2025

SHIFT-2
22nd January 2025 & Wednesday
PAPER-1

03:00 PM – 06:00 PM

SUBJECT: CHEMISTRY
 | JEE(Main) 2025 | DATE : 22-01-2025 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY

PART : CHEMISTRY
1. Which of the following ions does not show disproportion reaction
(1) ClO– (2) ClO2– (3) ClO3– (4) ClO4–
Ans. (4)
7
It doesnot undergo
Cl O 4– 
Highest disproport ionationreaction
Sol. oxidation
state

2. Density of 3M NaOH is 1.25 g/mL. Molality of solution is

(1) 2.79 (2) 3 (3) 2.17 (4) 2.65
Ans. (4)
1000  M 1000  3 3000
Sol. m= = = 2.65
1000 d – M  MM solute 1000  1.25 – 3  40 1130

3. Arrange according to CFSE value

(i) [Co(NH3)4]2+ (ii) [Co(NH3)6]3+ (iii) [Co(NH3)6]2+ (iv) [Co(en)3]3+
(1) (iv) > (ii) > (iii) > (i) (2) (iv) > (iii) > (ii) > (i) (3) (i) > (iii) > (ii) > (iv) (4) (i) > (ii) > (iii) > (iv)
Ans. (1)
Sol. Co2+ : [Ar] 4s03d7 | Co3+ : [Ar] 4d6
CFSE  Strength of ligand
CFSE  Charge on cation

4. 200 mL of 0.2 M solution of NaOH is mixed with 400 mL of 0.5 M NaOH solution. Molarity of mixture is
x × 10–1. x is :
Ans. (4)
200  0.2  400  0.5 40  200 240 12
Sol. M     0.4M
600 600 600 30

5. S1 : A spectral line is produced upon election transition from 2px  2py

S2 : 2px & 2py are degenerate orbitals
(1) S1 True, S2 False (2) S1 False, S2 True
(3) Both S1 & S2 True (4) Both S1 & S2 False
Ans. (2)
Sol. Since orbitals are degenerate, no spectral line will be produced in transition.

6. Select the correct statement :

(1) T, P, d – They are intensive variables (2) V, P, d – They are intensive variables
(3) m, V, P – They are extensive variables (4) m, V, T – They are extensive variables
Ans. (1)
Sol. T, P, d - intensive
m, V - extensive

7. Compare dipole moment

i. NF3 ii. CHCl3 iii. H2S iv. HBr
(1) i > ii > iii > iv (2) ii > iii > i > iv (3) ii > iii > iv > i (4) iii > I > iv > ii
Ans. 3
Sol. NF3 = 0.23 D CHCl3 = 1.04 D
H2S = 0.95 D HBr = 0.79 D

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 | JEE(Main) 2025 | DATE : 22-01-2025 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
8. Match the column
Column-I Column-II
 G 
(i)   (a) Cp
 T  p
 H 
(ii)   (b) CV
 T p
 U 
(iii)   (c) –S
 T  V
 G 
(iv)   (d) V
 P  T
(1) i-c, ii-a, iii-b, iv-d (2) i-b, ii-d, iii-a, iv-c (3) i-d, ii-c, iii-b, iv-a (4) i-c, ii-a, iii-d, iv-b
Ans. (1)
Sol. dG = Vdp – SdT
G
At constant P, = –S
T
G
At constant T, V
P
 H   U 
   Cp ;    Cv
 T   dT  V

9. Solubility product of salt Zr3(PO4)4 is Ksp then solubility of salt in term of Ksp is
1 1
7 5
 K sp  7  K sp  5  K sp   K sp 
(1)  
 (2)  
 (3)  
 (4)  

 27  256   27  256   27  256   27  256 
Ans. (1)
3 Zr 4   4PO 4
3–
Sol. Zr3(PO4)4
3s 4s
Ksp = (3s)3 (4s)4
Ksp = 27(s)3 × 256(s)4

