NALCO 2510
NALCO 2510
1907/2006
Product
NALCO® 2510
1.2 Relevant identified uses of the substance or mixture and uses advised against:
This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
Product
NALCO® 2510
Contains: 2,2-Dibromo-3-nitrilopropionamide
Hazard pictograms:
Hazard Statements:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
Precautionary Statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
None known
3.2 Mixture:
The details below include all impurities and by-products that contribute to the product classification or that have
an occupational exposure limit.
Product
NALCO® 2510
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt,
contact emergency responders.
INHALATION
Remove to fresh air, treat symptomatically. Get immediate medical attention.
SKIN CONTACT
Get immediate medical attention. Remove contaminated clothing. Wash clothing before reuse. Immediately flush
with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Contaminated
clothing, shoes, and leather goods must be discarded or cleaned before re-use. PROMPT ACTION IS
ESSENTIAL IN CASE OF CONTACT.
EYE CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention. PROMPT
ACTION IS ESSENTIAL IN CASE OF CONTACT.
INGESTION
Seek medical advice immediately, showing the label and/or SDS. If conscious, washout mouth and give water to
drink. If unconsious, do not give anything by mouth, place in the recovery position, check breathing and pulse. If
necessary give artifical respiration. Do not induce vomiting without medical advice.
4.2 Most important symptoms and effects, both acute and delayed:
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful
if inhaled.
Aspiration may cause lung damage. Probable mucosal damage may contraindicate the use of gastric lavage.
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.
Product
NALCO® 2510
In the event of a spill, prevent material and fire water from entering sewers or waterways.
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
In the event of a spill, prevent material from entering sewers or waterways. Do not allow material to contaminate
ground water system. Prevent product from entering drains. If drains, streams, soil or sewers become
contaminated, notify local authority.
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage
thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material.
Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
Product
NALCO® 2510
HANDLING
Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep
the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure . Keep an eye wash fountain available. Keep a
safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.
STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Containers require venting bungs to
avoid over pressure. Avoid extremes of temperature. Storage temperature <35°C. 12 month shelf life under
given storage conditions
Specific use(s) :
BIOCIDE
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Source: Substance(s) Basis ppm mg/m3
Manufacturer's 2,2-Dibromo-3-nitrilopropionamide
Recommendation CEILING 2
MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed
as referenced below:
Product
NALCO® 2510
ENGINEERING MEASURES:
Use general ventilation with local exhaust ventilation.
GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.
EYE/FACE PROTECTION
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.
SKIN PROTECTION
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Nitrile Viton Gloves should be replaced immediately if signs of
degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The
applicable European standard can be found in EN 374.
Wear a complete suit protecting against chemicals. Wear impervious apron and boots. The applicable European
standard can be found in EN 14605 and EN ISO 20345.
RESPIRATORY PROTECTION
If significant mists, vapors or aerosols are generated an approved respirator is recommended. Where
concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied
breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals
being handled. The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387.
Consider the use of filter type: A-B-E-K-P If respiratory protection is required, institute a complete respiratory
protection program including selection, fit testing, training, maintenance and inspection.
Note: These physical properties are typical values for this product and are subject to change.
9.1 Information on basic physical and chemical properties:
9.1 Information on basic physical and chemical properties:
Product
NALCO® 2510
Not applicable
10.1 Reactivity:
No data available.
Heat
Keep at temperature not exceeding 35 °C
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium
hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or
boiling and toxic vapors. Oxidizing agents Aluminum
Product
NALCO® 2510
Product:
Acute oral toxicity : LD50: 510 mg/kg, Rat, Test substance: Product
Acute inhalation toxicity : LC50: 1.25 - 1.4 mg/l, 4 hrs, Rat, Test substance: Product
Acute dermal toxicity : LD50: > 2,000 mg/kg, Rabbit, Test substance:
Product
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/eye : Causes severe skin burns and eye damage.
irritation
Respiratory or skin : May cause an allergic skin reaction.
sensitization
Genotoxicity
Assessment :
: Contains no ingredient listed as a mutagen
Carcinogenicity : Based on available data, the classification criteria are not met.
None of the substances in this product are listed as
carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the
American Conference of Governmental Industrial Hygienists
(ACGIH).
None of the substances in this product are listed as
carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the
American Conference of Governmental Industrial Hygienists
(ACGIH).
Reproductive toxicity : Based on available data, the classification criteria are not met.
Assessment:
Assessment: No toxicity to reproduction
STOT - single exposure : Remarks: Based on available data, the classification criteria
are not met.
STOT - repeated exposure : Based on available data, the classification criteria are not met.
