06-04-2025

1001CJA101016250002 JA

PART-1 : PHYSICS

SECTION-I (i)

1) If y = x3 – x2 then at x = 2 is

(A) 6
(B) 8
(C) 9
(D) 7

2) If f(x) = cos3(x2) then find f′(x)

(A) –6x cos2(x2) sin(x2)

(B) 6x cos2(x2) sin(x2)
(C) –3x cos2(x2) sin(2x2)
(D) –3 cos(x4) sin(2x2)

3) In a certain system of units, 1 unit of time is 20 sec, 1 unit of mass is 20 kg and 1 unit of length is
20 m. In this system, one unit of power will correspond to

(A) 20 watts

(B)
watts
(C) 400 watts
(D) 1 watts

4) If E, M, L, G are energy, mass, angular momentum and gravitational constant respectively then

can represent :

(A) Angle
(B) Momentum
(C) Angular Momentum
(D) Force

5) Which of the following x–t graphs represent a constant velocity motion?

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) An object is moving in a straight line. Its position versus time graph is shown below. There is a
detector at origin which analyze the motion of object between t = 6 and t = 8 seconds, which

statement describes the motion shown in the graph.

(A) detector observes the object to be moving towards origin.
(B) detector observes the object to be moving away from origin.
(C) Detector observes the motion at decreasing speed.
(D) Detector observes the motion at increasing speed.

2) A particle is moving in x axis according to relation x = (4t – t2 – 4)m :–

(A) Maximum x coordinate of particle is 4m

(B) Magnitude of average velocity is equal to average speed, for time interval t = 0s to t = 2s
(C) Average acceleration is equal to instantaneous acceleration during interval t = 0 to t = 2s
(D) Distance travelled in interval t = 0 to t = 4s is 8 m.

3) is resultant of . Magnitude of is and it makes 30° with . Magnitude of

is 20N. Choose the CORRECT option(s):

(A) Magnitude of is 20 N
(B) Magnitude of is
(C) Angle between and is 30°

(D) Component of along has magnitude

4) The x-component of the resultant of several vectors

(A) is equal to the sum of the x-components of the vectors

(B) may be smaller than the sum of the magnitudes of the vectors
(C) may be greater than the sum of the magnitudes of the vectors
(D) may be equal to the sum of the magnitudes of the vectors

5)

For the equation x = AC sin (Bt) + D e(BCt), where x and t represent position and time respectively,
which of the following is/are CORRECT?

(A) Dimension of AC is LT–1.

(B) Dimension of B is T–1.
(C) Dimension of AC and D are same.
(D) Dimension of C is T–1.

SECTION-I (iii)

Common Content for Question No. 1 to 2

Entries in List–I are representing physical quantities whereas entries in List–II are representing
dimensions and List-III representing SI units. Match the list.
 List-I List-II List-III

(P) Angle (1) M1L2T–3 (i) Joule

0 0 0
(Q) Power (2) MLT (ii) Unit Less

(R) Work (3) M1L2T–2 (iii) Radian

(S) Strain (4) M1L1T–2 (iv) Watt

1) Angle will be related as

(A) (P)(2)(i)
(B) (P)(1)(iii)
(C) (P)(4)(iii)
(D) (P)(2)(iii)

2) Power will be related as

(A) (Q)(4)(iv)
(B) (Q)(2)(ii)
(C) (Q)(1)(iv)
(D) (Q)(2)(iii)

Common Content for Question No. 3 to 4

We are given two vectors and .

3) What is the angle between and ?

(A) 0°
(B) 30°
(C) 90°
(D) 120°

4) Component of in x direction is

(A) 1
(B) 2
(C) 5
(D) 3

SECTION-II

1) A stone is dropped into a lake and circular waves are generated (with centre at the point where
stone falls in the lake) which travel at the constant rate of 10 cm/sec. At the instant when radius of
the circular wave is 9 cm, the rate at which the area enclosed by the circle is increasing is απ
cm2/sec. The value α is _______
2) In the given expression y = 4x (2 – x), find maximum value of y.

3) Velocity-position graph of a particle is as shown in the figure. The acceleration of the particle

when its velocity is 6m/s is _______ m/s2.

4) A car moving on a straight road covers one third of a certain distance with 20 km/h and the rest
with 60 km/h. The average speed (in km/hr) is :-

PART-2 : CHEMISTRY

SECTION-I (i)

1)

The electrons, identified by quantum number n and ℓ :

(i) n = 3 ; ℓ = 0
(ii) n = 5 ; ℓ = 2
(iii) n = 2 ; ℓ = 1
(iv) n = 4 ; ℓ = 3
can be placed in order of increasing energy from the lowest to highest as :

(A) (iii) < (i) < (iv) < (ii)

(B) (i) < (iii) < (iv) < (ii)
(C) (ii) < (iii) < (iv) < (i)
(D) (ii) < (iv) < (i) < (iii)

2) Which of the following set of quantum numbers represent maximum number of electrons in Ni
(Nickel)

(A) n = 2, ℓ = 1, m = +1
(B) n = 3, ℓ = 2, m = 0
(C) n = 3, m = 0, s =
(D) n = 4, m = 0, s =

3) Which of the following statement about an electron with m = +2 is incorrect ?

(A) The electron could be in the third shell

(B) The electron is in a non-spherical orbital
(C)
The electron may have ms = +
(D) The electron is in a d-orbital always

4) Imagine a universe in which the four quantum No. can have the following values.
n = 1 to ∞
l = 0 to (n + 1)
m = –(ℓ) to +(ℓ) including zero

s= ,– ,+ , +
Answer the following question based on the above values - If aufbau (n + ℓ) rule is valid then block
of Co is – [At. No. of Co = 27]

(A) s-block
(B) p-block
(C) d-block
(D) f-block

5) X, Y and Z are three consecutive elements. 'X' on addition of one electron and 'Y' on addition of
two electrons become isoelectronic with element 'Z'.
Select correct option :

(A) Atomic number of 'Y' is higher than atomic number of 'Z'

(B) Atomic number of 'Y' is higher than atomic number of 'X'
(C) Element 'Y' is placed in periodic table at left side of element 'X' if both are in same period
(D) Difference between total number of protons of 'X' and 'Y" is 2.

SECTION-I (ii)

1) An element have electronic configuration as [Kr]5s1 4d4 . CORRECT statement regarding element
is -

(A) Element must be Nb

(B) Element belongs to group no. ‘5’ according to the long form periodic table
(C) Number of electrons in element having ℓ = 2 are 4
(D) Element have spin magnetic moment B.M.

2) Select the INCORRECT statement (s) from the following options :-

(A) The nodal plane of px and py orbital is xy plane

(B) orbital has two nodal plane
(C) px, py and pz orbitals have the same value of ‘mℓ’

(D) dxy, and orbitals have the different orientation in space but have same value of ‘m’

3) Which of the following set of quantum number are impossible for last electron of Cl atom
according to ground state electronic configuration.
 n = 3 , ℓ = 2 , m = –2 , ms =
(A)

n = 3 , ℓ = 3 , m = –2 , ms =
(B)

(C)
n = 3 , ℓ = 1 , m = +1 , ms =

(D)
n = 2 , ℓ = 1 , m = 0 , ms =

4) Choose INCORRECT statements.

For transition elements, the 3d-orbitals are filled with electrons after 3p-orbitals and before 4s-
(A)
orbitals
(B) Zn, Cd, Hg are transition elements
(C) Mn contains total 8 valence electrons.
(D) Top-positions of Lother-Mayer's atomic volume curve occupied by alkaline earth metal

5) The value of shielding constant for last electron of an element is given as σ = 4 × 0.35 + 8 × 0.85
+ 1 × 2. This element will have –

(A) Smaller size as compare to oxygen element

(B) Smaller size as compare to Mg
(C) After addition of three electron, anionic species formed will be isoelectronic with Ar
(D) Atomic number 14

SECTION-I (iii)

Common Content for Question No. 1 to 2

In the modern periodic table, elements are arranged in order of increasing atomic numbers which is
related to the electronic configuration. Depending upon the type of orbitals receiving the last
electron, the elements in the periodic table have been divided into four blocks, viz, s, p, d and f. The
modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a
new energy shell. In accordance with the Aufbau principle, the seven periods (1 to 7) have 2, 8, 8,
18, 18, 32 and 32 elements respectively. To avoid the periodic table being too long, the two series of
f-block elements, called lanthanoids and actinoids are placed at the bottom of the main body of the
periodic table.

1) Choose correct option.

(A) Z = 46 , d-Block , 9th group , 6th period

(B) Z = 56 , p-Block , 2nd group , 5th period
(C) Z = 76 , d-Block , 8th group , 6th period
(D) Z = 57 , f-Block , 3rd group , 7th period

2) The last element of the p-block in 6th period is represented by the outermost electronic
configuration.

(A) 7s27p6
0
(B) 5f146d107s27p
(C) 4f145d106s26p6
(D) 4f145d106s26p4

Common Content for Question No. 3 to 4

Electronic configuration of elements give an idea about various properties of elements and hence it
is one of the basis for periodic classification of elements. An element prefers to stay in that
configuration in which its energy is least. A substance is said to show "Paramagnetic properties'" if it
has unpaired electrons.

3) Which of the following is expected to be paramagnetic :

(A) Cu+
(B) Zn+2
(C) Cr+3
(D) Ti+4

4) Which of the following options correctly mention the configuration which is most stable among Q

and R.

