reading is 2 divisions and 15th division of
circular scale coincides with reference line. Diameter of the wire is x mm. Find the value
of 100 x.

22. If coefficient of friction between all the surfaces is 0.50, then force, F (in N) required to
move the block of mass 4 kg is [g = 10 m/s2]

23. A block of mass 'm' placed on smooth horizontal surface is acted upon by a horizontal
force as shown, delivering constant power 'P'. If velocity of block changes from v0 to
qmv02
2v0, then time taken is ,find the value of q x n is
nP

r
24. Mass density of a disc is given by    0 , where  0 is constant, r is distance from
R
centre and R is radius of disc. Moment of inertia of disc about an axis passing through
n 0 R 4
centre and perpendicular to plane of disc is . Find the value of n  m is
m

25. The minimum and maximum distances of a planet from sun, revolving around the sun,
are x0 and 2x0 . If the maximum speed is v0 , then minimum acceleration of planet during
nv02
motion is . Find n  m
mx0
26. The height of liquid column raised in a capillary tube of certain radius when dipped in
liquid A vertically is 5cm. If the tube is dipped in a similar manner in another liquid B of
surface tension and density double the values of liquid A, the height of liquid column
raised in liquid B is xcm, then find the value of x _____

27. In an organ pipe successive resonance are obtained at 250 Hz, 350 Hz and 450 Hz. If the
speed of sound is 300 m/s, then length of organ pipe (in m) is x, then the value of 10x is
_____. (ignore end correction)

28. When photon of energy 4.0eV strikes the surface of a metal A, the ejected
photoelectrons have maximum kinetic energy TAeV and de-Broglie wave length A . The
maximum kinetic energy of photoelectrons liberated from another metal B by photon of
energy 4.50eV is TB  TA  1.5 eV . If the de-Broglie wave length of these photoelectrons
B  2A , then the work function of metal B is __ eV.

29. If at an instant the value of i is 1 A and it is increasing at the rate of 1 A / s then Va  Vb at

that instant will be______volt

30. Two lighter nuclei combine to from a comparatively heavier nucleus by the relation
given blow:
2
1 X  21 X  42Y

The binding energies per nucleon for 21 X and 42Y are 1.1 MeV and 7.6 MeV respectively. The
energy released in the process is ______ MeV
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. Titanium oxide  TiO2  is heated in stream of hydrogen to give water and new oxide

Ti x O y . If 1.6gm TiO 2 produces 1.44 gm Ti x O y , (atomic mass Ti = 48, O = 16), The sum

of ' x '& ' y ' is

1) 3 2) 5 3) 7 4) 8

32. The standard reduction potential for Zn+2/Zn; Ni+2/Ni and Fe+2/Fe are –0.76V, –0.23V, –
0.44V respectively. The reaction X + Y+2  X+2 + Y will be non-spontaneous when :

X Y

(I) Ni Fe

(II) Ni Zn

(III) Fe Zn

(IV) Zn Ni

1) I, II, IV 2) I, II, III 3) II, III, IV 4) I,III,IV

33. Consider the following chemical reaction and the corresponding kinetic data showing
the initial reaction rate as a function of the initial concentrations of the reactants:

H3AsO4(aq) + 2H3O+(aq) + 3I-(aq)  HAsO2(aq) + I3-(aq) + 4H2O(liq)

Initial Rate  10–5

[H3AsO4] [H3O+] [I–]
(M/sec)
3.7 0.001 0.01 0.10
7.4 0.001 0.01 0.20
7.4 0.002 0.01 0.10
3.7 0.002 0.005 0.20
Using the data, establish the correct reaction composite order.

1) 1 2) 2 3) 3 4) 4
34.. A 0.4m aqueous solution of Na x A has freezing point 3.720 C . If K f  H 2 O  is 1.86K kg
mol 1 . The value of ‘X” is (salt is 100% ionized).

1) 2 2) 3 3) 4 4) 6

35. Which of the following below electronic configuration of lanthanides is related to the
formation of stable +2 oxidation state.

