Ans Weekly Test 4
Ans Weekly Test 4
WEEKLY TEST - 04
DURATION ::180
DURATION Minutes
90 Minutes DATE : 27/08/2023 M. MARKS : 300
ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 61. (2)
31. (2)
2. (1) 62. (2)
32. (3)
3. (3) 63. (1)
33. (3)
4. (3) 64. (3)
34. (3)
5. (4) 65. (3)
35. (2)
6. (2) 66. (2)
36. (2)
7. (4) 67. (1)
37. (1)
8. (3) 68. (3)
38. (2)
9. (4) 69. (2)
39. (4)
10. (1) 70. (4)
40. (1)
11. (1) 71. (3)
41. (3)
12. (2) 72. (2)
42. (3)
13. (2) 73. (2)
43. (2)
14. (3) 74. (4)
44. (2)
15. (3) 75. (4)
45. (4)
16. (1) 76. (4)
46. (3)
17. (1) 77. (2)
47. (1)
18. (4) 78. (1)
48. (1)
19. (2) 79. (1)
49. (3)
20. (1) 80. (2)
50. (2)
21. (90) 81. (4)
51. (53)
22. (80) 82. (6)
52. (50)
23. (10) 83. (7)
53. (90)
24. (4) 84. (45)
54. (62)
25. (5) 85. (16)
55. (23)
26. (3) 86. (24)
56. (8)
27. (3) 87. (735)
57. (57)
28. (5) 88. (60)
58. (50)
29. (7) 89. (31)
59. (35)
30. (0) 90. (5)
60. (82)
[1]
SECTION-I (PHYSICS)
1. (1) 7. (4)
3l l 5 Since M is fixed its weight will be equal to the
Initial potential = m g +2mg = mgl tension, T in the string
2 2 2
Therefore, T = Mg
3l l 7 Centripetal force = T sin θ
Final potential = 2m g + mg = mgl
2 2 2 Mg r
m2 r
P = mgl 1
Mg
2. (1) 2 =
ml
1 2
mv0 = mgR(1 − cos ) Mg
2 =
ml
v02
= R − R cos = requires height Time taken by m to complete one revolution,
2g 2
T=
3. (3)
ml
T sin = ma and T cos = mg T = 2
So, a = g tan Mg
mg
Now, T = = mg 2 (given) 8. (3)
cos
1 F = −k ( yiˆ + xjˆ)
cos = , or = 45°
2 dW = F. dr = −k ( yiˆ + xjˆ)(dxiˆ + dyjˆ)
and a = g tan = g tan 45° = g dW = −kydx − kxdy −kd (xy)
1 W = −k[ xy]aa,,0a − ka2
work done, W = T .S = T at 2 2
2
( 1
)
9. (4)
= mg 2 ( g )(1)2 2 = mg 2 / 2 1 2
2 Applying conservation of energy mu =
2
1
4. (3) mgl + mv2
Let v2, v1 be the velocities at lowest point, highest 2
point of vertical circle. v = (u2 − 2gl )
v22 = 2gh = 2g 4 = 8g
v = v2 + u2 2(u2 − gl )
v = v = 4gr = 4g 1 = 4g
2
2
2
1 v = 4g
2
1
[2]
The above graphs show v-t graph from a-t graph
12. (2) & Then v2-t graph, which are self explanatory.
Maximum frictional force between the slab and 19. (2)
the block From given graphs:
fmax = N = mg; m = mass of upper block 3 3 3
ax = t and ay = − t + 1 vx = t 2 + C
Evidently, F < fmax 4 4 8
so, the two bodies will move together as a single At t = 0 ; vx = – 3 C = – 3
unit. If ‘a’ be their combined acceleration, then 3 3
F vx = t 2 − 3 dx = t 2 − 3 dt … (i)
a= 8 8
m+ M
3
Therefore, frictional force acting can be obtained Similary; dy = − t 2 − t + 4 dt … (ii)
1 2 8
as f = Ma, Using s = at , find S2 and S3. W = As dw = F.ds = F.(dx i + xy j)
2
(S3 – S2) f
w 4
3 3
dw = ti − t + 1 j x
0 0 4 4
13. (2)
3 2 3 2
Apply work energy theorem
8 t − 3 i + − 8 t − t + 4 j dt
W = KE
W = – 400J W = 10 J
Alternate solution:
14. (3) Area of the graph;
aTotal = ac (−iˆ) + at (− ˆj) a dt = 6 = V − (−3) V = 3.
