GR X CHEM RT 07.01.25 (1)

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CHEMISTRY REVISION TEST 07.01.

25 30M

Question - 1
Choose the correct answer from the given options: [5M]
(i) During the electrolysis of normal aqueous solution of Cu(II) chloride using graphite electrodes,
the anion which going to discharge at anode is:
(a) Cl- ion (b) OH- ion (c) Cu+2 (d) H+ ion
(ii) . If K+, H+ and Pb+2 ions migrate to cathode, such that concentration of K + ions is very high,
then the ion likely to discharge at cathode is:
(a) H+ (b) Pb+2 (c) K+ (d) all of these
(iii) . Assertion(A): Burning of magnesium ribbon to form MgO is a redox reaction:
Reason(R): Magnesium undergoes oxidation and oxygen undergoes reduction
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correctexplanation of A
(c) A is true but R is false
(d) A is false but R is true
(iv) Assertion(A): Carbon can easily reduce the oxides of highly reactive metals
Reason(R): Highly reactive metals have more affinity for oxygen than carbon
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correctexplanation of A
(c) A is true but R is false
(d) A is false but R is true
(v) The principal metal in an alloy known as type metal is:
(a) lead (b) tin (c) antimony (d) copper

Question-2
Match the following: [5M]

Column A Column B
(i) Highly reactive metals a) Iron pyrites
(ii) Pt and Au b) Aeroplane wings
(iii) Aluminium c) Extracted by electrolytic reaction
(iv) Moderately reactive metals d) Occur in free state
(v) FeS2 e) Galvanising
f) Oxides are broken by direct heating
g) Extracted by reduction using suitable
reducing agent

Question-3 [3M+2M]

(i) What products are formed when the following chemical compounds are electrolysed?

Compound Product at cathode Product at anode


Dil.H2SO 4
Molten lead bromide
Aqueous CuSO4 solution with
copper electrodes
(ii) Answer the following:
a) Name the element which serves as both as the anode and the cathode in the extraction of
aluminium?
b) Give the equation for the reaction which occurs at the anode when aluminium is extracted
by electrolysis?

Question -4

(i) Answer the following questions about electroplating a copper wire with silver: [3M+2M]
a) What ions must be present in the electrolyte?
b) Of what substance must the anode be made?
c) What sholud be made cathode?

(ii) Name an alloy of:


a) Lead used in joining metals for electrical welding
b) Iron used in manufacturing of surgical instruments

Question - 5

(i). Give reason: [3M+2M]

a) Although copper is a good conductor of electricity, it is a non-electrolyte?


b) An aqueous solution of sodium chloride conducts electricity?
c) In the electroplating of an article with silver, the electrolyte sodium argento -cyanide
Solution is preffered over silver nitrate solution?

(ii). The following questions are relevant to the extraction of Aluminium:


a) State the reason for addition of caustic alkali to bauxite ore during purification of bauxite?
b) Give a balanced chemical equation for the above reaction?

Question - 6
Write balanced chemical equations for the following based on purification followed by
electrolytic reduction of fused alumina: [5M]

a) On diluting sodium meta aluminate with water and on cooling to 500C, it gets hydrolysed to
give a precipitate
b) The precipitate is filtered, washed, dried and ignited at 1000 oC
c) Anodic reactions which leads to replace the anodes time to time during electrolytic reduction
d) Reaction at anode, during the electrolysis of copper sulphate solution using platinum as
elctrodes(both anode and cathode)
e) Reaction at cathode, during the electroplating an article with nickel

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