Chapter-1-2
Chapter-1-2
Introduction
environmental problems we are facing these days and in the past few years.
petroleum, coal, or natural gas, and are produced through a process known as
polymerization. Unlike other materials, plastic does not biodegrade. Plastics take
Based on the Center for Biological Diversity, the world uses 5 trillion
plastic bags a year. It can takes 1,000 years for a plastic bag to degrade in a
landfill. Unfortunately, the bags don't break down completely but instead
the environment. (According to Roja et al. 2019; Brahney et al. 2020), the current
coupled with a projected 11 billion tons by 2025. That's why transitioning from
in the next few years would be a big help for our environment and the animals
living in it.
health. Bioplastics are plastics are made from a renewable resource that can be
broken down naturally. As society seeks for more convenient alternatives for the
candidate for the replacement to the traditional plastic we have. Green algae is a
common and rapidly expanding aquatic organism that shows great potential for
biodegradable substitute for plastic waste, which might greatly lessen its negative
to alternative plastics for our daily activities. Using more bioplastic than the
traditional plastic is a must for our environment and for our own health as well.
The extensive use of plastics in the past years up until today has
threat to human health and wildlife. This crisis caused by plastic needs urgent
resources, such as starch and algae. Bioplastics are biodegradable, meaning the
material returns to its natural state when buried in the ground. These
pollution.
approximately 2.7 million tons of plastics each year. These number are alarming,
especially when 20 percent of these plastic make their way to the ocean. That's
why bioplastic are a need, especially in our country. However, challenges such
bioplastic. Moreover, using algae and other feedstock into bioplastic production
replacement for the traditional plastics we have. Focusing on its benefits in our
materials, the study provides a growing debate on the global crisis caused by
Theoretical Framework
the researches. These provide researchers with the various ideas, concepts, and
subjects to check.
Clark and Houwink (1950) suggests that plasticizers improve the lubrication
between the polymer chains in the rubber compound, which allows for easier
reducing the friction between the chains and allowing them to slide past one
another more easily. This results in a softer and more pliable material.
The lubricity theory implies that plasticizers increase the lubricant between
the rubber compound's polymer chains, allowing easier motion and increased
flexibility. This idea states that the plasticizer molecules are injected in between
the polymer chains and function as a lubricant, lowering friction and making it
easier for the chains to pass one another. The material becomes softer and more
pliable as a result.
However, Aikens (1944) Free Gel Theory, on the other hand, proposes
that plasticizers dissolve some of the polymer chains in the rubber compound,
creating a “free gel” of individual polymer molecules that are able to move
independently of one another. This free gel is then able to flow more easily,
amount of plasticizer added to the rubber compound determines the size of the
Free Gel Theory suggests that plasticizer break down a portion of the
follow from the easier flow of this free gel. The theory states that the size of the
free gel and, consequently, the degree of plasticization are determined by the
According to the Free Volume Theory by Wong and Pui (2020), the
decreases the intermolecular forces between the polymer chains, creating more
free volume. This increased free volume allows the polymer chains to move more
The Free Volume Theory suggests the amount of free volume produced
molecular makeup and how they interact with the polymer chains, different
All things considered, the free volume theory offers a helpful foundation for
affect the material's mechanical characteristics. the same process that produces
Conceptual Framework
Input Process Output
1. Fill a clear container with
water.
2. Add nutrients (nutrient
solution, pond water,
Green Algae aquatic animals).
Starch 3. Place the container in a
Vinegar sunny spot.
Glycerin 5. Blend the green algae.
Water 6. Combine water, vinegar, Green Algae
glycerin, cornstarch, and Bioplastic
algae in a pan.
7. Heat the mixture on low.
8. Pour it into a pan and
spread it out.
9. Mold the dried mixture
into bioplastic.
10.Let it dry.
input, process and output of the study. The inputs are green algae, starch,
vinegar, glycerin, and water. Moreover, in order to create the green algae
bioplastic, the researchers will blend the green algae. mix the right amount of
water, vinegar, glycerin, cornstarch, and green algae in a pan, mix and heat the
mixture in a low temperature, pour the mixture into a pan, spread out the mixture,
and let it dry, and mold the mixture to make the bioplastic.
