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Class 11 - Chemistry-Organic Chemistry

This document is a model question paper for Grade 11 Chemistry, featuring multiple-choice questions, assertion-reason type questions, and structural formula drawing tasks. It covers various topics such as resonance structures, inductive effects, isomerism, IUPAC nomenclature, and hybridization. Additionally, it includes case study questions related to organic chemistry and the properties of carbon.

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29 views6 pages

Class 11 - Chemistry-Organic Chemistry

This document is a model question paper for Grade 11 Chemistry, featuring multiple-choice questions, assertion-reason type questions, and structural formula drawing tasks. It covers various topics such as resonance structures, inductive effects, isomerism, IUPAC nomenclature, and hybridization. Additionally, it includes case study questions related to organic chemistry and the properties of carbon.

Uploaded by

Di Square Gaming
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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GRADE 11

CHEMISTRY
MODEL QUESTION PAPER

1. Which of the following cannot be represented by resonance structures?


a. Dimethyl ether
b. Nitrate anion
c. Carboxylate anion
d. Nitrobenzene

2. Inductive effect involves


a. displacement of σ electrons
b. delocalization of π electrons
c. delocalization of σ-electrons
d. displacement of π-electrons

3. Which of the following behaves both as a nucleophile and as an electrophile?


a. CH3C ≡ N
b. CH3OH
c. CH2 = CHCH3
d. CH3NH2

4. The kind of delocalization involving sigma bond in conjugation with pi electrons is called -
a. Inductive effect
b. Hyperconjugation effect
c. Electrometric effect
d. Mesomeric effect

5. Which of the following can act as an electrophile?


a. CN–
b. H2O
c. BF3
d. OH–

6. The type of isomerism not found in alkenes is


a. Chain isomerism
b. Geometrical isomerism
c. Metamerism
d. Position isomerism

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7. The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system
of nomenclature is:
a. –COOH, –SO3H, –CONH2, –CHO
b. –SO3H, –COOH, –CONH2, –CHO
c. –CHO, –COOH, –SO3H, –CONH2
d. –CONH2, –CHO, –SO3H, –COOH

8. The correct bond line formula of propanoic acid is


a.

b.

c.

d.

2
9. Write the IUPAC name of the following compound.

a. 4-methyl-4-ethyloctane
b. 4-Ethyl-4-methyloctane
c. 4-Ethyl-4-n-butylpentane
d. 2-Ethyl-2-butylpentane

ASSERTION REASON TYPE


a. Assertion and reason are both correct statements and reason is correct explanation for assertion.
b. Assertion and reason are both correct statements but reason is not correct explanation for assertion.
c. Assertion is correct statement but reason is wrong statement.
d. Assertion is wrong statement but reason is correct statement.

10. Assertion: But-1-ene and 2-Methylprop-1-ene are position isomers.


Reason: Position isomers have same molecular formula but differ in the position of functional
groups.

11. Assertion: Tertiary carbocations are more stable than primary carbocations.
Reason: Hyperconjugation as well as inductive effect due to additional alkyl groups stabilize tertiary
carbocations.

12. Assertion: Carbocations are planar in nature.


Reason: Carbocations are sp2 hybridised.

13. Assertion: IUPAC name of compound CH3CH=CH–CHO is But-2-enal.


Reason: Functional group gets preference over multiple bond in IUPAC name of a compound.

14. Assertion: Energy of resonance hybrid is equal to the average of energies of all canonical
forms. Reason: Resonance hybrid cannot be presented by a single structure.

2 Marks

15. Draw the structural formulae of the following compounds:


a. Ethoxypropane
b. 3,4,4,5 -Tetramethylheptane
16. Write bond-line formulas for the following.

3
a. Isopropyl alcohol
b. 2,3-Dimethylbutanal
17. What is metamerism? Give example.
18. Draw the resonance structures of aniline.
19. A tertiary butyl carbocation is more stable than isobutyl carbocation. Justify.

3 Marks

20. Write resonance structures of CH2=CH–CHO. Indicate relative stability of the contributing structures.
21. Find the error and write the correct IUPAC names of
a.1,6-Hexadiene
b. 2-Ethyl-2-pentene
23. (a) Write IUPAC names of the products obtained by addition reactions of HBr to hex-1-ene
(i) in the absence of peroxide and
(ii) in the presence of peroxide.
(b) State Markovnikov’s Rule
24. How will you convert?
(a) Hexane to benzene
(b) Benzene to nitrobenzene
(c) Ethyne to benzene
(d) Phenol to benzene
(e) Benzene to toluene
(f) Benzene to acetophenone

5 Marks

25. a. Arrange the following in the order of property indicated against each set
i.
(CH3)3CCH2+, (CH3)3C+, CH3CH2CH+2, CH3CH+CH2CH3 (in the order of their increasing stabilities)
ii.
–COOH, –CONH2, –CHO, -SO3H (In the decreasing priority order if present in same molecule)
b. Draw the resonance structures for the following compounds. Show the electron shift using curved arrow
notation.
i.
C6H5NO2
ii.
C6H5OH
c. What are structural isomers?

26. Write short notes on


a. Electromeric effect
b. Inductive effect
c. Hyperconjugation
d. Homolytic fission
e. Heterolytic fission
.

CASE STUDY TYPE QUESTIONS


The element carbon has the unique property called catenation due to which it forms covalent bonds with other
carbon atoms. It also forms covalent bonds with atoms of other elements like hydrogen, oxygen, nitrogen,
4
sulphur, phosphorus and halogens. The resulting compounds are studied under a separate branch of chemistry
called organic chemistry
The tetravalence of carbon and the formation of covalent bonds by it are explained in terms of its electronic
configuration and the hybridisation of s and p orbitals. The formation and the shapes of molecules like methane
(CH4), ethene (C2H4), ethyne (C2H2) are explained in terms of the use of sp3, sp2 and sp hybrid orbitals by
carbon atoms in the respective molecules. Hybridisation influences the bond length and bond enthalpy
(strength) in compounds. The organic compounds are classified based on their structures.

1. Change in hybridisation affects the carbon’s


(a) bond strength
(b) electronegativity
(c) bond length
(d) bond enthalpy

2. The IUPAC name for the following compound is

(a) 2-Chloro-1-nitro-5-methylbenzene
(b) m-Nitro-p-chlorotoluene
(c) 1-Chloro-4-methyl-2-nitrobenzene
(d) 1-Chloro-2-nitro-4-methylbenzene

3. The compound below is an example of

(a) Aliphatic Cyclic Compound


(b) alicyclic compound
(c) closed chain compound
(d) aliphatic compound

4. is an example of heterocyclic aromatic compound.


(a) Tropolone
(b) Pyridine
(c) Tetrahydrofuran
(d) Benzene

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