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=F o!-Ei
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rrJ b &e: E
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EA +EEE +i
:r$i :F
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 ::

TUMAKURU DTSTRICT P.U. COLLEGE PRINCIPALS' ASSOCIATION

i PRACTICE PAPER.I
i
i CHEN{TSTRY (34)
TIME:3hours lSminutes MAX.MARKS:70

Instructions: (1) The question paper has four parts. All the four parts are compulsory'
; PART-A carries 20 marks, each question carries one mark
. PART-B carries 8 marks. Each question carries two marks
PART-C carries 12 marks. Each question carries three marks
PART-D carries 30 marks. Each question carries five marks
' (2) Write batanced chemical equations and draw diagrams wherever necessary.
Use log table and simple calculators if necessary
(Use of scientific calculator is not allowed)

; PART-A

I. Select the correct option from the given choices. lx15 = 15

l. An electron trapped in an anion site in a crystal is called

a) F-center b) Frenkel Defect

c) Schottky defect d) Inerstitial defect

2. The l8w which indicates the relationship between solubility ofa gas in liquid and pressure is
a) Raoult's law b) Henry's law

c) Lowering ofvapour pressurc d)van't Hoff law

3. A plant cell shrinks when it is kept in a
a) Hypotonic solution b) Hypertonic solution
c) Isotonic solution d) Pure water

4. A standard hydrogen electrode has a zero potential because

a) Flydrogen can be most easily oxidised b) Hydrogen has only one electron

c) The electrode potential is assumed to be zero d) Hydrogen is the lightest element

5. Wherra chemical reaction takes place, during the course ofthe reaction the rate of reaction
zi) keeps on increasing with time b) remains constant with time
a
d) keeps on decreasing with time d) shows inegular trend with time

6. PowdEred substances are more effective adsorbents than their crystalline form because
ri) adsorption is an exothermic

U) they become inert and do not react with the adsorbate

d) the extent ofadsorption increases with increase in surface area ofthe adsorbate.

d) adsorption is more ifthe size ofadsorbent is small

7. Sulphide ores ofzinc/copper is concentrated by
process
a) Froth floatation b) Electromagnetic prccess

q) Gravity separation d) Distillation

i
8. Which compound is prepared by the following reaction
673 K, l bar
; Xe+ F2

: ---------.-.>
(2:1 volume ralio)

a) XeFr b) XeF2 c) XeF6 d) None ofthese

9. The rfrost common oxidation state of 3d series elements is

a) +2 b) +3 c) +4 d) +l
10. Which of the following ligands form a chelate

a) Acetate b) Oxalate c) Cyanide d) Ammonia

I l. The IUPAC name of tertiary butyl bromide is

d) 2-Bromo-2-methylpropane b) 3-Bromobutane

i) 4-Bromobutane d) 1,2-Bromo-3-methylpropane
12. Conversion ofethyt alcohol into acetaldehyde is an example of
a) Hydrolysis b) Reduction

c) Oxidation d) molecular rearrangement

l3.Oxidation oftoluene to benzaldehyde by chromyl chloride is called

a) Etard reaction b) Riemer- Tiemann reaction

c) WurE reaction d) Cannizaro's reaction

14. Amiire that cannot be prepared by Gabriel-phthalimide synthesis is

d) Aniline b) Benzyl amine

cf Methyl amin" d) ) rso-butylamine

15. The letter'D'in the carbohydrate c-D-Glucopyranose signifies

d) Dextrorotatry b) Configuration

i) Diamagnetic nature d) Mode of synthesis

II. Fill in the blanks by choosing the appropriate word from those given in the brackets:

I pyramidal, freon, morphine, pseudo first order, cellulose

acetate ] 1x5=5

16. used as semipermeable membrane in the desalination of sea water

---11--is
17. An acid hydrolysis ofethyl acetate is a reaction of
18. The geometry ofthe oxide ofxenon formed when XeF6 is hydrolysed is
19. is used as refrigerant in refrigerators and air conditioners.

