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Physical Science GR 12 Acids and Bases Worksheet Memo

The document is a worksheet memo on acids and bases for Grade 12 Physical Sciences, compiled by Dr. Sarita Swanepoel. It includes various chemical equations, calculations related to dissociation, neutralization, and ionization of acids and bases, as well as concepts of conjugated pairs and pH calculations. The memo serves as a study guide for understanding the behavior of acids and bases in different chemical reactions.

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0% found this document useful (0 votes)
54 views4 pages

Physical Science GR 12 Acids and Bases Worksheet Memo

The document is a worksheet memo on acids and bases for Grade 12 Physical Sciences, compiled by Dr. Sarita Swanepoel. It includes various chemical equations, calculations related to dissociation, neutralization, and ionization of acids and bases, as well as concepts of conjugated pairs and pH calculations. The memo serves as a study guide for understanding the behavior of acids and bases in different chemical reactions.

Uploaded by

baneleblose9
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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PHYSICAL

SCIENCES
GRADE 12
Acids and Bases

Worksheet - Memo
Compiled by:
Dr. Sarita Swanepoel
1 Memorandum: Acids and bases

1.1 KOH(s) K+ (aq) + OH− (aq) Dissociation


1.2 Zn(s) + 2HCl(aq) ZnCl2 (aq) + H2 (g) Redox
1.3 2LiOH(aq) + H2 SO4 (aq) Li2 SO4 (aq) + 2H2 O(l) Neutralisation
1.4 H2 SO4 (l) + 2H2 O(l) 2H3 O+ (aq) + SO4 −2 (aq) Ionisation
1.5 NH3 (aq) + HNO3 (aq) NH4 Cl(aq) Neutralisation
1.6 NaOH(aq)+ CH3 COOH(aq) CH3 COONa(aq) + H2 O(l) Neutralisation
2.1
conjugated pairs 2

base conj acid


HNO3 (g) + H2 O(ℓ) NO3 − (aq) + H3 O+ (aq)
acid conj base

conjugated pair 1
2.2 a. NH3 b. SO4 2− c. OH−
2.3 a. H3 PO4 b. H2 SO4 c. H3 O+
2.4 n1= n2 (No moles of acid added. Only H2 O added.)
c1 V1= c2 V2
(1,30)(75)= C2 (100)
C2= 0,975 mol · dm−3
m
2.5 c=
M ×V
m
0,04 =
40 × 0,24
m˜ = 0,384 g NaOH
2.6 n1 = n2
c1 V1 = c2 V2
(0,0015)(10) = 0,0005V2
V2 = 30 cm3 New volume
Vadded = 30 − 10
= 20 dm3
2.7 a. HA + H2 O(l) A− (aq) + H3 O+ (aq)
b. H3 O+ ions less than HA molecules (ionises incompletely)
c. H3 O+ ions equal to A− ions
2.8 a. Carbonic acid Bigger Ka indicates it ionises more completely
b. Carbonic acid It ionises more completely and produce more ions
c. Boric acid Less hydronium ions and Kw = [OH − ][H4 O + ]
c. Carbonic acid Bigger Ka indicates it ionises more completely. Produce more H3 O+ .

2.8 a. Every HR molecules produces ONE hydronium (H3 O+ ) ion when it ionises.
b. No. The H3 O+ ions produced is less than the HR molecules. Ionises incompletely

Junior Tukkie Winter School 1 Dr. S. Swanepoel (2020)


3.1 H2 SO4 is a strong acid and ionises completely
H2 SO4 + 2H2 O SO4 −2 (aq) + 2H3 O+ (aq)
H2 SO4 : H3 O +
1 : 2X
[H3 O ] = 2(0,0015) = 0,003 mol.dm−3
+

pH = −log[H3 O+ ]X
= −log(0,003)X
= 2,52X
3.2 LiOH is a strong base and dissociates completely
LiOH(s) Li+ (aq) + OH− (aq)
LiOH : OH −
1 : 1X
[OH ] = 0,004 mol.dm−3

Kw = [OH − ][H3 O + ]X
1 × 10−14 = (0,004)[H3 O + ]
[H3 O+ ] = 2,50 × 10−12 mol.dm−3
pH = −log[H3 O+ ]X
= −log(2,50 × 10−12 )X
= 11,60X
m
3.3 c= X
M ×V
1,89
= X
63 × 2
= 0,015 mol · cm−3

HNO3 is a strong acid and ionises completely


HNO3 + H2 O NO3 − (aq) + H3 O+ (aq)
HN O3 : H3 O +
1 : 1X
[H3 O ] = 0,015mol.dm−3
+

pH = −log[H3 O+ ]X
= −log(0,015)X
= 1,82X
3.4 pH = −log[H3 O+ ]X
4,3 = −log[H3 O+ ]
[H3 O+ ] = 5,01 × 10−4 mol.dm−3
Kw = [OH − ][H3 O + ]X
1 × 10−14 = [OH − ](5,01 × 10−5 )X
[OH − ] = 1,99 × 10−10 mol.dm−3 X (2,00 × 10−10 )

Junior Tukkie Winter School 2 Dr. S. Swanepoel (2020)


3.5 m
c=
M ×V
0,28
=
40 × 0,5
= 0,014 mol · dm−3

NaOH is a strong base and dissociates completely


NaOH(s) Li+ (aq) + OH− (aq)
N aOH : OH −
1 : 1
[OH ] = 0,014 mol.dm−3

Kw = [OH − ][H3 O + ]
1 × 10−14 = (0,014)[H3 O + ]
[H3 O+ ] = 7,14 × 10−13 mol.dm−3
pH = −log[H3 O+ ]
= −log(7,14 × 10−13 )
= 12,15
3.6 a. pH = −log[H3 O+ ]
12,2 = −log[H3 O+ ]
[H3 O+ ] = 6,31 × 10−13 mol.dm−3
b. Kw = [OH − ][H3 O + ]
1 × 10−14 = [OH − ](6,31 × 10−13 )
[OH − ] = 1,58 × 10−2 mol.dm−3

NaOH is a strong base and dissociates completely


NaOH(s) Li+ (aq) + OH− (aq)
N aOH : OH −
1 : 1
[N aOH] = 1,58 × 10−2 mol.dm−3
m
c=
M ×V
m
1,58 × 10−2 =
40 × 0,25
= 0,158 mol · dm−3
4.1 a. hydrolysis
b. basic
c. CH3 COO− + H2 O CH3 COOH + OH−
4.2 a. Pipette
b. 2NaOH + H2 CO3 Na2 CO3 + H2 O
c. Phenolphthalein. Strong base with weak acid gives basic end point.
d. Pink
e. Distilled water AND THEN some of the acid solution
f. Decreases
g. na Ca Va
=
nb cb Vb
1 0,1(25)
=
2 Cb (20)
cb = 1,25 mol.dm−3

Junior Tukkie Winter School 1 Dr. S. Swanepoel (2020)

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