Test ID : 197

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.CUMULATIVE TEST - 11. A

Std : Long term Max. Marks: 400
Test Date : 03.01.2022 CHEMISTRY & BOTANY Time : 2 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 100 x 4 = 400
CH 3 1) n-butane 2) n-pentane
| 3) n-hexane 4) isobutane
1. CH 3 − CHMgCl + CH 3 − C − OH  →P
| | 7. Which of the following reagent can be used for
CH 3 CH 3 the following conversion?
What is ‘P’?
1) Isobutane 2) n-butane
3) tert butyl chloride 4) propane
2. Isopropyl bromide on Wurtz reaction gives
1) Zn-Hg/HCl 2) NH2-NH2/OH-
1) Hexane
3) Red P + HI 4) All the above
2) Propane
8. CH3MgBr + CH3CH2OH → X
3) Isopropane
What is X?
4) 2,3-dimethylbutane
3. Which of the following alkane has lowest
boiling point? 1) CH4 2)
1) Isobutane 2) n-pentane
3) Isopentane 4) Neopentane
4. Which of the following compound(s) on 3) 4) CH3-CH3
hydrogenation produces n-Butane?
9. Pyrolysis of alkanes is a
1) 1-Butene 2) 2-Butene
1) Nucleophilic addition reaction
3) Both (1) and (2) 4) Isobutene
2) Free radical substitution reaction
5. Kolbe’s electrolysis of potassium propanoate
3) Electrophilic addition reaction
gives majorly
1) Butane 2) Propane 4) Free radical elimination reaction
3) Hexane 4) Ethane 10. Which of the following reagent used for the
conversion of n-hexane to benzene?
6. When ethyl chloride and n-propyl chloride
undergoes wurtz reaction which is not 1) Cr2O3 2) V2O5
obtained? 3) Mo2O3 4) All of these
 2 Test ID : 197
11. Which of the following conversion is incorrect? 17. Which of the following alkane oxidized by
Incomplete
1) CH4 + O2 → C(s) + H2O KMnO4
combustion
Mo 2 O3 1) propane 2) ethane
2) CH4 + O2  → HCHO + H2O
Cu /523K 3) n-butane 4) iso-butane
3) CH4 + O2  → 2CH3OH
light
3( CH COO ) Mn 18. C3H8 + Cl2  → C3H7Cl + HCl is an
4) CH3CH3+O2  2
→ CH3CHO+ H2O
example of which of the following type of
12. Number of monohalogenated products
(including stereoisomers) possible when reactions?
isopentane undergoes halogenation in presence 1) Free radical substitution reaction
of sunlight 2) Electrophilic substitution reaction
1) 4 2) 6 3) Free radical addition reaction
3) 5 4) 7 4) Electrophilic addition reaction
13. n-octane in presence of Cr2O3/Al2O3 at 873K
19. Possible products are
changes to
1) C6H12 + H2 2) C4H8 + C2H6
1) 2) 3) C3H6 + C2H4 + CH4 4) All
20. During electrolysis of sodium salt of acetic
acid, ethane is formed. Which of the following
3) 4) statement is wrong regarding it
1) 1 mole ethane and 2 mole CO2 released at
14. In iodination, for the preparation of anode 1mole H2 is released at cathode
iodomethane in good yield compound(s) used 2) Electrolytic solution left over turns blue
is litmus into red
1) HIO3 2) HgO
3) It follows free radical mechanism
3) HNO3 4) All of the above
4) Oxidation takes place at anode and
15. What is X in the following sequence of
reduction takes place at cathode
reactions?
X  Na NaOH/CaO
→ Z  → CH4 21. Eclipsed conformer of ethane is less stable
− 1 H2
2
than staggered because of
1) Methyl chloride 2) Ethanoic acid
1) Angle strain
3) Propane 4) Methanoic acid
2) Torisional strain
Cl 2
16. 
