S.No.

TEST / Live Online CSCP

Yash Patil
FIITJEE Computer Based All India Test Series for JEE Main & JEE Advanced 2023
with Live Online Concept Strengthening Classroom Program (CSCP)
Schedule
Test Dates & Timings
1 PART TEST - I (Main) November 12, 2022 (3:00 PM to 6:00 PM)
Live Online CSCP by FIITJEE Delhi November 15, 2022 (10:30 AM to 5:30 PM)
2 PART TEST - I (Advanced) November 20, 2022 (Paper 1- 9:00 AM to 12:00 PM Paper 2- 2:30 PM to 5:30 PM)
Live Online CSCP by FIITJEE Delhi November 22, 2022 (10:30 AM to 5:30 PM)
3 PART TEST - II (Main) December 3, 2022 (3:00 PM to 6:00 PM)
Live Online CSCP by FIITJEE Delhi December 6, 2022 (12:45 PM to 7:45 PM)
4 PART TEST - II (Advanced) December 11, 2022 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)
Live Online CSCP by FIITJEE Delhi December 13, 2022 (12:45 PM to 7:45 PM)
5 PART TEST - III (Main) December 17, 2022 (3:00 PM to 6:00 PM)
Live Online CSCP by FIITJEE Delhi December 20, 2022 (12:45 PM to 7:45 PM)
6 PART TEST - III (Advanced) December 25, 2022 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)
Live Online CSCP by FIITJEE Delhi December 27, 2022 (12:45 PM to 7:45 PM)
7*, 8* FULL TEST - I (Main) & Full Test -I (Advanced) December 28, 2022 (Tests will be live for 7 days at fiitjee.glorifire.com)
9 FULL TEST - II (Main) January 7, 2023 (3:00 PM to 6:00 PM)
Live Online CSCP by FIITJEE Delhi January 10, 2023 (12:45 PM to 7:45 PM)
10 FULL TEST - III (Main) January 11, 2023 (3:00 PM to 6:00 PM)
Live Online CSCP by FIITJEE Delhi January 13, 2023 (12:45 PM to 7:45 PM)
11 OPEN TEST (Main) January 15, 2023 (9:00 AM to 12:00 PM)
Live Online CSCP by FIITJEE Delhi January 17, 2023, 12:45 PM onwards
12* FULL TEST V (Main) January 18, 2023 (Tests will be live for 7 days at fiitjee.glorifire.com)
13 FULL TEST - VI (Main) January 19, 2023 (9:00 AM to 12:00 PM)
14*, 15* CONCEPT RECAPITULATION TEST – I, II (Main) January 20, 2023 (Tests will be live for 7 days at fiitjee.glorifire.com)

TG ~ @bohring_bot
16 OPEN TEST I (Advanced) February 5, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi February 7, 2023 (12:45 PM to 7:45 PM)
17*, 18*, 19* FULL TEST III, IV & V (Advanced) February 8, 2023 (Tests will be live for 7 days at fiitjee.glorifire.com)

20 FULL TEST - VII (Main) March 22, 2023 (9:00 AM to 12:00 PM)

Live Online CSCP by FIITJEE Delhi March 24, 2023 (12:45 PM to 7:45 PM)
21 FULL TEST - VIII (Main) March 25, 2023 (3:00 PM to 6:00 PM)

Live Online CSCP by FIITJEE Delhi March 26, 2023 (12:45 PM to 7:45 PM)
22*,23* CONCEPT RECAPITULATION TEST PAPERS – SET III, IV (Main) March 27, 2023 (Test will be live for 7 days at fiitjee.glorifire.com)

24 FULL TEST - IX (Main) March 28, 2023 (9:00 AM to 12:00 PM)

Live Online CSCP by FIITJEE Delhi March 29, 2023 (12:45 PM to 7:45 PM)
25 FULL TEST - X (Main) March 31, 2023 (3:00 PM to 6:00 PM)

Live Online CSCP by FIITJEE Delhi April 1, 2023 (12:45 PM to 7:45 PM)
26 FULL TEST - XI (Main) April 2, 2023 (9:00 AM to 12:00 PM)

27 OPEN TEST II (Advanced) April 16, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi April 18, 2023 (10:30 AM to 5:30 PM)

28 FULL TEST - VII (Advanced) April 23, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi April 25, 2023 (10:30 AM to 5:30 PM)
29*,30*,
CONCEPT RECAPITULATION TEST PAPERS - SET I, II, III & IV (Advanced) April 26, 2023 (Test will be live for 7 days at fiitjee.glorifire.com)
31*,32*
33 FULL TEST - VIII (Advanced) April 30, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi May 2, 2023 (10:30 AM to 5:30 PM)

34 FULL TEST - IX (Advanced) May 7, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi May 9, 2023 (10:30 AM to 5:30 PM)

35 FULL TEST - X (Advanced) May 14, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi May 16, 2023 (10:30 AM to 5:30 PM)

36 FULL TEST - XI (Advanced) May 21, 2023 (Paper 1-9:00 AM to 12:00 PM Paper 2-2:30 PM to 5:30 PM)

Live Online CSCP by FIITJEE Delhi May 23, 2023 (10:30 AM to 5:30 PM)

1. Tests can be taken from CBT Centers located at cities namely Ahmedabad, Allahabad, Amritsar, Bangalore, Bhilai, Bhopal, Bhubaneswar, Bokaro, Chandigarh, Chennai, Cuttack, Delhi (Dwarka), Delhi (East),
Delhi (North-West), Delhi (South), Delhi NCR (Faridabad), Delhi NCR (Ghaziabad), Delhi NCR (Gurugram), Delhi NCR (Noida), Dhanbad, Durgapur, Gorakhpur, Gwalior, Hyderabad, Indore, Jaipur, Jamshedpur,
Jodhpur, Kanpur, Kharagpur, Kolkata, Kota, Lucknow, Meerut, Mumbai, Nagpur, Patna, Pune, Raipur, Ranchi, Vadodara, Varanasi, Vijayawada, Visakhapatnam.
2. Tests can also be taken from home on one’s own computer.
3. * marked Tests can be taken only at https://fiitjee.glorifire.com. Tests will be live for 7 days from the given date.
4. Link for Live Online CSCP will be sent by WhatsApp to your registered mobile number one/ two days before the session.
 Part Test - I
Yash Patil
FIITJEE Computer Based All India Test Series for JEE Main, 2023
Syllabus

Atomic Structure, Chemical Kinetics, Chemical Equilibrium, Balancing of Redox Reaction, Ionic Equilibrium, Chemical Bonding, s-Block and Hydrogen, Boron and
CHEMISTRY Carbon Family, Periodic Properties

Sets, Relations and Functions, Limits, Continuity and Differentiability, Application of Derivatives, Indefinite Integration, Definite Integrals and their Properties,
MATHEMATICS Area, Differential Equations, Volume & Surface

Units and Measurement, Kinematics (Motion in One Dimension), Vectors, Kinematics (Motion in Two and Three Dimensions), Relative motion, Laws of Motion,
PHYSICS
Work, Energy and Power, Center of mass, Conservation of momentum Collisions, Circular motion, Rotational Motion

Part Test -II

CHEMISTRY Organic Chemistry (Including GOC), Practical Organic Chemistry, Biomolecules, Polymers

MATHEMATICS Trigonometric Ratios and Identities, Trigonometric Equations, Heights and distance, Solution of triangle,Straight Lines, Circles, Parabola, Ellipse, Hyperbola

Kinetic theory of gases, Heat and Thermodynamics (second law+reversible and irreversible process, carnot engine+thermal expansion + calorimetry), Transfer of
Heat + convection, Electrostatics, Current Electricity (color code of resistors), Thermal Effects of Current, Magnetic Effects of Current, Pure magnetism (current loop
PHYSICS as magnetic dipole and its moment), bar magnet, magnetic field lines, earth magnetism, para-dia-ferro), Magnets, susceptibility and permeability, hysteresis,
eleectromagnets and permanent magnets, Magnetostatics, Electromagnetics Induction and Alternating Currents (ac generator and transformer, watless current,
quality factor)

Part Test - III

Group V to VIII, Transition Elements & Coordination Compounds, f-Block elements, Ores and Metallurgy, Liquid Solution, Surface Chemistry, Electrochemistry,
CHEMISTRY
Thermodynamics & Thermochemistry, Stoichiometry, Gaseous State, Qualitative Analysis, Solid State, Environmental Chemistry, Chemistry in Everyday Life

Progression and Series, Quadratic Equations and Expressions, Complex Numbers, Binomial Theorem, Matrices, Determinants, Permutation and Combination,
MATHEMATICS
Statistics (Measures of Dispersion) and Probability, Probability Distribution, Binomial Distribution, Vector, Three Dimensional Geometry

Oscillations (forced and damped oscillations), Wave & Sound, Ray Optics (microscope and astronomical telescope), Wave Optics (diffraction (single slit), resolving

TG ~ @bohring_bot
power of microscope and astronomical telescope, polarisation, brewesters law, uses of polaroids and polarised light), Electromagnetic Waves, Dual Nature of Matter
PHYSICS
& Radiation, Atoms, Molecules and Nuclei, Electronic Devices & Communication Systems, Experimental Skills in Physics, Gravitation, Properties of Solids and Fluids +
streamline flow, turbulent flow, reynolds number, Geometrical Optics, Semi Conductor Devices

Note : Full Tests syllabi will be same as that of Part Test - I, II & III combined.

FIITJEE Computer Based All India Test Series for JEE Advanced, 2023
Syllabus
Part Test - I

Atomic Structure, Chemical Kinetics, Chemical Equilibrium, Balancing of Redox Reaction, Ionic Equilibrium, Chemical Bonding, s-Block and Hydrogen, Boron
CHEMISTRY
and Carbon Family
Functions, Limits, Continuity and Differentiability, Application of Derivatives, Indefinite Integration, Definite Integrals and their properties, Area, Differential
MATHEMATICS Equations

PHYSICS Kinematics, Laws of Motion, Work, Energy and Power, Conservation of Momentum, Rotation

Part Test - II

CHEMISTRY Organic Chemistry (Including GOC), Practical Organic Chemistry, Biomolecules, Polymers

MATHEMATICS Trigonometric ratios and Identities, Trigonometric equations, Solution of triangles, Straight Lines,Circles, Parabola, Ellipse, Hyperbola

PHYSICS Heat and Thermodynamics, Electrostatics, Current Electricity, Magnetics, Electromagnetic Induction, A.C. Circuit

Part Test - III

Group V to VIII, Transition Elements & Coordination Compounds, Ores and Metallurgy, Liquid Solution, Electrochemistry, Thermodynamics & Thermochemistry,
CHEMISTRY
Stoichiometry, Gaseous State,Qualitative Analysis, Solid State

Progression and Series, Quadratic Equation s and Expressions, Complex Numbers, BinomialTheorem, Matrices, Determinants, Permutation and Combination, Probability,
MATHEMATICS Vector, Three Dimensional Geometry

PHYSICS Gravitation, Fluids, Simple Harmonic Motion, Waves & Sound, Optics, Modern Physics, Error Analysis

Note : Full Tests syllabi will be same as that of Part Test - I, II & III combined.
 Yash Patil
FIITJEE
ALL INDIA TEST SERIES
PART TEST – I

JEE (Main)-2023
TEST DATE: 12-11-2022
Time Allotted: 3 Hours Maximum Marks: 300

General Instructions:

TG ~ @bohring_bot
 The test consists of total 90 questions.

