Custom Practice Test - 20-Jan

Contact Number: 9667591930 / 8527521718

Chemistry-Section-A 7. The first and second dissociation constants of

an acid H2A are 1.0 × 10–5 & 5.0 × 10–10
1. Given that the ionic product of Ni (OH)2 is 2 respectively. The overall dissociation constant
× 10−15 . The solubility of Ni (OH)2 in 0.1 M of the acid will be :
NaOH is ; 1. 5.0 × 10–5 2. 5.0 × 1015
1. 2 × 10−8 M 3. 5.0 × 10–15 4. 0.2 × 105
2. 1 × 10 M
−13

3. 1 × 10 M
8
8. The pH of 10-6 M CH3COOH will be:

4. 2 × 10
−13
M (ka of CH3COOH = 1.8 × 10-5 & log 4.24 =0.63)
1. 5.37
2. If 0.01 M acetic acid solution is 1% ionised, 2. 7.0
then pH of this acetic acid solution is: 3. Slightly more than 6
1. 3 2. 2 4. 6.95
3. 4 4. 1
9. Which of the following solutions acts as a
buffer?
1. H Cl + N H4 Cl
3. Which of the following acts as a lewis acid?
2. CH3 COON H4 + H2 O
1. N H3
3. N aOH + CH3 COON a
2. SnCl4
4. H N O3 + N aN O3
3. CCl4
4. None of above
10. The following solutions were prepared by
mixing different volumes of NaOH and HCl of
4. Which of the following salts will give the
different concentrations :
highest pH in water? M M
1. KCl A) 60 mL 10 H CI + 40 mL 10 N aOH
2. NaCl B) 55 mL
M
H CI + 45 mL
M
N aOH
3. Na2CO3 M
10
M
10

C) 75 mL H CI + 25 mL N aOH
4. CuSO4 5 5
M M
D) 100 mL
10
H CI + 100 mL
10
N aOH

5. Which of these is least likely to act as Lewis pH of which one of them will be equal to 1?
base? 1. B
1. F – 2. A
2. BF3 3. D
3. PF3 4. C
4. CO
11. The percentage of pyridine (C5H5N) that
forms pyridinium ion (C5H5N+H) In A 0.10 M
aqueous pyridine solution (Kb for C5H5N = 1.7 ×
6. At 25°C, the solubility product of Mg(OH)2 is
10–9) is?
1.0 × 10-11. At which pH, will Mg2+ ions start
1. 0.0060%
precipitating in the form of Mg(OH)2 from a 2. 0.013%
solution of 0.001 M Mg2+ ions? 3. 0.77%
1. 8 4. 1.6%
2. 9
3. 10
4. 11

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 Custom Practice Test - 20-Jan
Contact Number: 9667591930 / 8527521718

12. The molar solubility of Cd(OH)2 is 1.84 × 10– 17. The concentration of Ag+ ions in a saturated
5 M in water. The expected solubility of Cd(OH) –4 –1
2 solution of Ag2C2O4 is 2.2 × 10 mol L .
in a buffer solution of pH = 12 is: The solubility product of Ag2C2O4 is:
1. 2.66×10–12 2. 4.5×10–11
−10
1. 2. 49 × 10 M

2. 1. 84 × 10 M
−9
3. 5.3×10–12 4. 2.42×10–8
−11
3. 6. 23 × 10 M

4. 1.49×10 M
−9

18. Match complexes given in column I with Ksp

13. The dissociation constant of acids HA, HB, values given in column II and mark the
HC, and HD are 1.3×10-13, 1.8×10-2, 6.23 ×10-7 , appropriate choice:
and 8.5×108 respectively. The weakest acid is: Column I Column II
1. HA (Complex) Ksp Values
2. HB
(A) F e(OH )3 (i) Ksp = s2
3. HC
4. HD (B) Ag2 CrO4 (ii) Ksp = 27s4
(C) CH3 COOAg (iii) Ksp = 108s
5