20. An ezrample for narcotic analgesic is

 a

PART-B

III.Answer any four of the following. Each question carries two marks. 4 x 2=8

2l . Givd any two differences between Frenkel defect and Schottky defect.
22. Statt Kohlrausch law of independent migration of ions. Write the mathematical
expression for limiting molar conductivity of calcium chloride.
23. What is the rate of a reaction? Give an example for unimolecular reaction.
24. Give any two differences between lanthanoids and actinoidds.
25. How is Phenol converted into Salicylic acidby Reimer-Tiemann reaction? Write the equation.

26. What is the action of nitrating mixture on benzoic acid? Write the chemical equation.
27 . WhaS are antifertility drugs? Give an example
28. Mention any two differences between soaps and detergents.

ART-C
IV. Answer any four of the following. Each question carries three marks 4 x3 = 12

29. a) Write the balanced chemical equations for the reactions involved in the hydrometallurgy
ofgold.
b) Write the composition of copper matte (2+l)
30. a) Write any one anomalous property of nitrogen
b) Write the catalyst for the oxidation of ammonia by atmospheric oxygen
c) Name the gas liberated when copper reacts with dil. HNO3
3 l. Write the balanced chemical equations involved in the manufacture of sulphuric acid from
sulptur.dioxide by contact process (3)

32. Conrplete the following chemical equations (3)

(a) 2Ca(OHl, + 2 Cl2 + CaCl2+2H2O

(b) so, + cl2+ 2H2o .................+ 2 HCt

(c) Bh+3F2

33. a) Name the 3d-series element which do not exhibit variable oxidation state
-
b) Second ionization enthalpy ofcopper is exceptionally high. Give reason
c) Qr*'t*l is more stable than Cu*l(aq) , Give reason. (l+l+l)
34. a) Ifow is potassium permanganate prepared from pyrolusite? Write equations.
b) Write the formula to calculate spin only magnetic moment (2+l)
35. Using valence bond theory account for the hybridization, geometry and magnetic property of
lco(NHr)ol" (3)
36. a) Explain ionization isomerism with an example.

b) Give an example for heteroleptic complexes. (2+l)

 : PART-D
V. Answer any three of the following. Each question carries five marks' 3x5=15
:
(3)
37. a) Calculate the packing efficiency in body centered cubic lattice'
its unit
b) Silver forms ccp lattice and X-ray studies of its crystals show that the edge length of
cell is 408.6 pm. Calculate the density of silver (Atomic mass = 107'9 u)' (2)

38. a) The boiling point of benzene is 353.23 K. When l '80 g of a non-volatile solute was

.dissolved in 90 g of benzene, the boiling point is raised to 354.1I K. Calculate the molar
of the solute. (K5 for benzene is 2.53 K kg mol-') (3)
mass
(2)
b) which type of azeotrope show a large deviation from Raoult's law? Give an example.
a) The standard electrode potential for Daniell cell is I .l V. Calculate the standard
Gibbs
39.
n
cnergy for the reaction:

2n1.1* Cu*21"qy ---+ Zn+21"0; + Cq.1

b;' Write the equation for the anodic reaction during rusting of iron'
c)l Give one use of lead storage battery
(3+l+l)

40. a) Derive the integrated rate equation for the rate constant ofa Zero order reaction. (3)
'Write
b) the equation which relates rate constant of and temperature of a reaction. Name the
(2)
equation.

(3)
41. a) Explain Adsorption theory ofheterogeneous Catalysis
b) 1Define DialYsis of colloids. (l)
(l )
c)lWhat is Kraft temPerature?
o
VI. Answer any three of the following. Each question carries five marks 3x5=15

42. a).Write the SN2 reaction mechanism for the conversion of chloromethane to Methanol. Q)

b)ExplainFriedel-CraftsacylationreactionbytakingChlorobenzeneasanexample.Q)
reason. (1)
c) Chlorobenzene is less reactive towards nucleophilic substitution reaction. Give one

43. a) Write the three step mechanism involved in the conversion of Ethanol to Ethene
b) ldentify the products A and B in the following equation
cH.
I Excess Hl
H3C--1-O-C,Hs
cHs
(2+2+t)
 44.