2.1. Flexibility
2.2. Durability
2.3. Transparency
3.1. Texture
3.2. Quality
3.3. Sturdiness
4.1. Suitability
4.2. Reliability
4.3. Practicality
chosen topic. The result of this study will merit the following:
Students. This study may enhance their knowledge about the use of
Parents. This study aims to help the parents to have understanding on the
use of plastics.
Teachers. This study may help the teachers to teach their students about
starch and turning them into plastic-like substances. The bioplastics are put into
bioplastic in common products like packaging and disposable products. The main
point of emphasis is looking at how maximizing the use of green algae could
reduce the negative impacts associated with conventional plastics on the
environment.
The study covers mainly green algae and does not include red and brown
address the challenges of mass production. The study only used algae
specifically from string algae, so the results might not apply to other types of
algae.
Definition of Terms
The following terms are defined operationally to help the readers better
make the thing stronger physically and also to prevent it from being damaged
Suitability. This term helps people identify the appropriate and compatible
person to use product and to know who should avoid and use them.
Reliability. It refers to a quality that identifies what a person can trust and
use properly.
Durability. This term refers to the strength of the plastic to carry different
weights to test its function; it also tests the reliability of the bioplastic.
Transparency. As used in this study, this refers to the physical quality of
the plastic to be transparent to easily detect or see the things placed on the
plastic.
Texture. This term refers to the quality of the plastic that can be felt when
hardness.
Quality. In this study, this refers to the overall function and characteristics
Eco-friendly. In this study, this term refers to the good benefits or non-
Plastic Pollution. These are different types of plastic objects that affect
can be replaced, and you have and will get an eternal supply.
CHAPTER II
This chapter presents the review of literature and studies that serve as the
Related Literature
Flexibility
sources, such as vegetable fats and oils, corn starch, straw, woodchips, sawdust,
recycled food waste, etc. Some bioplastics are obtained by processing directly
are chemically synthesised from sugar derivatives and lipids from either plants or
natural gas.
environmentally friendly. They are made from renewable resources and may be
Bioplastics, which are types of plastics that are made from plant sources
materials not only because of their variety, but also because of the multitude of
between them, such as the development of bioplastics using plants, animals, and
others, using them to see the different properties of each possible bioplastic.
Because of that, they can see how the strength and flexibility of a bioplastic can
be applied using them. The relationship between the three is that all bioplastics
are self-made. It is applied with flexibility, and there are different materials that
are made to achieve it. It has a lot of relationship with the research in the
Durability
Biopolymers Reuse, Recycling and Disposal is the first book covering all
waste streams. The book investigates the benefits and weaknesses, social,
cycle analysis, all supported by case studies, literature references, and detailed
bioplastics. The book also covers additives and modifiers for biopolymers and
The relationship of these three is that they all achieved the durability of a
bioplastic by using other materials to achieve it. They explored other roles of a
bioplastic and compared it, and they did know the difference of a bioplastic from
other materials to be used. Study carefully how it works to properly achieve the
durability of a bioplastic.
Transparency
However, such properties are not required for all plastic applications such
2022).