1)  Xe 4 f 7 ,5d 1 ,6s 2 2)  Xe 4 f 14 ,5d 1 ,6s 2 3)  Xe 4 f 7 , 6s2 4)  Xe 4 f 1 ,5d 1, 6s 2

36. Co  NH 3 4  NO2 2  Cl exhibits:

1) linkage isomerism, geometrical isomerism and optical isomerism

2) linkage isomerism, ionization isomerism and optical isomerism

3) linkage isomerism, ionization isomerism and geometrical isomerism

4) ionization isomerism, geometrical isomerism and optical isomerism

37. The enthalpy of combustion of propane (C3H8) gas in terms of given data is :
Bond energy (kJ/mol)
 C—H  O=O  C=O  O—H  C—C
+x1 +x2 +x3 +x4 +x5
Resonance energy of CO2 is –z kJ/mol and  Hvaporization [H2O(l)] is y kJ/mol.
1) 8x1 + 2x5 + 5x2 – 6x3 – 8x4 – 4y – 3z
2) 6x1 + x5 + 5x2 – 3x3 – 4x4 – 4y – 3z
3) 8x1 + 2x5 + 5x2 – 6x3 – 8x4 – y – z
4) 8x1 + x5 + 5x2 – 6x3 – 8x4 – 4y + 3z
N0
38. atoms of X (g) are converted into X+ (g) by absorbing E1 energy. 2N0 atoms of X (g)
2

are converted into X–(g) by releasing E2 energy. Calculate ionisation enthalpy and
electron gain enthalpy of X(g) per atom.
2E1 E2 E2 2E1
1) I.E. = ,  egH = – 2) I.E. = – ,  egH =
N0 2N0 2N0 N0

E1 E2 N0
3) I.E. = ,  egH = – 4) I.E. = ,  egH = – 2N0
2N0 2N0 2E1 E2
39. For an octahedral complex, which of the following d-electron configuration will give
maximum CFSE?

1) high spin, d 6 2) low spin, d 5 3) low spin, d 4 4) high spin, d 7

40. In ICl2 , ICl2 and ICl4 sum of the bond pairs and lone pairs on eachiodine atom in the
given ionic species are

1) 2,2 and 4 2) 2,3 and 2 3) 4,5 and 4 4) 4,5 and 6

41. 0.2 g of an organic compound was analysed by kjeldahl’s method. Ammonia evolved
was absorbed in 60mL N / 5 H 2 SO4 . Unused acid required 40 mL of N/10 NaOH for
complete neutralisation. Find the percentage of nitrogen in the compound.

1) 70 % 2) 56 % 3) 46 % 4) 66 %

42. The correct order of increasing C  O bond length of CO, CO32 , CO2 is
1) CO32  CO2  CO 2) CO2  CO32  CO
3) CO  CO32  CO2 4) CO  CO2  CO32
43. The major product in the following reaction.

1) 2)

3) 4)
44. Which of the following can give immediate turbidity on treatment with Lucas Reagent?

1) 2) CH3  CH 2  CH 2  OH

3) CH 2  CH  CH  OH 4)
|
CH3

45.

Product (P) and (Q) respectively

1) 2)

3) 4)
46.

1) 2)

3) 4)
47.

A, C, D are
CH2CH2CH3 OH CH3 CH CH3 OH

A) , ,CH3COCH3 B) , ,CH3COCH3

CH3 CH CH3 COCH3 CH3 CH CH3 OH

OH
C) ,CH3OH D) , , CH3
, CH CH3

48. Which is the product formed when cyclohexanone undergoes aldol condensation
followed by heating?

1) 2) 3) 4) O O

49. Which of the following reactions will not give propane?

50. The IUPAC name of the following compound is:

1) 3- ethyl – 4 – methylhex – 4 – ene 2) 4,4 – diethyl – 3 – methylbut – 2 – ene

3) 4-methyl – 3 – ethylhex -4-ene 4) 4-ethyl-3-methylhex-2-ene
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. The angular velocity of an electron occupying the second Bohr orbit of He+ ion is

2.067 × 10x rad/sec, what is x___________

CH3
| Br2 /hv
52. CH3  C  CH 2  CH3   isomeric monobromo compound ‘X’ (major)
|
CH3

The position of the bromine atom in the major product ‘X’ is___ (as per IUPAC

Nomenclature)

53. Number of dipeptides possible using alanine, glycine and tyrosine is ‘X’ then what is the

value of 5x?

54. Sum of basicity of H3PO4, H3PO3 and H3PO2 is equal to

55. A buffer solution is formed by mixing 100 mL 0.01 M CH3COOH with 200 mL 0.02

MCH3COONa. If this buffer solution is made to 1.0 L by adding 700 mL of water, pH

will change by a factor of ‘x’ then what is the value of x+12?

56. Given the half-cell reactions:

M   aq.  e   M  s  ; E 0  0.52V

M 2   aq.  2e   M  s  ; E 0  0.34V

If equilibrium constant of the reaction

2 M   aq.  M  s   M 2   aq.

2.303RT
Is ‘K’ find value of log10 K  ?(Given that  0.06 )
F
57. The osmotic pressure of a solution in atm obtained on mixing each 50 mL of 1.2 % w/v
urea solution and 2.4 % w/v glucose solution at 300 K is:(R = 0.08 litre atm K 1mol 1 )

58. Consider the following compounds and count number of compounds which can produce
tribromo derivatives on reaction with Br2 / H 2O .