 Each subject (PCM) has 30 questions.

 This question paper contains Three Parts.

 Part-A is Physics, Part-B is Chemistry and Part-C is Mathematics.

 Each part has only two sections: Section-A and Section-B.

 Section – A : Attempt all questions.

 Section – B : Do any five questions out of 10 questions.

Section-A (01 – 20, 31 – 50, 61 – 80) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.

Section-B (21 – 30, 51 – 60, 81 – 90) contains 30 Numerical based questions. The answer to each
question is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 2

Physics PART – A

SECTION – A
(Single Choice Answer Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. In the diagram, the variation of coefficient of friction of the surface is shown. The external force F
applied on board is equal to 2Mg. Now the board is gently pulled so it starts moving. The
variation of acceleration of board with respect to displacement has been shown. The ratio tan 1:
tan 2: tan 3 is
F a
smooth smooth
A B C D
l l l 3
Coefficient of friction for
A to B = 3, B to C = 2, C to D = 
2
1
x
(A) 3 : 2 : 1 (B) 3 : 4 : 1
(C) 3 : 4 : 5 (D) 1 : 2 : 3

2.
TG ~ @bohring_bot
In terms of the basic units of mass M, length L, time T and charge Q, the dimensions of magnetic
permeability of vacuum 0 are
(A) [MLQ2] (B) [ML2T1Q2]
1
(C) [LTQ ] (D) [LT1Q1]

3. A thin massless rod of length 2 has equal point masses m attached at its 
ends as shown in the figure. The rod is rotating about an axis passing
m
through its centre and making angle  with it. The magnitude of net torque
about O is

(A) 2m 2 2 sin  cos  (B) 2m 2 2 sin  
2 2 2 2 2 2 O
(C) 2m  sin  (D) 2m  cos 

4. A rain drop falling vertically under gravity gathers moisture from the atmosphere at a rate given by
dm
 kt 2 , where m is the instantaneous mass, t is time and k is a constant. The equation of
dt
dv dm
motion of the rain drop is m v  mg
dt dt
If the drop starts falling at t = 0, with zero initall velocity and initial mass m0(m0 = 2 gm, k = 12
gm/s3 and g = 1000 cm/s2), the velocity v of the drop after one second is
(A) 250 cm/s (B) 500 cm/s
(C) 750 cm/s (D) 1000 cm/s

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 3 AITS-PT-I-PCM-JEE(Main)/2023

  2 x2 
5. A particle is released at x = 1 in a force field F(x)   2  ˆ x  0. Which one of the following
 x,
x 2 

statement is FALSE?

(A) F(x) is conservative
(B) The angular momentum of the particle about the origin is constant
(C) The particle moves towards x  2
(D) The particle moves towards the origin

6. A small mass M, is given an initial velocity v0, and it M v0

A X B
slides from A to B via two possible paths; either down
the shallow dip X or over the hump Y, both of which are
the same shape but inverted. Friction is to be ignored.
Along which path does the mass take the shortest time M v0
to slide from A to B? A Y B
(A) Via X (B) Via Y
(C) You cannot say (D) Same time taken
7. The graph below represents the kinetic energy, gravitational potential energy, and total energy of
a moving block. Which best describes the motion of the block?

Key

TG ~ @bohring_bot
Energy Kinetic energy
Gravitational potential energy
Total energy
0
Distance moved
(A) Sliding down an incline with constant friction
(B) Falling at a constant velocity
(C) Acceleration on a flat horizontal surface
(D) Falling freely under gravity

8. A ball of mass m is attached to the end of a thread fastened to the top of a O

vertical rod which is fitted to a horizontally revolving round table as shown. If w

the thread forms an angle  with the vertical, the angular velocity  of table is
g r r
(A) (B)
 cos  g tan
gtan  g tan 
(C) (D)
r   sin  r

9. In the figure shown, pulley and spring are ideal. If k is spring constant of
spring, the potential energy stored in it at equilibrium is (m1 > m2)
2m12 g2 2m22 g2
(A) (B)
k k
2 2 2 2
(m1  m2 ) g 1 (m1  m2 ) g
(C) (D) m1
k 2 k m2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 4

A
10. A rod of mass m and length  is hinged at one of its end A as shown in the
figure. A force F is applied at a distance ‘x’ from A. The acceleration of centre
of mass ‘a’ varies with ‘x’ as x

(A) a (B) a

x x
(C) a (D) a

x x

11. A smooth rod OP is fixed vertically. A disc of mass m and radius R P

is rolling without slipping on a rough horizontal surface as shown.
Velocity of centre of mass of disc is v0. A rod AB of length L is
connected with disc at A, R/2 distance vertically up from centre of
A

TG ~ @bohring_bot
disc with pin joint (about which it can rotate freely), other end of the 60° v0
rod is attached to a small smooth ring B, which can move freely B R
over rod OP. At an instant rod AB makes an angle 60° with the
O
vertical. The velocity of ring on the vertical rod at this instant is
3 3 3
(A) v0 (B) v 0
2 2
v
(C) v0 (D) 0
2

12. The police is chasing a thief and both move on same straight v(m/s)
road. After passing a particular point, their velocity v vary with
time t as shown in the figure. When will the police catch the thief?
(A) 90 sec (B) 80 sec
(C) 60 sec (D) 120 sec
30 40 t(s)

13. Last mango in the mango tree is located at 30 m horizontal and 40 m vertical from a boy. The
speed and angle with horizontal with which the boy should throw a stone so as to hit the last
mango?
(A) 50 m/s, tan1(2) (B) 30 m/s, tan1(3)
(C) 30 m/s, tan1(2) (D) 20 m/s, tan1(3)

14. A plate bent at right angles along its centre line, is placed onto a horizontal
fixed cylinder of radius R as shown. The minimum co-efficient of friction
between the cylinder and the plate so that plate does not slip off the cylinder
will be (Assume mass of plate and cylinder to be same) R
1
(A) (B) 2 Side view
2
1
(C) 2  1 (D) 1 
2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 5 AITS-PT-I-PCM-JEE(Main)/2023

15. Two sectors made of same material and same radius R but angle 120
and 60 are arranged as shown with centre as origin. Find the location of
centre of mass?
2R( 3  1) R( 3  1)
(A) (B)
3 3 60 60
3R( 3  1) 4R( 3  1)
(C) (D) O
3 3

30 30

16. Two object of the same mass slide down on two different
smooth fixed incline plane of same height but of different
angles. When they reach the bottom then I1 and I2 are the h
impulse of the weight of first and second object. Choose the
2 1
correct option.

I1 sin 1 I1 sin 2
(A)  (B) 
I2 sin  2 I2 sin 1

TG ~ @bohring_bot
I1 tan 1 I1 tan  2
(C)  (D) 
I2 tan  2 I2 tan 1

17. The instantaneous velocity of a body moving in a straight line v (m/s)

changes with time as shown in the figure. Choose the correct 5
average velocity versus time depicting the same motion? 4
3
2
1

1 2 3 4 t (sec)

(A) vavg (B) vavg

4 4
3 3
2 2
1 1

1 2 3 4 t (sec) 1 2 3 4 t (sec)
(C) vavg (D) vavg

4 4
3 3
2 2
1 1

1 2 3 4 t (sec) 1 2 3 4 t (sec)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 6

18. A cylinder of mass M and radius R is resting on two corner

edges A and B as shown in the figure. The normal reaction
at the edges A and B are: (Neglect friction)
60 30
A

(A) NA  2NB (B) NB  2NA

Mg 2 3Mg
(C) NA  (D) NB 
2 5

19. A square laminar sheet with side a and mass M, has mass per y
 x
unit area given by (x)  0 1   . Moment of inertia of the +a/2
 a
sheet about y axis is (a, 0)
Ma2 Ma2 x
(A) (B)
2 4 a/2
2
Ma Ma2
(C) (D)
6 12

20.
TG ~ @bohring_bot
A spring is compressed between two toy carts of masses m1 and m2. When the toy carts are
released, the spring exerts on each toy cart equal and opposite forces for the same time t. If the
coefficients of friction  between the ground and the toy carts are equal, then the displacements
of the toy carts are in the ratio
s m s m
(A) 1  2 (B) 1  1
s2 m1 s2 m 2
2 2
s m  s m 
(C) 1   2  (D) 1   1 
s2  m1  s2  m 2 

SECTION – B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.


21. A shell if fired at an angle  with horizontal up a plane inclined at an angle . The value of  for
6

maximum range is . Fid the value of k.
k

22. Two blocks A and B 1 kg and 2 kg respectively are kept on a turn y


table 1 m away from axis yy as shown in the figure. Consider  = 1kg
0.5 between all contact surfaces and pulley to be massless and
frictionless. The angular speed of the turn table for which the blocks 2kg
just begin to slide is 5k . Find k. (Take g = 10 m/s2) y
1m

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 7 AITS-PT-I-PCM-JEE(Main)/2023

23. Two objects of masses m and 2m are moving at speeds of v and v / 2, respectively. After
undergoing a completely inelastic collision, they move together with a speed of v / 3. The angle
between the initial velocity of the two objects is K. Find the value of k.

24. If there is a positive error of 50% in the measurement of velocity of a body, then the error in the
measurement of kinetic energy is k%. Find the value of k.

25. The motion of a point A on the rim of a wheel rolling uniformly along a horizontal path has the
form
x = 2(5t  sin 5t)
y = 2(1  cos 5t)
The distance which it traverses between two successive contacts with the roadbed is k meter.
Find the value of k.