high degree of crystallinity, optical purity, gas barrier properties, and high melting
The other approach entails the blending of algal biomass with bio or
strategy utilizes the algal biomass as a “filler” and requires methods such as
thermal–mechanical (compression molding) techniques to produce the bioplastic
sachet and any other transparent like plastic but in a much eco-friendly way as it
research because we are also aiming for a transparent bioplastic without making
any harmful substance for our environment as we are also aiming for a better
Texture
Chaiklieng, S. (2023) stated that the fusion of agar bioplastics with a fabric
transferred from the uneven surfaces of the fabric, were evident on the surfaces
of the agar bioplastics. Agar bioplastics are biodegradable, but the fabric also
agar bioplastics are a challenge. Moreover, these samples derived from agar
According to Arung, E. T., .et.al (2024) the another way is to use the
bioplastics for cosmetic products that specifically do not demand high chemical
exhibit a more tactile and softer texture, which offers a significant advantage in
agent, and vinegar to facilitate the dissolution of starch. These ingredients were
mixed in a heated pan together with dried seaweeds, and the resulting mixture
was promptly transferred onto a flat surface lined with foil before solidification
thickness of the final product. The outcomes of the tensile strength examination
on the size, form, moisture content, texture, and rate of decomposition of the
appearance to traditional plastics. Bioplastics can achieve a good texture with the
help of glycerin, water, cornstarch, and vinegar. The study explains that glycerin
utilizing these materials to produce green algae bioplastics can result in a smooth
Quality
According to Vandenberghe, L., .et.al. (2023) the bioplastics final quality
employed during any treatment method, and avoid using the common plasticizer
PLA is already used in packaging applications, shopping bags, and cups. The
recent focus is widely applied in tissue engineering, due to the range of the
melting temperature (T) and the glass transition temperature (T) presented by the
polymers produced from algal waste leftovers, which solves waste disposal
study. The finished products will disintegrate in the soil and can be utilized to
enhance the agriculture quality. These results will motivate the industry to
engage in bioplastics production study and development in collaboration with
aesthetic quality and strength at varying substrate volumetric water contents. The
water content can influence the bioplastic's properties, leading to changes in the
traditional plastics. The findings of these studies are relevant to our research, as
they indicate that green algae bioplastics can achieve comparable quality,
Sturdiness
substitute for plastics made from petroleum because they are biocompatible and
particular kind of PHA. It can be composted and degrades naturally, lessening its
synthesis. These are the major stages of producing bioplastics from microalgae.
Then, the mechanical properties, such as tensile strength and elongation, of the
microalgae can have varying tensile strengths depending on factors such as the
microalgae strain used, the polymerization process, and any additives included in
can stretch before breaking. It is a critical property for flexible applications such
Analysis (TGA) and Differential Scanning Calorimetry (DSC) were used in this
procedure.
According to Sefrienda AR, et al. (2023). Even if there are several natural
resources for making bioplastics, many of these sources will contribute to the
food crisis, which is a great issue. The food economy can suffer because of the
grow quickly, these microalgae are best suited to produce bioplastics. In addition,
the key features of bioplastics. As the percentage of algae biomass in the PLA
blend rises, the tensile strength will drop. This is a result of the algae and PLA's
bioplastic for it to be more useful. Bioplastics made from algae starch can still be
strengthened with the help of protein. Making the bioplastic more reliable
knowing its natural composition helps mitigate the bad effects of petroleum
plastics in our environment. These three related literature are relevant to our
bioplastic.
Suitability
Chia, et al. (2020) stated that the increased global demand for plastic
materials has led to severe plastic waste pollution, particularly to the marine
environment. This critical issue affects both sea life and human beings since
microplastics can enter the food chain and cause several health impacts. Plastic
recycling, chemical treatments, incineration and landfill are apparently not the
optimum solutions for reducing plastic pollution. Hence, this review presents two
bioplastic production using algae, to solve the increased global plastic waste.
Algae, particularly microalgae, can degrade the plastic materials through the
toxins systems or enzymes synthesized by microalgae itself while using the
plastic polymers as carbon sources. Utilizing algae for plastic biodegradation has
been critically reviewed in this paper to demonstrate the mechanism and how
microplastics affect the algae. On the other hand, algae-derived bioplastics have
Cinar et al. (2020) mentioned the plastic waste production around the
world is increasing, which leads to global plastic waste pollution. The need for an
edible crops have been available for decades. Aside from these feedstocks,
producing sugars for bacterial fermentation and subsequently used for the
First, in contrast to plastics made from petroleum, they give a simple and
sustainable resource. Next, bioplastics made from algae can have structural,
making them suitable for a wide range of uses. Importantly the impact of this
biodegradable.