Aspiration toxicity : No aspiration toxicity classification
Product
NALCO® 2510
12.1 Toxicity:
The following results are for the product along with results on the hazardous components. The following results
are for the active components.
Product:
Toxicity to fish : LC50: 7.5 mg/l, 96 hrs, Sheepshead Minnow, Test substance:
Product
: LC50: 1.8 - 2.2 mg/l, Fathead Minnow, Test substance: Active
Substance
: LC50: 3.3 mg/l, Sheepshead Minnow
: NOEC: 3.2 mg/l, 96 hrs, Sheepshead Minnow, Test
substance: Product
Toxicity to daphnia and other : LC50: 4.2 mg/l, 96 hrs, Mysid Shrimp (Mysidopsis bahia), Test
aquatic invertebrates. substance: Product
: LC50: 6.67 mg/l, 48 hrs, Ceriodaphnia dubia, Test substance:
Product
: LC50: 0.66 mg/l, Daphnia magna, Test substance: Active
Substance
: EC50: 3.2 mg/l, 96 hrs, Mysid Shrimp (Mysidopsis bahia),
Test substance: Product
: NOEC: 5.0 mg/l, 48 hrs, Ceriodaphnia dubia, Test substance:
Product
Toxicity to algae : LC50: 0.30 mg/l, Green Algae (Pseudokirchneriella
subcapitata, previously Selenastrum capricornutum)
Product:
Bioaccumulation : Bioconcentration factor (BCF): < 100, Test substance: Active
Substance, This substance has a low potential to
bioconcentrate .
Product:
Biochemical Oxygen : Biological degradation: Approx, 70-80%, 28 Day, OECD 301 B
Demand (BOD) (Modified Strum Test)
Chemical Oxygen Demand : 1,110,000 mg/l
(COD)
Additional ecological : Product contains organic halogens, may contribute to AOX.
information
Product
NALCO® 2510
If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.
This product is suitable for disposal in an approved landfill or by controlled incineration. This product is ashless
and can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant
and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
14.1 UN number: UN 3265
14.2 UN proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(2,2-Dibromo-3-nitrilopropionamide)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user: Not applicable.
Product
NALCO® 2510
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
INTERNATIONAL REGULATIONS
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR
176.300 Slimicides, 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty
foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods.
For use at a maximum level of 0.005% of dry weight fiber. Limitation for compliance with 176.170 and 176.180:
For use only as a preservative at a level not to exceed 100 parts per million (as active)in coating formulations
and in component slurries and emulsions, used in the production of paper and paperboard and coatings for
paper and paperboard.
NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances &
Non-Food Compounds):
NSF Registration number for this product is: 141683
This product is acceptable for treating boilers, steam lines, and/or cooling systems (G7) where neither the
treated water nor the steam produced may contact edible products in and around food processing areas.
EUROPE
Safety Data Sheet according to Regulation (EC) No 1907/2006.
Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.
CANADA
Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification
requirements.
UNITED STATES
This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
Product
NALCO® 2510
LIST OF RELEVANT R-PHRASES, NOTAS AND HAZARD STATEMENTS IN SECTION 2.1 AND 3
H301 - Toxic if swallowed.
H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H330 - Fatal if inhaled.
H332 - Harmful if inhaled.
H400 - Very toxic to aquatic life.
H412 - Harmful to aquatic life with long lasting effects.
OEL - OEL
R20/22 - Harmful by inhalation and if swallowed.
R23/25 - Toxic by inhalation and if swallowed.
R34 - Causes burns.
R43 - May cause sensitization by skin contact.
R50 - Very toxic to aquatic organisms.
This product Safety Data Sheet provides health, safety, and regulatory information. The information contained in
this Safety Data Sheet is based on data available to us at the date of issue , and is provided in good faith, and
believed to be accurate and reliable at the date of issue, however, no warranty, express or implied is provided,
and Nalco disclaims all liability for reliance on such information. The product is to be used in applications
consistent with Nalco’s product literature. For any other uses, exposures should be evaluated so that the
appropriate handling practices and training programs can be established to ensure safe working conditions and
operations . It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use,
and to ensure that its activities comply with all federal, state, provincial, or local laws and regulations.
Regulatory requirements are subject to change and may differ between European Member States and Nations.
Individuals handling this product should be informed of the recommended safety precautions and should have
access to this information. Please consult your local sales representative for any further information.
REFERENCES
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
The possible key literature references and data sources which may have been used in conjunction with the
consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including
(EC) No. 1907/2006, (EC) No. 1272/2008, 67/548/EEC, 1999/45/EC), supplier data, inter-net, ESIS, IUCLID,
ERIcards, Non European official regulatory data and other data sources.
Product
NALCO® 2510
Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth