GAMAZYME TDS

Revision

SAFETY DATA SHEET

1 Identification of the substance or preparation and of the company/undertaking
Product Name: GAMAZYME TDS
Datasheet Number: 712042 3. 0. 0
Use of the substance/preparation: Cleaning agent
Product Part Number: 712042 (100 x 50 gram)
Recommended / Intended use: : Cleaning agent
Name of Supplier: Wilhelmsen Maritime Services AS
Address of Supplier: Willem Barentszstraat 50
3165 AB Rotterdam-Albrandswaard, The Netherlands

Telephone: +31 10 4877 777

Fax: +31 10 4877 888
Responsible Person: Leen de Visser, Product HSE Manager, Tel.: +31 6 538 63736
Name of Manufacturer: UNITOR CHEMICALS AS
Address of Manufacturer: P.O.Box 15
3141 Kjøpmannskjær
Norway.
Telephone: +47 333 515 00
Emergency Telephone: NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
American Chemistry Council +1 703 527 3887, Greece +30 210 7793777
2 Composition/information on ingredients
Chemical Name Concentration CAS Number EC Number R Phrases Symbols
Citric acid <60 77-92-9 201-069-1 36 Xi
Sulphamic acid <25 5329-14-6 226-218-8 36/38, 52/53 -
Viable bacterial cultures 10-30 N/A N/A - -

3 Hazards identification
- Odour: Odourless
- Appearance: powder, grey, dispersible in water
- Contact with eyes: Causes irritation
- Contact with skin: May cause irritation
- Inhalation: Mildly irritating to respiratory system, May cause breathing difficulty
- Ingestion: Not regarded as a potential route of exposure.

Irritant

4 First aid measures

Contact with skin
- Wash affected area with plenty of soap and water
- Seek medical attention if irritation persists
Contact with eyes
- If substance has got into eyes, immediately wash out with plenty of water for at least 15 minutes
- Irrigate eyes thoroughly whilst lifting eyelids
- Obtain immediate medical attention
Ingestion
- Do not induce vomiting
- Never give anything by mouth to an unconscious person
- Give 200-300mls (half pint) water to drink
- Obtain immediate medical attention
Inhalation
- Inhalation is unlikely to occur
- Remove patient to fresh air
- Seek medical advice if necessary

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4 First aid measures (....)
General
- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) (S45)
5 Fire-fighting measures
- Smoke from fires is corrosive
- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
- Substance evolves toxic fumes, wear self-contained breathing apparatus
6 Accidental release measures
Personal Precautions
- Wear protective clothing as per section 8
Environmental Precautions
- No special precautions are required for this product
Clean Up Actions
- Sweep or shovel-up spillage and remove to a safe place
- Flush spill area with copious amounts of water
Special Precautions
- Avoid release to the environment. Refer to special instructions/Safety data sheets (S61)
- Wear protective clothing as per section 8
7 Handling and storage
Handling
- Wear protective clothing as per section 8
- Avoid contact with skin and eyes (S24/25)
- Eyewash bottles should be available
Storage
- Keep in a cool, dry, well ventilated place
- Recommended storage temperature between 0 and 45 °C
8 Exposure controls and personal protection
Exposure Limits
- No exposure limits have been set for this substance
Exposure controls
- No special precautions are required for this product
Occupational exposure controls
- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are recommended)
- Respiratory protection may be required under exceptional circumstances when excessive air
contamination exists

Gloves Goggles No Smoking

9 Physical and chemical properties

- Odour: Odourless
- Appearance: powder, grey, dispersible in water
- pH ~1.5 at 1 % concentration
- Boiling point - not applicable
- Vapour pressure - not applicable
- Vapour density - not applicable
- Water solubility ~100 g/l
- Density 1300 - 1500 kg/m3
10 Stability and reactivity
- This article is considered stable under normal conditions
- Avoid overheating
- Incompatible with strong oxidizing substances, Incompatible with alkalis (strong bases)
11 Toxicological information
Toxicological information
- No experimental data available

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11 Toxicological information (....)
Inhalation
- Inhalation is unlikely to occur
- May cause breathing difficulty
Contact with skin
- In cases of severe exposure, redness and irritation may develop
Contact with eyes
- May cause pain
Ingestion
- No effects for small dosage. Large dose effects not known
- May cause gastro-intestinal disturbances
Carcinogenicity
- No evidence of carcinogenic effects
12 Ecological information
Ecotoxicity
- This product contains components which are classified in the EU as dangerous for the environment.
Mobility
- Completely soluble in water
Persistence and Biodegradability
- Its main ingredients will either dissolve rapidly and dissociate in water or are readily/inherently biodegradable.
- If this substance is discharged at low concentrations into an adapted biological effluent treatment plant,
the degrading action of the activated sludge will not be affected
Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
Other Adverse Effects
- No environmental problems are expected when the product is used / handled correctly.
In its intended use, the product will not be released into the environment.
13 Disposal considerations
Classification
- EU Waste class: 06.01
Disposal considerations
- Disposal should be in accordance with local, state or national legislation
14 Transport information
- Not classified as hazardous for transport
15 Regulatory information

Irritant

Risk Phrases
- Irritating to eyes and skin (R36/38)
Safety Phrases
- Avoid contact with skin (S24)
- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice (S26)
- Wear suitable gloves (S37)
16 Other information
(R36: Irritating to eyes. R36/38: Irritating to eyes and skin. R52/53: Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.)

The information provided about the product on this Safety Data Sheet has been compiled from knowledge of
the individual constituents
The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product
in terms of safety requirements and does not signify any warranty with regard to the product's properties
The data given here only applies when product used for proper application(s). The product is not sold as suitable
for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other
application(s) without seeking advice from manufacturer
This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive (67/548/EEC)
This Safety Data Sheet is provided in compliance with The Dangerous Preparations Directive (88/379/EEC)
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GAMAZYME TDS
Revision
16 Other information (....)
This Safety Data Sheet is provided in compliance with The Safety Data Sheets Directive (2001/58EC)

Date of Last Change 12/20/2006 4