Reliability
plastics will be 20% of global annual oil by 2050, and thus there is an inevitable
plastics in the market due to sustainability, less carbon footprint, lower toxicity
can be processed and utilized to make biopolymers. Also, these species have a
and algae, are explored substantially for their bioplastic production repertoire,
fact that algae and cyanobacteria are feasible alternative source for bio-plastic,
there have been limited studies on strain selection and optimization of culture
conditions for the bio plastic production. Naturally, algae and cynobacteria can
the recent study on genetic engineering of Synechocystis sp. coupled with abiotic
easily accessible and renewable resources due to their quick growth rates and
which reduces waste and resource consumption and provides a organic and eco-
friendly method. Thirdly, algae based bioplastics offer a strong substitute for
plastics made from petroleum due to their natural biodegradability and minimal
environmental impact.
Practicality
derived bioplastics.
Petrochemical raw materials are not the only way to get the same function
as plastic. Rethink people’s habits of manufacturing and using materials and try
to turn bio-based materials into new materials of products. A new mode and
pattern, or even new and alternative materials, are expected to replace the old
one. Materials with “plastic” properties can also be obtained from raw materials
and freshwater macroalgae. The algae derivatives have the potential to be used
as key ingredients for bioplastic production, such as starch and PHAs or only as
these plants to make plastic instead of oil. The elements found in algae can be
used to create polymers that seem like ordinary plastic but are more
environment because they are made from a renewable resource and decompose
easier.
Related Studies
Flexibility
Plastics are a vital asset for humanity, often providing functionality that
grains or sugarcane. They not only fulfill the current demands of the modern
starch-based bioplastics. The results show that the strength of bioplastics can be
increased by using various natural fibers such as cotton, jute, hair and wool.
higher tensile strength, flexural strength and thermal stability as well as a lower
films. The whole life cycle assessment showed that the cellulose bioplastic is an
to construct a valuable bioplastic directly from cellulose pulps rather than their
derivatives.
If they use the right materials to make a bioplastic, they will realize how
flexible and strong your creation is. It is important that they know what they are
and the right size of materials when it comes to developing bioplastic for its good
outcome, especially for its flexibility. They also used different materials to see
what made them different. Their relationship with making bioplastic using green
Durability
This paper is aimed to observe the best condition for optimal tensile
bioplastic by soil buried. To achieve this goal, bioplastic was prepared by using
bioplastic with optimum tensile strength was then analysed for durability by
burying the sample in soil. Optimum tensile strength of bioplastics was obtained
at 28.6 MPa with the optimum concentration of bamboo cellulose microfibril and
potassium chloride of 5%-w/w and 3%-w/w, respectively. Post durability test, the
The aim of this review paper is to summarise the bioplastics that are
feedstock for the bioplastics production. The current technologies and methods
bioplastics are being reviewed. This review will provide a better understanding in
interventions can be made in order to increase the life span of the material, make
tapioca starch gives the finest, smoothest, flexible and strengthful biopolymer
among all. Issues on sustainability, designing and sensing the unpredictable and
searching for “new” materials for a greener and sustainable future are the main
core of bioplastic production. Regarding the negative carbon footprint and long-
term environmental effects of fossil-based plastics through landfill and
incineration, the search for such a material brings forth a deeper material
disciplines. Through this production, we need to figure out deeply the nature of
new starch based materials in architecture, which are eco-friendly, cheaper and
important to know this thing because it is one of the important things to keep the
bioplastic you make strong and durable. Its relationship with the production of
bioplastic using green algae is that it has a process followed to achieve the
you can tell how strong it is and how long you can use it.
Transparency
devices and agricultural films. These algal bioplastics are part of the broader
et al. 2024)
plastic dispersed in aquatic environments and lands: tons of plastic waste are
dispersed into oceans every year, causing global environmental pollution, and
the use of petroleum-based plastic products led the research to look for new
biodegradable and not toxic for human health and the environment.
corn, potato, vegetable oils, wood, food waste, cereal crops, and so on. The main
polyethylene (PE). The latest invention that shows a bright future is bioplastics
made from seaweeds. Seaweeds are promising for making bioplastics as they
can form films. They have many benefits as raw materials compared to other
planted in seawater instead of land, abundant and high yield. Moreover, since
some seaweeds are edible, they can be utilized in food packaging industries.