26. Three identical equilateral prisms A, B and C are arranged

A C
as shown in the figure. Mass of each prism is M  3 kg.
F B F
Two horizontal forces of equal magnitude (F) are applied on
A and C as shown in the figure. Find the minimum value of
F in newton so that A and C loose contact with the floor.
(Ignore friction and take g = 10 m/s2)

27. A modern machine gun fires 3600 bullets per minute with 600 km/hr. If each bullet weights 200

TG ~ @bohring_bot
500
gm then the power of the gun is kilowatt. Find the value of m.
m

28. A solid cylinder rolls down an incline plane of angle . The least value of coefficient of friction so
tan 
that the cylinder rolls without slipping is . Find the value of k.
k

29. Two blocks of masses 2 kg and 3 kg are placed on a plank. An 10N

external force of 10 N is acting on 2 kg block and the whole system
2kg
including the plank is moving vertically up with a constant acceleration a0
a0 = 2 m/s2. The normal reaction force between the 3 kg block and 3kg
 Plank
Plank is  N. Find the value of . (g = 10 m/s2)
10

30. A smooth cylindrical glass lies on the ground. A small particle of mass R
m lies on the bottom surface touching circumference as shown in the
figure. The minimum value of v 0 (along the circumference) such that
Kgh
particle just reaches at the top of glass is . Find the value of K. h
3

v0
R/2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 8

Chemistry PART – B

SECTION – A
(Single Choice Answer Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

31. The CORRECT order of electron gain enthalpy of B, Be, N and C is (consider magnitude only)
(A) Be < B < C < N
(B) Be < N < B < C
(C) N < Be < C < B
(D) N < C < B < Be

32. Which of the following properties is INCORRECTLY matched?

(A) F2  Cl2  Br2  I2  Oxidi sin g character 
(B) K  Mg  Al  B Metallic character 
(C) C  Be  B  Li 1st
Ionisation enthalpy 
(D) Li  Na  K  Rb Chemical reactivity 

The minimum uncertainty in the velocity of a particle of mass 1.1  10 28 kg will be if its

TG ~ @bohring_bot
33.
 
uncertainty in position is 3  1010 cm h  6.62  1034 Js .
(A) 1.6  106 ms 1
(B) 2.6  105 ms 1
(C) 3.6  105 ms1
(D) 1.6  105 ms 1

34. The coefficients of BaCrO4, KI, CrCl3 and KCl in the balanced equation of the following reaction
are respectively
BaCrO 4  KI  HCl  BaCl2  I2  KCl  CrCl3  H2 O

BaCrO 4 KI CrCl3 KCl

(A) 2 6 2 6
(B) 6 2 6 6
(C) 2 2 6 6
(D) 6 6 2 2

35. At a given temperature, the rate constant for the decomposition of HI on a metal surface is
0.06 Ms 1
2HI  g  H2  g  I2  g 
The time taken for the concentration of HI to fall from 1.50 M to 0.30 M is
(A) 10 s
(B) 20 s
(C) 15 s
(D) 8 s

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 9 AITS-PT-I-PCM-JEE(Main)/2023

36. The increasing order of bond angles in OF2 ,OCl2 ,ClO2 and H2 O is…….
(A) OF2  H2 O  OCl2  ClO2
(B) H2 O  F2 O  Cl2 O  ClO2
(C) OF2  Cl2 O  H2 O  ClO2
(D) ClO 2  Cl2 O  OF2  H2 O

37. Consider the following reactions in equilibrium


N2  3H2  2NH3 K 1 


N2  O2 
 2NO K 2 
1
H2  

O2  H2 O K 3 
2
Then the equilibrium constant for the reaction
5
2NH3  O2  2NO  3H2 O
2
(All the above reactions are in homogeneous equilibrium)
K K
(A) 2 3
K1
K 2K 13
(B)

TG ~ @bohring_bot
K3
K 2K 33
(C)
K1
K 2 K1
(D)
K3

38. The pH of pure water at 25o C and 35o C are 7 and 6 respectively. The heat of formation of
H  aq and OH  aq ions in Kcalmol1 is
(A) 84.5
(B) + 84.5
(C) 94.5
(D) + 94.5

1
39. A hypothetical small particle of mass ‘m’ moves in such a way that its potential energy   m kr 4 .
2
Where k is a constant and r is its distance from the nucleus (origin). Assuming Bohr’s model r is
directly proportional to
(A) n2
(B) n
(C) n
(D) 3 n

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 10

40. Consider the reaction in equilibrium



 2H2 O  g  Sn   
SnO2  s  2H2  g 

at 300 K, the equilibrium mixture was found to contain 40% by volume of H2  g . The K P for the
reaction is
(A) 1.15
(B) 10.9
(C) 7.75
(D) 2.25

41. The three reactions are given below



A  g  B  g  
 C  g  D  g … (I)



A  g  
 C  g   D  g … (II)



A  g   B  g 
 D  g … (III)
Which of the following statement is INCORRECT?
(A) Increase in pressure shifts the equilibrium (II)nd to the left
(B) Decrease in volume shifts the (III)rd equilibrium to right
(C) Addition of He at constant volume shifts the (II)nd equilibrium to left
(D) Addition of He at constant pressure shifts the (III)rd equilibrium to left

TG ~ @bohring_bot
42. At high temperature and at a pressure of around 2 atm, nitrogen gas is bubbled over calcium
carbide, the major product obtained is
(A) Calcium cyanide
(B) Calcium cyanamide
(C) Calcium nitride
(D) Calcium

43. Which of the following statement is NOT correct?

(A) Stability of peroxides and superoxides of alkali metals increases with increase in the size of
metal ion.
(B) Sodium hydroxide does not absorb water from atmosphere.
(C) Lithium fluoride is less soluble in water due to its high lattice enthalpy.
(D) Caesium iodide is less soluble in water due to low hydration enthalpy.

44. In solid state, beryllium chloride has

(A) Three centre-four electron bonds.
(B) Three centre-three electron bonds.
(C) Two centre-three electron bonds.
(D) Two centre-two electron bonds.

45. Consider the following silicates

I. Pyro silicates II. Cyclic silicates
III. Double chain silicates IV. Single chain silicates
V. 3D-silicates VI. Sheet silicates
The silicates in which only two corners per tetrahedron are shared
(A) I, II, IV
(B) IV, VI
(C) I, VI
(D) II, IV

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 11 AITS-PT-I-PCM-JEE(Main)/2023

46. Select the CORRECT sequence of geometry of the given molecules/ions

Borazon, Borazole, B3 O 6 , Al2 Cl6
(A) Non planar, non planar, non planar, planar
(B) Planar, planar, non planar, non planar
(C) Non planar, non planar, non planar, planar
(D) Non planar, planar, planar, non planar

47. Consider the following species

  
NO2 , NO2 , N O2 ,NO3
Select the INCORRECT statement for the above molecule/ions?
(A) NO2 is paramagnetic
  o
(B) NO2 is linear, NO2 is bent having bond angle more than 120

(C) NO3 has bond order 1.33
(D) NO2 has bond angle more than 120o

48. Consider the compounds LiH, NaH, Li2 CO3 and Na2 CO3 . Select the compound (s) which
decomposes on heating around 400 – 500oC.
(A) LiH, Li2 CO3
(B) NaH, Na2 CO3

TG ~ @bohring_bot
(C) LiH, NaH
(D) NaH, Li2 CO3

49. Which of the following statement(s) is(are) NOT correct?

I. Bond length order is H2  H2  H2 .
II. O2 ,NO,N2 have bond order 2.5.
III. Bond order varies from 0 to 4.
IV. In NO3 and BO3 the bond order is same between central atom and side atom.
(A) I, II
(B) II, III
(C) I, IV
(D) I, III

50. Select the INCORRECT statement regarding Diborane (B2H6)

(A) Maximum 6 H-atoms lie in a plane
(B) Maximum 6 atoms lie in a plane
(C) There is hindered rotation between two boron atoms
(D) Terminal H – B – H bond angle is greater than bridge H – B – H bond angle

SECTION – B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

51. A sample of solid AgCl was treated with 5.00 mL of 1.5 M Na2CO3 solution to give Ag2CO3. The
remaining Cl ion concentration was found to be 0.0026 g L1 . The solubility product of AgCl is
given by x  10 y . Then the value of (x + y) is………(Rounded off to nearest integer).
K SP of Ag2 CO3  8.2  1012 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 12

1
52. A tiny particle moving with a velocity th times the velocity of light. If uncertainty in the position
60
6.62
is  1012 m, then the minimum uncertainty in kinetic energy is x  10 y J, then the value of
3.14
xy is…….

53. Potassium permanganate reacts with sulfur dioxide in acidic medium to produce a product
containing bisulphate ion(s) and same other product(s). The sum total of coefficients of potassium
permanganate and the product containing bisulphate ions in the balanced equation is…….

54. For a reaction which following first order kinetics the half life is 693 s and the values of pre
exponential factor and activation energy are 4  1013 Hz and 98.6 kJ mol1 respectively, then the
temperature in Kelvin when half life is 693 s, is…… (log2 = 0.30)

55. An equilibrium mixture at 300 K contains N2 O 4 and NO2 at 0.28 and 1.1 atm respectively. If the
volume of container get doubled, the equilibrium pressure of NO2  g is x  102 atm , then the
value of x is………

56. Total number of species having used all three P-orbitals for hybridisation of central atom and are
non-polar also is…..

TG ~ @bohring_bot

XeO2 F2 , SnCl2 , IF5 , I3 , XeO 4 ,  XeF7  , SO2

57. The number of correct order(s) in the following is……..

1. CH4  CCl4  CF4 (Electronegativity of carbon)
2. Mg  K   S   Se  (Ionic radius order)
3. LiF  NaF  KF  RbF (Lattice energy order)
4. Li  Mg  Al3 (Hydration energy order)
5. Cl2  F2  Br2  I2 (Bond energy order)

H O
58. Na2 O2 2
PQ
Ice cold 

H2 O Room temperature 

PR 

 M  M2 
If molar mass of (Q) and (R) are M1 and M2 respectively then the value of  1  is......
 2 

59. A 1.025 g sample containing a weak acid HA (MW = 82) is dissolved in 60 mL of water and
titrated with 0.25 M NaOH. When half of the acid was neutralized, the pH was found to be 5.0 and
at the equivalence point the pH is 9.0. The mass percent of weak acid HX in the sample is…….%.

