SAFETY DATA SHEET

Section 1. Identification
Product name : WAW436X
Product code : WAW436X

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Acidic Cleaning Agent

Print date : 8/16/2023

Validation date : 8/16/2023
Version : 2.03

Supplier's details : Baker Petrolite LLC

12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)

number (with hours of Baker Petrolite: 800-231-3606
operation) (001)281-276-5400
CHEMTREC Int'l 01-703-527-3887 (International 24 hour)
BPC

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : ACUTE TOXICITY (inhalation) - Category 4
substance or mixture SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Causes severe skin burns and eye damage.
Harmful if inhaled.
Precautionary statements
Prevention : Wear protective gloves, protective clothing and eye or face protection. Use only
outdoors or in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after
handling.
Response : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor. IF SWALLOWED: Immediately call a
POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER or doctor. Wash contaminated clothing before
reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON

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Section 2. Hazards identification

CENTER or doctor.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Hydrochloric acid 10 - 20 7647-01-0
Isopropanol 1-5 67-63-0
Polyoxyalkylenes 0.1 - 1 Trade secret.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes
while holding the eyelid(s) open. Check for and remove any contact lenses. Chemical
burns must be treated promptly by a physician.
Inhalation : Call a poison center or physician. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected
area with soap and mild detergent for at least 20 - 60 minutes. Wash contaminated skin
with soap and water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Chemical burns must
be treated promptly by a physician. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Ingestion : Call a poison center or physician. Wash out mouth with water. If material has been
swallowed and the exposed person is conscious, give small quantities of water to drink.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Chemical
burns must be treated promptly by a physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled.
Skin contact : Causes severe burns.
Ingestion : No known significant effects or critical hazards.

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Section 4. First aid measures

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : No specific data.
Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : carbon dioxide,carbon monoxide,halogenated compounds
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

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Section 6. Accidental release measures

Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). The spilled material may be neutralized with sodium carbonate,
sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the spilled
product. Note: see Section 1 for emergency contact information and Section 13 for
waste disposal.
If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep
in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Keep away from alkalis. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a dry, cool and well-ventilated area,
including any away from incompatible materials (see Section 10). Store locked up. Separate from
incompatibilities alkalis. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Hydrochloric acid ACGIH TLV (United States, 1/2022).
C: 2 ppm
OSHA PEL 1989 (United States, 3/1989).
CEIL: 5 ppm
CEIL: 7 mg/m³
NIOSH REL (United States, 10/2020).
CEIL: 5 ppm
CEIL: 7 mg/m³
OSHA PEL (United States, 5/2018).
CEIL: 5 ppm
CEIL: 7 mg/m³
CAL OSHA PEL (United States, 5/2018).
C: 2 ppm
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Section 8. Exposure controls/personal protection

TWA: 0.45 mg/m³ 8 hours.
TWA: 0.3 ppm 8 hours.

Isopropanol ACGIH TLV (United States, 4/2014).

STEL: 400 ppm, 0 times per shift, 15 minutes.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2013).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 10 hours.
TWA: 400 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.
Polyoxyalkylenes None.
Consult local authorities for acceptable exposure limits.
If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.
Biological exposure indices
No exposure indices known.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles. If inhalation hazards exist, a full-face respirator may be
required instead.
Hand protection : Chemical-resistant gloves.
Skin protection : Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin
contact.
Respiratory protection : If a risk assessment indicates it is necessary, use a properly fitted, air purifying or
supplied air respirator complying with an approved standard. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.

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Section 9. Physical and chemical properties and safety

characteristics
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid. [Clear to hazy.]
Color : Colorless to yellow.
Odor : Acidic.
Odor threshold : Not available.
pH : <1
: Neat - without dilution.
Melting point/freezing point : Not available.
Initial Boiling Point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: >93.4°C (>200.1°F) [SFCC]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability : Slightly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure : Not available.
Relative vapor density : Not available.
Relative density : 1.08
Density : 9 (lbs/gal)
Solubility(ies) :
Media Result
cold water Soluble
hot water Soluble

Partition coefficient: n- : Not applicable.

octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
VOC : Not available.
Pour Point : Not available.
Particle characteristics
Median particle size : Not applicable.