(Lim, C., et.al., 2021).
alternative for the petroleum plastics today. These studies are relevant to our
much more presentable but still preserving its identity as a eco-friendly solution.
Texture
petro-plastics are one of the fossil products which should be replaced by bio-
based plastics. In this study, potato peels were used to produce bioplastics by
the extraction of the starch from the peels and adding some ingredients such as
water, glycerin, vinegar and industrial colors with different ratios and in
coherence. It was found that when the glycerin ratio increases the produced
bioplastic becomes more flexible and vice versa when the glycerin ratio
decreases the produced bioplastic becomes hard. It was concluded that the bio-
bioplastics
By bringing do it yourself (DIY) materials into the textile design field, this
using textile surface design methods, and how the relationship between texture
and colours can be advanced in the design of complex textured surfaces. The
method develops a hybrid strategy for designing a new material category
combining DIY and digital tools, which offers a more sustainable alternative to
source, and angle of viewing. The results are methods of creating complex colour
The banana (Musa acuminata) is the most common type used in the food
industry, often for making banana chips or fried bananas. After the flesh is
consumed, most stall vendors will throw away the banana peels in abundance at
dumping areas, creating lots of food waste pollution. Additionally, some research
has found that banana peels contain high levels of starch, approximately 18.5%,
making them a suitable source for manufacturing bioplastics. However, there are
few efforts in producing bioplastic from banana peels. Most of the research used
resulting in distinct textures. This suggests that the texture of bioplastics depends
on the materials used. Therefore the green algae bioplastics may also exhibit
Quality
macroalgae bioplastics are the high costs of large-scale production and the need
production include reducing plastic waste and greenhouse gas emissions, using
healthier materials in various life practices, and developing a promising area for
that make PHAs a feasible source material for bioplastics, either as a direct
bioplastics, with the most prevalent being the development of gas and water
feedstocks or biomass, i.e., food waste, sugarcane, plant oil, starch crops, and
agents, such as lignocellulosic fibre, starch, and cellulose, are added into
properties of the bioplastics are on-par with conventional plastics, which later
reinforced bioplastics are the sustainability and potential applications in the future
Traditional plastics possess good quality, but they harm the environment.
algae bioplastics have the potential to meet the high standards of bioplastics
Sturdiness
microalgal starch at pilot scale with high yields, and highlights the potential of
microalgal starch for the production of TPS using industrially relevant processes.
The use of polymeric materials is widely spread around the world. These
materials, such as metals and wood, mainly because of their properties and
fossil fuels. These plastics entail several issues since their primary raw material
favourable that the material maintains specific properties throughout time, but it is
also desirable to discard them easily after their use. There are some alternative
processes usually used to manage this kind of waste: recycling (one of the most
production of energy by burning the waste but ends up producing toxic emissions
sources are becoming more popular. These materials are considered more
from fossil fuels, offering benefits such as a long lifespan and resistance to
from microalgae can be greatly aided by the proper extraction and pre-treatment
three studies proposed that sturdiness is indeed needed for the bioplastic to
thrive if the world transion from petroleum plastics to bioplastics. This study is
related to our research because improving the sturdiness of the bioplastic means
improving its capability to be more useful than the petro based plastic especially
plastic.
Suitability
also outlines the current state of technological developments in the field of algae-
based bioplastic, both in industry and in research, and highlights the creation of
novel solutions for green bioplastic production employing algal polymers. Finally,
the cost economics of the bioplastic production using algal biopolymers are
clearly mentioned with future directions of next level bioplastic production. In his
study, the cost estimation was given at laboratory level bioplastic production
the end of the product life cycle. A solution that could reconcile the practicality
and low cost of plastic packaging with a reduced environmental footprint is the
biodegrade is properly treated at the end of their life, limiting the environmental
friendly plastic made from natural resources is known as bioplastic. The supplies
include sugarcane, potato starch, corn, wheat, soybeans, milk protein, collagen,
gelatin, algae, and other microorganisms. Competition between land and water
results from the production of bioplastics from these plant sources. Additionally,
the method of making bioplastics is highly challenging. These sources create
bioplastics, but they have lower mechanical and water resistance qualities.