Abetophenone Benzaldehyde (2)

b) Write the products A and B formed in the following reaction

KOH/ethylene glycol
* H2N-NH,
l.+ A E t l\2
,FO H,O
heat
(2)

c) Write the structure of products formed in the following reaction.

1,c..?o
tl o
. -,\ ll
Il I * . ,l_rr,__El
H^N''\'\l
(l)
45. a) How Benzamide is converted into aniline? Write the chemical equation. (2)
b) Explain Sandmeyer reaction using suitable example. (2)
c) Why aromatic primary amines can not be prepared by Gabriel Phthalimide synthesis. (l)
46. a) Write the Uaworth structure of Maltose (2)

b) Name any one nitrogen base present both in RNA and DNA (l)
c) Deficiency ofwhich vitamin causes scurvy disease. (l)
d) Name the amino acid which do not have chiral carbon atom (t)
47. a) How is Buna-N prepared? Write the equation. (2\

b) How is Nylon-6 prepared? Write the equation (2)

c) Give an example for biodegradable polymer (l)

Prepared py:
Dr. Lokesh K usc. pr'o
Chemistry Lecturer
Govt. P U College for boys (UU-0135)
Tiptur (T), Tumakuru (D)

':

I
 TUMAKURU DISTRICT P.U. COLLEGE PRINCIPALS' ASSOCIATION
PRACTICE PAPER.2
CHEMISTRY (34)
TIME:3hours lSminutes MAX.MARKS:70

Instructiom: (1) The question paper has four parts. All the four pafts are compulsory'
PART-A carries 20 marks, each question carries one mark.
I PART-B carries 8 marks. Each question carries two marks
PART-C carries 12 marks. Each question carries three marks
PART-D carries 30 marks. Each question carries five marks
(2) Write balanced chemical equations and draw diagrams wherever necessary.
Use log table and simple calculators if necessall
( Use of scientific calculator is not allowed)

i PART-A

I. Select the correct option from the given choices' 1x15=15

l. Tvoe of attractive force between molecules of HzO in ice is-

forces
a) London b) hydrogen bonding

b)ilectrostatic d) dipote-dipole

2. Oxygen. dissolved in water is an example for a binary solution ofthe type

a) gas in gas b) liquid in gas

b) gas in liquid d) liquid in liquid

3. Desalination of water is done by

osmosis
a) reverse b) filtration

c) osmosis d) boiling

4. The quantity ofelectricity required to reduce Cu*2 to Cu*l is

i-
a)2F b) 3F

c)'96487F d) lF
5. For the ieaction A + B ---' products, the rate law is r = k[A]rD [B]12, the total order is-
+
a) { b) tl2
b) tzero d) ll4
6. One of the following is WRONG regarding the characteristics of enzymes as catalysts
a) highly active at optimumpH b) highly active at optimum temperature

b) catalyse a specific reaction d) become inefficient ifcoenzymes are present

i
 7. Nickel is refined by

a) van Arkel method b) Mond's process

b) distillation d) liquation
8. A radioactive noble gas is-

a) He b) Ar c) Kr d) Rn
9. A col8ured ion in aqueous medium among the following
is_
a) Cr3* b) Sc3* c) Tia* d) Zn2t
10. The coordination number ofthe central metal ion in [Co(en)3]*3is
a) three b) two c) six d) four
I l. A geminal dihalide among the following is_

a) CHTCHCIz b) CHr=911-3.
c) CHr(Cl[HdCl) d) cH3-CH2-l
12. A Grignard reagent gives a primary alcohol when treated with
a) R-CO-R b) H-CHO
c) R-CHO d) Hzo
13. In Stephen reduction a nitrile conve(ed into
f,) amide b) alcohol
c) carboxylic acid d) aldehyde
14. The strongest base in gaseous state is

a) CH3-NH2 b) NH3
c) CHrNH-CHr d) (CH:)rN

15. A water-soluble vitamin is-

1)D b)C c)A d)K

II' Fill in the branks by choosing the appropriate word from those given
in the brackets:
[Helium, racemic mixture, solute, tranquiliser, Arrhenius] lx5:5
l6' The relative lowering of vapour pressure of solution containing a
non-volatile solute is equal to
the inole fraction of
l7' The ielation between the rate constant and activation energy is given
by-equation.
18. The iroble gas with ns2 configuration is_
19. An dquimolar mixture of enantiomers is called
20. Veronal is used as
 9

PART-B

III. Ansrver any four ofthe following. Each question carries two marks. 4x2=8

2l . What are diamagnetic substances? Give an example.

