Solution Report 172

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(0999DJA161103230019) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Main)


MAJOR TEST
(Academic Session : 2023 - 2024)
25-02-2024

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE


Test Type : Full Syllabus
ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. B C B D B B B C D B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D A B D B D A B B C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 2 4 3 2 4 5 2 30 4 3

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. C D C A D A A B D B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D C B C D C C D D A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 7 3 2 6 7 5576 2 5 1 5

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C B A C D C B C D D
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C A D D C C D B C C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 4 2 8 3 13 6 7 5 2 4

HINT – SHEET
PART-1 : PHYSICS 3. Ans ( B )
SECTION-I 3 5
v= v
2L 4L′
1. Ans ( B ) L′ 5
1 1 =
L = Iω = MR2 ω (∵ I = MR2 ) L 6
2 2
2. Ans ( C ) 4. Ans ( D )
Maxima of potential energy curve gives position
of unstable equilibrium
So, at x2, there is unstable equilibrium.
5. Ans ( B )
Δ U does not depends on path, work done by gas
Option (3) depends on path.

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6. Ans ( B ) 11. Ans ( D )
Let V be the volume of liquid flown out of
Force same ⇒ stress same
container
7. Ans ( B ) AL 3γ
0.5 V = [γΔT + 2γΔT + 3γΔT ] − A ( ΔT ) L
Velocity gradient = 3 2
2.5
× 10−2 3γ ALγΔT
2 = 2ALγΔT − AL ΔT =
as force on the plate due to viscosity is from 2 2
12. Ans ( A )
upper as well as lower portion of the oil, equal
dN hC
× =P
from each part, dt λ
Then, F = 2ηA dv = 2 × η × (0.5)
0.5
dN h
dz 1.25 × 10−2 F= = ma
dt λ

1 2
S= at
2
⇒ η = 2.5 × 10 – 2 kg – sec/m2
1 P
8. Ans ( C ) S= × × t2
2 mc
x = a cos ω t; y = a sin ω t
1 3 × 10−3
= × × (3600)2
vx = – a ω sin ω t; vy = a ω cos ω t 2 −3
50 × 10 × 3 × 10 8

^ ^
v¯ = −aω sin ωti + aω cos tj 36 × 36 × 104
= × 10−6 = 1.3mm
2 2 2
|v| = √a ω sin ωt + a ω cos ωt 2 2 2 1010

|v| = a ω 13. Ans ( B )

Distance = |v| ×t E→P = E→1 + E→2


π aπ
= 100 × =
200 2
9. Ans ( D ) E→1 = E.F. due to inner charge

E→2 = E.F. due to outer charge

4
( πR3 ρ)
1 3 Rρ
E→1 = ⋅ =
4π∈0 (6R)
2 108∈0
4πρ
( ) (7R3 )
−1 3 −7Rρ
E→2 = ⋅ =
4π∈0 (6R)
2 108∈0
x = 10 cos (2t – 60°)
14. Ans ( D )
Theory part

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15. Ans ( B ) 18. Ans ( B )

Applying Kirchoff's Law 24 – iR – Ki2 = 0 and


F = Bi1 ℓ + Bi2 ℓ = B ℓ (i1 + i2) = Bi ℓ
Prod = 2PR
19. Ans ( B )
16. Ans ( D ) Phase diff between top & middle is π .
& middle & bottom is π .
∴ between top & bottom is 2 π .

20. Ans ( C )
Total energy of SHM (After impulse)
1
mω2 A2 = mω2 A21
4−Q 1−Q 1+Q 2
after redistribution, 2
+
1

1
=0
∴ A1 = √2A
Q = 0.8
charge on 2F capacitor reduces by 20 % PART-1 : PHYSICS
SECTION-II
17. Ans ( A )
R1 R2 200 20 1. Ans ( 2 )
R= = = Ω
1 1
R1 + R2 30 3 E = −(13.6eV )Z 2 ( − )
2
(Z + 2) Z2
dR dR dR
= 21 + 22 Z 2 − (Z + 2)
3
4(Z + 1) × 13.6
R2 R1 R2 = −13.6 × (
2
) =
2
eV ...(i)
(Z + 2) (Z + 2)

dR 1 0.5 h2
400
= + [Now energy of electron is k= ;
100 400 2λ2 m
9

4 1 9 1 h
( we have λ = )
dR = + = = Ω
2mk
9 18 18 2 √

or, k = 6eV
4(Z + 1) × 13.6
So, = 6 + 4.2 = 10.2eV
(Z + 2)2
Z+1 3
or, 2
= ⇒ (Z − 2)(3Z + 2) = 0
(Z + 2) 16