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

OH
COOH

59. The time for half life period of a certain reaction A  products is 1 hour when the initial
concentration of the reactant ‘A’ is 2.0 mol L1 . What time does it take for its
concentration to come from 0.50 to 0.25 mol L1 is X  10 2 h x is, if it is a zero order
reaction?

60. Total number of bonds in PCl5 which are at 900 to each other, is:
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. Statement-1: The point Z lies on the circle Z  2  i  1 . The point Z0 on the circle with
4
maximum argument is given by Z 0  2  cos   i sin   where tan   and
5

Statement-2: Point Z on the circle Z  2  i  1 nearest to the origin has modulus  5 1
1) Statement 1 is true, statement 2 is true, statement 2 is a correct explanation of
statement 1

2) Statement 1 is true, statement 2 is true, statement 2 is not correct explanation of

statement 1

3) Statement 1 is true, statement 2 is false

4) Statement 1 is false, statement 2 is true.

 bc b 2  bc c 2  bc
62. If a  cot 80 0 , b  cot 600 and c  cot 40 0 , then the value of a 2  ac ac c 2  ac
a 2  ab b 2  ab ab

is equal to

1)2 2) 1 3)4 4)3

63. f  x  is a cubic polynomial x3  ax 2  bx  c such that f  x   0 has three distinct integral

roots and f  g  x    0 does not have real roots, where g  x   x 2  2 x  5 then the minimum
value of a  b  c is

1)504 2) 532 3)719 4)764

64. In how many ways can 17 persons depart from railway station in 2 cars and 3 autos
given that 2 particular persons depart by the same car (4 persons can sit in a car and 3
persons can sit in an auto) is

15! 16! 17! 15!

1) 2) 3) 4)
2!4! 3!  2! 4! 3! 2!4! 3! 4! 3!
3 2 3 3 3
65. In a test an examinee either guess or copies or knows the answer to a multiple choice
question with four choices of which only one option is correct. The probability that he
makes a guess is 1/3 and the probability that he copies the answer is 1/6, the probability
that his answer is correct given that he copied is 1/8, then the probability that he know
the answer to the question given that he correctly answered it is

1)24/29 2)23/29 3)22/29 4)21/29

66. A random variable X has the probability distribution

X: 1 2 3 4 5 6 7 8
P  X  :0.15 0.23 0.12 0.10 0.20 0.08 0.07 0.05

For the events E   X is a prime number and F   X  4 then probability of P  E  F 

1)0.87 2)0.77 3)0.35 4)0.50

67. If g  x   max y 2  xy , 0  y  1 then minimum value of g  x  for real x is a  2 b (a, b are

natural numbers) then a + b = ______

1) 5 2) 11 3) 24 4) 2

68. A lamp of negligible height is placed on the ground m1 mt away from a wall. A man m2
m1
mt tall is walking at a speed of mt / sec from the lamp to the nearest point on the wall.
10
When he is midway between the lamp and the wall, the rate of change in the length of
his shadow on the wall is

5m2 2m2 m2 m2

1) m/s 2) m/s 3) m/s 4) m/s
2 5 2 5

  2x  
  1  2cos  3k  
69. If f ( x)       , then number of points where
k 1  3 
 
 

 xf ( x)  xf ( x )  ( x  1) x 2  3 x  2 is non-differentiable in x  (0,3 ) is equal to

(where [.] denotes greatest integer function)

1) 5 2) 6 3) 4 4) 8
70. A flight of stairs has 10 steps. A person can go up the steps one at a time, two at a time
or any combination of 1s and 2s. The total number of ways in which the person can go
up the stairs is

1) 75 2) 79 5) 85 4) 89
   
71. Let k , l , m, n are four distinct unit vectors in a three-dimensional space such that
          1   A
k . l  l . m  m.k  n.l  n.m  . If the value of k . n can be expressed as , where A, B
11 B
are coprime positive integers, then the unit digit of the value of (A+B) is ________

1) 0 2) 4 5) 6 4) 8
1
dx
72. The value of   5  2 x  2 x 1  e
0
2 24 x

is

       
2 2 2 2
1 11  1 1 11  1 1 11  1 1 11  1
1) ln 2) ln 3) ln 4) ln
2 11 10 11 10 2 11 10 11 10

The area bounded by the two branches of curve  y  x   x3 and the straight line x  1 is
2
73.