22. Mention any two methods of preventing corrosion of metals.

23. The rate constant ofa first order reaction is 3 x l0-3 s-1. Calculate its half-life in seconds.

24. Study ofactinoids is very difficult. Give reasons.

25. Write equation for the reaction between anisole and Brz in ethanoic acid. Name the major product.

26. Horv is a carboxylic acid prepared from a Grignard reagerrt? Give general equation.

27. Give an example each for- (i) antiseptic (ii) narcotic analgesic.

28. What is the role of the following in food- (i) BHA (ii) saccharin
t PART-C

IV. Answer any four ofthe following. Each question carries three marks 4x3=12

29. Explain the process of obtaining the blister copper from copper matte with equations. (3)

30. Foi the manufacture of ammonia by Haber's process-

(i) Draw the flow chart (ii) Give the equation with the conditions applied (3)

31. Complete the following equations: (l+l+l)

a) PbS (s) + 4 Or(g) ..-..---------- PbSO4+-

b) so2G) + cl2(g) charcoal -
silent electric discharse

32. a) Write the structure of chloric acid (HOClOz).

b) Mention any two anomalous properties of fluorine. (3)

33. Wliat are interstitial compounds of d-block metals? Write any two proporties of interstitial
cornpounds. (3)

34. How is potassium permanganate prepare d commercially from MnOz? Name the intermediate. (3)

35. Using VBT, explain hybridization, structure and magnetic property ofthe complex [CoF6]3-. (3)

36. a),Give the IUPAC name of [N(CO)41. (l+2)

b),What type of isomerism is exhibited by coordinate complexes having ambidentate ligands?

j
 0

PART-D
V. Answer any three of the following. Each question carries five marks.
3x5=15
37. a) Calculate the packing efficiency in body centered cubic lattice. (3)
b) Find the number particles per unit cell in FCC lattice. e)
38. a) when l8g ofa non-volatire sorute is dissolved in r50g ofwater, the freezing point
of H2o
decreases by 0.9K. calcurate the molar mass of sorute.(Ks of water is l.g6 K kg mor-r)
b) State Henry's law and give its mathematical form. e+2)
39. a) A cell reaction given as: N(s) + 2 Ag*(o.00lM)---+ Nir*(o.0lM) + 2Ag(s), calculate
the E
if Eo forNi(s)[Ni,.(aq) ll Ag.GO lAg(s) is 1.05 V. (3)

b) Write the equations for cathodic and anodic reactions of H2-O2 fuel cell.
(2)
40. a) Derive the integrated rate equation for the rate constant of a zero order reaction.
(3)

b) Explain the effect ofcatalyst on activation energy using a schematic graph.

(2)

41. a) Mention any three characteristics of chemisorption.

(3)

b) Write a note on electrophoresis ofa colloid.

(2)
i

VI. Answer any three ofthe following. Each question carries five marks.
3x5=15
42, a) write equations involved in SNlmechanism of conversion of tert-butyl bromide into
teft- butyl alcohol by heating with aq.KOH. Indicate the slowest step.
(3)

b) Explain Wurtz reaction with an example. e)

43' a) write the structure ofthe major organic product in the following reactions. (3)
i*
i) cH3 - cH {H, + H,O --l-----.-------
' i0 CH3 -CH2 -Br + CH3 -ONa-.------.-.-----

otl

iit)

d Zr,\at

b).IVrite the equation for Reimer-Tiemann reaction. e)

zl4. a) Give the mechanism for the addition of HCN to carbonyl
compound in presence of a base.
I

b) What is aldol condensation reaction? Give an example.

