GAS HYDRATES
GAS HYDRATES
HYDRATES
• Gas hydrates are a crystalline solid formed of water and gas.
• It looks and acts much like ice, but it contains huge amounts of
methane.
• It is known to occur on every continent, and it exists in huge quantities
in marine sediments in a layer several hundred meters thick directly
below the sea floor and in association with permafrost in the Arctic.
• It is not stable at normal sea-level pressures and temperatures, which is
the primary reason that it is a challenge to study.
• Gas hydrates are important for three reasons:
• They may contain a major energy resource.
• It may be a significant hazard because it alters sea floor sediment
stability, influencing collapse and land sliding
• The hydrate reservoir may have strong influence on the environment
and climate, because methane is a significant greenhouse gas.
• It is known that some polar
components between the sizes of
argon (0.35 nm) and ethyl
cyclohexane (0.9 - 1) can also
form hydrates.
• Natural gas hydrates commonly
called gas hydrates the crystalline
compounds formed when water
molecule and methane gas exist
together at the right temperature
and pressure. Methane hydrate is
stable at a temperature slightly
above or below 0˚C with high
pressure.
Gas hydrates deposits compared with other
fuel resources, units = 1015 g of carbon
• Hydrate deposits are generally found in waters deeper than 300 m
• Their zones of existence is from seafloor to a depth of few hundred
metres and this is also a function of the local thermal gradient.
• Based on research and investigation, huge amount of methane gas is
believed to be trapped in the hydrate deposits as well as the sediments
beneath these deposits.
• Exploration and development of gas hydrate reserves is the key
solution to unlimited supply of energy.
• This source of energy is pure and environmentally friendly.
• They are restricted to the shallow lithosphere(2000m – 4000m depth).
FORMATION OF GAS HYDRATES
• When water molecules come in contact with gas molecules at low
temperature and high pressure, different geometric structures
contrary to that of a hexagonal ice are formed.
• The water molecules serve as host molecules and create cage lattices
that can hold gas molecules as guest molecules.
• These cage-like crystalline structures are less dense than crystalline
water structure because of the presence of the gas molecules.
• The gas hydrate formed is held together by the hydrogen bonds of the
water molecules and also stabilized by Vander Waals forces holding
the gas and water molecules together.
• The Vander Waals force is responsible for the stable nature of the gas
hydrate and even makes the hydrate more stable than normal ice
formed by water.