(A) Q-I and R-I

(B) Q-I and R-II
(C) Q-II and R-I
(D) Q-II and R-II

SECTION-II

1) The number of degenerate orbitals in absence of external magnetic field & electric field in third
excitation state of Be3+ is "x" times the degeneracy value in 1st excited state of He+ and maximum
number of electrons in Ge atom for which n + ℓ + m = 3 is y then find y – x?

2) Calculate the difference in magnitude of Zeff on 4s and 3d-electron of Sc.

3) Out of following pairs, how many number of pairs of species in which size of first specie is higher
as compare to second species. (O, O+), (Ga, Aℓ), (Na+, F–), (Na+, Mg2+), (N, O), (I–, Cl–), (Mg+ , Mg2+),
(Ca2+, P3–), (Zn, Cu) (Cl– , H– )

4) In other universe if quantum number are given as

n = 1 to ∞
ℓ = 0 to + (n + 1)
m = –(ℓ + 1) to + (ℓ + 1) including zero

ms = ,0,
Then find total number of elements in 3rd period of periodic table.

PART-3 : MATHEMATICS

SECTION-I (i)

1) The numbers 221, 315, 59,69,116 are arranged from smallest to largest. The number which will be in
the middle is -

(A) 221
(B) 315
(C) 59
(D) 116

2)

If (x + y)(y + z)(z + x) = 11 and x + y + z = 11, then value of x3 + y3 + z3 is -

(A) 1320
(B) 1364
(C) 1164
(D) 1298

3) In the given diagram, if the radius of the smaller circle is 2 unit and larger circle is 3 unit, then
the area of the triangle BCD will be (A and B are centres of the two circles)

(A)
sq. unit

(B)
sq. unit
(C)
sq. unit
(D) 3 sq. unit

4) Product of all values of x satisying the equation

(A)

(B) 3

(C)

(D)

5) If , then equals -

(A) 14
(B) – 2
(C) 4
(D) 2

SECTION-I (ii)

1) If and

are two sets, then (where z denotes set of integers)

(A) number of subsets of A × B is 26

(B) number of subsets of A × B is 6
(C) n(A) > n(B)
(D) n(A) < n(B)

2) If S is the set of all real x such that is positive, then S contains

(A)

(B)

(C)

(D)
3)

If then x =

(A) 1
(B) –1
(C) 0

(D)

4) If 2a2 + 5b2 – 2ab – 6a – 6b + 9 = 0, where a,b ∈ R, then

(A) (a + b)2 = 16
(B) (a + b)2 < 16
(C) (a – b)2 = 4
(D) a + b is divisible by 3.

2–x 2+x
5) If x1, x2 (x1 > x2) are solutions of 3 +3 = 82, then

(A) x1 + x2 = 0

(B)

(C)

(D)

SECTION-I (iii)

Common Content for Question No. 1 to 2

Let and .

1) Let and , then value of is -

(A) 328
(B) 0

(C)

(D)

2) is -

(A) 0
(B) 1
(C) 2
(D) 3

Common Content for Question No. 3 to 4

Let A denote the largest negative integer value of x which satisfies

B denotes the smallest positive integer value of x which satisfies (x + 3)(3x – 2)5 (7 – x)3 (5x + 8)2 ≥ 0

C denotes the number of integral values of x which satisfies .

3) A + 5B + 3C is a multiple of

(A) 2
(B) 4
(C) 3
(D) 5

4) The value of A + 3B equals

(A) 0
(B) 1
(C) 2
(D) 3

SECTION-II

1) Real numbers a,b,c satisfy the equation a + b + c = 26, . The value of

is

2) The unit digit in is -

3) A polynomial in x of degree greater than 3 leaves remainder 2,1,–1 when divided by

(x –1), (x + 2), (x + 1) respectively. If value of remainder when polynomial is divided by
(x2 – 1) (x + 2) is ax2 + bx + c, then the value of 6a – 2b + 3c is

4) The number of possible ordered pairs (m,n) (where m and n are non-negative integers) which
satisfy mn – 2m – n = 4 is (are)
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5
A. B A D C C

SECTION-I (ii)

Q. 6 7 8 9 10
A. A B,C,D A,D A,B,D B,C

SECTION-I (iii)

Q. 11 12 13 14
A. D C C C

SECTION-II

Q. 15 16 17 18
A. 180 4 6 36

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23
A. A C D C C

SECTION-I (ii)

Q. 24 25 26 27 28
A. A,B,D A,C,D A,B,D A,B,C,D B,C

SECTION-I (iii)

Q. 29 30 31 32
A. C C C B

SECTION-II

Q. 33 34 35 36
A. 4 0 6 45

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 37 38 39 40 41
A. A D A D D

SECTION-I (ii)

Q. 42 43 44 45 46
A. A,C A,D A,D B,D A,C,D

SECTION-I (iii)

Q. 47 48 49 50
A. D C C B

SECTION-II

Q. 51 52 53 54
A. 725 4 2 4
 SOLUTIONS

PART-1 : PHYSICS

3)

n1u1 = n2u2
ML2T–3 = 20kg (20m)2 (20sec)–3

= kgm2sec–3
= 1 watt

4)
= [ML2T–1] = [Angular Momentum]

6) From t = 6 sec to t = 8 sec. velocity of particle is towards – ve x-axis and position is positive
so object to be moving towards origin.

