SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006 (REACH) Article 31, Annex II as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: SILKOLENE WASH-OFF

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Cleaning agent/ Cleaner

Uses advised against: No uses advised against identified.

1.3 Details of the supplier of the safety data sheet

Manufacturer / Supplier FUCHS LUBRICANTS (UK) PLC.

New Century Street
Hanley
Stoke-on-Trent, Staffordshire, ST1 5HU
UK

Telephone: +44 (0) 1782 203700

Contact Person: Product Safety department

Telephone: +44 (0) 1782 203700
E-mail: product.safety@fuchs-oil.com

1.4 Emergency telephone number: UK NHS: Dial 111. Ireland NPIS: Dial +353 1 8092566.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The product has been classified and labelled as hazardous according to regulation (EU) 1272/2008 (CLP).

Classification according to Regulation (EC) No 1272/2008 as amended.

Health Hazards
Serious eye irritation Category 2 H319: Causes serious eye irritation.

Hazard summary
Physical Hazards: No data available.

2.2 Label Elements

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Product name: SILKOLENE WASH-OFF

Signal Words: Warning

Hazard Statement(s): H319: Causes serious eye irritation.

Precautionary Statements

Prevention: P280: Wear eye protection.

Response: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several

minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.

2.3 Other hazards: By handling of mineral oil products and chemical products no particular
hazard is known when normal precautions (item 7) and personal protective
equipment (item 8) are kept.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

General information: Mixture based on ionic- and nonionic tensides in combination with
stabilizers. This product is applied only as solution or emulsion in water.

Chemical name Identifier Concentration * REACH Registration Notes

No.
alcohol, ethoxylated Polymer 1,00 - <3,00%
Dipropylene glycol methyl ether, EINECS: 252-104-2 1,00 - <5,00% 01-2119450011-60
mixed isomers
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.

Classification

Chemical name Identifier Classification

alcohol, ethoxylated Polymer CLP: Eye Irrit. 1;H318, Acute Tox. 4;H302
Dipropylene glycol methyl ether, EINECS: 252-104-2 CLP:
mixed isomers
CLP: Regulation No. 1272/2008.

For the wording of the listed hazard statements refer to section 16.

SECTION 4: First aid measures

General: Instantly remove any clothing soiled by the product.

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4.1 Description of first aid measures

Inhalation: Supply fresh air; consult doctor in case of symptoms.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Skin Contact: Wash with soap and water.

Ingestion: Rinse mouth thoroughly.

4.2 Most important symptoms Causes serious eye irritation.

and effects, both acute and
delayed:

4.3 Indication of any immediate When handing over this safety data sheet, please make the remark:
medical attention and "Cleaner". Get medical attention if symptoms occur.
special treatment needed

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing CO2, fire extinguishing powder or fog like water spraying. Extinguish larger
media: fires with alcohol resistant foam or spray water with suitable surfactant
added

Unsuitable extinguishing Water with a full water jet.

media:

5.2 Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or
mixture:

5.3 Advice for firefighters

Special fire fighting Move container from fire area if it can be done without risk. Dispose of fire
procedures: debris and contaminated fire fighting water inaccordance with official
regulations. Collect contaminated fire fighting water separately. It must not
enter drains.

Special protective Self-contained breathing apparatus and full protective clothing must be
equipment for fire-fighters: worn in case of fire.

SECTION 6: Accidental release measures

6.1 Personal precautions, In case of spills, beware of slippery floors and surfaces.
protective equipment and
emergency procedures:

6.2 Environmental Precautions: Prevent from spreading (e.g. by binding or oil barriers). Avoid release to the
environment. Environmental manager must be informed of all major
spillages. Prevent further leakage or spillage if safe to do so. Do not allow
to enter drainage system, surface or ground water.

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Product name: SILKOLENE WASH-OFF
6.3 Methods and material for Absorb with liquid-binding material (sand, diatomite, acidbinders, universal
containment and cleaning binders, sawdust). Dispose of the material collected according to
up: regulations. Stop the flow of material, if this is without risk.

6.4 Reference to other See Section 8 of the SDS for Personal Protective Equipment. See Section
sections: 7 for information on safe handling See Section 13 for information on
disposal.

Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk.

SECTION 7: Handling and storage:

7.1 Precautions for safe Avoid contact with eyes. Wash hands thoroughly after handling. Do not eat,
handling: drink or smoke when working with the product. Take usual precautions
when handling mineral oil products or chemical products. Prevent formation
of aerosols. Observe good industrial hygiene practices. Provide adequate
ventilation.

7.2 Conditions for safe storage, Local regulations concerning handling and storage of waterpolluting
including any products have to be followed.
incompatibilities:

7.3 Specific end use(s): Not applicable

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Occupational Exposure Limits
Chemical name Type Exposure Limit Values Source

Dipropylene glycol methyl TWA 50 ppm 308 mg/m3 UK. EH40 Workplace Exposure Limits (WELs)
ether, mixed isomers (12 2011)

8.2 Exposure controls

Appropriate engineering Provide adequate ventilation. Ventilation rates should be matched to
controls: conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment

General information: Wash hands before breaks and after work. Use personal protective
equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the
personal protective equipment. The usual precautionary measures should
be adhered to inhandling the chemicals or the mineral oil products.

Eye/face protection: Safety glasses (EN 166) recommended during refilling.

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Product name: SILKOLENE WASH-OFF
Skin protection
Hand Protection: Material: Nitrile-butadiene rubber (NBR).
Min. Breakthrough time: >= 480 min
Recommended thickness of the material: >= 0,38 mm

Avoid long-term and repeated skin contact. Suitable gloves can be

recommended by the glove supplier. Use skin protection cream for
preventive skin protection. Protective gloves, where permitted in acc. to
safety directions. The exact break through time has to be found out by the
manufacturer of the protective gloves and has to be observed.

Other: Do not carry cleaning cloths impregnated with the product in trouser
pockets. Wear suitable protective clothing.

Respiratory Protection: Ensure good ventilation/exhaustion at the workplace. Avoid breathing

vapour/ aerosol.

Thermal hazards: Not known.

Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.

Environmental Controls: No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Yellow-green
Odor: Characteristic
Odor Threshold: Not applicable for mixtures
pH: 11,5 - 12,5 (, 20 °C)
Freezing point: Not applicable for mixtures
Boiling Point: Value not relevant for classification
Flash Point: Not applicable
Evaporation Rate: Not applicable for mixtures
Flammability (solid, gas): Value not relevant for classification
Flammability Limit - Upper (%)–: Not applicable for mixtures
Flammability Limit - Lower (%)–: Not applicable for mixtures
Vapor pressure: Not applicable for mixtures
Vapor density (air=1): Not applicable for mixtures
Density: 1,00 g/cm3 (15 °C)
Solubility(ies)
Solubility in Water: Soluble
Solubility (other): No data available.

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Product name: SILKOLENE WASH-OFF

Partition coefficient (n-octanol/water): Not applicable for mixtures

Autoignition Temperature: Value not relevant for classification
Decomposition Temperature: Value not relevant for classification
Flow time Value not relevant for classification
Explosive properties: Value not relevant for classification
Oxidizing properties: Value not relevant for classification
9.2 Other information No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity: Stable under normal use conditions.

10.2 Chemical Stability: Stable under normal use conditions.

10.3 Possibility of hazardous Stable under normal use conditions.

reactions:

10.4 Conditions to avoid: Stable under normal use conditions.

10.5 Incompatible Materials: Strong oxidizing substances. Strong acids. Strong bases.

10.6 Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

SECTION 11: Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Ingestion: No data available.

Skin Contact: No data available.

Eye contact: Causes eye irritation.

11.1 Information on toxicological effects

Acute toxicity

Oral
Product: ATEmix: 20.000 mg/kg
Specified substance(s)
alcohol, ethoxylated LD 50 (Mouse): 500 - 2.000 mg/kg

Dipropylene glycol methyl LD 50 (Rat): 5.135 mg/kg

ether, mixed isomers

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Dermal
Product:
Not classified for acute toxicity based on available data.
Specified substance(s)
Dipropylene glycol methyl LD 50 (Rat): 9.500 mg/kg
ether, mixed isomers

Inhalation
Product:
Not classified for acute toxicity based on available data.