14. A certain reversible reaction comes to

equilibrium with high concentration of (D) Ca3 (P O4 )2 (iv) Ksp = 4s
3

products and low concentration of reactants. Of

the following, which is the most likely value of 1. (A) →(iii), (B)→(ii), (C) →(iv), (D)→ (i)
the equilibrium constant for this reaction? 2. (A) →(ii), (B)→(iv), (C) →(i), (D)→ (iii)
1. Keq = –1 × 10 2. Keq = 1 × 10
−5 −5 3. (A) →(i), (B)→(iii), (C) →(ii), (D)→ (iv)
4. (A) →(iv), (B)→(i), (C) →(iii), (D)→ (ii)
3. Keq = 1 4. Keq = 1 × 10
5

19. Aqueous solution of which of the following

salts is not a neutral solution?
15. If the concentration of OH- ions in the 1. N aCl
reaction Fe(OH)3(s) ⇌ Fe3+(aq) + 3OH-(aq) is 2. CH3 COON H4
3. N a2 SO4
reduced by a factor of 1/4, then the equilibrium
4. None of these
concentration of Fe3+ will increase by:
1. 8 times 20. The ratio of F- and HCOO- in a mixture of 0.1
2. 16 times
3. 64 times M HF (Ka = 6. 6 × 10−4 ) and 0.2 M HCOOH
4. 4 times (Ka = 2 × 10
−4
) is:

1. 2 : 2.3 2. 1 : 3.3
16. The concentrations of A, B and C that
represent the equilibrium concentration for the 3. 3.3 : 2 4. 3.3 : 1
−1
reaction A + 2B ⇌ 2Chaving Kc = 2M
are:
1. [A]= 1 M; [B]= 2 M; [C]= 2 M 21. The amount of water in litres that must be
2. [A]= 2 M; [B]= 2 M; [C]= 1 M added to 1 litre of an aqueous solution of HCl
3. [A]= 1 M; [B]= 2 M; [C]= 1 M with a pH of 1 to create an aqueous solution
4. [A]= 2 M; [B]= 1 M; [C]= 2 M with pH of 2, is:
1. 2.0 L
2. 9.0 L
3. 0.1 L
4. 0.9 L

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 Custom Practice Test - 20-Jan
Contact Number: 9667591930 / 8527521718

22. pH of Ba(OH )2 is 11. Then the solubility 26. A 20-litre container at 400 K contains
product of Ba(OH )2 is: CO2 (g) at pressure 0.4 atm and an excess of SrO
1. 10 M3
−6
(neglecting the volume of solid SrO). The
2. 5 × 10 M
−7 3 volume of the container is now decreased by
moving the movable piston fitted in the
M3
−10
3. 5 × 10
container.
M3
−10
4. 10 The maximum volume of the container, when
the pressure of CO2 attains its maximum value
23. Given the reaction: A + B ⇌ C + D. If,
will be:
initially, the concentration of A and B are equal
(Given that: SrCO3(s) ⇋ SrO(s) + CO2(g) , Kp =
and, at equilibrium, the concentration of D is
twice that of A, then what will be the 1.6 atm)
equilibrium constant of a reaction? 1. 10 litre 2. 2 litre
1. 4/9 3. 4 litre 4. 5 litre
2. 9/4
3. 1/9
4. 4 27. At room temperature, MY and NY3, two
nearly insoluble salts, have the same Ksp values
24.
of 6.2 × 10-13. The true statement regarding MY
When Cu (II) and sulphide ions and NY3 is:
are mixed, they react together
Assertion (A): The molar solubility of MY in water is less
extremely quickly to give a 1. than that of NY .
solid. 3
The equilibrium constant of The salts MY and NY3 are more soluble in 0.5
2+ 2-
2.
M KY than in pure water.
Reason (R): Cu (aq) + S (aq) ⇋ CuS(s)
is high because the solubility The addition of the salt of KY to a solution of
product is low. 3. MY and NY3 will have no effect on their
solubilities.
Both (A) and (R) are True and (R) is the The molar solubilities of MY and NY3 in
1. 4.
correct explanation of (A) water are identical.
2. Both (A) and (R) are False.
3. (A) is True but (R) is False.
Both (A) and (R) are True but (R) is not 28. If an alcoholic beverage has a pH of 4.7,
4.
the correct explanation of (A) what is the concentration of OH- ions in the
solution?
−14 2 −2
(Given: Kw = 10 mol L )
25. Read the statements and mark the 1. 3 × 10
−10