1) 1/5 sq.unit 2) 3/5 sq.unit 3) 4/5 sq.unit 4) 8/5 sq.unit

74. Statement-1: Period of f  x   sin 3x cos 3x   cos 3x sin 3x where [ ] denotes the greatest
2
integer function, is
3

Statement-2: Period of  x where {} denotes the fractional part of x, is 1

1) Statement-1is True, Statement-2 is True; Statement-2 is a correct explanation

forStatement-1

2) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation

for Statement-1

3) Statement-1 is True, Statement-2 is False

4) Statement-1 is False, Statement-2 is True

 101 101
1
75. Let a1 , a2 , a3 ,....., a101 are in GP with a51  25 and  ai  125 , then the value of   a  equals
i 1 i 1  i 
to
1)5 2)1/5 3)1/25 4)1/125
n log3 8
 1   1 
76. The last term in the binomial expansion of  3 2   is  3  then the 5th term from
 2 3 9 
the beginning is
1 1
1) 10 C6 2) 2.10 C4 3) .10 C4 4) .10 C4
2 3
77. The mean and variance of 7 observations are 8 and 16 respectively. If five observations
out of them are 2, 4, 10, 12, 14 then the product of the two observations is
1)48 2)49 3)36 4)24

 
78. If  a  b  sin       a  b  sin     and a tan  b tan  c then the value of sin  is equal to
2 2
2ab 2bc 2bc 2ab
1) 2) 3) 4)
a  b2  c 2
2
a  b2  c 2
2
a  b2  c 2
2
a  b2  c 2
2

1   tan x  sin x    tan x  sin x    tan x  sin x   ...

79. The value of lim
x  0
1  x3  x 3  x3  ...

1)1 2)1/2 3)1/4 4)-1

 x2 y2   x y 
80. sin     cos 1 
1
  2  is equal to
 4 9  2 2 3 2 

  3
1) 2)  3) 4)
2 2 2

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. Let z1  10  6i and z2  4  6i . If z is any complex number such that the argument of

 z  z1  /  z  z2  is and if z  7  9i is k then k2=
4

82. The value of tan 780 tan 420  tan120 tan 480 
83. Consider a polynomial p  x  of the least degree that has a maximum equal to 6 at x=1

and a minimum equal to 2 at x=3 then the value of p  2   p '  0   7 is

84. A line with direction ratios (2,1,2) intersects the lines r   j    i  j  k  and

 
r  i   2i  j  k at A and B respectively then length of AB is

x 3 y 8 z 3 x3 y7 z 6
85. If the shortest distance between the lines   and   is
3 1 1 3 2 4

 30 units then the value of  is

If 1   x   1  8 x  24 x 2  ..... and a line through P  , n  cuts the circle x2  y 2  4 in A and B

n
86.
then PA.PB 

87. If a variable line xcos  y sin   p  is parameter  which is a chord of the hyperbola

x2 y 2
  1 subtends a right angle at the centre of the hyperbola and always touches a
16 25
circle of radius ‘r’ then ‘3r’ is

f ' x g  x  g ' x f  x  f  x  g  x 
88. Let   f  x  g  x  f  x g  x  g 2  x
dx = m tan 1 
 n g  x  
  c where m, n  N and c


is constant of integration then m2  n2 

89. If P is the number of discontinuity points of f  x    x    x  2 where  is the G.I.F

 3x 4  2 
and q is the limiting value of lt   then p  q  2 is
 x  3x  4 
x  8

90. If f  x  is a polynomial of degree 4 with leading coefficient “1” satisfying

 f 12   f  8  
f 1  10, f  2   20 and f  3  30 then   is
 19840 
Sec: (MODEL-A,B&C) GTM-13(N) Date: 11-01-24
Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 4 2 3 3 4 4 3 5 4
6 1 7 2 8 4 9 2 10 4
11 4 12 1 13 2 14 1 15 1
16 1 17 1 18 1 19 4 20 3
21 223 22 10 23 6 24 10 25 48
26 5 27 15 28 4 29 5 30 26

CHEMISTRY
31 2 32 2 33 4 34 3 35 3
36 3 37 1 38 1 39 2 40 4
41 2 42 4 43 1 44 3 45 2
46 2 47 2 48 2 49 4 50 4
51 16 52 3 53 45 54 6 55 12
56 6 57 4 58 5 59 25 60 6

MATHEMATICS
61 4 62 2 63 3 64 4 65 1
66 2 67 1 68 2 69 1 70 4
71 4 72 1 73 3 74 4 75 2
76 1 77 1 78 2 79 2 80 4
81 18 82 4 83 6 84 3 85 3
86 16 87 20 88 8 89 5 90 1
 SOLUTIONS
PHYSICS
E
1. F   E 1V 1T 1 
VT
  1,   1,   1
2.   MB sin 
 sin 
 1 sin 1  sin 900
  
 2 sin  2  / 2 sin  2
 2  300
Angle of rotation  90  30  600
 mg 1
3. 0.1  2 xdx   mv02
2
2
v0  10 m / s
v02
4. aA 
R
VA  2v0
v A2
RC   4R
aA
l l
5. T  2 ; TM  
g g
Mgl
l 
YA
Mgl
l'  l 
YA
1 A
 l '  l 
Y Mgl
T 2  A
  M2  1
T  Mg
V 
6. WAC  PV 0 0 
 V0 
 P0 
2 PV
0 0 ln  0 0 ln  3 
  PV
P
P
P 0
3
7. PV  RT
 T0   V 2 
P  R 
 V 
dP
0
dV
T
  02    0
V
8.