hν
→ A 3) Steric strain
(Major) 4) van der Waals strain
Among the monochlorinated products, the 22. The number of enantiomeric pairs formed
major product ‘A’ is when 2-methyl pentane is subjected to mono
chlorination is
1) 2) 1) 0 2) 1
Cl
Cl 3) 2 4) 3
23. C-C bond breaks preferentially than C-H bond
3) Cl 4) during pyrolysis of an alkane. The reason is
A
 3 Test ID : 197
1) C-C bond energy is less than that of C-H 28. Incorrect reaction in the following is
bond Cu (or ) Fe
1) 2CH4 + O2  → 2CH3OH
200o C
2) The intermediate formed when C-C bond Mo 2 O3
2) CH4 + O2  → HCHO + H2O
breaks is less stable
(O)
3) CH3 – (CH2)n – CH3  →
3) C-H bond is stabilised by hyper conjugation Manganese acetate

4) C-H bond is polar CH3(CH2)nCOOH + H2O

KMnO4
24. The alkane which is not formed when a 4) (CH3)3CH → CH3 − CH − CH 2 OH
|
mixture of n-propyl chloride and isopropyl CH 3
chloride is subjected to wurtz react ion, is 29. 1mole alkane required 3.5 moles of oxygen for
1) n-hexane complete combustion, then molar mass of
2) 2,-3 dimethyl butane alkane is ____ grams
3) 2-methyl pentane 1) 16 2) 30
4) 2,2 dimethyl butane 3) 44 4) 58
30. Of the five isomeric hexanes, the isomer which
25. Which statement is not correct regarding
can be give two monochlorinated compound is
halogenation?
1) n – hexane
1) Fluorination is fast when compared to other
2) 2, 3 – dimethyl butane
halogenation reaction
3) 2,2 – dimethyl butane
2) Iodination is slow and reversible 4) 2 – methyl pentane
3) HgO (or) HIO3 (or) HNO3 are added to 31. The reaction of ethane with Cl2 in the presence
suppress backward reaction during of sunlight form the products except
iodination 1) C2H5Cl 2) C4H10
4) Rearrangement takes place during 3) HCl 4) C3H8
halogenation 32. Statement-I : Purification by crystallization is
26. Column – I Column – II based on the difference in the solubility of the
Compound (Type of ‘H’ it has) organic compound and the impurities present
in it.
A) Neopentane P) 1o
Statement-II : Mixture of acetone and methyl
B) 2-methyl butane Q) 2o alcohol can be separated by fractional
C) Cyclo butane R) 3o distillation method.
D) Ethane 1) Both statement-I & II are correct
1) A-P, B-P,Q,R, C-Q, D-P 2) Both statement-I & II are false
2) A-P,Q, B-P,Q,R, C-Q, D-P 3) Statement-I is correct, II is wrong
3) A-R, B-P,Q, C-R, D-P 4) Statement-I is wrong, II is correct
33. Incorrect match.
4) A-Q, B-Q, C-S, D-R
Cr2 O3 (773K)
1) Sugar + Sand – Separated by crystallization
27. X →
Al2 O3 (500 − 600 atm)
Toulene then X : is 2) Aniline & Water – Separated by steam
1) n-pentane 2) n-hexane distillation
3) 2-methyl hexane 4) n-heptane 3) Benzene and aniline – Fractional distillation
4) Camphor – Purified by sublimation
A
 4 Test ID : 197
34. Correct match is 3) Dumas method is used to calculate % of
a) Paper i) Partition nitrogen
chromatography chromatography 4) Halogens are estimated using carius method
b) Thin layer ii) adsorbent 41. In kjeldahl’s method the ammonia evolved
chromatography from 0.5g of organic compound is neutralized
c) Silica gel and iii) adsorption theory by 20ml of 1N H2SO4. Find % of nitrogen
alumina 1) 88% 2) 44%
d) Column iv) absorption theory 3) 56% 4) 22%
chromatography 42. Which is correct about paper chromatography?
1) a-i, b-ii, c-iii. d-iv 2) a-i, b-ii, c-iv, d-iii a) It is a adsorption chromatography
3) a-i, b-iii, c-ii, d-iii 4) a-i, b-iii, c-ii, d-iv b) it is a partition chromatography
35. Formula of Prussian blue is
c) it has a stationary phase only
1) K3[Fe(CN)6]