Skin Corrosion/Irritation:
Product: Based on available data, the classification criteria are not met.

Serious Eye Damage/Eye Irritation:

Product: Based on available data, the classification criteria are met.

Respiratory or Skin Sensitization:

Product: Skin sensitizer: Based on available data, the classification criteria are not
met.
Respiratory sensitizer: Based on available data, the classification criteria
are not met.

Germ Cell Mutagenicity

Product: Based on available data, the classification criteria are not met.

Carcinogenicity
Product: Based on available data, the classification criteria are not met.

Reproductive toxicity
Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Single Exposure

Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Repeated Exposure

Product: Based on available data, the classification criteria are not met.

Aspiration Hazard
Product: Based on available data, the classification criteria are not met.

Other adverse effects: No data available.

SECTION 12: Ecological information

12.1 Toxicity

Acute toxicity
Product: Based on available data, the classification criteria are not met.

Fish
Specified substance(s)
Dipropylene glycol methyl LC 50 (Fish, 96 h): > 1.000 mg/l (OECD 203)

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ether, mixed isomers

Aquatic Invertebrates
Specified substance(s)
alcohol, ethoxylated EC 50 (Water Flea, 48 h): 10 - 100 mg/l

Dipropylene glycol methyl EC 50 (Water Flea, 48 h): 1.919 mg/l (OECD 202)
ether, mixed isomers

Chronic ToxicityProduct: Based on available data, the classification criteria are not met.

12.2 Persistence and Degradability

Biodegradation
Product: Not applicable for mixtures
Specified substance(s)
Dipropylene glycol methyl 75 % (28 d, OECD 301F) Readily biodegradable
ether, mixed isomers

12.3 Bioaccumulative potential

Product: Not applicable for mixtures

12.4 Mobility in soil:

Product: Not applicable for mixtures

12.5 Results of PBT and vPvB The product does not contain any substances fulfilling the PBT/vPvB criteria.
assessment:

12.6 Other adverse effects: No data available.

Water Hazard Class Classification not possible

(WGK):

SECTION 13: Disposal considerations

13.1 Waste treatment methods

General information: Dispose in accordance with all applicable regulations.

Disposal methods: Do not empty into drains; dispose of this material and its container in a safe
way. When storing used products, ensure that the waste categories and
mixing instructions are observed.

European Waste Codes

07 06 01*: aqueous washing liquids and mother liquors

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Product name: SILKOLENE WASH-OFF
SECTION 14: Transport information

ADR/RID
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
Hazard No. (ADR): –
Tunnel restriction code: –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

ADN
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
14.3 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

IMDG
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
EmS No.: –
14.3 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

IATA
14.1 UN Number: –
14.2 Proper Shipping Name: –
14.3 Transport Hazard Class(es):
Class: Non-dangerous goods
Label(s): –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

EU Regulations

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Product name: SILKOLENE WASH-OFF

Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none

Regulation (EC) No. 850/2004 on persistent organic pollutants: none

15.2 Chemical safety No Chemical Safety Assessment has been carried out.
assessment:

SECTION 16: Other information

Revision Information: Vertical lines in the margin indicate an amendment.

Wording of the H-statements in section 2 and 3

H302 Harmful if swallowed.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.

Other information: The classification complies with the current EU lists; however, it has been
supplemented with expert literature information and information provided
by/about our company. It was derived from the test data and/or the
application of the conventional method.

Revision Date: 13.04.2018

Disclaimer: The data contained in this safety data sheet are based on our current
knowledge and experience and are given to the best of our knowledge and
belief. It characterizes the product only with regard to safety requirements for
handling, transport and disposal. The data do not describe the product's
properties (tech. product specification). Neither should any agreed property
nor the suitability of the product for any specific technical application be
deduced from the data contained in this safety data sheet. Modifications on
this document are not allowed. The data are not transferable to other
products. In the case of mixing the product with other products or in the case
of processing, the data in this safety data sheet are not necessarily valid for
the new-made material. It is the responsibility of the recipient of the product to
observe federal, state and local law. Please contact us to obtain up-to-date
safety data sheets. This document was issued electronically and has no
signature.

Issue Date: 18.08.2015

Revision Date: 13.04.2018 Version: 2.3
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