SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

2.0 10/05/2022 000000259967 Date of first issue: 11/16/2020

SECTION 1. IDENTIFICATION

Product name : MasterFlow 648 PART B

Product code : 000000000055361032 000000000055361032

Manufacturer or supplier's details

Company name of supplier : Master Builders-Construction Systems
US, LLC

Address : 23700 CHAGRIN BLVD

Beachwood OH 44122

Emergency telephone : ChemTel: +1-813-248-0585

National Emergency Tele- : USA: +1-800-255-3924 ChemTel contract no. MIS9240420

phone Number

Recommended use of the chemical and restrictions on use

Recommended use : Injection or grouting applications

Restrictions on use : Reserved for industrial and professional use.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Oral) : Category 4

Skin corrosion : Category 1B

Serious eye damage : Category 1

Skin sensitization : Category 1

Specific target organ toxicity : Category 3 (Respiratory system)

- single exposure

Short-term (acute) aquatic : Category 3

hazard

Long-term (chronic) aquatic : Category 2

hazard

GHS label elements

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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Hazard pictograms :

Signal Word : Danger

Hazard Statements : H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H402 Harmful to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements :
Prevention:
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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Other hazards
Use of part A and part B without Part C in this three part product system is not recommended es-
pecially when applied to small spaces. The mixing of part A and part B generates heat, which
may cause the mixture of A and B without part C to spurt violently from voids, thereby creating
the potential for unexpected contact with product on exposed skin or in eyes.
Avoid contact with water, alcohols, acidic, basic, or oxidizing materials.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Amines

fatty acids

Components
Chemical name CAS-No. Concentration (% w/w)
Fatty acids, tall-oil, reaction products 68953-36-6 >= 50 - < 70
with tetraethylenepentamine
triethylenetetramine 112-24-3 >= 10 - < 20
2,4,6- 90-72-2 >= 5 - < 10
tris(dimethylaminomethyl)phenol
3,6,9-triazaundecamethylene-1,11- 112-57-2 >= 5 - < 10
diamine
Bis[(dimethylamino)methyl]phenol 71074-89-0 >= 1 - < 5
Fatty acids, C18-unsatd., trimers, 147900-93-4 >= 0.1 - < 1
compds. with oleylamine
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : First aid personnel should pay attention to their own safety.
Immediately remove contaminated clothing.

If inhaled : If difficulties occur after vapour/aerosol has been inhaled,

remove to fresh air and seek medical attention.

In case of skin contact : After contact with skin, wash immediately with plenty of water
and soap.
Under no circumstances should organic solvent be used.
If irritation develops, seek medical attention.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Remove contact lenses.
Keep eye wide open while rinsing.
Seek medical advice.
If eye irritation persists, consult a specialist.

If swallowed : Immediately rinse mouth and then drink 200-300 ml of water,

seek medical attention.
Do not induce vomiting unless told to by a poison control cen-
ter or doctor.

Most important symptoms : Harmful if swallowed.

and effects, both acute and Causes severe skin burns and eye damage.

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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delayed May cause an allergic skin reaction.

May cause respiratory irritation.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam

Water spray
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : water jet

media

Hazardous combustion prod- : nitrogen oxides

ucts fumes/smoke
carbon black
corrosive gases/vapours

Further information : The degree of risk is governed by the burning substance and
the fire conditions.
Contaminated extinguishing water must be disposed of in
accordance with official regulations.

Special protective equipment : Firefighters should be equipped with self-contained breathing

for fire-fighters apparatus and turn-out gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective clothing.

tive equipment and emer- Do not breathe vapour/aerosol/spray mists.
gency procedures Handle in accordance with good building materials hygiene
and safety practice.

Environmental precautions : Contain contaminated water/firefighting water.

Do not discharge into drains/surface waters/groundwater.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Wear personal protective equipment.

Avoid contact with the skin, eyes and clothing.
Avoid inhalation of mists/vapours.
Ensure adequate ventilation.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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place.
Protect from direct sunlight.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.

Recommended storage tem- : > 32 °F / > 0 °C

perature

Further information on stor- : PROTECT FROM FREEZING.

age stability

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
triethylenetetramine 112-24-3 TWA 1 ppm US WEEL
3,6,9-triazaundecamethylene- 112-57-2 TWA 5 mg/m3 US WEEL
1,11-diamine
Engineering measures : Ensure adequate ventilation.

Personal protective equipment

Respiratory protection : Wear appropriate certified respirator when exposure limits
may be exceeded.
Use NIOSH approved respiratory protection.

Hand protection

Remarks : Wear chemical resistant protective gloves. Manufacturer's

directions for use should be observed because of great di-
versity of types.

Eye protection : Tightly fitting safety goggles (chemical goggles) and face
shield.

Skin and body protection : Body protection must be chosen depending on activity and
possible exposure, e.g. head protection, apron, protective
boots, chemical-protection suit.