60. The pH of the resultant solution of 25 mL of 0.1 M HCl, 50 mL of 0.2 M HNO3 and 25 mL of 0.1 M
NaOH is……

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 13 AITS-PT-I-PCM-JEE(Main)/2023

Mathematics PART – C

SECTION – A
(Single Choice Answer Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

x
4 2
61. Let f be a differentiable function satisfying   x  p  1 f p  dp = x + x  x  [2, ), then value of
0
2

  f '  x   f  x   dx is
2
(A) 0 (B) 36
(C) 72 (D) 18

3
1   cos2x cos 4xcos6x cos8x cos10x  P
62. Let P = lim 2
, then the value of   is
x 0 (tan x)  10 
(A) 66 (B) 33
(C) 22 (D) 11

TG ~ @bohring_bot
n
 r  1 n  r 
63. If A = lim  sin  2  and B = lim  sin   , then value of 2A + B is
n  n  n  n n
r 1 r 1

2 2
(A) 1 (B)
 
 1 
(C) (D) 1
2 2

1
64. Let f(x) = 2
, x  (0, 1), then which of the following is INCORRECT ?
2
sin x   x  a 
(A) f(x) is always increasing in (0, 1) (B) f(x) is always decreasing in (0, 1)
(C) f(x) is increasing if a  (2, 3) (D) f(x) is decreasing if a  (2, 3)

1 1 1 1
65. 
If A   1  x 2023  2022 dx and B   1  x 
2022 2023
dx , then find the value of
0 0

 A 3  B3   A 4  B 4 
 3  4  is
 B   B 
(A) 0 (B) 1
(C) 2 (D) none of these

 x2  x  4    x2  x  3  
66. The exhaustive set of domain of the function f(x) = sgn  2   tan   2   , (where [.]
 x x3 x  x  4
is G.I.F.) is
1 
(A) (, 0) (B)  ,3 
3 
 1 
(C)  ,3  (D) (, )
3 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 14


67. If the area bounded between the curves y = tanx, y = sinx, x = 0 and x = is A, the A is equal to
4
1 1 1
(A) ln2  (B) ln2
2 2 2
1
(C) (D) none of these
2

  1
2
68. Let f(x) be a function, such that f(x) = x + sinx and I1   f  x  dx, I2   f 1  x  dx and I3   e x dx ,
0 0 0
then which of the following is true ?
(A) I1 > I2 > I3 (B) I3 > I2 > I1
(C) I1 > I3 > I2 (D) I3 > I1 > I2

x x
2
69. If f  x     ln t  dt and g  x    ln t  dt , then area bounded between the curve y = f'(x) and
0 0
y = g'(x) between x = 1 to x = e is
(A) e  3 (B) 3
(C) e (D) 3  e

L2
1 1 x3  1

TG ~ @bohring_bot
70. Let L1  lim sec x, L 2  lim sec x , then the value of  x 2  1 dx
x  x 
L1


(A)  (B)
2

(C) (D) 0
4

 12 x 
71. lim   2  is equal to
x 1
 n1 n(n  1)x  3(2n  1)x  9 
11 3
(A) (B)
60 16
13 9
(C) (D)
64 44

72. Water is being filled at the rate of 100 litre/min in a conical vessel (vertex downwards) with axis
 5 
vertical. Its semi vertical angle is tan1   . The rate (in square meter per minute) at which the
 12 
wet curved surface area of the tank is increasing, when the depth of water in tank is 3 meters is
13 13
(A) (B)
75 25
1 3
(C) (D)
5 11
2
73. The area of the region bounded by A = {(x, y) : x  4  y  min{2x + 11, 9, 12  6x} is
511 947
(A) (B)
12 12
437 240
(C) (D)
8 7

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 15 AITS-PT-I-PCM-JEE(Main)/2023

t  
x5
Let f  t    e x   dx, then f(1) + f(1) is equal to
2
74. 2 
0
 
 x 4  2x 2  2  

3e 1 7e 1
(A)  (B) 
10 4 50 4
7e 1 2e 1
(C)  (D) 
50 2 5 2

75. lim
x 
 
x 4  kx 3  3x 2  mx  2  x 4  2x 3  nx 2  3x  p = 4 then k + n is equal to
(A) 3 (B) 7
(C) 5 (D) 0
2
x 3 sin2022 x 2
76. If I   dx is equal to
0 cos2022 x 2  sin2022 x 2
2

(A) (B) 22
2
(C) 2 (D) 0

dy x  y  4
77. If the solution curve of the differential equation  passes through the point (3, 2) and

TG ~ @bohring_bot
dx xy
(p + 2, 3), p > 0, then
 1  1
p
  
(A) 2 tan1    loge p2  1 (B) tan1    loge p2  1
p
 1   1  p2  1 
(C) 2 tan1  2

  loge p  2p  2  (D) 2 tan1    loge 
p

 p  1  p 


min  x  6  ,x 2  4  x  0
 
78. Let f : [4, 2]  R be given as f  x   
 max x, x
2

0x2 
If the area bounded by y = f(x) and x-axis in A then the value of 3A is equal to
(A) 19 (B) 35
(C) 37 (D) 32
t
log10 x
79. If f  t    dx , t > 0, then f(e4) + f(e4) is equal to
1
1  x
16
(A) 8 (B)
loge 10
8 e4  1
(C) (D)
loge 10 2loge 10

 x3  2x2  3x  9 x  2
80. Let f(x) =  , then the set of all values of k for which f(x) has maximum
2

3x  log3 k  5 x  2 
value at x = 2 is
(A)  4 2, 4 2  (B)  5, 4 2  
(C)  4 2,  5  5, 4 2   (D) 5, 2 2  

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM-JEE(Main)/2023
Yash Patil 16

SECTION – B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

 x2  x  2 
81. The number of solution of the equation sin1  x    2   0 , [.] is G.I.F.
 x  x  1

2
2  
82. The area bounded between the curves y = sin1(sinx) and y     is 'A', then the
4  2
 8A 
value of  2  (where [.] is G.I.F) is
 

0 x  x2
x 
83. Let f(x) be a function defined as f(x)  x 0 x 1  
2
 2

 sin x  3 4  x , then the

2
x x  1 0
number of integers in the range of f(x) is (where [.] is G.I.F)

84. The number of points where the function f : R  R, f(x) = |x  2| cos|x2  3x| sin|x  2| + (x  1) |x3

TG ~ @bohring_bot
 8x2 + 7x| is non differentiable is

a 0 1 
85. Let m = a b b  and det(m) = 37, if a, b, c are positive integers, then least value of trace(m)
0 1 c 
is

d2 y
86. If y = y(x) is an implicit function of x such that loge(x + y) = 6xy, then at x = 0 is equal to ____
dx 2
 x 3 
87. 
If the value of lim 3  2cos x cos 2x
x 0
 2 
 x  is equal to ea, then a is equal to

88. If the tangent to the curve y = x 3  2x2 + 4x + 4, at the point (a, b) (where a > 0) is also tangent to
the curve y = 3x2 + 2x  1 at (1, 4), then a + b is equal to

12x15  5x18 1
89. If f(x) =  dx and 16f(1)  1 = 0 and f(1) = , then |k| =
8 3 k
 2x 3
 3  7x 
e
n
 x log x 
23
90. Let In = dx where n  N, if 24I15 = I14 + BI13, then  +  is equal to
1

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
FIITJEE
ALL INDIA TEST SERIES
PART TEST – I

JEE (Main)-2023
TEST DATE: 12-11-2022

ANSWERS, HINTS & SOLUTIONS

Physics TG ~ @bohring_bot PART – A

SECTION – A

1. A
Sol. If the block has moved by distance x, F  2Mg
smooth
 Mg 2Mg 3Mg A
Ma = 2Mg     l  x   l
B
l
C
l
D
x
 3 3 3l 
 g 2g 3g
a  2g     l  x  
 3 3 3l 
da1 3g nd rd
 [for 2 and 3 cells similarly]
dx 3l
tan 1: tan 2 : tan 3 = 3 : 2 : 1

2. A
    I
F  I d  B, B  0  F  I2 0
Sol.  d
2
Q
2
 [MLT ] =   0
T
 0 = [MLQ2]

3. A
      
Sol. L  m  r  (  r )  m  r  (  r )  2m  r   sin   2m 2 sin 
dL  
Torque =    J  2m 2 sin(90   )sin   2m2 cos  sin 
dt

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 2

4. B
dm kt 3
Sol.  kt 2  m  2
dt 3
dv dm dv
m v  mg  m  vkt 2  mg
dt dt dt
dv kt 2 dv 3kt 2
 v  g  3 v  g which is linear differential equation
dt m dt kt  6
v(kt 3  6)  g(kt 3  6)dt  c , t = 0, v = 0  c = 0

4
g(kt  24t)
v
4(kt 3  6)
3 2
Put 2 gm, k = 12 gm/s and g = 100 cm/s ) and t = 1
1000(12  24)
v  500 cm/sec
4(12  6)

5. C
  2 x2 
Sol. F(x)   2 
x  eˆ x , x  0
 2 
Work done in a cycle is zero so conservative
 

TG ~ @bohring_bot
r  F  0 , so angular momentum is conserved
 2 x2 
For equilibrium point F = 0  F   2    0  x   2, 2 x > 0 so equilibrium point is 2
x 2 

dF 4 2x
To check stable and unstable equilibrium point 0 3  0
dx x 2
dF 4 2x 4
At x  2, 0  3    2 = ve
dx x 2 2 2
So, it is unstable point so particle moves away from point x = 2
So, it is obvious that it will moves towards origin.

6. A
Sol. Speed is never less than v 0 in x whereas in y it is less than v 0 first and then increases t v 0 so, y
take more time.

7. D
Sol. Friction will produce heat energy and so the total energy will not be PE + KE (or all of the PE will
not turn into KE). At a constant velocity there is no gain of KE. On a horizontal surface there is no
change of PE. Falling freely, the PE turns solely into KE.

8. C
Sol. T sin   m2R Tcos
T cos   mg T 
2R
tan   Tsin
g
gtan  gtan  mg
 
R r   sin  R= r+lsin

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 3 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

9. A
Sol. T = m 1g
kx  2T  2m1g
2T
2m1g
x
k
T
2 2
2m12 g2 T
1 1 4m1 g T
Energy stored = kx2 = k = T
2 2 k2 k m1
m2
m1g T1

10. B
Sol. The rod will rotate about point A with angular acceleration:
 Fx 3Fx
  
I m 2 m 2
3
 3 Fx
 a  or a  x
2 2 m
i.e., a-x graph is a straigth line passing through origin.