(3+2)
' 45. a) Bxplain preparation of benzene diazonium chloride from aniline. (2)
b) l{ow does aniline react with bromine water? (2)
c) Write the IUPAC name of trimethyl amine. (l)
a) (iive reactions to show the following in glucose

(i) a straight chain ofsix carbon atoms.

(ii) an aldehyde group. (2)
b) What are essential amino acids? Give an example. (l)
c) Name the sugar moiety present in DNA. (l)
47. a) How is Teflon manufactured? Mention one use of it. (3)
b) Cive an example each for (i) synthetic rubber (ii) biodegradable polymer (2)

o
Prepared by:
B. A. Harish
Chemistry Lecturer
Sarvodaya P U College
Tumakuru (D)
 run4AKURUDrsrR'"rFhtsfi
b.Jfl=rEH["rpALs'AssocrAiloN
j CIIEMISTRY (34)
TIME: thours
:' lsminutes MAX.MARKS:70
Instructiotrs: (1) The question paper has four parts. All the four parts are compulsory. :
i PART-A carries 20 marks, each question carries one mark.
; pAnt- B carries 8 marks. Each question carries two marks
;. PART-C carries 12 marks. Each question carries three marks
PART-D carries 30 marks. Each question carries five marks
' 12; Write balanced chemical equations and draw diagrams wherever necessary.
, ( Use ofscientific calculator is not allowed) ;

I. Select the correct option from the given choices. lxl5 : 15

l. Whiph of the following is not a ferro-magnetic ?

a) Cobalt b) Iron
ti
c) Manganese d) Nickel
2. A Molar solution is one that contains one mole of solute in
a) 10009 ofsolvent b) I L ofsolvent .:

c) I L ofsolution d) 22.4 L ofsolution

3. Which among the following binary solution will show positive deviation from Raoult's law?
a) Water-Hydrochloric acid b) Acetone-Chlorofom
c) Water-Nitic acid d) Ethanol- Acetone
4. An electro chemical cell can behave like an electrolytic cell when
d) E"ar = o b) Ecerr >Ec*r

5. Molecularity of the reaction 2 NO + Oz ---+ 2 NOz is

d)2 b) 3
q)4 Ol
6. Whiih one is not an emulsion
a) Foam b) Ice cream
o) Milk d) Butter
7. Zone refining method is used for the refining of
ri)Aluminium b) Copper
o) Germanium d) Gold

.q
 i

8. The most abundant noble gas in atmosphere is

Argon
a) b) Neon
c) Helium d) Krypton
9. ThJelement does not show variable valency is
Mungur"r"
u; b)Zinc
c) Iron d) Chromium
10. [EDTA]4 is an example for
a) ligand
Hexadentate b) Bidentate ligand
c) Monodentate ligand d) euadridentate ligand
I l. Name of the following reaction is

R-ct + Nal Acetone - R-t + Nacl

a) Fittig reaction b) Wurtz reaction
c) Finkelstein reaction d) Swartz reaction
a. Luc3s reagent does not react at room temperature with

a) l0- Alcohol b) 20- Alcohol c) both a and b d) 30- Alcohol

i
a. Which of the following compound undergo Cannizaro,s reaction ?

b) Acetaldehyde b) Acetone c) Benzaldehyde d) Benzoic acid

a. Hinsberg reagent is
i
a) C2H5COCI b) CoHsCOCI
c) CuHsSOzCl d) C:HsSo:Cl
15. Identify the nitrogenous base present only in RNA

a) Thymine b) Cyosine
C) Guanine d) Uracil

b) Fill in the blanks by choosing the appropriate word from those given in the brackets:
d
(Sodium Benzoate, Natural gas, Henry's raw, zero order reaction, chirar carbon)

Ix5=5
16. Preparation ofsoda water is based on the application of
17. lna , the half life period is directly proportional to initial concentration of
reactant.