2 
t
T 12
T
t
24
 /2
 Rd cos 
9.  dE 0
 4 0 R 2


E sin  2
4 0 R
0
2 
E 
4 0 R 2 2 0 R
10. Since equivalent capacitance increases, charge on capacitor 4 increases. By KVL, charge on
capacitor 2 decreases.
11. Req  2
For max power, R  2
Eeq
 3  Eeq  6V
2
6
I   1.5 A
4
P0  1.5   2  4.5W
2

12. Inductance can be set to be analogous to mass, as it poses inertia to current change in the electrical
circuit.

2V0  3t

13. VC   1  e 2 RC

3  
2V  1 
VC  0 1  
3  3
4V
VC  0
9
VC 2V0
I 
2R 9R
14. V  5  3sin t 
32 59
Vrms  52  
2 2
   ^
15. E  B is along positive Z-direction. B is along positive j direction.
  
16.   2 c   c 
2 4
1
 sin  c     2

D
17.  max 
d0  a0
D
 min 
d 0  a0
1 1 1 1 1 1  225
18.  R 2  2   R    
  n1 n2    9 25  16 R
19. Req  6
v0
I  4A
Req
20. Reading = 17+8  0.1-2  0.1=17.6 mm
21. L.C. =0.01 mm, zero error =-0.08 mm
Reading = 2 mm+15  0.01+0.08=2.23 mm
22. f T
2T  0.50  4  10  T  10 N
dv
23. mv P
dt
m v 2 2v0
P
t 2 v0
2
R
I   dI 
R 0
24.  0 r 4 dr

2 0 R 5 2 0 R 4
T 
5R 5
v
25. v1  0
2
2  x0  2 x0  4 x0
Radius of curvature at farthest position  
3 3
2
 v0 
2 3v 2
amin    0
4 x0 16 x0
3
2 s cos 
26. Height of capillary rise =
 gR
2 S A cos 
When in A 5cm=
 AgR
2 S cos 
When in B h= B
 BgR
S B  2 S A and  B  2  A
2  2 S A  cos 
h  5cm
2  AgR
27. f 0  50 Hz
v
f0 
4l
300
50   l  1.5m
4l
A T  1.5
 A
28. B TA
A 1

B 2
TA  2eV , TB  0.5eV
B  EB  TB  4eV
29. Va  5  10  10  1  Vb
 Va  Vb  5V
30. Energy released = Change in B.E. (7.6 × 4) – [4 × 1.1] = 26 MeV

CHEMISTRY
31. 1.6 gm oxide looses 0.16 gm
80 gm oxide looses = 8 gm ‘O’ = ½ mole of ‘O’
TiO 1   TiO 3  Ti 2O3
 2  2
 2

32. Zn + Ni Zn+2 + Ni
+2
o o
Eº = ENi2 / Ni – EZn2 / Zn
= –0.23 – (–0.76) = + 0.53 V
Positive value shows that the process is spontaneous.
Rest of all (I) (II) (III) combination have negative Eº value.
(I) Eº = –0.44 – (–0.23) = –0.21 V
(II) Eº = –0.76 – (–0.23) = –0.53 V
(III) Eº = –0.76 – (–0.44) = –0.32 V
33. HINT: Assume rate law
r = K[H3AsO4]x [H3O+]y [I–]z
Solving by the help of various experiments
x = 1, y = 2 and z=1
total order = 4
34. Tf  i Kf m
3.72  i  1.86  0.4
i  5 n  4
35. Hint: Due to extra stability of half-filled f-subshell.
36. Co  NH 3 4  ONO 2  Cl =linkage isomers
Co  NH 3 4  NO2  Cl   NO2 = ionization isomers
37. C3H8(g) + 5O2 3CO2(g) + 4H2O()
6  B.E. (C  O) 
8  B.E. (C — H)   8  B.E.(O — H) 
CH =  2  B.E. (C — C) –  
 3 | R.E. | of CO2 
 5  B.E. (O  O)   
 4   vap H(H2 O) 
38. X(g)  X+(g) + e–
If I.E. is ionisation enthalpy, then
N0 2E1
 (I.E.) = E1  I.E. =
2 N0
X(g) + e–  X–(g)
If  egH is electron gain enthalpy, then
E2
 2N0(E.A.) = – E2   egH = – .
2N0

39. (A) High spin, d 6 :CFSE=  0.6  2  0.4  4   0  0.4 0

(A) Low spin d 5 ; CFSE =  0.6  2  0.4  5  0  2.00
(B) Low spin d 4 ; CFSE=  0.6  2  0.4  4   0  1.6 0
(C) High spin d 7 ; CFSE=  0.6  2  0.4  5  0  0.8 0
Magnitude of CFSE is maximum in (B)
40.

