Chemical Kinetics DPP 01_773_1721738365303

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Neutron NEET 2024 Chemistry Sankalp

Chemical Kinetics
DPP - 01
Rate of Reaction, Ralation Between Rate of Reaction & Individual Rate
d[H2 ]
Q 1. For the reaction N2 + 3H2 ⟶ 2NH3, how are the rate of reaction expressions inter-related dt
and
d[NH3 ]
dt
?
1 d[H ] 1 d[NH3 ]
(a) − 3 dt2 = +2 dt
1 d[H2 ] 1 d[NH3 ]
(b) − 2 dt
= +3 dt
1 d[H2 ] 1 d[NH3 ]
(c) + 2 dt = − 2 dt
1 d[H ] 1 d[NH ]
(d) + 3 dt2 = − 2 dt 3

Q 2. Consider the reaction : 2N2O4 ⇌ 4NO2


d[N2 O4 ] d[NO2 ]
If − = k and = k′ then
dt dt
(a) 2k′ = k
(b) k ′ = 2k
(c) k ′ = k
1
(d) k = k′
4

Q 3. For the reaction 2NH3 ⟶ N2 + 3H2,


d[NH3 ] d[N2 ] d[H2 ]
If − dt
= k1 [NH3 ], dt
= k 2 [NH3 ], dt
= k 3 [NH3 ], then the relation between k1, k2 and k3
is
(a) k1 = k2 = k3
(b) k1 = 3k2 = 2k3
(c) 1.5k1 = 3k2 = k3
(d) 2k1 = k2 = 3k3

Q 4. Consider the reaction, 2N2O5 ⟶ 4NO2 + O2


In the reaction, NO2 is being formed at the rate of 0.0125 mol L-1 s-1. What is the rate of reaction at this
time?
(a) 0.0018 mol L-1 s-1
(b) 0.0031 mol L-1 s-1
(c) 0.0041 mol L-1 s-1
(d) 0.050 mol L-1 s-1

Q 5. For a reaction R ⟶ P, the concentration of a reactant changes from 0.05 M to 0.04 M in 30 minutes.
What will be the average rate of reaction in minutes?
(a) 4 × 10-4 M min-1
(b) 8 × 10-4 M min-1
(c) 3.3 × 10-4 M min-1
(d) 2.2 × 10-4 M min-1

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Neutron NEET 2024 Chemistry Sankalp
Chemical Kinetics
DPP - 01
Q 6. In a reaction, 2HI ⟶ H2 + I2, the concentration of HI decreases from 0.5 mol L-1 to 0.4 mol L-1 in 10
minutes. What is the rate of reaction during this interval?
(a) 5 × 10-3 M min-1
(b) 2.5 × 10-3 M min-1
(c) 5 × 10-2 M min-1
(d) 2.5 × 10-2 M min-1

Q 7. Nitrogen dioxide (NO2) dissociates into nitric oxide (NO) and oxygen (O 2) as follows:
2NO2 ⟶ 2NO + O2
If the rate of decrease of concentration of NO2 is 6.0 × 10-12 mol L-1 s-1. What will be the rate
of increase of concentration of O2?
(a) 3.0 × 10-12 mol L-1 s-1
(b) 6.0 × 10-12 mol L-1 s-1
(c) 1.0 × 10-12 mol L-1 s-1
(d) 1.5 × 10-12 mol L-1 s-1

Q8. The rate of disappearance of SO2 in the reaction, 2SO2 + O2 ⟶ 2SO3 is 1.28 × 10-5 M s-1. The rate
of appearance of SO3 is
(a) 0.64 × 10-5 M s-1
(b) 0.32 × 10-5 M s-1
(c) 2.56 × 10-5 M s-1
(d) 1.28 × 10-5 M s-1

Q 9. In a reaction, 2X ⟶ Y, the concentration of X decreases from 0.50 M to 0.38 M in 10 min. What is the
rate of reaction in M s-1 during this interval?
(a) 1 × 10-4
(b) 4 × 10-2
(c) 2 × 10-2
(d) 1 × 10-2

Q 10. For the reaction, 2N2O5 ⟶ 4NO2 + O2 rate and rate constant are 1.02 × 10-4 mol L-1 s-1 and 3.4 × 10-5
s-1 respectively. The concentration of N2O5 in mol L-1 will be
(a) 3.4 × 10-4
(b) 3.0
(c) 5.2
(d) 3.2 × 10-5

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Neutron NEET 2024 Chemistry Sankalp
Chemical Kinetics
DPP - 01
Answer Key

S 1. Ans. (a)

S 2. Ans. (b)

S 3. Ans. (c)

S 4. Ans. (b)

S 5. Ans. (c)

S 6. Ans. (a)

S 7. Ans. (a)

S 8. Ans. (d)

S 9. Ans. (a)

S 10. Ans. (b)


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