 K sp  7
S   

 27  256 

10. Sum of number of 4d electrons in Nb & Ru is

Ans. (11)
Sol. Nb(5s14d4) & Ru(5s14d7)

11. Statement-I : Corrosion is an electrochemical process, in which pure metal is present at anode and
impure is present at cathode.
Statement-II : Corrosion occur foster in alkaline medium than in acidic medium.
(1) Both Statement-I & Statement-II are true.
(2) Both Statement-I is true & Statement-II is false.
(3) Statement-I is false & Statement-II is true.
(4) Both Statement-I and Statement-II is false.
Ans. (4)
Sol. Statement-I : Corrosion is an electrochemical process which oxidation of metal take place at anode but
impure metal is not present at cathode.
Statement-II : Corrosion occur foster in acidic medium.

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 | JEE(Main) 2025 | DATE : 22-01-2025 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
12. Find number of hydrogen in [Ni(DMG)2]
Ans. (14)
Sol.
Ni2+ + DMG + NH4OH [Ni(DMG)2]

H-bond

O– H–O
CH3–C=N
N
Ni2+ C–CH3
CH3–C=N
C–CH3
O–H O–
N

H-bond
No. of H-atom = 14

13. Given below are two statements

S-I : Lassaigne test is used for detection of nitrogen, phosphorous, sulphur and halogen.
S-II : Lassaigne extract is made with magnesium metal.
(1) Both Statement I and statement II are true
(2) Both statement I and statement II are false
(3) Statement I is true but statement II is false
(4) Statement I is false but statement II is true
Ans. (3)

CH3

1. CrO Cl / CS
14.  
2 2 2
 Filtrate A
2. H3O
3. NaHSO 3
4. Filter

dil. HCl
A   B
Compound A and B are respectively
ONa
CH(OCrOHCl2)2 CH=O CH CH=O
SO3H

(1) ; (2) ;

CH=O COOH CH(OCrOHCl2)2 COOH

(3) ; (4) ;

Ans. (2)

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 | JEE(Main) 2025 | DATE : 22-01-2025 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
ONa
CH3 CH(OCrOHCl2)2 CH=O CH
SO3H
CrO Cl HO NaHSO
Sol. 
2 2
2 
3


A
CH=O

dil. HCl


15. Which of the following has ‘two secondary’ hydrogens.

(1) 2,2, 3, 3-dimethyl pentane (2) 2,2,3,4-dimethyl heptane
(3) 4-ethyl-2,2-dimethyl benzene (4) NOT
Ans. (1)

16. Correct order of stability of cation.

+ +
(a) CH3O CH2 (b) CH3 CH2

+ +
CH2 CH2
(c) (d)
OMe CH3

(1) a > b > c > d (2) c > a > d > b (3) a > c > d > b (4) c > b > a > d
Ans. (3)

17. Total number of -electron in a compound with molecular formula C6H6, which adds four moles of H2
and gives one single product on mono bromination.
Ans. (8)
H2
4 mole

Sol.
Br2/
Br

Br2
18. Major product
hv
Br Br
Br
Br
(1) (2) (3) (4)
Ans. (2)
*

Sol. Radical is most stable

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 | JEE(Main) 2025 | DATE : 22-01-2025 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY

1. Mg, ether
R–Br
19. 2.H3O+
Possible number of position isomers of R–Br, which gives the above product is
(1) 4 (2) 3 (3) 5 (4) 6
Ans. (1)

Br
, , & -with us/ether
Sol. Br Br Br
Followed by hydrolysis gives the required product.

20. Which of the following compound can be derived from (D) Glyceraldehyde.
HO
CHO CHO CHO HO
OH OH
OH OH OH
(i) (ii) (iii) OH (iv)
OH OH OH OH
OH OH OH CHO
(1) I & II (2) I, III & IV (3) I, II, III (4) II, III & Iv
Ans. (2)

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To Know more : sms RESO at 56677 | Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN : U80302RJ2007PLC024029
7340010333

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