11. A

TG ~ @bohring_bot
3v 0 3 3
Sol. v cos60  cos30 , v  v0
2 2

12. C
t
v t v t2
Sol. v1  0 , S1  0
40 40 2
30

v0 t v t2 t
v2   3v0 , S 2  0  3v 0 t 30
10 20
S1 = S2
 t = 60 sec

13. B
Sol. v min  g(y  x 2  y 2 )  30 m/s
v2
tan   3
gx

14. C
Sol. N1  f2  2mg …(i) N1
N2  f1 …(ii) A
f1 B
f1  N1 …(iii)
f2
f2  N2 …(iv)
mg N2
Taking moment about corner B of plate
(mg  N2 )R  N1R
mg  N2  N1 …(v) C
From (i), (ii) & (v), mg
f1  f2  mg …(vi)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 4

From (iii), (iv) & (vi),  2  2  1  0 or

  2 1

15. A
2R sin 
Sol. Centre of mass of arc is
3
m1 = 2m, m2 = m
     
2m  2R sin     2R sin   
 3
  6
 m
    
3 3   2 
6 
      2R( 3  1)
centre of mass  
3m 3

16. A
  |pi|sin
Sol. impulse  pf  pi

pi

pf
pf |pi|cos

TG ~ @bohring_bot mg

mg sin

17. A
Sol. t = 0 to t = 1 sec
v = 4t m/s
s = 2t2 m
s(t = 0) = 0 m, s(t=1) = 2m
s
v average   2 m/s
t
t = 1 to t = 2 sec
v = 2 m/s
s = 2t m
s ( t = 1) = 2m, s(t = 2) = 4m
vaverage = 2 m/s

18. C
Sol. A cylinder of mass M NB
NA
For equilibrium NA cos 60 + NB cos 30 = Mg
30 60
and NA sin60  NB sin30
Mg
On solving NB = 3NA ; NA  Mg
2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 5 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

19. C
 x y
Sol. dM  0  1   dx
 a
 a
M 0 dx
2
x
 d(MOI) = dmx2
Ma2
MOI  dMx 2 
 6

20. C
Sol. Minimum stopping distance = s
Force of friction  mg
Work done against the friction W  mgs
Initial kinetic energy of the toy cart  p2 / 2m 
 
mgs  p2 / 2m 
2
s1  m2 
 
s2  m1 

TG ~ @bohring_bot
SECTION – B

21. 3
Sol. Let the shell hit the plane at p(x, y), the range being AP = R, as
shown in the figure. The equation for the projectile’s motion is
gx 2
y  x tan   2 …(i) R P(x, y)
2u cos 2  

Now y = R sin  …(ii)
A B 2R
x = R cos  …(iii)
Using equation (ii) and equation (iii) in equation (i) and simplifying
2u2 cos  sin(   )
R
gcos2 
dR
The maximum range is obtained by setting  0 , holding u,  and g constant. This gives
d

cos(2   )  0 or 2   
2

22. 5
Sol. for block A
T  mA g  mA 2R
For block B
T  (mA  mB )g  mA g  mB2R
g(3mA  mB )

R(mB  mA )

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 6

23. 120
Sol. As px = 0, py = 0
For x direction,
v cos  cos  v
 2m   mv  3m 
2 2 2 3
cos  cos  1
 2mv  mv    cos 60
2 2 3

 60    120
2

24. 125
1
Sol. Kinetic energy E  mv 2
2
E v 2  v 2
  100   100  (1.5)2  1  100
E v 2  
E
 100  125%
E

25. 16
v  v 2x  v 2y

TG ~ @bohring_bot
Sol.
v x = 10  10 cos 5t, vy = +10 sin 5t
 5t 
v  20 sin  
2
t
 5t 
0

S  20 sin  dt , t = 2
2
So, S = 16 m
26. 30
Sol. A begins to climb B if F cos 60  Mg sin 60
F  3 Mg
F  30 N
27. 3
1
n mv 2 2
2 3600  1   500 
Sol. Power = K.E./ time =    (0.2)  
t 60  2   3 
 500  3
=    10 watt
 3 

28. 3
Sol. a = g(sin    cos )
Rz R(mgcos R)
Also, a = R,   2gcos 
I 1
mR2
2
 g (sin   r cos ) = 2g cos 
tan 

3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 7 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

29. 7
Sol. 2a0 = N1  10  2g 10N

2kg
a0

N1 2g
N1 = 34 N N1
3a0 = N2  N1  3g
3kg
N2 = 70 N a0

N2 3g

30. 8
Sol. By the conservation of energy
1 1
mv 20  mgh  mv 2 …(i)
2 2
By conservation of angular momentum
mv0R
 mvR
2
From equation (i) and equation (ii)
8gh
v0 
3

TG ~ @bohring_bot
k=8

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 8

Chemistry PART – B

SECTION – A

31. B
Sol. Be B C N
2s2 2s2p1 2s2p2 2s2p3
Be and N have stable configurations, so do not accept electron easily, hence for these elements
the process is Endothermic.
So, correct order is Be < N < B < C

32. D
Sol. On moving down the group the IE1 of Gr(1) elements decreases continuously hence reactivity
increases.

33. D
h
Sol. v  x  (Using uncertainty principle)
4m
6.62  1034
 v 
4  3.14  1.1  1028  3  1012
 v  1.597  105  1.6  105 ms 1

34.
Sol.
A TG ~ @bohring_bot
The ionic equation is
Acidic
CrO 4  I

 HCl 
medium
 Cr   I2
 6   
 1  3   0 
 2CrO   
4  6I  16H   2Cr   3I2  8H2 O
or
2BaCrO4  6KI  16HCl  2CrCl3  3I2  8H2 O  6KCl  2BaCl2

35. A
Sol. 2HI  g  H2  g  I2  g  (follows zero order kinetics)
1 d R  o
  k R 
2 dt
Ro   R 
t
2k
1.50  0.30
t
2  0.06
1.20
t  10 s
0.12

36. A
Sol. O Cl
O O < <
<
Cl 111o Cl O 118o O
F 103o F H 104.5o H

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 9 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

H2 O has larger bp – bp repulsion than OF2 and OCl2 has larger steric repulsion between two
large Cl atoms while in ClO2 the bond angle is 118o close to 120o .  
37. C
 1 
Sol. 

2NH3 
 N2  3H2   … (1)
 K1 


N2  O2 
 2NO K 2  … (2)

3
3H2  
O 2  
 3H2 O K 3
3
  … (3)
2
Adding (1), (2) and (3)
5
2NH3  O 2  2NO  3H2 O  K eq 
2
K K3
 K eq  2 3
K1

38. B
Sol. 

H2 O    
 H  aq  OH  aq
 

At 25o C, H   OH   107 M

TG ~ @bohring_bot
 K W1  10 14

At 35o C, H   OH   106 M

 K W2  1012
K W2 H  T2  T1 
Now, 2.303 log   
K W1 R  T1T2 
12
10 H  308  298 
 2.303 log 
14
 
10 2  308  298 
H 10
 2.303  2  
2 308  298
 H  84.551 Kcal mol1
Since, 84.551 Kcal mol1 is the enthalpy change for the reaction

39. D
1 1 1
Sol. KE   PE      mkr 4 
2 2 2 
1 1
KE  mkr 4  mv 2
4 2
mkr 4 .2 1 4
 v2   kr … (1)
4.m 2
nh n2 h2
Since, mvr   v2  … (2)
2 4 2 m 2 r 2
From (1) and (2)
1 4 n2 h2
kr 
2 4 2 m 2 r 2
 r 6  n2  r  3 n

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 10

40. D
P2H O g
2
Sol. KP  … (1)
P2H  g
2

40
PH2   PT  0.4PT
40  60
60
PH2O   PT  0.6PT
40  60
PH O 0.6PT 3
 2    1.5
PH2 0.4PT 2
2
 From Eq. (1) K P  1.5   2.25

41. C
Sol. (A)  ng  0,  in P shifts the equilibrium 
(B)  in volume in (III)rd equilibrium shifts the equilibrium  ng  0  
(C) At constant volume no effect of addition of He
(D) At constant pressure, addition of He shifts the equilibrium  ng  0  

TG ~ @bohring_bot
42. B
2 atm
Sol. CaC2  N2 
high temp.
 CaCN2 C
Calcium cyanamide

43. B
Sol. (A) On moving down the group, the size of metal ion increases, so stability of
peroxides/superoxides increases.
i.e. Large cation – Lagre anion interactions increases.
(B) NaOH is hygroscopic in nature.
lattice H hyd H
(C), (D) Fact based on and .

44. A
Sol. In solid state, BeCl2 exists as a polymer.
Cl
Cl
Cl
Be
Be
Be
Cl
Cl Cl

(four electrons are shared between three atoms, so 3c-4e type of bonds are present)

45. D
Sol. I. – 1 corner shared
II. – 2 corners shared
III. – One unit shares 2 corners while one unit shares 3-corners.
IV. – 2 corners shared
V. – 4 corners shared
VI – 3 corners shared

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 11 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

46. D
Sol. Borazon  Diamond like structure (Non-planar)
Borazole  Inorganic benzene (Planar)
O

O O

B3 O6
Planar 
B B
O O
O
Cl
Cl
Cl
Al
Al2 Cl6 Al
Cl
Cl Cl
(Non-planar)

47.
Sol.
B
TG ~ @bohring_bot
NO2  odd electron species
 Paramagnetic
 
NO2 is linear while NO2 and NO2 are bent.

NO2  lp – bp repulsion
NO2  bond angle is around 134o
 4
Bond order of NO3 is  1.33
3
 
 
Bond angles, NO2 115o , NO2 180o , NO2 134o   
48. D
Sol. LiH  Stable
NaH  Unstable
Li2 CO3  Unstable
Na2 CO3  Stable
(Around 400 – 500oC)

49. C
Sol. I.  Bond length order is H2  H2  H2
II. Isoelectronic species, so identical bond order.
III.  Fact.
IV  NO3  Re sonance  , BO3 no resonance  .

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 12

50. A
Sol.
H
H H

B B

H H
H
Maximum 4 – H atoms lie in a plane.
Maximum 6 – atoms (4H + 2B) lie in a plane.
Bridge (B – H) is stronger than terminal (B – H)
Terminal (H – B – H) bond angle > Bridge (H – B – H) bond angle.

SECTION – B

51. 12
Sol. Ag2 CO3  s   2Ag  aq  CO3  aq 
2
K SP   Ag  CO3 
2  8.2  10 12 
  Ag    
 7.5 / 5 

TG ~ @bohring_bot
2  82 
  Ag     10 12 
 15 
 6
  Ag   2.34  10 M

Now K SP  AgCl    Ag  Cl 

 0.0026 
K SP  2.34  106   
 35.5 
K SP  1.71  10 10
 x  1.71, y  10
 x  y  1.71  10  11.71  12

52. 20
1
Sol. KE  mv 2
2
1 
 d  KE   d  mv 2 
 2 
 d  KE   mv  dv  … (1)
h
Since, dv  dx 
4m
h
 dv  … (2)
4m  dx 
From (1) and (2)
h
d KE   mv.
4m.  dx 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 13 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

1 3  108  6.62  1034

 d  KE   
60 6.62
4  3.14   1012
3.14
1
 d  KE    1014  1.25  1016 J
80
 x  1.25, y  16
 xy  1.25  16  20

53. 7
Sol. The ionic equation involved is
MnO4  aq   SO2  g  H aq  Mn  aq   HSO 4  aq
The balanced equation is
2MnO4  aq   5SO2  g   2H2 O     H  aq  2Mn  aq   5HSO 4  aq
 Sum total of coefficient(s) = 2 + 5 = 7.

