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Ionic Equilibrium _2

The document is a classroom test focused on ionic equilibrium, comprising multiple-choice questions and assertion-reasoning statements. It covers various concepts such as acid-base reactions, buffer solutions, solubility products, and dissociation constants. The test is structured into two sections, with Section A containing direct questions and Section B requiring the selection of correct assertions and reasons.

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Rudra Sarkar
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8 views

Ionic Equilibrium _2

The document is a classroom test focused on ionic equilibrium, comprising multiple-choice questions and assertion-reasoning statements. It covers various concepts such as acid-base reactions, buffer solutions, solubility products, and dissociation constants. The test is structured into two sections, with Section A containing direct questions and Section B requiring the selection of correct assertions and reasons.

Uploaded by

Rudra Sarkar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Classroom Test-1/ Ionic Equilibrium / Marks – 25

Section A
1. What will happen if a small amount of hydrochloric acid is added to a 0.1 M solution of
HF?
a) The percent ionization of HF will increase.
b) The percent ionization of HF will decrease.
c) The percent ionization of HF will remain unchanged.
d) Ka for HF will increase.

2. Which of the following is true for a buffered solution?


a) The solution resists change in its [H+].
b) The solution will not change its pH very much even if a concentrated acid is added.
c) The solution will not change its pH very much even if a strong base is added.
d) All of these.

3. The solubility of A2X3 is y mol/dm3. Its solubility product is


a) 6y4 b) 64y4 c) 36y5 d) 108y5

4. Dissociation constant of H2O at 25oC is


a) 10-14 b) 1014 c) 14 d) 1.8 x 10-16

5. pKa of a base (Kb = 1 x 10-5) is


a) 5 b) – 9 c) – 5 d) 9

6. In which of the following cases is the acid strength highest?


a) Ka = 10-6 b) pKa = 5 c) pKb = 10 d) Kb = 10-11

7. At 90oC, pure water has [H3O+] = 10-6 mole/litre. The value of Kw at 90oC is
a) 10-6 b) 10-8 c) 10-12 d) 10-14

8. 10-2 mole of KOH is dissolved in 10 litres of water. The pH of the solution is


a) 12 b) 2 c) 3 d) 11

9. The pH of a 10-8 M HCl solution is


a) 8 b) 7.02 c) 7 d) 6.98

10. If the temperature of water is increased from 25oC to 45oC, the pH of water at 45oC will
be
a) 7 b) slightly greater than 7 c) < 7 d) 8

11. The dissociation constant of an acid HA is 1 x 10-5. The pH of 0.1 molar solution
of the acid will be approximately
a) 3 b) 5 c) 1 d) 6

12. The pH of a buffer solution of 0.1 M NH4OH and 0.1 M NH4Cl is (pKb = 4.0)
a) 1 b) 4 c) 10 d) 13

13. In a buffer solution of a weak acid and its salt, if the ratio of the concentration
of the salt to that of the acid is increased ten times, the pH of the buffer
a) increases by 1 b) increases 10 times c) decreases 10 times d) decreases by 1

14. When a salt of a weak acid and a weak base is dissolved in water at 25oC, the
pH of the resulting solution will always
a) be 7 b) be greater than 7
c) be less than 7 d) depend upon Ka and Kb values

15. Ksp for AgCl in water at 25oC is 1.8 x 10-10. If 10-5 mole of Ag+ ions are added
to this solution, Ksp will be
a) 1.8 x 10-15 b) 1.8 x10-10 c) 1.8 x 10-5 d) none of these

16. If the solubility of PbCl2 is S moles/litre, the solubility product is


a) S3 b) 27S4 c) S2 d) 4S3
17. Which of the following are Lewis acids?
a) BCl3 and AlCl3 b) PH3 and BCl3 c) AlCl3 and SiCl4 d) PH3 and SiCl4

18. Which of the following is the conjugate base of HPO42-?


a) H3PO4 b) H2PO4- c) PO43- d) HPO42-

19. Which of the following is a basic buffer?


a) CH3COOH + CH3COONa b) NH4Cl+ NH4OH
c) NaHCO3 + Na2CO3 d) NaH2PO4 + Na2HPO4

20. Which of the following are Lewis bases?


a) NH3 and BH3 b) NH3 and H2O
c) AlCl3 and CCl4 d) SiCl4 and PH3
Section B
Each of these questions contain two statements, Assertion and Reason. Each of these questions
also has four alternative choices, only one of which is the correct answer. You have to select
one of the codes (a), (b), (c) and (d) given below. (a) Assertion is correct, reason is correct;
reason is a correct explanation for assertion. (b) Assertion is correct, reason is correct; reason
is not a correct explanation for assertion (c) Assertion is correct, reason is incorrect (d)
Assertion is incorrect, reason is correct.

21. Assertion: Addition of silver ions to a mixture of aqueous sodium chloride and sodium
bromide solution will first precipitate AgBr rather than AgCl.
Reason: Ksp of AgCl > Ksp of AgBr.
22. Assertion: The addition of HCl(aq.) to CH3COOH (aq.) decrease the ionisation of
CH3COOH (aq.).
Reason: Due to the common ion effect H+, ionisation of CH3COOH decreases.
23. Assertion: The ionisation constants of weak diprotic acid are in the order of Ka1 > Ka2.
Reason: Removal of H+ from anion is difficult as compared to neutral atom.
24. Assertion: A substance that can either at as an acid or a base is called ampholyte.
Reason: Bisulfide ion (HS-) and bicarbonate ion (HCO3-) are both ampholytes.
25. Assertion: It is difficult to distinguish the strengths of the strong acids such as
HCl, H2SO4, HNO3, HBr, HI in dilute aqueous solutions.
Reason: In dilute aqueous solution all strong acids donate a proton to water and are
essentially. 100% ionised to produce a solution containing H3O+ ions plus the anions of
strong acid.

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