41. Mass of organic compound = 0.2 g

N
Unused acid required = 40 mL NaOH
10
N N N
40 mL NaOH  40mL H 2 SO4  20mL H 2 SO4
10 10 5

N N
Acid used for absorption of ammonia= (60-20)mL H 2 SO4  40mL H 2 SO4
5 5
1
1.4   40
1.4  N1  V 5 1.4  40
Percentage of nitrogen =    56%
W 0.2 0.2  5
no of bond's in between two atom
42. Bond order of CO2 (by resonance method)=
no of resonating structures
4
i.e., bond order in CO32 (by resonance method)=  1.33
3
1
Bond length 
Bond order
43.

44. The compound A, despite a tertiary alcohol, cannot be readily converted into chloride because OH
is present at bridge head. The compound C, allyl alcohol can be readily converted into allyl chloride,
whose formation is responsible for white cloudiness.
45. t  BuO   astearic ally hindered base will give Hofmann elimination as major product. Where
as EtO  will give Saytzeffs product.
46.
solution : B
eletrophilic

aromaticsubstitution 

N  NCl 

47.

 
(A) is not possible because CH 3  CH 2  C H 2 is less stable than CH 3  C H  CH 3
(C) is not possible because acetophenone and CH 3OH cannot be formed.
OH
(D) is not possible because |
CH 3  CH  CH 3
48.
49.

50.

2Ze2
51. Velocity of an electron in He+ ion in an orbit = .....(i)
nh
n 2 h2
Radius of He+ ion in an orbit = ....(ii)
42me2 Z
By equations (i) and (ii),
u 83 Z2me4
Angular velocity () = = ....(iii)
r n3 h3
8  (22 / 7)3  (2)2  (9.108  1028 )  (4.803  10 10 )4
= = 2.067 × 1016 sec–1.
(2)3  (6.626  1026 )3
CH3 CH3 Br
| | |
Br2 /hv
52. CH3  C  CH 2  CH3   CH3  C  CH  CH3 (One chiral carbon)
| | 
CH3 CH3
2
53. Number of possible dipeptides is (3) = 9
5x9=45
54. Basicity of H3PO4, H3PO3 and H3PO2 are 3, 2, 1 respectively.
 sum of basicity = 6

55. On dilution (addition of water) pH of the buffer solution will not change therefore x=0 and
x+12=12
56.  M   aq.   e   M  s   2 : E 0  0.52V
M  s   M 2   aq.  2e : E 0  0.34V
____________________________________________________

2M   M  s   M 2 E 0  0.52  0.34  0.18

At equilibrium Ecell  0
0.06
Hence E 0  log k
2
0.18  2
log k  6
0.06
57. The molar masses of glucose and urea are 60 g/mol and 180g/mol respectively.
50mL  1.2 g
The number of moles of urea   0.01mol
100mL  60 g / mol
50mL  2.4 g
The number of moles glucose 
100mL  180 g / mol
 0.0067 mol
0.01 mol  0.0067 mol 1000mL
The molar concentration    0.167 M
50 mL  50 mL 1L
The osmotic pressure is   CRT
 0.167 M  0.08 L.atm / mol / K  300 K
 4 atm
58.
59. For a zero order reaction ……(1)
 A 0
For zero order reaction K  ……..(2)
2t 1
2

Since  A 0   2M, t 1  1h, K  1

2
 from equation (1)
0.25
t  0.25 h
1
60.