x ( x) f ( x) f
[3]
T1 27. (3)
=9
V = ( 2 g 2 − a 2 ) R2
1/4
T2
24. (4)
( )
1/4
F = −k ( xiˆ + yjˆ) = ( 0.2) 102 − 1 27
2
W = F. ds = ( 3 27 )
1/4
= 3m/sec
= −k ( xiˆ + yjˆ)(dxiˆ + dyjˆ)
= −kxdx − kydy 28. (5)
1
Use this expressions to find the solution. v1t = x 2R = 10 t 2
2
1
25. (5) v1t = 3R 2R = 10 t 2
mv 2 2
T − mg sin = 9gR
R v12 =
m(v02 + 2 gl sin 30) 4
4mg − mg sin 30 = 1 98 1 2
l gR − mv = −mg 2R
2 4
m
5g 2
v0 = v = 35
2
29. (7)
26. (3)
uB2 sin 2 2 g (h − hB )sin 2 30
mv 2
h0 = 3 + = 3+
N + mg cos = 2g 2g
R
4 (given) = 3 + h sin2 30° – hB sin2 30°
mv 2
If N = 0 then mg cos = h (3) 7 h
R = 3 + − ; = h = 7m
4 4 4 4
V = Rg cos
2 30. (0)
1 1
m 95Rg x = (t − 3)2 = t 2 − 6t + 9
2 5
dx
1
= mg R(1 + cos ) + m( Rg cos )2 v= = 2t − 6
2 dt
at t = 0, v = – 6 ; at t = 6, v = + 6
3
cos = 1
5 initial KE = m(−6)2 = 18m
2
3
= cos−1 1
final KE = m(6) = 18m
2
5
2
SECTION-II (CHEMISTRY)
31. (2) Cp,m = (3N –2) R
Tc·Vc−1 = TH ·VH−1 H = n · (3N – 2)R · T
−1 |w| = n·R ·T
7/5−1
Tc VH 1
= =
| w|
=
1
TH Vc 4 H 3N − 2
Tc 1 2/5
Now, = 100 1 − % = 100 1 − % 33. (3)
TH 4 (I) Hf of H+
(V) Hf of CO2(g)
32. (3) II → O2(g) ⎯⎯→ O2(g) Hf O2
1 1
Cv,m = 3 × R + 3 × R + (3N – 6) × R = (3N – 3) 1
2 2 III → N2 + 2H2 + Cl2 Hf NH4Cl
2
R
[4]
IV → P4 (white) +...... Hf P4O10
34. (3) 37. (1)
Let internal energy of 1 mole of monoatomic gas 1 3 1 9
(i) – (ii) – (iii) + (iv)
be U1 and internal energy of mixture containing 1 4 4 8 4
mole of each monoatomic gas and diatomic gas 0.5 NH3 + 0.75 N2O ⎯⎯
→ N2 (g) + 0.75 H2O (l)
be U2 0.75 N2H4 + 0.75 H2O ⎯⎯
→ 0.75 N2O + 2.25 H2
U = U2 – U1 (g)
= (Cv,m)monoT + (Cv,m)dia T – (Cv,m)mono T 1
0.25 N2H4 + 0.25 H2O ⎯⎯→ 0.5 NH3 + O2(g)
U = (Cv,m)diaT 8
Hence internal energy increases 2.25 H2 + 1.125 O2 ⎯⎯
→ 2.25 H2O (g)
Now H = U + (PV) = – 620.5
H = (Cv,m)dia T + V(P)
Since on adding diatomic gas to monoatomic gas 38. (2)
number of moles of gas increases, P (A) 2NH3 (g) → N2(g) + 3H2(g)
H will also increase. ng = + 1 s = +ve
3
1 R + 1 R
5 (B) During polymerisation S < 0 due to chain
Now (Cm)mix = 2 2 = 2R formation.
2 T V
(C) Ssystem = nCv,m ln f + nR ln f for
C 3 Ti Vi
Cv,m = 2R, Cp,m = 3R, P = = 1.5 1.6
CV 2
Tf
(for monoatomic gas) irreversible Now S = n Cv,m 1n + nR
Ti
35. (2) Vf
In for reversible compression. since the
During irreversible adiabatic expansion T Vi
decreases process is adiabatic.