18. The commercial source of Helium

19. The carbon attached to 4 different atoms/groups is called
20. An example for food preservative is

q
 PART.B
b) Answer any four of the following. Each question carries two marks. 4 x 2=g
21. Calculate number of atoms in BCC crystal Lattice
22. State Faraday's First law of electrolysis. Write its mathematical form.
23. Mention 2 conditions required for effective collision between two reacting molecules
24. Wrire any 2 causes for Lanthanide contraction
25. Expfain the preparation ofphenol from Cumene with equation
26. Among formic acid (Methonoic acid) and acetic acid (Ethanoic acid) which one is less acidic ?
Give reason.
27. What are antacids? Give one example.

28. What are broad spectrum antibiotic ? Give one example

,ART-C

c)
:
Answer any four of the following. Each question carries three marks 4 x 3 = 12
29. With neat labeled diagram describe the extraction of aluminium by Hall-Heroult process and

writb the cathodic and anodic equations (3)

30. Wrfte the balanced chemical equations with reaction conditions involved in the manufacture of
nitric acid by Ostwald process. (3)
3 L Merltion any 3 reasons for the anomalous behavior of oxygen. (3)
32. a) What are the interhalogen compounds? Give one example.
b) Why interhalogen compounds are more reactive than halogens?
33. Givii reasons:

a) Manganese exhibit highest oxidation state among 3d series elements.

b) Cu2*isparamagnetic.
c) Transition elements are good catalysts. (l +l+l)
34. wriie the balanced chemical equations in the manufacture ofpotassium dichromate from

chromite ore. (3)

35' on ?he basis ofvalence bond theory, explain hybridization, geometry and magnetic propeny
or [rui1cry412'
36. Statb any three postulates of Werner,s theory of coordination compounds. (3)
\

F'
 PART-D
d) Ansu er any three ofthe following. Each question carries five marks. 3x5=15
37. a) Calculate the packing efficiency in Face centered cubic lattice
b).4n element having atomic mass 63.1 g mol-r has face centered cubic unit cell with edge
length 3.608 x l0'E cm. Calculate the density ofthe unit cell.
(Given Na = 6.622 x 1023 atoms mol-r) (3+2)
38. a) l.7l g of sugar (Molar mass of sugar 342) is dissolved in 500 cm3 of a solution at 300K.
rrVhat will be its osmotic pressure? (Given R: 0.083 Lbar mol-rK-r;
b) What is reverse osmosis? Mention its one application. (3+2)
39. a) Calculate the emf of the cell in which the following reaction takes place.
Ni19 + 2 Ag+ (0.002 M)---+ Ni2* 10.t60 M; + 2 Ag 1.y given that E"g11 = 1.05 V.
b) Write any 2 methods to prevent the corrosion. (3+2)
40. a) Derive the integrated rate equation for the rate constant ofa first order reaction.
b) Write Arrhenius equation and name the terms. (3 +2)
41. a) What is homogeneous catalysis? Give one example
b) What is Brownian movement? How is it caused?
c) Mme a shape selective catalyst (2+2+1)
e) Answer any three of the following. Each question carries five marks 3xF15
42. a) Explain the mechanism ofthe conversion oftertiary butyl bromide into tertiary butyl
alcohol. Mention the order of reaction.
b) Explain Swartz reaction. (3+2)
43. a) Write the three steps involved in the mechanism ofacid catalyzed dehydration of ethanol to
dthane.

b) Explain the conversion ofphenol to picric acid. Write the equation. (3+2)
44. a) Write the structure of organic products formed in the following reaction.
. cocl
I

;.\ H,
pd+.so,
*
U
\ zn-nyncr
:Fo
L SnClHCl
R-CN
' 2. HrO*

b) Explain Etard's reaction with an example (3+2)

;
 I

45. a) Explain the preparation of methanamine by Gabriel - Phthalimide synthesis

b) Name the product formed when aniline is heated with chloroform and ethanolic potassium

hydroxide? Write equation. (3+2)

46. a) Write Haworth's structure of Sucrose and name the type ofbond between monosaccharides.

b) What is Zwitter ion? Write its general formula. (3+2)

47. a) How is Nylon-6 prepared? Mention its one use.

b) Explain vulcanization of rubber. (3+2)

o

Prepared lry:
Shridevi P.
Chemistry Lecturer
Empress Girls Govemment P U College (UU-0051)
Tumakuru (D)

.
I