appropriate option:
2. 5 × 10
−10

The melting point of ice

3. 1 × 10
−10

Assertion (A): decreases with the increase of

4. 5 × 10
−8

pressure.
Reason (R): Ice contracts on melting.
29. On adding inert gas at constant volume,
equilibrium shifts in the forward direction will
Both (A) and (R) are True and (R) correctly take place in -
1.
explains (A)
Both (A) and (R) are True but (R) does not 1. N2 (g) + 3H2 (g) ⇌ 2N H3 (g)
2.
correctly explain (A) 2. P Cl5 (g) ⇌ P Cl3 (g) + Cl2 (g)
3. (A) is True but (R) is False 3. H2 (g) + I2 (g) ⇌ 2H I (g)
4. Both (A) and (R) are False 4. None of the above.

Page: 3
 Custom Practice Test - 20-Jan
Contact Number: 9667591930 / 8527521718

30. Buffer solutions have constant acidity and 35. The value of Kc of the reaction 2A⇌B+C is
alkalinity because: 2x10-3. At a given time, the composition of the
reaction mixture is [A] = [B] =[C] = 3x10-4 M.
these give unionized acid or base on reaction Select the correct option:
1.
with added acid or alkali. 1. Qc < Kc
acid and alkali in these solutions are 2. Qc > Kc
2.
shielded from attack by other ions
3. Qc = Kc
3. they have large excess of H+ or OH- ions
4. Qc ≠ Kc
4. they have fixed value of pH

31. Given that the equilibrium constant

Chemistry-Section-B
KC at 36. For the given reaction, the degree of
800 K for the reaction N2(𝑔)+3H2(𝑔)⇋2NH3(𝑔) is dissociation of B was found to be 20% at 300 K
64. What is the equilibrium constant KC at 800 K and 24% at 500K.
for the given-below reaction is: 2 A( s) + B(g) ⇌ C(g) + 2D(s) + E(s)

NH3(g) ⇌ 1/2N2(g) + 3/2H2(g) The rate of backward reaction:

1 Increases with increase in pressure and
1.
1
2. 1.
temperature
4 8
Increases with increase in pressure and
1 2.
3. 8 4. decrease in temperature
64
Depends on temperature only and decreases
3.
with increase in temperature
32. Aqueous solution of which of the following 4. Increases with increase in concentration of B
compounds is the best conductor of electric and increase in the temperature
current?
1. Acetic acid, C2 H4 O2
2. Hydrochloric acid, HCl 37. The nature of an aqueous solution of
3. Ammonia, NH3 NaHCO₃ is:
4. Fructose, C6 H12 O6 1. Acidic
2. Alkaline
3. Slightly alkaline
4. Slightly acidic
33. The dissociation constant of a substituted
benzoic acid at 25°C is 1 × 10−4 . The pH of a
38. In a basic buffer, 0.0025 mole of NH4Cl and
0.01 M solution of its sodium salt of benzoic
acid is: 0.15 mole of NH4OH are present. The pH of the
1. 6 2. 7 solution will be :
(Given pKb = 4.74)
3. 8 4. 9
1. 11.04 2. 10.24
3. 6.52 4. 5.48
34. 3O2 ( g) ⇌ 2O3 (g)
For the above reaction at 298 K, Kc is found to
−59
be 3.0 × 10 . If the concentration of O2 at
equilibrium is 0.040 M, then the concentration
of O3 in M is:
1. 1.2 × 1021
2. 4.38 × 10−32
−63
3. 1.9 × 10
4. 2.4 × 1031