d) rate of adsorption and Rf values are
2) K4[Fe(CN)6].xH2O
inversely proportional
3) Fe4[Fe(CN)6]3.xH2O
1) a and c only 2) b and d only
4) [Fe(CN)5NOS]4-
3) a, b and c 4) a, b, c and d
36. 0.24g of organic compound gave 0.22 g of
43. How many chain isomers possible for C5H12?
CO2, the percentage of C in the compound is
1) 25% 2) 22% 1) 2 2) 3
3) 32% 4) 68% 3) 4 4) 5
37. In carious method 0.2g of organic compound 44. Sodium formate on Kolbe’s electrolytic
gave 0.188 g of AgBr. Find the percentage of Br method gives mainly
1) 60% 2) 27% 1) Methane 2) Ethane
3) 73% 4) 40% 3) Propane 4) Hydrogen
38. The substance which can be used as an 45. When two alkyl halides like methyl iodide and
adsorbent in column chromatography is ethyl iodide are involved in wurtz reaction
1) Al2O3 2) Na2O then the products are
3) Ca(OH)2 4) NaCl 1) only butane
39. Glycerol can be purified by 2) only ethane
1) Reduced pressure distillation 3) propane only
2) Normal distillation
4) mixture of ethane, propane and butane
3) Steam distillation
46. Among isomers of pentane which is correct
4) Fraction distillation
order of boiling point?
40. Which is incorrect?
1) isopentane > n-pentane > neopentane
1) Camphor can be purified by sublimation
2) neopentane > isopentane > n-pentane
2) In case nitrogen and sulphur both present in
3) n-pentane > isopentane > neopentane
an organic compound the product sodium
thiocyanate formed is blue in colour 4) n-pentane > neopentane > isopentane
A
 5 Test ID : 197
47. Why iodine substitution of alkanes need 53. Biosynthesis of amino acids occurs from
catalyst? A) Ketoacids B) Amino acids
1) iodine is low electro negative element C) Methane
1) A and B 2) B and C
2) iodination of alkane is reversible and slow
3) A and C 4) All of the above
3) iodine is weak oxidizing agent 54. More than one aminations are required for the
4) iodine is a solid synthesis of
1) Glutamic acid 2) Aspartic acid
48. 3) Glutamine 4) Both (2) and (3)
55. Incorrect statement from the following.
Here X is 1) Amides and ureides contain more nitrogen
1) Cr2O3 2) AlCl3 than amino acids
3) Al2O3 4) Pt 2) Ureids have high nitrogen to carbon ratio
49. Methane can be prepared by 3) In amides hydroxyl group of carboxylic
group replaced by amine group
1) Wurtz reaction 4) In legume roots, the energy required for N2
2) Reduction of alkyl halides fixation provided by photosynthesis
3) Kolbe electrolysis 56. Identify the intermediate/s which is/are formed
4) Decarboxylation of formic acid during biological nitrogen fixation.
Mo 2 O3 1) Diimine 2) Hydragene
50. CH3CH3  →X
3) Ammonium ion 4) Both (1) and (2)
(CH3COO) 2 Mn
CH3CH3 + O2  →Y 57. The net utilisation of electrons for the
X and Y are respectively production of 10 molecules of ammonia
1) both are acetaldehydes 1) 60 2) 30
3) 40 4) 8
2) both are acetic acid
58. Arrange the following events that are occur
3) x is acetaldehyde y is acetic acid during root nodule formation in a correct
4) x is acetone y is acetaldehyde order.
51. What are the forms of nitrogen that are A) Secretion of flavonoids by root hair
transported to other parts of the plants via B) Bacteria colonies around root hair and
xylem? attached to root hair.
A) Amino acids C) Infection thread formation
D) Root hair curling and hook formation
B) Amides
E) Differentiation of bacterial cells into
C) Urides
specialized N2 fixing cells
D) Inorganic nitrogen
1) A, B, C, D and E 2) A, B, D, C and E
1) A, B and C only 2) B, C and D only 3) D, E, C, A and B 4) E, C, D, A and B
3) A, C and D only 4) A, B, C and D 59. Identify correct statement w.r.t leg
52. Transaminase and glutamate dehydrogenase haemoglobin.
are belongs to the classes 1) It act as a oxygen scavenger and remove the
1) Oxidoreductases and transferases oxygen from the visinity of nitrogenase
respectively 2) It act as a oxygen scavenger and release the
2) Transferases and hydrolases respectively oxygen in the visinity of nitrogenase
3) Transferases and oxidoreductases 3) It act as nitrogen scavenger and remove the
respectively nitrogen from the visinity of nitrogenase
4) Oxido reductases and isomerases 4) It act as nitrogen scavenger and release the
respectively nitrogen in the visinity of nitrogenase

A
 6 Test ID : 197
− +
60. What is the first stable product biological 66. 2NH3 + 3O2 → 2NO2 + 2H + 2H2O
nitrogen fixation? The above reaction is carried out by
1) Diimine 2) Hydragene 1) Rhizobium 2) Thiobacillus
3) Ammonia 4) Ammonium ion 3) Nitrococcus 4) Pseudomonas
61. Statement – I : Rhizobium shows the 67. What is the source of atmospheric nitrogen
facultative symbiotic association with root pool?