54. 310
Sol. k  AeEa /RT
Ea
logK  log A 
2.303RT
 0.693  98.6  1000
 
TG ~ @bohring_bot
13
 log    log 4  10 
 693  2.303  8.314  T
or
4  1013 98.6  1000
 log 3

10 2.303  8.314  T
 T  310.1 K  310K

55. 64
Sol. N2 O 4  g  2NO2  g 
0.28 1.1
2

KP 
P   1.1
NO2
2

 4.32
P  0.28
N2O 4

Now, volume is doubled, so pressure will become half and reaction proceeds in forward direction
N2 O 4  g  2NO2  g
 0.28   1.1 
  P   2P 
 2   2 
2
 0.55  2P 
 KP 
 0.14  P 
2
 0.55   2  0.55  2P 
 4.32 
0.14  P
0.3025  2.20P

0.14  P
(Ignoring P2 terms)
 P  0.046 atm
 PNO2  0.55  2  0.046  0.642

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 14

 64.2  102 atm

 x  64.2  64

56. 2
Sol. XeO2 F2  AB 4 L  sp3 d  Polar  
2
SnCl2  AB2 L  sp  Polar  
IF5  AB5 L  sp3 d2  Polar  
I3  AB2 L2  sp3  Polar  
XeO 4  AB4  sp3  Non  Polar ()
 3 3
 XeF7   AB7  sp d  Non  Polar ()
2
SO2  AB 2L  sp  Polar  
57. 4
Sol. 1. Correct as EN of side atom increases, EN of carbon increases.
2. Correct, Mg  3rd period
K  / S   4 th period and isoelectronic
Se   5th period

TG ~ @bohring_bot
3. Correct as moving down the group cationic size increases so lattice energy decreases
1
4. Correct as Hydration energy 
Size of cation
5. Incorrect as the bond energy order among halogens is
Cl2  Br2  F2  I2

58. 33
H O
Sol. Na2 O2  2H2 O 2
Ice cold
2NaOH H2 O2
P  Q 
Room
2Na2 O2  2H2 O 
temperature
 4NaOH O2 
P  R 
M1  M2 34  32
Hence,   33
2 2

59. 80
Sol. At half neutralization S  A
S
pH  pK a  log
A
 pH  pK a  pK a  5.0
Now, at equivalence point,
1
PH   pK W  pK a  log C 
2
1
9  14  5  log C 
2
 C  0.1 M
Let, V mL of NaOH is used

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 15 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

0.25  V
Meq. NaOH   0.1 = Meq. (salt)
60  V
 Volume (V) = 40 mL
Meq. of acid = millimoles of acid = 0.25 × 40 = 10
Mass of acid (HX) = 10  103  82 = 0.829
0.82
Mass%   100  80%
1.025

60. 1
Sol. H 
  total  25  0.1  50  0.2  12.5 milim oles
OH 
  total  25  0.1  2.5 mi lim oles
12.5  2.5
 H  
final 25  50  25
10 1
H 
  final  100 M  10 M
 pH   log H 
final

 1
pH   log    1.00
 10 

TG ~ @bohring_bot

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 16

Mathematics PART – C

SECTION – A

61. C
Sol. f'(x) + f(x) = 12x 2 + 2

62. B
Sol. Use expansion and collect the coefficient of x 2
 P = 330

63. A
x3
Sol. For A x  sin x  x and for B use limit as a sum
6
1 2
A= ,B=
2 

64. D
1
Sol. f'(x) =
2 2
 sin2x  2  x  a    0  x  (0, 1) and a  (2, 3)
 2
sin x   x  a  
65.

Sol.
C

AB=
TG ~ @bohring_bot
1

 f  x  dx 
f (1)

 f 1  x  dx  0 , and also A = B.
0 f (0)

66. D
Sol. Domain is R.

67. D
 /4
1 1 
Sol. A   tan x  sin x  dx   2 ln2  2
 1

0

68. A
2 2
Sol. I1   2, I2   2, I3  1
2 2

69. D
e

 ln x  ln x   dx  3  e
2 2
Sol. f'(x) = (lnx) , g'(x) = (lnx), so area =
1

70. D

Sol. L1 = L2 =
2

71. B

Sol. Tn 
 n  1 x  3   nx  3   1  1
 n  1 x  3  nx  3  nx  3 n  1 x  3
S12 = V1  V2 + V2  V3 + ……. V12  V13 = V1  V13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 17 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

1 1
= 
x  3 13x  3
1 1 3
lim  
x 1 4 16 16

72. A
5 r 5h
Sol. tan =  r
12 h 12
dv
= 0.1 m3/min
dt
1 25h3 h
v = r 2h  l
3 432
2
dv 25h dh 25 dh 
   0.1   33
dt 144 dt 144 dt
16 dh
 
250 dt
65h2
Now s = rl = r h2  r 2 
144
ds 65 dh 65 16 13 2
  2h   23  m /min
dt 144 dt 144 250 75

73.
Sol.
A
TG ~ @bohring_bot
x2  4 = 2x + 11
x = 3, 5  A(3, 5)
y = 2x + 11

2x + 11 = 9
x = 1  B(1, 9)
1  B C y=9
C  ,9  and D(2, 0)
2 
A
D

y = 12  6x
1 1/2 2

  2x  11   x     12  6x   x 
2
Required area  4 dx   9  x 2  4 dx  2
 4 dx
3 1 1/2
1 1/2 2

  2x  x   13  x dx   16  6x  x  dx
2 2 2
=  15 dx 
3 1 1/2
1 3 1/2 2
x3 x x3
= x2   15x  13x   16x  3x  2
3 3
3 1
3 1/2

40 153 81 511
=   
3 8 8 12

74. B
2
e t t5 e
Sol. ft   2
 f  1 
25
t 4
 2t 2  2 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 18

dv 1 ev v 2
Let x2 = v   2x   2
dv
dx 2 v 2  2v  2
 
 
1 v 1 2v  2  1 ev
 e 
2   v 2  2v  2 v 2  2v  2 2  2
2 v  2v  2
   

2
1 ex

2 x 4  2x 2  2
2 t 2
1 ex  et 1 1
 f t    4  
2 x  2x 2  2
4  t  2t  2 2  2
2
0  
e 1
 f 1  
10 4
e e 1 7e 1
 f(1) + f(1) =    
10 25 4 50 4

75. B
k  2  x3   3  n  x 2   m  3  x   2  p 
Sol. lim
x 
x 4  kx 3  3x 2  mx  2  x 4  2x 3  nx 2  3x  p

TG ~ @bohring_bot
k – 2 has to be 0 else limit wont be finite
 k=2
Now dividing Num. & Den by x2
m  3  2  b
3  n  
lim x x2
x  a 3 b 2 2 c 3 d
1  2  3  4  1  2  3  4
x x x x x x x x
3n 3n
   4  n = 5.
2 2

76. A
2
dt 1 t sin2022 t dt
Sol. Let x 2  t   2x  I   cos2022 t  sin2022 t
dx 2 0
2 2022 2
1  2  t  sin t  sin2022 t
 I  cos2022 t  sin2022 t  2I  
2 0 0 cos2022 t  sin2022 t

2
 sin2022 t
 2I  4  2022
0 cos t  sin2022 t

2
 cos2022 t
 2I  4  2022
0 cos t  sin2022 t

2
2
 4I  4   dt  I  .
0
2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 19 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

77. A
dy  x  2    y  2 
Sol. 
dx  x  2    y  2 
put x  2 = h, y  2 = k
dk h  k
 put k = vh
dh h  k
dv 1  v
 v h 
dh 1  v
1 v dh 1
 
1 v 2
dv  
h
 tan1 v  ln 1  v 2  lnh  c
2
 
2
 y  2  1   y  2  
 tan1    ln 1  2
 ln  x  2   c
 x  2  2   x  2  
 it passes through (3, 2)
1
 tan10 = ln1 + ln1 + c  c = 0
2
 it also passes through (p + 2, 3)
 1 1  1 
tan1    ln  1  2   lnp
p 2  p 

TG ~ @bohring_bot
 1
 2 tan1    ln 1  p2
p
 
78. B
2 0 1 2
2
Sol. A   x  6   x dx   xdx   x 2 dx
4 2 0 1
8 2 7 35
= 6   
3 3 3 3

4 2 1

79. C
e4
Sol.     log
f e 4
1 x
x
dx 10
…(1)
1
1 dx 1
Let x =  
v dv v 2
1/t 1/t
log10 (1/ v) 1 log10 v
 f(t) =   2 dv   dv
1 v v(v  1)
1 1 1
v
4 4
1/t e e
log10 v log10 v log10 x
 f t    v  v  1
 f e 4   
v  v  1
dv  
x  x  1
dx …(2)
1 1 1
Add (1) and (2)
e4
4 1 4 ln x  1
f(e ) + f(e ) =  (1  x)  1  x  dx
ln10 1

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 20

e4
e4 2
1 ln x 1  ln x 
=  
ln10 1
x ln10 2
1

1 8
= 16 
2ln10 ln10

80. C
Sol. Let g(x) = x3  2x2 + 3x  9
2
g'(x) = 3x  4x + 3 > 0  x  R
 g(x) is always increasing
 g(2) = 8  8 + 6  9 = 3 is maximum value for x  2
If 3x + log3(k2  5)  3 for x > 2
then we have maximum at x = 2
2 3 2
 6 + log3(k  5)  3  log (k  5)  3

 k2  5  27  k  4 2 k  4 2  0  
2
k  4 2,4 2  and k  5 > 0


 k  ,  5    5,  
 k   4 2,  5    5, 4 2 

81. 1 TG ~ @bohring_bot
 x2  x  2 
SECTION – B

Sol.  2  1
 x  x  1

82. 1
3 2
Sol. A= 
8 4

83. 4
Sol. Df = [2, 2] as f  x   3  4  x2 
Rf =  0,2 3 

84. 2
Sol. f(x) = cos(x2  3x) |x  2| sin|x  2| + (x  1) |x| |x  1| |x  7|
 f(x) non differentiable at x = 0 and 7 only.