Page: 4
 Custom Practice Test - 20-Jan
Contact Number: 9667591930 / 8527521718

39. Given a system:

43. Calculate the number of H + ions present
in 1 ml of a solution whose pH is 13.
A(s) ⇌ 2B(g) + 3C(g).
1. 3.022 × 10
−16

If the concentration of C at eqilibrium is 2. 3.022 × 1013

increased by a factor 2, it will cause the
3. 6.022 × 10
7

eqilibrium concentration of B to change to:

4. 6.022 × 10
23

1. two times of its original value

2. one half of its original value
44. The species, among the following, that act as
3. 2√2 times of its original value both Brönsted acid and base is/are:
1
4. times of its original value 1. H2 P O−
2 √2 2
2−
2. HP O
3
40. Among the following, the correct statement 3. H P O2−
about a chemical equilibrium is : 4

4. All of the above

Equilibrium constant is independent of
1. 45. The decreasing order of the acidic nature of
temperature.
H2 SO4 (I), H3 PO4 (II), and HClO4 (III)
Equilibrium constant tells us how fast the
2. is:
reaction reaches equilibrium.
1. I>II>III
At equilibrium, the forward and the 2. I>III>II
backward reactions stop so that the 3. III>I>II
3.
concentrations of reactants and products are 4. III>II>I
constant.
The value of equilibrium constant is 46. The values of Ksp of CaCO3 and CaC2O4 are
4. independent of initial concentrations of the
4.7 × 10–9 and 1.3 × 10–9 respectively at 25°C. If
reactants and products.
the mixture of these two is washed with water,
what is the concentration of Ca2+ ions in the
water?
41. What substance could be added to one liter
of water to serve as a buffer? 1. 5.831 × 10–5 M
–5
1. One mole of CH3 CO2 H and 0.5 moles of 2. 6.856 × 10 M
NaOH 3. 3.606 × 10–5 M
2. One mole of NH4Cl and one mole of HCl 4. 7.746 × 10–5 M
3. One mole of NH4OH and one mole of NaOH
4. One mole of CH3 CO2 H and one mole of 47. One mole of a compound AB reacts with one
HCl mole of a compound CD according to the
equation AB(g) + CD(g) ⇌ AD(g) + CB(g). When
42. Among the given compounds, which one equilibrium had been established, it was found
3
would have the lowest value of the hydrolysis that 4 mole each of the reactants AB and CD
constant (KH ) ? had been converted to AD and CB. The
1. AlCl3 equilibrium constant for the reaction is:
2. CuSO4 (Volume remained constant during reaction)
3. N H4 Cl 1. 6/15
4. CH3 COON a 2. 1/9
3. 19/5
4. 9

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 Custom Practice Test - 20-Jan
Contact Number: 9667591930 / 8527521718

48. The solubility of Ca(OH)2 in water is:

[Given: Ksp Ca(OH)2 in water = 5.5 × 10–6]
1. 1.77 × 10–6
2. 1.11 × 10–6
3. 1.11 × 10–2
4. 2.77 × 10–2

49. The equilibrium constant for the reaction

N2 (g) + O2 (g) ⇌ 2NO(g)
−4
at temperature T is 4 × 10 . The value of Kc
for the reaction,
1 1
NO(g) ⇌
2
N2 (g) +
2
O2 (g) at the same
temperature) is :

2
1. 2.5 × 10
2. 5 × 101
−4
3. 4 × 10
4. 2 × 10−2

50. The pH of an ammonium phosphate

solution, if the pKa of phosphoric acid and the
pKb of ammonium
hydroxide are 5.23 and 4.75 respectively, is:
1. 8 2. 6
3. 7 4. 10

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