Because the bioplastics made from these crops are unstable and cause issues
with the food economy, microalgae are being used as a source for making
and ability for CO2 fixation, microalgae are employed as a source to create
bioplastic. Microalgae are suitable for making high-quality bioplastics due to their
(PHB), Polylactic acid (PLA), Polyethylene (PE), Poly vinyl chloride (PVC), and
and eco-friendly plastic that helps the environment to lessen the use of petroleum
for plastic since algae has the characteristics that can be used to make a
bioplastic without affecting the environment. The use of algae also helps the
bioplastic.
Reliability
including green seaweeds belonging to the Ulva genus, are utilized in producing
these bioplastics. These bioplastics can be derived from waste, thus do not
derived from algae have demonstrated superior durability, strength, and pliability
utilize bioplastics derived from algae. These algal bioplastics possess unique
biobased ones reduces 1.8 tons CO2 emissions. Here, we begin with highlighting
and less dependency on climatic conditions for cultivation. These are the reasons
for current boom in the algal bioplastic market. However, it is still not at par in
price with the petroleum-based plastics. A brief market research has been done
to better evaluate the current global status and future scope of algal bioplastics.
obtained through the biorefinery approach can be processed into PHA under
certain nutrient limitations. Additionally, microalgae biomass can act as potential
such as lipids and cellulose are found to be promising for the production of
bioplastics. Moving on, the intermediate processing of bioplastic via lactic acid
polylactic acid due to cost efficiency, minimum solvent usage, low energy
consumption, and fast rate of reaction. Moreover, the reliability and effectiveness
reliable. According to the studies presented, the use of green algae is reliable to
make a durable, strong, and flexible plastic. It also helps the environment to
lower carbon footprints reducing the emission of greenhouse gases. Algae is also
reliable since it has the characteristics that a plastic should have. In relation to
the study, the related studies support the ability of an Algae to be an alternative
bioplastic. Furthermore, algae are renewable sources and can act as potential
Practicality
Dalal et al., (2023) stated that padina pavonica, a macroalga, has recently
gained attention due to its high content of bioactive components, which increases
its value as a natural feed additive resource in practical aquaculture. The effects
bacteria in rabbitfish Siganus rivulatus fry were studied by Monier et al. With
increasing Padina pavonica rate, all experimental fish diets showed significant
compared to the control. Upon increasing dietary Padina pavonica levels, total
that has many practical applications including its use as a feedstock in the
amount of plastics being released into the environment, thereby creating micro-
not been able to replace petroplastics yet due to their complex production
the raw material; the plastics obtained are known as cell-plastics. The direct use
of green algal cells for plastic production has several advantages. Through
photosynthesis, green algae uses CO2 as the carbon source to construct new
cells; therefore, depending on the rate of CO2 assimilation, the growth activity of
the grown cell is greater than that of the ordinary terrestrial plants. Algal cells
have shown potential for application in robust cell-plastics owing to their rigid cell
wall structure.
The low cost of plastics and its resourcefulness have flagged a way for an
to have toxic properties on humans, animals and the environment, the bio
plastics came into being. Bio plastics are biodegradable and can be stemmed
plastics. Though, there are various sources of bio plastics like plants, animals
substitutes for the manufacture of bio plastics because of its high biomass, its
are cost effective, minimalize the effect on the food chain and do not depend on
chemicals.
These related studies are significant to the study when it comes to the
practicality of using green algae for bioproducts. It talks about the availability and
studies support the practicality of algae in a community and its ability to provide
an effective low cost for the production of plastics. The cultivation of green algae
for bioproducts has many advantages, not only in utilizing it but also when it
comes to the production of different things. Since algae have a high nutritional
value and can grow rapidly, they can help to provide or to be a source for various
aquaculture fields, which help to produce a lot of benefits and advantages for