Protective measures : Avoid contact with the skin, eyes and clothing.
In order to prevent contamination while handling, closed
working clothes and working gloves should be used.
Handle in accordance with good building materials hygiene
and safety practice.

Hygiene measures : When using, do not eat, drink or smoke.

Hands and/or face should be washed before breaks and at
the end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

2.0 10/05/2022 000000259967 Date of first issue: 11/16/2020

Replace if necessary (e.g. pinhole leaks).

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste

Color : amber

Odor : ammonia-like

Odor Threshold : No data available

pH : alkaline

Melting point : No data available

Boiling point : No data available

Flash point : approx. 300 °F / 149 °C

Method: Standard Method of Test for Flash Point by Setaflash

Closed Tester

Evaporation rate : No data available

Flammability (solid, gas) : not highly flammable

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapor pressure : < 1 hPa (68 °F / 20 °C)

Relative density : No data available

Density : approx. 0.96 g/cm3 (approx. 68 °F / 20 °C)

Solubility(ies)
Water solubility : insoluble (68 °F / 20 °C)

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Autoignition temperature : approx. 561 °F / 294 °C

Decomposition temperature : No decomposition if stored and handled as pre-

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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scribed/indicated.

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Explosive properties : Not explosive

Oxidizing properties : Based on its structural properties the product is not classified
as oxidizing.

Sublimation point : No data available

Molecular weight : Not applicable

Metal corrosion rate : Corrosive effects to metal are not anticipated.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No hazardous reactions if stored and handled as pre-

scribed/indicated.

Chemical stability : The product is stable if stored and handled as pre-

scribed/indicated.

Possibility of hazardous reac- : The product is stable if stored and handled as pre-
tions scribed/indicated.

Conditions to avoid : See SDS section 7 - Handling and storage.

Incompatible materials : Strong acids

Strong bases
Strong oxidizing agents

Hazardous decomposition : No hazardous decomposition products if stored and handled

products as prescribed/indicated.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if swallowed.
Product:
Acute oral toxicity : Acute toxicity estimate: 1,614 mg/kg
Method: Calculation method

Skin corrosion/irritation
Causes severe burns.

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MasterFlow 648 PART B

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Serious eye damage/eye irritation

Causes serious eye damage.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
May cause respiratory irritation.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks : Health injuries are not known or expected under normal use.
The product has not been tested. The statements on toxicolo-
gy have been derived from the properties of the individual
components.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity : Harmful to aquatic life.

Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Components:

Fatty acids, tall-oil, reaction products with tetraethylenepentamine:

M-Factor (Acute aquatic tox- : 10
icity)

M-Factor (Chronic aquatic : 1

toxicity)

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

2.0 10/05/2022 000000259967 Date of first issue: 11/16/2020

Persistence and degradability

No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not discharge product into the environment without control.
mation The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual
components.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with national, state and local regula-
tions.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Do not discharge into drains/surface waters/groundwater.

Contaminated packaging : Dispose of container and any rinsate in an environmentally

safe manner.
Uncleaned empties should be disposed of in the same man-
ner as the contents.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE, TALLOIL FATTY
ACIDS, REACTION PRODUCTS WITH
TETRAETHYLENEPENTAMINE)
Class : 8
Packing group : II
Labels : 8
IATA-DGR
UN/ID No. : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE, TALLOIL FATTY
ACIDS, REACTION PRODUCTS WITH

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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TETRAETHYLENEPENTAMINE)
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo : 855
aircraft)
Packing instruction (passen- : 851
ger aircraft)
IMDG-Code
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE, TALLOIL FATTY
ACIDS, REACTION PRODUCTS WITH
TETRAETHYLENEPENTAMINE)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
UN/ID/NA number : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.

(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE, TALLOIL FATTY
ACIDS, REACTION PRODUCTS WITH
TETRAETHYLENEPENTAMINE)
Class : 8
Packing group : II
Labels : CORROSIVE
ERG Code : 153
Marine pollutant : yes

SECTION 15. REGULATORY INFORMATION

US State Regulations

Pennsylvania Right To Know

triethylenetetramine 112-24-3
3,6,9-triazaundecamethylene-1,11-diamine 112-57-2
New Jersey Right To Know
triethylenetetramine 112-24-3
3,6,9-triazaundecamethylene-1,11-diamine 112-57-2
The ingredients of this product are reported in the following inventories:
TSCA : All substances listed as active on the TSCA inventory

DSL : All components of this product are on the Canadian DSL

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SAFETY DATA SHEET

MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH

1 FLAMMABILITY

Health Instability
3 0 PHYSICAL HAZARD

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
cant hazards or risks. The "*" represents
Special hazard a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

US WEEL : USA. Workplace Environmental Exposure Levels (WEEL)
US WEEL / TWA : 8-hr TWA

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-
tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-
monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-
trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-
istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-

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MasterFlow 648 PART B

Version Revision Date: SDS Number: Date of last issue: 11/16/2020

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es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and
Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Con-
trol Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on
the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Revision Date : 10/05/2022

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

US / EN

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