Total six Cl Ax  P  Cleq bonds at 900 to each other

MATHS
61. Consider statement-2
y

z  2i 1
P
1
C

O x

Q is the point on the circle which is nearest to the origin

OQ  OC  CQ = 5  1
Statement-2 is true
Consider statement-1
Point on the circle with maximum argument is 1
1 1
If COP    sin    tan  
5 2
4
and arg  z0   2  tan 1  
3
Statement-1 is false.
63. Let 1 ,  2 and  3 be the roots of f  x   0
Such that 1   2   3 and g  x  takes all values from  6,  
g  x    x  1  6  6
2

 3  7,  2  8, 1  9
 a  b  c  719
Minimum value of a  b  c is 719
1   2   3  a  a  24  a  24
 1 2   2 3   31  b  b  191
1 2 3  c
 c  504
a  b  c  719
64. Make 1 group of 2 persons, 1 group of 4 persons and 3 groups of 3 persons among 15 persons
15!
(except 2 particular persons) hence the number of ways by grouping method is
2!4! 3! 3!
3

Now we add that 2 persons in the group of 2 persons and thus the number of arrangements of these
15! 15!
groups into cars and autos is  2! 3! 
2!4! 3! 3! 4! 3!
3 3

65. E1 be the event that the answers is guessed

E2 be the event that the answer is copied
E3 be the event that the examinee knows the answer and
E be the event that the examinee answer correctly
1 1
P  E1   , P  E2  
3 6
Assume that event E1 , E2 and E3 are exhaustive P  E1   P  E2   P  E3   1
1
 P  E3  
2
E 1  E  1 E
P    , P    , P    1 (Probability of answering correctly by knowing)
 E1  4  E2  8  E3 
E
P  E3  P  
E 
P 3    E3  
24
 E E  E   E  29
P  E1  P    P  E2  P    P  E3  P  
E
 1 E
 2  E3 
66. P  E   P  2   P  3  P  5   P  7   0.62
P  F   P 1  P  2   P  3  0.50
P  E  F   P  2   P  3  0.35
PE  F   PE  PF   PE  F 
 0.62  0.50  0.35  0.77
68. Let BP=x from the similar triangle properly
A

m2

B P O
m1

AO m2 mm
  AO  1 2
m1 x x
d  AO  m1m2 dx

dt x 2 dt
m
When x  1
2
d  AO  2m
 2 m/s
dt 5
 1
dx
72. Let I   1
0  5  2 x  2 x 1  e 
2 2 4 x

By kings rule
e 2  4 x dx
1
I  2
0  5  2 x  2 x 1  e 
2 2 4 x

Adding 1 and 2
1
11 1
1 1 1  x
dx dx dx 1
2I      ln 2 2
0 5  2 x  x
5  2 x  2 x 2 2
0 11  1
2
2 11 11  1
0
 x    x  
4  2 2  2 0
1  11  1  1  11  1 
2 ln    ln  
2 11  11  1  11  11  1 

 
2

1 11  1
I ln
2 11 10
73.
y

y  x  x3/2

O 1 x
y  x x 3/2

 y  x
2
 x 3  y  x   x 3/ 2
 y  x  x3/2
y  x  x3/2  1, y  x  x3/2  2
1 is an increasing function
2 meets x=axis at x=0,1
1

  x  x    x  x dx
3/ 2 3/ 2
Required area
0
1 1
2  4
 2  x 3/ 2 dx  2  x 5/ 2   sq.units
0 5 0 5
74.  x  x   x  which is periodic with period 1.
Statement 2 is true.
Consider Statement 1.
f  x   sin  3 x  3 x   sin 3 x 
1
Using Statement 2, period of f  x  is .
3
Statement 1 is false.
75. Let 1st term be ‘a1’ and common ratio be ‘r’ then a1  a1r  a1r 2  .....  a1r 100  125
a1 1  r101 
  125  let 0  r  1
1 r
1  1  
101

    1
101
1 1 1 1 1 a1  r    here 1  1
 a   a   2  ...  100    
  a1r a1r a1r 1  r 
r 1 i 1 1
r


1  r  101


1

125

125

125

125

1
a1r 100
1  r  a1r 100
a1  a1r 50   a51   25 5
2 2 2

n log83
 1   1 
76. Last term expansion is cn     
n

 2   33 9 
8
 1 n / 2   1 log3 5
 3log 3 2
  1 
n

  5/3   3 3

2  3 
5
5 1
 35log3 2  3log3 2  2 5     n  10
2
4

   1  10 2 1 10
6
th
 5 term from the beginning 10
c4 3
2    c4 2 . 22  c4
 2
77. Let the two numbers be a, b
2  4  10  12  14  a  b
x  8
7
 a  b  14  1
x  xi  2 2

 2
 
 n 
 16
i

N  
 460  a  b  16  64   7  a 2  b2  100  2
2 2

From 1 and 2, a  b  2  3
a  8, b  6
78. a sin      sin      b sin      sin    
 2a sin  cos   2a sin  cos 
 a tan   b tan 
 