85. 12
Sol. a = 1, b = 6, c = 5

86. 96
Sol. Put x = 0 we get y = 1
ln(x + y) = 6xy
Differentiate w.r.t. x
1  dy   xdy 
1    6  y
x  y  dx   dx 

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 21 AITS-PT-I-PCM(Sol.)-JEE(Main)/2023

dy
at x = 0, y = 1  5
dx
dy  dy 
 1  6 x  y  x  y
dx  dx 
Differentiate w.r.t. x both side
d2 y   xd2 y dy dy   xdy  dy  
  6  (x  y)      y  1  
dx 2 
  dx
2
dx dx   dx  dx  
= 6(1(0 + 5 + 5) + 1(6)) = 96

87. 9
 x 3 
Sol.
x 0

 lim 3  2cos x cos 2x
 2 

 x  is of the form 1
 2  2 cos x cos 2x 
lim 
x  0 x2  x  3 
 
 it is equal to e
2  2cos x cos 2x
Now, lim
x 0 x2
2cos x
  sin2x  2  cos 2x   sin x 
= lim 2 cos 2x
x 0 2x
2cos x sin 2x

TG ~ @bohring_bot
 2 sin x cos 2x
= lim cos 2x
x 0 2x
=2+1=3
 2  2 cos x cos 2x 
lim 
x  0 x2  x  3 
 
 e
= e33  e9  a = 9

88. 14
dy  dy 
Sol. = 3x2  4x + 4    = 3a2  4a + 4
dx  dx (a,b)
dy  dy 
= 6x + 2    =8
dx  dx (1,4)
2
 3a2  4a + 4 = 8  a = 2, 
3
 b = 8  8 + 8 + 4 = 12

89. 144
12x15  5x18 12x 9  5x 6
Sol.  dx  
5 3 3

x 24 7  3x 8  2x   7  3x 8
 2x 5 
dt
Let 7 + 3x8 + 2x5 = t  = 24x9  10x6
dx
1 1 1 t 2 1
=  dt   c  c
2  t3 2 2 2

4 7  3x 8  2x 5 
1 1 1
 f 1    c  c = 0
16 16 4  7  3  2 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-PT-I-PCM(Sol.)-JEE(Main)/2023
Yash Patil 22

1 1 1
 f(x) =  f(1) = 2

5 2 4  6  144

4 7  3x 8  2x 
90. 23
n
e 
23

Sol. In =  x  lo g x  dx
   
1 II  I 
e e n 1
x 24  ln x  x24
n
 In = (lnx) 24   x 24 dx
n
1 1

e24 nIn1
 In    24In = e24  nIn1
24 24
24
Put n = 15 24I15 = e  15I14 …(1)
Put n = 14 24I14 = e24  14I13 …(2)
24I15  24I14 = 14I13  15I14
24I15 = 9I14 + 14I13

TG ~ @bohring_bot

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
FIITJEE
ALL INDIA TEST SERIES
JEE (Advanced)-2023
PART TEST – I
PAPER –1
TEST DATE: 20-11-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-B.
Section – A (01 –06, 19 – 24, 37 – 42): This section contains EIGHTEEN (18) questions. Each question has

TG ~ @bohring_bot
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 – 10, 25 – 28, 43 – 46): This section contains TWELVE (12) Matching List Type Questions.
Each question has FOUR statements in List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II
entries (P), (Q), (R), (S) and (T). The codes for lists have choices (A), (B), (C), (D) out of which, ONLY ONE of
these four options is correct answer.
Section – B (11 – 18, 29 – 36, 47 – 54): This section contains TWENTY FOUR (24) numerical based
questions. The answer to each question is a NUMERICAL VALUE. If the numerical value has more than
two decimal places, truncate/round-off the value to TWO decimal places.

MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 2

Physics PART – I

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).

1. Four dancers start their dance by forming a square with side

v
 = 9m. After that, they always move anticlockwise towards their
neighbour with variable velocity v  k x where k = 0.1 m 1/2sec1 v
and x is the distance of the closest neighbour in meter. Then
choose the correct option(s).
v

(A) All the dancers will meet with each other at t = 60 sec after they start their dance.
(B) Angular velocity of the line joining the adjacent dancers increases with time.
(C) All the dancers will meet with each other at t = 63 sec after they start their dance.
(D) Magnitude of acceleration of each dancer is remains constant with time.
2. A point object of mass m = 2kg is connected to a cylinder of radius R = 1m v0

TG ~ @bohring_bot
via a massless inextensible rope. At time t = 0 the object is moving with an
initial velocity v0 = 5 m/s perpendicular to the rope as shown in the figure.
The rope has initial length L0 = 10 m and having non zero tension. Figure
shows the top view and the motion of the object is taking place on the
horizontal smooth surface and the cylinder is always fixed. The point
object moves such that the rope wraps up around the cylinder. The rope
will break when the tension in the rope exceeds 100 N. Then choose the
correct option(s).
(A) Kinetic energy of the object at the instant when the rope breaks is 25 J.
(B) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is less than 5 kg-m2/sec.
(C) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is equal to 5 kg-m2/sec.
(D) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is greater than to 5 kg-m2/sec.
3. Two discs are mounted on thin, lightweight rods oriented
through their centres and normal to the discs. These axles are
constrained to be vertical at all times, and the discs can pivot
frictionlessly on the rods. The discs have identical thickness
and are made up of the same material, but having different
radii r1 and r2. The discs are given angular velocities 1 and 2,
respectively, and L1 and L2 represents angular momentum of
the discs along their rotational axis respectively. Now they are r1 r2
brought into contact at the edges. After the discs interact via
friction it is found that both discs come exactly to a halt. Which
of the following(s) must hold? Ignore effects associated with
the vertical rods.
(A) 1r14  2r24 (B) 1r13  2r23
L1 r1 L1 1r12
(C)  (D) 
L 2 r2 L 2 2r22

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 3 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023

4. A dumbbell is formed by connecting two identical particles A J A

m m
each of mass m with a massless rod. The system is placed on
a horizontal smooth surface and impulse J is applied in two J C C
ways as shown in the figure as situation-(i) and situation-(ii).
Then just after the application of impulse, choose the correct
option(s). m m
B B
Situation-(i) Situation-(ii)
(A) Velocity of centre of mass with respect to ground frame in situation-(i) and situation-(ii) are
same.
(B) Kinetic energy of the dumbbell with respect to centre of mass frame in situation-(i) and
situation-(ii) are same.
(C) Angular momentum of the dumbbell with respect to centre of mass frame in situation-(i) and
situation-(ii) are different.
(D) Velocity of particle A in situation-(ii) is double of velocity of particle A in situation-(i) just after
the application of impulse.

5. Three particles A, B and C are simultaneously thrown from a cliff

and their trajectories are shown in the given figure. Neglect air
resistance and take gravity to be uniform during the motion. If
uyA , uBy and uCy denotes the initial vertical components of velocity
of particles A, B and C respectively and the times tA, tB and tC, they B
take to hit the ground respectively. Then A

TG ~ @bohring_bot
C
(A) uBy  uCy  uyA (B) uBy  uyA  uCy
(C) t A  t C  tB (D) t C  t A  tB

6. A thin rod has an unknown non-uniform density. It is mounted CM

on an axle passing perpendicular to it, through its centre of
mass as shown and is then rotated about the axle. The axle
divides the rod into two parts, one on each side of it. Which of 
the following must be true, no matter how the mass in the rod is
distributed?
(A) The two part must have the same mass.
(B) The magnitudes of the linear momentum of the two parts must be equal.
(C) The magnitudes of the angular momentum of the two parts about the centre of mass must be
equal.
(D) The kinetic energies of two parts must be equal.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 4

Section – A (Maximum Marks: 12)

This section contains FOUR (04) Matching List Type Questions. Each question has FOUR statements in
List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II entries (P), (Q), (R), (S) and (T). The
codes for lists have choices (A), (B), (C), (D) out of which ONLY ONE of these four options is correct
answer.

7. List –I describes for systems and List-II gives possible value of work done in Joules.
List –I List -II
(I) A plank of mass 100 kg is placed on a smooth horizontal (P) +100J
surface at rest along with a man. Now man starts moving on
the plank with relative velocity of 3 m/s with respect to plank.
The work done by man is
50 kg
urel = 3 m/s

100 kg

(II) A block of mass 2 kg is placed on a smooth track and imparted (Q) 100J
a velocity of 10 m/s to the left and observed by an observer
moving with 5 m/s as shown in the figure. Work done by the
normal force applied by the track on the block upto the instant
when the block reaches the highest point on the track in the

TG ~ @bohring_bot
frame of observer. Assume that block never loose contact with
the track. (take g = 10 m/s2)

10 m/s w.r.t 5 m/s w.r.t

ground ground
2 kg

(III) A particle of mass 1 kg is projected from an unstable (R) +150J

equilibrium point N towards a stable equilibrium point S with
negligible velocity in a conservative force field having potential
energy function
 1  2 2
U   J / m 4   x  10   x  30  , where x is in meters.
 100 
Then work done by conservative force during the displacement
from N to S is
(IV) A solid hemisphere of mass 4 kg and radius 10 m is slowly (S) 150J
turned as shown in the figure. Then work done by external
force in turning is (Take g = 10 m/s2)

(T) Zero
Which one of the following options is correct ?
(A) I  R, II  T, III  P, IV  P
(B) I  S, II  T, III  Q, IV  P
(C) I  R, II  Q, III  P, IV  P
(D) I  T, II  Q, III  Q, IV  P

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 5 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023

8. A disc placed on a frictionless horizontal plank is rotating with a

 y
constant angualr velocity  about its vertical axis. Now the plank is

made to move with a constant acceleration a on a straight path.
Initially the centre of the disc is at the origin of xyz space which is
fixed with the plank and xy plane is on the plank. List-I gives some x
 
possible a ,  and List-II gives trajectories of instantaneous centre
of rotation of the disc.