A) Industrial combustions
system of legumes. B) Forest fires
Statement – II : Root nodule formation C) Automobile exhausts
require multiple interactions between D) Power generation stations
rhizobium and root of host plants. E) Evaporation of ammonia
1) Both the statements are correct 1) A, B, C and D only
2) A, B, D and E only
2) Both the statements are incorrect 3) B, C, D and E only
3) Statement – I is correct, statement – II is 4) A, B, C, D and E
incorrect 68. Apart from carbon, hydrogen and oxygen, the
4) Statement – I is incorrect, statement – II is most common macroelement in living
correct organisms is
62. Match the following 1) Nitrogen 2) Potassium
Column – I Column – II 3) Phosphorus 4) Magnesium
69. The passive movement of ions from symplast
A) Azotobacter i) Filamentous to the apoplast usually occurs through
N2 fixer 1) Pumps 2) Aquaporins
B) Rhodospirillum ii) Aerobic N2 3) Ion channels 4) All
fixer 70. Incorrect statement w.r.t manganese toxicity
1) It inhibit calcium translocation in shoot
C) Rhizobium iii) Anaerobic N2
apex
fixer
2) It competes with Mg for binding with
D) Frankia iv) Symbiotic N2 enzyme
fixer 3) It competes with Mg and Fe for uptake by
1) A – iii, B – iv, C – ii, D – i root hair
2) A – ii, B – iii, C – iv, D – i 4) It competes with Mo for binding with
3) A – iii, B – ii, C – iv, D – i enzyme
71. Deficiency symptoms of which element tend
4) A – ii, B – iii, C – iv, D – i
to occur initially in the young leaves?
63. Which among the following fix the
1) Nitrogen 2) Potassium
atmospheric nitrogen in both free living and
3) Magnesium 4) Calcium
symbiotic conditions?
72. Necrosis is due to deficiency of
1) Rhizobium 2) Azotobacter 1) K, N, Mg, S, Fe, Mn, Zn and Mo
3) Anabaena 4) Rhodospirillum 2) Ca, Mg, Cu and K
64. Denitrification is a 3) N, S, K and Mo
1) oxidation process 4) N, K and Mo
2) reduction process 73. Plants obtain molybdenum in the form of
3) phosphorylation process 1) MoO22- 2) Mo O22+
-
4) dephosphorylation process 3) MoO2 4) MoO2+
65. Identify the chemoautotroph from the 74. The element which is necessary for the
following synthesis of auxin is
1) Rhizobium 2) Frankia 1) K 2) Zn
3) Anabaena 4) Nitrosomonas 3) Cl 4) B
A
 7 Test ID : 197
75. Identify the metal ion/s which is/are 80. Sulphur is the component of
compound of Nitrogenase enzyme A) Thiamine B) Biotin
1) Molybdenum 2) Nitrogen C) Coenzyme A D) Ferredoxin
3) Copper 4) Both (1) and (2) 1) A, B and C 2) B, C and D
76. Boron is required for 3) A, C and D 4) A, B, C and D
1) Calcium uptake 2) Pollen germination 81. Identify the correct statement w.r.t functions
3) Cell differentiation 4) All of the above of elements
77. Match the following enzymes w.r.t their A) Calcium required for normal functioning of
activators the cell membrane
B) Phosphorus is a constituent of certain
Column – I Column – II
proteins
A) Magnesium i) Nitrate C) Potassium helps to maintain anion cation
reductase balance
B) Zinc ii) Alcohol D) Manganese play important role in nitrogen
dehydrogenase metabolism
1) A, B and C 2) A, B and D
C) Molybdenum iii) PEPcase 3) B, C and D 4) A, B, C and D
1) A – ii, B – i, C – iii 82. Correct expression about nitrogen metabolism
2) A – i, B – ii, C – ii 1) Nitrogen fixation is highly expensive than
3) A – iii, B – ii, C – i CO2 fixation
4) A – iii, B – i, C – ii 2) At physiological pH, ammonia converted to
78. Match the following. amino acid (or) amides in xylem vessels
3) Nitrogenase require oxygen for its
Column – I Column – II
functioning
I) Structural a) Mg 4) Nitrogen fixation is a oxidation reaction
element 83. Which one of the following roles is not
II) Enzyme b) Ca characteristic of an essential element?