7) x = (4t – t2 – 4)m

v= = 4 – 2t Velocity is in positive direction initially

x will be maximum when = 0 so t = 2 sec

⇒ x (t = 2) = 0
In t = 0 to t = 2 sec. direction does not change. Hence average velocity = average speed (B)
Also, acceleration is uniform. So Average acceleration = Instantaneous acceleration (C).
In t = 0 to t = 2 sec. distance travelled is 4m and at t = 4 sec. x = – 4.
So total distance travelled = 8m

9) Theory based

0 0 0
11) Angle - M L T -Radian

12) Power - M1L2T–3 – watt

 15)

A = πR2

= 2π(9cm)(10 cm/s) = 180 π cm2/s

∴ α = 180

17)
a = (6)(1) m/s2
a = 6 m/s2

18) and
Total time t = t1 + t2

Average speed

PART-2 : CHEMISTRY

19)

Energy is given by (n + ℓ) value. When (n + ℓ) value is equal, the orbital with greater n-value
has greater energy.

Energy Thus, energy

(i) 3+0=3

(ii) 5+2=7
(iii) < (i) < (iv) < (ii)
(iii) 2 + 1 = 3

(iv) 4 + 3 = 7

21) First three statements are correct

PART-3 : MATHEMATICS

37) The numerical order of the numbers will be same as of their cube roots.
27 = 128, 35 = 243, 53 = 125, 63 = 216, 112 = 121
121 < 125 < 128 < 216 < 243
hence 221

38) Use : (x + y + z)3

= x3 + y3 + z3 + 3(x + y)(y + z)(z + x)
(11)3 = x3 + y3 + z3 + 3(11)
∴ x3 + y3 + z3 = 1298

39)

40)

5x2 – 14x – 3 = 0

41)

x3 – 8 – 6x(x – 2) = 2 + 22 + 3 × 2
x3 – 8 – 6x2 + 12x = 6x – 6
x3 – 6x2 + 6x = 2

42) A = (x – 3)(x2 + 3x + 2) = 0
⇒ x = 3, x = –1, –2
⇒ A = {–1, –2, 3}
B⇒1<x<4
⇒ B = {2, 3}

43)

⇒ x ∈ (–∞,–1) ∪

44)

∴
Also x = 1 is an obvious solution

45) [a2 + b2 + (3)2 – 2 × 3a – 2 × 3b + 2ab] + a2 + 4b2 – 4ab = 0

⇒ (a + b – 3)2 + (a – 2b)2 = 0
⇒ a + b – 3 = 0 and a – 2b = 0
⇒ a = 2 and b = 1

46)
9t2 – 82t + 9 = 0 (let 3x = t)
(9t – 1) (t – 9) = 0

t= t=9
3x = 3–2 3 = 32
x

x = –2 x=2
⇒ x1 = 2 x2 = –2
47)

By solving it is

48)

⇒ t2 = t + 2
⇒t=2

49) A + 5B + 3C = –2 + 5(1) + 3(2)

= –2 + 5 + 6
= 9, which is a multiple of 3

50)

⇒
∴ A = –2
Now, (x + 3) (3x – 2)5 (7 – x)3 (5x + 8)2 ≥ 0
⇒ (x + 3) (3x – 2)5 (x – 7)3 (5x + 8)2 ≤ 0

∴
So, B=1

Also,
x ∈ (–4, –3) ∪ [–2, –1]
So, c = 2
∴ A + 3B = –2 + 3(1) = 1

51) Multiplying the two given equations gives

, and subtracting 3 from both sides gives

the

52)
∴ Unit digit in 310 × 217 × 711
= Unit digit in 9 × 2 × 3 = 4

53) ƒ(x) = (x – 1)(x + 1)(x + 2)Q(x) + ax2 + bx + c

ƒ(1) = 2 ⇒ a + b + c = 2
ƒ(–2) = 1 ⇒ 4a – 2b + c = 1
ƒ(–1) = –1 ⇒ a – b + c = –1
add 6a – 2b + 3c = 2

54) m(n – 2) – n + 2 = 6
⇒ (n – 2) (m – 1) = 6
if m – 1 ≥ –1, n – 2 ≥ –2
(m – 1) (n – 2) = 6 is not achievable
when m – 1 & n – 1 both are negative