List –I List -II

 
a  2ˆj m/s ,   4kˆ rad/s
(I) 2 (P) y=4
 2 
(II) a  2ˆj m/s ,   4kˆ rad/s (Q) y = 4x2 (x  0)
 
(III) a  2iˆ m/s2,   4kˆ rad/s (R) y = 4x2 (x  0)
 
(IV) a  2iˆ m/s2,   4kˆ rad/s (S) x = 4y2 (y  0)
(T) x = 4y2 (y  0)
Which one of the following options is correct ?
(A) I  P, II  Q, III  T, IV  S
(B) I  Q, II  R, III  S, IV  T
(C) I  Q, II  S, III  T, IV  R
(D) I  R, II  Q, III  S, IV  T

TG ~ @bohring_bot
9. Figure shows a system of multiple blocks  = 0.1 D
placed over each other and connected  = 0.4 1kg A
 = 0.2 1kg B 3kg
through an inextensible string. All the 1kg  = 0.5
C
pulleys are ideal and frictionless. List-I S1 S2
shows the surfaces between which the
friction is asked and List-II gives the value
of friction acting between the surfaces.
(Take g = 10 m/s2)
E 2kg

List –I List –II

(I) Between A and B (P) 15 N
(II) Between B and C (Q) 9.4 N
(III) Between C and S1 (R) 7.2 N
(IV) Between D and S2 (S) 6N
(T) 1N
Which one of the following options is correct ?
(A) I  T, II  R, III  S, IV  Q
(B) I  T, II  R, III  S, IV  P
(C) I  T, II  S, III  R, IV  Q
(D) I  T, II  Q, III  R, IV  P

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 6

10. A disc of mass m is placed over a horizontal smooth surface (xy plane) z
such that the centre of the disc is at the origin of the xyz space, as y
shown in the figure. Radius of the disc is R = 1m and is rotating with an

angular velocity 0  6kˆ rad/s and having zero velocity of centre of 0

mass. A particle of same mass m hits the disc with a speed v = 8 m/s x

in each case of list-I. List-I gives the trajectory and velocity direction of
the particle before hitting the disc and the coefficient of restitutions (e)
of the collision. List-II gives the angular velocity of the disc just after the
collision (in rad/s)
List –I List -II
(I) x = 0, y = R and v̂  kˆ , e = 0 (P) 3
(II) x 3 ˆ 1ˆ (Q) 5
y , z = 0 and v̂  i j, e = 1
3 2 2
(III) y = R, z = 0 and v̂  ˆi , e = 0 (R) 6
(IV) R (S) 7
y  , z = 0 and v̂  ˆi , e = 0
2
(T) 8
Which one of the following options is correct ?
(A) I  P, II  Q, III  R, IV  T

TG ~ @bohring_bot
(B) I  S, II  Q, III  P, IV  R
(C) I  P, II  R, III  S, IV  Q
(D) I  S, II  P, III  Q, IV  T

Section – B (Maximum Marks: 24)

This section contains EIGHT (08) numerical based questions. The answer to each question is a
NUMERICAL VALUE. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.

11. Two massless rods are attached to F 0.5m 2m

frictionless pivots, with their ends
touching. The distances between
the pivot points and the endpoints
of the rods are shown in the figure.
2m 1m F1
Neglect friction force between the
rods, if a force F = 9N is applied at
the left end of the left rod, what
force F1 (in newton) must be
applied at the right end of the right
rod to keep the system in
equilibrium.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 7 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023

12. A small sphere slides with a speed v = 60 m/s on

a frictionless horizontal surface between two
parallel massive walls. One of which is fixed and
the other can be moved. Initial distance between
walls is L. The sphere bounces between the walls
perfectly elastically. Now the right wall is moved
towards the left walls by a distance 0.01 L with
speed 0.0001v. Then what is the final speed of v
the sphere after the said movement of the wall in Movable
m/s. Fixed wall L
wall

13. Figure shows a laptop made of two identical uniform plates,

each of mass m = 1 kg connected by a hinge and placed on a
rough horizontal surface as shown. The hinge is locked when
the screen makes an angle of 120 from the keypad of the
laptop. Assume that the laptop does not slide on the horizontal 120
surface, then what is the minimum force (in newton) that can
be applied on the top of the laptop, in the plane of the page to
cause the bottom of the laptop to lift off the ground? (Take g =
10 m/s2)

14. A block of mass m = 1 kg is dropped vertically onto a fixed ramp from a height of h = 2.5 m with
angle  = 37 with horizontal and having coefficient of static friction and kinetic friction = 0.5. The

TG ~ @bohring_bot
block is dropped in such a way that it does not rotate after colliding with the ramp. Through this
problem assume that the time of the collision is negligible. The block slides down the ramp
immediately after impact. What it the speed (in m/s) of the block right after the collision? (Take g
= 10 m/s2)

15. One end of the non stretchable rope is uA

tied to a fixed knob O, while other end
B of the rope is moving horizontally
with a constant velocity uB = 1 m/s.  B uB
A
That rope goes through a small ring A,
which can move freely along a
horizontal straight rod as shown in the
figure. Determine velocity uA of the ring
(in m/s), when inclined section of the
rope makes an angle  = 30 with the O
rod.

16. Two small bodies with masses m and 2m are attached to a spring of 2m
v0
negligible mass. Initially the compressed spring form a straight vertical
line, when both objects are launched with same velocities v 0 = 1 m/s in k
2h
the horizontal direction as shown in the figure. Initial height of the lower
g
body is h = 1 m from the ground, while distance of heavier body is 2h = m
2m. After t = 0.1 sec from the launch, lower body hits the ground. v0
Determine height H (in m) of the upper body from the ground at that h
moment of time. (assume no air drag and g = 10 m/s2)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 8

17. A right triangular wooden block of mass M = 4 kg is at rest on a m m

smooth table as shown in the figure. Two smaller wooden cubes M
both of mass m = 2 kg, initially at rest on the two sides of the 37 53
larger block start sliding down. What is the normal force (in
2
newton) applied by the system on the table? (take g = 9.8 m/s )

18. The ‘wall of death’ ride consists of a drum with d

diameter d = 10m which rotates at an angular velocity  d
 as shown in the figure-(a). Passengers stand

against the inside vertical rough wall and as the ride
speeds up to angular velocity , they are held against
the wall and can not slide down due to friction with
the wall. The rotating drum is now tilted so that its  = 37
axis of rotation is  = 37 above the horizontal as
Figure-(a) Figure-(b)
shown in the figure-(b). If the coefficient of friction
between the wall and the passenger is  = 0.5, then
find the minimum angular velocity 0 (in rad/s) of the
drum so that passengers are held against the wall at
the highest point. (Take g = 10 m/s2)

TG ~ @bohring_bot

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 9 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023

Chemistry PART – II

Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).

19. Which of the following species are polar as well as non-planar?

(A) XeF4
(B) H2 O2
(C) XeF 5
(D) XeF5

20. All bonds are equivalent in

(A) Cr2 O72 
(B) HCO3
(C) XeO46 
(D) SF6

TG ~ @bohring_bot
1  6r r 2  r /3ao
21. The radial part R  r    o  2  e represent for an orbital. (ao is Bohr’s radius of H-
9 a3/2
o a ao 
atom)
Choose the correct statement about the orbital
(A) this orbital may have one nodal plane in yz plane
(B) it is 3p orbital
(C) one node will be found at the r  6ao distance from nucleus
(D) this orbital can accommodate maximum 6 electrons

22. Which of the following geometry is most likely form from sp3 d  hybridisation ?
(A) Linear
(B) Tetrahedral
(C) Bent T-shaped
(D) See-Saw

23. Find the incorrect statement

(A) Iodine exists as I82 ion in Cs2I8
(B) Oxidation state of Cr in CrO5 and CrO83  is +6
(C) FeCl2 is more ionic than FeCl3
(D) LiO2 and NaO2 are yellow coloured compound but KO2 is colourless

24. Consider the following options and choose the correct one
(A) In the given equilibrium 2SO2  O2  2SO3
If O2 is added and the volume of the reaction vessel is reduced the equilibrium is shift in
product side.
(B) If we add CrO24 ion in saturated solution of Ag2 CrO 4 it will decreases  Ag  .

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil
AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 10

(C) Three sparingly soluble salt A 2B, AB and AB3 are given. If all the three having same value of
solubility product (KSP). In the saturated solution the correct order of their solubilities is
AB  A 2 B  AB3 .
(D) If in option (A) inert gas is added at constant pressure and temperature. Partial pressure of
SO3 will be remain same.

Section – A (Maximum Marks: 12)

This section contains FOUR (04) Matching List Type Questions. Each question has FOUR statements in
List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II entries (P), (Q), (R), (S) and (T). The
codes for lists have choices (A), (B), (C), (D) out of which ONLY ONE of these four options is correct
answer.

25. If tx represents time required for a fraction x of a reactant to be reacted during a reaction involving
only one reactant. Then match List – I with List – II.
List – I List – II
(I) Zero order reaction (P) t 3/4
3
t1/2
(II) First order reaction (Q) t1/4
2
t1/8
(III) Second order reaction (R) t 7/8 3

t 3/ 4 2

TG ~ @bohring_bot
(IV) Order of reaction  1 (S)   1  ekt
 
(T) t100%
2
t 50%
(   degree of dissociation, k  rate constant)
(A) I→Q, T; II→R, S; III→P; IV→P, R, S
(B) I→Q; II→R, T; III→P; IV→P, R
(C) I→ T; II→P; III→R, S; IV→Q, T
(D) I→R, T; II→Q; III→ P; IV→P, Q

26. List – I contains properties and List – II contains moles or ions

List – I List – II
(I) 2 lone pair on central atom (P) XeF
5
(II) Zero dipole moment (Q) NF3
(III) Planar (R) ICl3
(IV) All adjacent bond angle are equal (S) XeF4
(T) PCl3F2
(A) I→P, R, S; II→S, T; III→P, Q,R, S; IV→P, Q, R, S, T
(B) I→P, R, S; II→P, S, T; III→P, R, S; IV→P, Q,R, S
(C) I→P, R, T; II→R, S, T; III→R, S; IV→S, T
(D) I→P,S, T; II→P, R, S; III→P, Q,R, S, T; IV→P, R, S

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
 Yash Patil 11 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023

27. List – I contains compounds with bond parameter and List – II contains bond parameter
decreasing order (x1, x2, x3 are bond length while , ,  are bond angle)
List – I List – II
(I) OH NH2 (P) x1  x 3  x 2
F

B B B
x1 x2 x3
  
F F F F F F
(II) (Q) 

N
N N

 F
  Cl F F
H Cl Cl
H H
(III) (R) 

O O O
x1 x2 x3


TG ~ @bohring_bot
 
H H F F Cl Cl
(IV) S8 S2 F2 S2 Cl2 (S) x 3  x 2  x1
 S  S bond length  x1 x2 x3
(T) 
(A) I→S,T; II→R; III→Q,S; IV→S
(B) I→R, S; II→Q; III→S, T; IV→P
(C) I→R,S; II→R; III→Q, S; IV→P
(D) I→R,S; II→T; III→S,T; IV→S

28. List – I contains elements and compounds in respective properties and List – II contains
decreasing order of properties.
List – I List – II
(I) B Al Ga In (P) 4 > 3 > 2 > 1
1 2 3 4  Atomic size 
(II) NaOH KOH RbOH CsOH (Q) 4>2>3>1
1 2 3 4  Thermal stability 
(III) SiO2 CO2 CaO Cs2 O (R) 1>2>3>4
1 2 3 4 Basic strength 
(IV) BeF2 BaF2 CaF2 MgF2 (S) 4>3>1>2
1 2 3 4  Water so lub ility 
(T) 2>3>4>1
(A) I→Q; II→S; III→P; IV→T
(B) I→Q; II→P; III→S; IV→T
(C) I→P; II→Q; III→S; IV→R
(D) I→Q; II→P; III→S; IV→R

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com