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, metals, acids
and alkalis.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Hydrochloric acid LC50 Inhalation Vapor Mouse (as 400 mg/m³ 4 hours
aerosol)
LC50 Inhalation Vapor Rat 3124 ppm 1 hours
LD50 Oral Rabbit 900 mg/kg -
LD50 Oral Rat - Female 238 to 277 mg/kg -
Isopropanol LC50 Inhalation Vapor Rat >10000 ppm 6 hours
LD50 Dermal Rabbit 6.29 g/kg -
LD50 Oral Rat 4700 mg/kg -
Polyoxyalkylenes LD50 Dermal Rabbit 5000 mg/kg -
LD50 Oral Rat 1000 mg/kg -
Irritation/Corrosion
No available toxicity data.
Sensitization
No available toxicity data.
Mutagenicity
No available toxicity data.
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Hydrochloric acid - 3 -
Isopropanol - 3 -
Reproductive toxicity
No available toxicity data.
Teratogenicity
No available toxicity data.
Specific target organ toxicity (single exposure)

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Section 11. Toxicological information

Name Category Route of Target organs
exposure
Isopropanol Category 3 - Narcotic effects

Specific target organ toxicity (repeated exposure)

Not applicable.
Aspiration hazard
Not available.

Information on the likely : Routes of entry anticipated: Dermal, Inhalation, Eyes.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled.
Skin contact : Causes severe burns.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : No specific data.
Skin contact : pain or irritation,redness,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

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Section 11. Toxicological information

Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
WAW436X Not Not Not 19.7 Not
available. available. available. available.
Hydrochloric acid Not Not Not 3 Not
available. available. available. available.
Isopropanol 4700 6290 Not Not Not
available. available. available.
Polyoxyalkylenes 1000 5000 Not Not Not
available. available. available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Hydrochloric acid Acute LC50 240000 µg/l Marine water Crustaceans - Carcinus maenas 48 hours
Acute LC50 282 ppm Fresh water Fish - Gambusia affinis 96 hours
Isopropanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours
Polyoxyalkylenes Acute EC50 0.22 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1400 to 1700 µg/l Fresh Crustaceans - Gammarus sp. 48 hours
water
Acute LC50 700 µg/l Fresh water Fish - Pimephales promelas - Fry 96 hours
Chronic NOEC 77 µg/l Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 160 µg/l Fresh water Fish - Pimephales promelas - 30 days
Adult

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Hydrochloric acid 0.25 - Low
Isopropanol 0.05 - Low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations

Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

Section 14. Transport information

DOT Classification TDG Classification IMDG IATA
UN number UN1789 UN1789 UN1789 UN1789

UN proper HYDROCHLORIC HYDROCHLORIC HYDROCHLORIC HYDROCHLORIC

shipping name ACID, SOLUTION ACID, SOLUTION ACID, SOLUTION ACID, SOLUTION
Transport 8 8 8 8
hazard class(es)

Packing group II II II II
Environmental No. No. No. No.
hazards

Additional information
DOT Classification : Reportable quantity 32777 lbs / 14880.8 kg [3639.9 gal / 13778.5 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.40-2.42 (Class 8).

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments
DOT Reportable Hydrochloric acid, 3642 gal of this product.
Quantity

Marine pollutant Not available.

North-America NAERG : 157

Section 15. Regulatory information

U.S. Federal regulations : TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are active or exempted.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Hydrogen chloride; Phosphoric acid, solution;
Formaldehyde, solution

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Section 15. Regulatory information

Clean Air Act (CAA) 112 regulated toxic substances: Hydrogen chloride
United States - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :
List name Status Ingredient name Name on list Conc.
United States - Clean Air Act Section Listed Hydrochloric acid Hydrochloric acid 10 - 20
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Methanol Methanol 0.1 - 1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Formaldehyde Formaldehyde 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)

SARA 302/304
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
Hydrochloric acid 10 - 20 Yes. 500 - 5000 -
Formaldehyde 0 - 0.1 Yes. 500 6.7 100 1.3
SARA 311/312
Classification : ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
SARA 313
Product name CAS number %

Supplier notification Hydrochloric acid 7647-01-0 10 - 20

Isopropanol 67-63-0 1-5
California Prop. 65
WARNING: This product can expose you to chemicals including formaldehyde, which is known to the State of
California to cause cancer, and methanol, which is known to the State of California to cause birth defects or other
reproductive harm. For more information go to www.P65Warnings.ca.gov.
Canada
Canada (CEPA DSL): : All components are listed or exempted.

Section 16. Other information

National Fire Protection Association (U.S.A.)

1 Flammability BPC
Health 3 0 Instability
Special

History
Date of printing : 8/16/2023
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available

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Section 16. Other information

SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

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