Alcohol, Phenol and Ether

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Tucsdoy

papergold
Date: II

Acchs.Pheneland Ethex
CHhCHsCHs

Phenol
CHaCta H3CH,O-RIAX

Ax Ay

omern tatue c Atcohst:


CHaOH Methonl
CH2-CH
-CHa
HacHacHtaOHRuspyk
GLYCEROI Alcshsl
CH3-CH-CHa LRep-2-cl

CHzctHaCHyCsaH Butyl Acchal Gut-l-sl

CHg-q4-CH-at QMetylpusp-L-&
Cits
CH3
CHg-c-oH.
7benaeve haaCnd
papergold
Date

Nomenctatuxt of heno
PhencL
OH

CH3

OH
Catechsl Benzent L2de
Resckci Benzen L3diel
BenzenLcil

Nemenatuei
TUPACNam&
o
Ak
Ether
ALkare
Commern NameALku Akyl Ethc
Systemah Nam di Alku he
CH3-Q- CHa MeHhc Methan
GHs -O-Gtts Lo cthyl Ethex Ethoxy Elhan
papergold
Date I

Melhs EkapulEihi Meihezy ne


Hh-o-Ch CH¡CHa

ats-o-CHy Cts Hgtal PhenåL Etht Hkptexay bn2en


Mehyl iso- pkepyMthez iopan
CH3 Ethex

txample
7:1

Stuct Funchomal GKEUD:


-Alcohol
96 pice metx
upzamBand
ushena
is cihstangle bluo Coxbon amd
lo9S but n alshol Hudusgen
Jo8.1Gve Reoson
Band argle is alcehelis sliohtly ess
loBL
papergold
Date I

-Pheoot
Quaerhm phenk, Cackon Ghou pouiall couble bend
Gnd hat s he ellect it cctueraqsiuiy
Rsen Becauss
Shou pushaly sphybxidised Casben in benzenl
coakty bSY chaMacte and dus te
this, caben"shôu hght Electuenuqoliutty
éEthec
QLshn shy im Ethex bond angle is moe tham AlcehE
and Phent 2

AlLbhel and Phenol because ALkyl- Azyl

Bepuatien
Alcshal
1Aem Ad Catolyst Hyduakion

=tH,0
OH (Alcsnsl )
H
+ Ho

(Alcetel)
papergold
Date:II

ridahisn Methed i a40,)


Hyduaboaien Lydstgnpex Qrid
Ankrnaxkeok Rule
Khakasho

SHE
dinide
Fyd

cHa
Cso= CHy-CH¡-CH¡ -CHy-CHy -CH,B-H zHs-ak
CHs CtlaCH2
3C+a CHy CHtyOH + BcoH),
CHsHCt CH3 OHCH2 Alcohsl
CMa Yeild ) E6]

H RHO
Aldehude Chokmaldehyd
Re
R Ketrene

RO
oH Cassxshic.
AGd
papergold
-Reduimg Atdehyd Omd Ketent
Date 1 I

R
UAthy R-CH,O Redudmgts Ahent :
Fowec
Aldeyde qive Hteo
Spedes im Reochiom
OH 2-1-&AtHy
Na 8Hy
R-c-R R-CRI 3- fdy Pt/ Ni
Ketane
Finely iuisible "

R--OH R-CHOHL
LEAHy LNhGHy is mmsst
expensiveHcuing
S0Jox ndustkial puxpsc e use EsTERagent
R-c-oH.
Estex

Eum pignad Rragant


Metal
CHa ct-Crahnnayen
Hg
H, +

R KetenR--R'
y
/
yis UAHy
Rc
-RI OH
’R-CH,OH H2Acshsl
msst
Ase
pensiue
ve
wse
EsTudui
ER mg.
RoHot
papergold
Date

R-tg-X
Rat, CH t Hgo

ALRC RHgX H--0HgxtHho

X
RR'RHOH NqOLT

Ts ase kn8un as Caxbslic Ad

Stuing
+Noc
618K (3o3ae pyono
Chxom oLEUM CH,S,01)

Bengen Bemzin fheo


SuphemiC Aid
3 Chxogn
NH2
Benaen di NEN
Azoniuna
Na
Hola
Hao
Barzenc
de Azowvn
Chloids
papergold
Date 1I
CHSCHCHS
OH

Physia
BP o
Alcehe
Repadt
t
es fhenil

Phenol:
Ubally Alcahslanc Phend
Cexopaud te (Gthex SubstoncLShaueuth
omlea mass stoniaBPoS
Exampe : CHaCHaOH
CHg-0- CHg
Mleculax Mass- 4+6tlk- Hban
Boiing oint - 35LK Qt6t66Enu
Cy,CH,
MOleculay Maus- yuamL

Alcehl Cnd Ethex have Sam elclar


Mass butt
dilexenc in BrP because la alLehel hylegn
between tue meucules alcehol bendin
Casbsntake ntexelcu at atactitn
Plcohel GPm fm Hale
alkanc bcz ash m f Cakbé
‘ theL BPalss Tmuns5
papergold
Date:
NOTE: Chan Legth Susacafutat

lubilityi Maxe cmsunt a solate clissote

Alchsland hnel an cisselue im ater


im ane pkepten

Ro-H O-H-O

Because_alcohl and phênel beth can tm

Tiis tupe Cmpnd ake Hydusphsbi


Hyduophobic ismgt cisshve un LUatex- Tt is
Orily
: Tt
cepodh dissohie án bls, lipidaC Bshen)
Can ben Cham S9
28 t can take fax Hydorhebic pat als9 1
Solubiliky amd staxt Jem uwater and
dissotue im men- pelox
poxt Bengesa ,
NepthaleuCCla
papergold
Date

Ghemcal Bspedica
AlcohL Vex veKsatile m natw
Nudeephle e
Eledephile -Ve
Pleshol behaves aa a
Nclesphile :CHs-CHott
*OH thu bond blw QH8 buak
Ialcehe xaleose.
mudeephle
Alcshol alie behaue ke om Acd

Alcehel behaves as a Electuaphile :


CHg-Cth--H+ H

Cho-E Electkephile
papergold
Date:1|
tH
Metal
Salt
tMetal
GkNal
AGd

Sodium
Aoricl

CHz Ctla
341
Aluminium test buteal

enaxide
ONG

Reaction wth HX

R-QH + HX R-X + H,o

R-COR

ndet HA
R
papergold
Date:
1'ALkyl Chlgúcds RAkyl Chleßdu
Tuxbck NenSein 3Aleyt hl eicde

Sueucas
oithi
xagent pduaacloudiness mmediatey
CHs
Ans- CHa
CH

Keoction atlh Pxs CPhaspheuaus ihalid

ehydzaien (Batz
to Sous HaPos, H, Poy
Acd)theenaue H
ond fgm Akere
H2 Soy
+HO
H OH Akene
1'Acohs!
CHy-CH-H3 EK CH-CHs Ct, t H,O.
GH
2*Acshol CH
CHa--OH 3381

3Alcshl
322>L
-GKdex kReacuity hycxation
Nttxatin

phams
hituoO-

p-nitxephenl
papergold
DcterII

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