2a tan 2b tan
2  2 1
2  2
1  tan 1  tan
2 2

b tan c
   2
a tan  b tan  c  tan  2
2 2 2 a
  
From 1 and 2 we get tan
2
a 2
 b 2  c 2   bc  1  tan 2 
 2

2 tan
2  2bc
 sin  
   a  b2  c 2
2
1  tan 2  
2
79. Let  tan x  sin x    tan x  sin x    tan x  sin x   .....
y  tan x  sin x   y
 y 2  y   tan x  sin x   0
1  1  4  tan x  sin x 
y
2

Again z  x3  x3  x3  ....
 x3  z  z 2  z  x3  0
1  1  4 x3
z
2

lim
1  1  4  tan x  sin x 
 lim

4  tan x  sin x   1  1  4 x3 
x 0
1  1  4 x 3 x 0

4 x 3 1  1  4  tan x  sin x  
 sin x sin x 
  
 1  1 4x
3
 sin x 1  cos x  1  1  4 x3
 lim 
cos x 1 
 lim 
x 0

x3 1  1  4  tan x  sin x  
x 0 x3 cos x 1  1  4  tan x  sin x 

sin x 2sin 2 x / 2 1 1  1  4 x3 1 11 1

 lim . . .  1. .1. 
x 0 x 4 x / 4 cos x 1  1  4  tan x  sin x 
2
2 11 2
80. Put x  2cos  , y  3sin 
 1 1 
sin 1 1  cos 1  cos   sin   2 
 2 2 
   
sin 1 1  cos 1  cos      2 
  4 
 
1  cos      2  1
 4
   
1  cos      1  cos      1
 4  4
   3
  cos 1 1  2    cos 1  1    
2 2 2 2

81. Let z  x  iy
z  z1   x  10    y  6  i
z  z2   x  4    y  6  i
 z  z1  
arg  
 z  z2  4
 6  y  6  
 tan 1  2

  x  10  x  4    y  6   4
 x2  y 2  14 x 18 y  112  0
z  7  9i   x  7    y  9   x 2  14 x  y 2  18 y  130  112  130  18
2 2 2
83. The polynomial is every where differentiable function
 The points of extremum can only be the no.of derivative
The derivative of polynomial is P1  x   a  x  1 x  3   a  x 2  4 x  3 
P 1  6
x
 x3 4
P  x    P  x  dx  6  a   2 x 2  3 x    6
1

1  3 3
Also P(3)=6  a  3
P  x   x3  6 x2  9 x  2
 P  2   4, P1  0   9
 P  2   P1  0   7  6
x  0 y 1 z  0 x 1 y  0 z  0
84. L1      L2    
1 1 1 , 2 1 1
Any point on L1 and L2 be   ,   1,   and  2   1,  ,   respectively.
2  1       1   
 
2 1 2
On solving   1,   3
A   3, 2,3 , B  1,1,1
AB  4  1  4  3
a  c b d 
 
85. Shortest distance 
bd
Here a  3i  8 j  3k , b  3i  j  k , c  3i  7 j  6k , d  3i  2 j  4k
270
 Shortest distance   270  3 30   30    3
270
n  2 n 2 n  n  1
1   x   1  x 
n
86.  ....
1! 2!
= 1  8 x  24 x 2  ....
 n  8 and  2 n  n  1  48
   2, n  4
Now P  , n    2, 4 
Any line through P cuts the circle x 2  y 2  4 at A and B
 PA.PB  S11  4  16  4  16
87. Combined equation of pair of lines AC and BC can be obtained by homogenizing the hyperbola
x2 y 2
  1 with the help of AB
16 25
A
B

C  0, 0  x
 2
x 2 y 2  x cos   y sin  
  
16 25  p 
 1 cos   2  1 sin 2   2 xy sin  cos 
2
x2    y    0
 16 p2   25 p2  p2
ACB  900
1 cos 2  1 sin 2 
    0
16 p2 25 p2
20
 p
3
Also Cl=P always perpendicular to given variable line hence variable line always touches a circle of
20
radius p  r   3r  20units
3
f 1  x  g  x   g 1  x  f  x  dx
88. I 

 f  x   g  x   g  x  f  x   g  x 2 
f 1  x  g  x   g1  x  f  x 


 g  x 
2

dx
 f  x  f  x
  1 1
 g  x  g  x
f  x 2tdt
Put 1  t 2  I   2
g  x t  2 t
2  t 
I tan 1  c
2  2
 f  x 1 
 2 tan 1   c
 2g  x  2 
 
 f  x   g  x  
 2 tan 1  c
 2 g  x  
m  2, n  2
m2  n2  8
89. f  x    x    x  2
  x    x  2   x    x   2  2
So f  x  is constant function
It is continuous every where  p  0
 3x 4  2 
q  lt  3
 x  3x  4 
x  8

pq25
90. f  x   10 x   x  1 x  2  x  3 x   
f 12   f  8 
 f 12   f  8   19840  1
19840