activator 1) being a component of biomolecules
2) changing the chemistry of soil
III) Osmoregulates c) Na+
3) being a compound of energy related
IV) Component of d) P compounds
energy related 4) activation and inhibition of enzymes
compound 84. The process of phloem loading is
1) I – b, II – a, III – c, IV – d 1) Symplast and active
2) I – d, II – a, III – c, IV – b 2) Symplast and passive
3) Apoplast and active
3) I – a, II – b, III – c, IV – d
4) Apoplast and passive
4) I – d, II – C, III – b, IV – a
85. Phloem transport is bidirectional this is
79. How many of the given elements act as
because
activators of enzymes? 1) roots also synthesis food materials
Molybdenum, Copper, Zinc, Manganese, 2) vasculature is present in both root and shoot
Iron, Magnesium, Calcium, Potassium 3) source and sink relationship is reversed
1) Six 2) Seven depending on plant needs
3) Eight 4) Five 4) it translocate the food materials

A
 8 Test ID : 197
86. Xylem exudates may contain 94. Who demonstrated experimentally that sun
1) Inorganic nitrogen, sulphur, phosphorus light is essential to plants for purifying the air
2) Organic nitrogen, sulphur, phosphorus fouled by burning candle or breathing
3) Water and some hormones animals?
4) All of the above 1) Joseph Priestley 2) Jan Ingenhousz
87. Where a plant adjust the quantity and type of 3) FF Blackman 4) T.W. Engelmann
solutes that reach the xylem?
95. Find mismatch the following
1) Transport proteins of root endodermal cells
1) T.W Engelmann – Action spectrum
2) Transport proteins of stem endodermal cells
3) Transport proteins of root pericycle cells 2) Jan Ingenhousz – Light is important factor
4) Transport proteins of stem pericycle cells for photosynthesis
88. The forces generated by transpiration can 3) Molls experiment – Variegated leaf
create pressures sufficient to lift the continues 4) Van Neil – Microbiologist
column of water over 96. Identify the photosynthetic pigments present
1) 150 meters height 2) 130 metres height in higher plants
3) 180 meters height 4) 160 metres height I. Chlorophylls II. Carotenes
89. Pickout the odd one w.r.t their relation with III. Anthocyanins IV. Xanthophylls
transpiration V. Phycobilins
1) Temperature 2) Wind speed 1) I, II and III 2) II, III and IV
3) Humidity 4) Light 3) II, IV and V 4) I , II and IV
90. Ascent of xylem sap depends on
97. Separation of leaf pigments is possible
1) Cohessive fosses between water molecules
through
2) Adhesive fosses between water and polar
surfaces 1) Autoradiography
3) The state of water 2) Ultracentrifugation
4) All of the above 3) Paper chromatography
91. Guttation is not operative during day time 4) Fractional distillation
because 98. Force required for ascent of xylem sap
1) the pressure generated by transpiration pull develops in
is greater than root pressure 1) Root 2) Shoot
2) the pressure generated by transpiration pull 3) Leaves 4) all of the above
is lower than root pressure
3) it is a passive process 99. Transpiration and photosynthesis is a
4) it is a active process compromise as it
92. The isotope of carbon used extensively for 1) creates transpiration pull
studies in photosynthesis is 2) Transports minerals
1) C13 2) C14 3) Supplies water for photosynthesis
3) C15 4) C16 4) More than one option
93. T.W. Engelmann experiment of photosynthesis 100. Stomatal distribution is equal on both surfaces
involved in of the leaf in
1) Cladophora and anaerobic bacteria 1) Dorsiventral leaves
2) Blue green algae and purple sulphur 2) Isobilateral leaves
bacteria 3) Hydrophytes
3) Cladophora and aerobic bacteria 4) Xerophytes
4) Green algae and green sulphur bacteria
***All The Best***
A