So, the value of Z = 2 (neglecting the

negative/fractional value)

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2. Ans ( 4 ) 7. Ans ( 2 )
T
f∝√
μ
µ = ρ × Area of cross section = ρ π r2 L mL2
mg = α
1 2 3
∴f∝
r 3 g 3
α= = (2) rad/s2
3. Ans ( 3 ) 2 L 2

n=2

8. Ans ( 30 )
kq 9 × 109 × 9 × 10−6
V= =
Req = Rin CB 27
4 × 12 81 × 1000
= = 3Ω = = 3000 volt
4 + 12 27
4. Ans ( 2 ) 9. Ans ( 4 )
q = CV For equilibrium F = 0

dq
=C
dV
⇒i=C
dV x2 – 6x + 5 = 0
dt dt dt
V t
x = 1, 5
i0 sin 2πt
∴ ∫ dV = ∫ dt distance between = 5 – 1 = 4m
C
0 0
t 10. Ans ( 3 )
i0 i0
⇒V = ∫ (sin 2πt) dt = [cos 2πt]t0 Deviation produced by one is cancelled by the
C 2πC
0 other :
i
= 0 [cos 2πt − 1] Use δ = A(µ – 1)
2πC
−2i0 PART-2 : CHEMISTRY
∴ Vmax =
2πC SECTION-I
5. Ans ( 4 ) 1. Ans ( C )
N – mg = ma
2mg – mg = ma ⇒ a = 10
2t0 + 2 = 10
t0 = 4
6. Ans ( 5 ) ortho nitro phenol has intramolecular H – bond.
v ∝ x2 2. Ans ( D )
V′ 100 Be2 does not exist because according to MOT,
= ⇒ V ′ = 25V
V 4 bond order is zero.

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3. Ans ( C ) 10. Ans ( B )
Amphoteric oxide- ΔP
Acc. to R.L. V.P. ⇒ = XB
(A) CO(neutral oxide) P0
0.80 − 0.60 0.20
(B) N2O(neutral oxide) XB = = = 0.25
0.8 0.80
(C) Pb2O3 (Amphoteric oxide)
11. Ans ( D )
(D) N2O4 (acidic oxide)
(C) is the correct answer
4. Ans ( A )

is optically active but its


12. Ans ( C )
Cu
trans form is optically inactive. CH3CH2CH2OH −−−→ CH3CH2CHO.
300C

5. Ans ( D ) 13. Ans ( B )


sp3d2 Cu2+ Given reaction is an example of intramolecular
Cannizzaro reaction.
6. Ans ( A )
pH dependent equilibrium exist between CrO42– 15. Ans ( D )
and Cr2 O2−
7
AlCl3
7. Ans ( A ) −−−→
(E3 )H = −1.51 eV
P.E. = 2 × E 16. Ans ( C )
Theory based.
8. Ans ( B )
2NH3(g) N2(g) + 3H2(g) 17. Ans ( C )
17
1 + (2 – 1) (0.7) =
Mobs
Mobs = 10
9. Ans ( D ) (does not reduce the ester).
If SRP ↑­ oxidising power ↑­ reducing power ↓
SOP ↓
So order will be Br – < Fe2+ < Al (reduces both ketone and ester).
18. Ans ( D )
Fact

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PART-2 : CHEMISTRY 4. Ans ( 6 )
SECTION-II C4Hx + 4 + x O2 → 4CO2 + x H2O
( )
4 2
1. Ans ( 7 ) x
10 ml 10 (4 + ) ml
4
(i) Planar molecules → XeF2, ClF3, H2O,
= 55 ml
[XeF5] – , I3 – , BCl3, XeF4
(ii) SF4 → See - Saw shape ∴x=6
PCl5 → Trigonal bipyramidal
5. Ans ( 7 )
SF6 → Square bipyramidal Equivalent of acid and base are same. Hence
IF7 → Pentagonal bipyramidal resulting solution is neutral.
2. Ans ( 3 ) 6. Ans ( 5576 )
1
t1/2 ∝ where P → partial pressure
(P )n−1
(t1/2 )1 n−1
P2
=( )
(t1/2 )2 P1
n−1
235 250
=( )
Δ Hformation = IE1 + Δ Heg1 + LE
940 500

1 1
n−1 = 495.8 + ( – 325) + ( – 728.4)
=( )
4 2
= – 557.6
2 n−1
1 1
( ) = ( ) = – 5576 × 10 – 1 KJ/mol.
2 2
Note: The above calculation is not for
n=3
Δ Hformation but for Δ HReaction.

3. Ans ( 2 ) But on the basis of given data it is the best ans.


(M → Mn+(0.02M) + ne– ) × 2 7. Ans ( 2 )
(2H+ + 2e– → H2) × n ΔU = q + w
300 = 400 – 0.5 × Δ V × 100
2M + 2nH+ → 2Mn+ + nH2
Δ V = 2L
(0.02)2
0.81 = (0.76 + 0) – 0.0591 log 8. Ans ( 5 )
2n (1)2n
0.0591 b, c, d, g, h
⇒ (0.81 – 0.76) = log 4 × 10–4
2n
n = – 0.0591 × log 4 × 10–4
2 × 0.5
= – 0.591 (–4 + 0.6) = 2.

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9. Ans ( 1 ) 3. Ans ( A )
Optically active compounds rotate PPL.

PART-3 : MATHEMATICS
SECTION-I
1. Ans ( C )
Max. |z – w| = c1c2 + r1 + r2 = 5 + √2
Take the image of B in line y = x – 1 say Q.
where c1,c2, r1,r2 are the centres & radius of the
x−6 y+1 −2 (6 + 1 − 1)
given two circles. = = = Q(0, 5)
1 −1 2
2. Ans ( B )
∴ Max|PA – PB| = |PA – PQ| = 2
¯ = zw
z+w ¯ , |z| = 1
4. Ans ( C )

⇒z=
¯ −1
w
(x – 1)2 + (y – 2)2 = 4
¯
|w| x = 1 + 2cos θ
⇒ |z| = =1
¯ − 1|
|w
y = 2 + 2sin θ
⇒ |w| = |w – 1|
⇒ x2 + y2 = (1 + 2cos θ )2 + (2 + 2sin θ )2
⇒ w lies on perpendicular =1 + 4cos θ + 4cos2 θ + 4 + 4sin2 θ + 8sin θ

bisector of line joining = 9 + 4cos θ + 8sin θ

⇒ x2 + y2 ∈ [ 9 − √42 + 82 , 9 + √42 + 82 ]
(0,0) and (1,0)
5. Ans ( D )
i.e. x = 1
2 x2 + y2 = 9 ⇒ x = 3cos θ , y = 3sin θ
9 9
+
9cos θ 9sin2 θ
2

= sec2 θ + cosec2 θ = 2 + tan2 θ + cot2 θ ≥ 4

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6. Ans ( C ) 11. Ans ( C )
Equation of radical axis x2
−1 ⩽ log2 ( ) ⩽ 1
2
10x + 4y – b – a = 0 1 x2
⇒ ⩽ ⩽ 2
2 2
Centre of first circle ( – 4, – 4)
⇒ 1 ⩽ x2 ⩽ 4
∴ 10( – 4) + 4( – 4) – b – a = 0

a + b = – 56 ⇒ x ∈ [−2, −1] ∪ [1, 2]

7. Ans ( B ) 12. Ans ( A )


It is chord with a given middle point i.e. Put x = cos θ
|sin θ|
x + y = 20 y=
1 + |cos θ|
1 1
∴ a = ,b = 13. Ans ( D )
2 2
dy
8. Ans ( C ) + xy = x ( Linear differential equation)
4
dx
t
−x2
∫ sin √xdx ∴ Solution is y (x) = 1 + e 2
t2 4t3 sin t2 2t sin t
lim = lim − =0 ∞ −x2
t→0 t2 t→0 2t 2t So, area = ∫ e 2 dx
0
9. Ans ( D )
1 14. Ans ( D )
tan2 x − 2
∫ tan−1 ( ) dx Domain : x + y + 1 > 0 & y – x + 2 > 0
3 tan x
0
squaring x + y + 1 > y – x + 2
1
tan x 1
=∫ [ tan−1 ( ) − tan−1 (cot x)] dx x>
2 2
0

1
π π 1
=k−∫ ( − x) dx = k − +
2 2 2
0

10. Ans ( D )
f(x) = [x] + 2 + [x]2 – 8
f(x) = ([x] + 3) ([x] – 2)
Clearly f(x) = 0 for x ∈ [2, 3) many one
Also output of f(x) is always an integer. shaded area indicates required region
1 3 3 9
⇒ f(x) is into A= × × = sq. units
2 2 2 8

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15. Ans ( C ) 19. Ans ( C )
−3π
sin – 1x + sin – 1y + sin – 1z = f(
2
=
1
2 )

–1 –1 –1 −π x−2 4
− 34
+ 66
⇒ sin x = sin y = sin z = (x−2)2 (x−2)
2
⇒ x = y = z = –1 (x − 2)
2
(x − 2)2
= 2
=
4 − 34(x − 2) + 66(x − 2) 2(3x − 7)(11x − 24)
⇒ xy + yz + zx = 3
2 7 24
16. Ans ( C ) ⇒ f( ) is discontinuous at x = 2, ,
x−2 3 11
11
2
Consider Sn = ∑ tan−1 20. Ans ( C )
r=1 r2
2
⇒ Sn = ∑ tan−1
1 + (r2 − 1)
n
⇒ Sn = ∑ tan−1 (r + 1) – tan – 1 (r – 1)
r=1

⇒ tan – 1 n + tan – 1(n + 1) – tan – 1 0 – tan – 1 1

π π π 3π
⇒ S∞ = + − ⇒ S∞ =
2 2 4 4
PART-3 : MATHEMATICS
17. Ans ( D )
e|x| (ea
2
−x2 − 1) SECTION-II
lim
a→x (a+x) sin(a−x).(a−x)
= e|x| 1. Ans ( 4 )
(a−x)
f(x + 2y) = 2yf(x) + xf(y) – 3xy + 1 ⇒ f(0) = 1
Now f(x) (|x2 – 1|) = 1 ⇒ |x2 – 1|=e – |x| Let y = 0, then f(x) = x +1
2. Ans ( 2 )
Need to check at doubtful points
discont at x ∈ I only
18. Ans ( B ) at x = – 1 ⇒ f ( – 1+) = 1 + 0 = 1
LHS lim fgh (0 − λ) = fg ( O+ ) = f ( I − )
⇒ f (– 1–) = 2 + 1 = 3
h→0
at x = 0 ⇒ f (0+) = 0 + 0 = 0
2
= 2(1 − λ) −2=0
⇒ f (0 – ) = 1 + 1 = 2
RHS lim fgh (0 + λ) = fg ( O+ ) at x = 1 ⇒ f (1+) = 1 + 0 = 1
h→0

= f (I − ) = 2(1 − λ) − 2 = 0
2 ⇒ f (1 – ) = 0 + 1 = 1
discont. at two points

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3. Ans ( 8 ) 7. Ans ( 7 )
1 0 2⎤
2

4 must be obtained on atleast one dice
A. adj (A ) = ⎢ 2 1 0⎥

1 0 1⎦
x = number of dice on which 4 is obtained
2
∵ A.(adjA) = A(adjA).(adjA) = |A| I adj(A)
required probability

1 0 2⎤
⇒ |A|adj(A) = ⎢ 2 1 0⎥ = P(x = 1) + P(x = 2) + P(x = 3) + P(x = 4)

1 0 1⎦ 4 4
C1 × 3 × 3 × 3 C2 × 3 2 4C
3 .3 1
= + + +
take determinant on both the sides 6 4
6 4
6 4
64
175
=
⇒ |A|5 = – 1 ⇒ |A| = – 1 1296
8. Ans ( 5 )
1 ⎡
0 2⎤
⇒ adjA = − ⎢ 2 1 0⎥ n = 5!6!

1 0 1⎦ m = 5! 6C2.5C4.2C1.4!
4. Ans ( 3 ) m
∴ =5
f( – 2.3) = 1 + | – 2.3| = 3.3 n
9. Ans ( 2 )
∴ f{f( – 2.3)} = f(3.3) = [3.3] = 3
−1 ⩽ log|x| |x − 2| ⩽ 1 (|x| > 1)
5. Ans ( 13 ) 1
⩽ |x − 2| ⩽ |x|
a2 + b2 = |I2 + A| |I2 − A| −1 |x| 
x∈(1,∞)

θ θ 1 ⩽ ∣∣x2 − 2x∣∣ ⇒ x2−2x ⩽ −1 or x2−


2x ⩾ 1
= sec2 × cos2 = 1  
2 2 x=1 x∈(−∞,1−√2]∪[1+√2,∞)
6. Ans ( 6 )
n! 5 but x ∈ (1, ∞ ) ⇒ x ∈ [ 1 + √2, ∞)
p= =
nn 324 tan2 θ
least value of ⇒ sec θ − cos θ
By hit and trial we get n = 6 sec θ
1
⇒ 1 + √2 − =2
1 + √2

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10. Ans ( 4 )
x y 3 2
+ =1 ⇒ + =1
a b a b
2 3
⇒ =1−
b a
2a (a − 3) + 3 6
⇒b= = 2( ) =2+
a−3 (a − 3) (a − 3)

a = 4, b = 8 & a = 2 but b = – 4

a = 5, b = 5 a = 1 but b = – 1
a = 6, b = 4 a = 0 but b = 0
a = 9, b = 3
Only positive integral values of a & b are
possible.

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