(T2,iso) > (T2,adi)irr P2,iso > (P2,adia)irr. Ssurrounding = 0
P Ssystem = 0 for inversible process
Tf V
nCv,m In + nR In f = 0
Ti Vi
[5]
G° < 0 at standard condition dP H H + ve
= = = as Vl – Vs > 0
KC > 1 so reaction is non dT TV T ( Vl – Vs ) + ve
spontaneous at 300 K for all solids except H2O.
spontaneous at 400 K 45. (4)
1.2 H 100 4
H = H1 × + H2 ×
1
(C) ln =
0.98 R 120000 5 5
4 1
H° = 1200 R ln
1.2 = 100 × + 200 ×
0.98 5 5
= 80 + 40 = 120 cal
(D) G° = H° – TS°
–RT In Kc = H° – TS°
46. (3)
H
S° = + R ln Kc From (ii) + 3 × (iii) – (i) ; Hº = (– 700) +
T
3(–158) – (–180) = – 994 kJ/mol]
1.2
1200R ln
= 0.98 + R ln 0.98
47. (1)
300
1.2
= 4R ln + R ln 0.98
0.98
40. (1)
2 R 320
V1 =
4 = 205 + (–2 × 80 – 40)
2 R 640 =+5
V2 =
8 The process is endothermic
V = 0 So, the solubility will increase with increase
so w = 0 in temperature.
51. (53)
dG = V.dP –S.dT ; at const. volume 55. (23)
G = V.P – (10 + 10−2 T).dT W = – Pext (V2 – V1) = – 3 Lbar.
P1V1 P2 V2
P1 P2 = T2 = 600 K
= P2 = 1 × 400/300 T1 T2
T1 T2
U = nCVm T
4
G = 24.6 × 3 − 1 × 100 – = 20 L bar.
= U = q + w
T 2 T 2
10 100 + 10−2 2 − 1 q = 23 Lbar
2 2
1 56. (8)
G = 24.6 × × 100 – [1000 + 10–2 ×
3 In P–V diagram
160000 90000 A to B temperature increases
2 − 2 ]
TB > TA
= 24.6 × × 100 – 1000 – 350 = –530 J ] In B to C first temperature increases & then
decreases. This can be obtained from T-V
52. (50) equation At the mid point of line BC
C (graphite) ⎯→ C (diamond) temperature will be maximum.
H = U + P2V2 – P1V1
H – U 57. (57)
12 12 Volume displaced by piston
= (500 × 103 × 105 N/m2) − × 10–6 = Volume change of Cl2 (g)
3 2
= –500 × 2×103 ×105 × 10–6 = 500 cm2 × 48 cm2
= –100 kJ /mole = 24 l
Moles of Cl2 consumed in the reaction
53. (90) PV 1 24
n= =
n1Cv1dT + n2Cv2dT = –(n1RT + n2RT)
dV RT 0.08 300
V n=1
dT
=
R dV
– H° for the above process
T Cv V n H 1 342
1/2
= = = 114 K Cal
T2 V T2 V1 3 3
1
ln = – ln 2 =
T1 2 V1 T1 V2
58. (50)
T T
T2 – T1 = 1 – T1 = – 1 H° = U° + ngRT
2 2
1 3 1 5
H° = – 43 kJ mol–1
H = R + R + R + R (T)
2 2 2 2 HoT2 = HTo1 + CP (T2 − T1 )
=
1
(6R)T = 3RT = –3(2)(150) = – 900 T1 = 500 K ]
2
calories] 59. (35)
2A (g) ⎯→ B(g) + C(g)
54. (62) 1 2 1 atm
V2
Ssystem = nRln 2 × R × ln 2 5 2.5
V1 Q= =2 =2
( 2.5)2
11.52 J/K
G = G + RTln Q
[7]
= (60 + 20 – 2 × 40) + 8.3 × 300 ln 2 CH4(g) + 2O2 (g) ⎯→ CO2(g) + 2H2O (g)
= 1743 J H° = – 810 kJ/mole
....(i)
−810 103 810 103
60. (82) = S° = = – 3 J/K
CH4(g) + 2O2(g) → CO2(g) + 2H2O(l); H° = – T 270 103
890 So(comb) = – 3 – (118.5) × 2 = – 240 J/K
...(ii) mole
2H2O (l) → 2H2O(g); H° = +(40×2) –G° = – H° + S° = 890 + [300 ×
__________________________________ (–240)]/1000 = 818 kJ / mole]
SECTION-III (MATHEMATICS)
61. (2)
Since, z| + z = 3 + i 64. (3)
Let z = a + ib, then If we put minimum number of balls required in
|z| + z = 3 + i a2 + b2 + a + ib = 3 + i n(n −1)
each box. Balls left are which can be
Compare real and imaginary coefficients on both 2
n2 + n − 2
sides 2
put in Cn−1 ways without restriction.
b = 1, a2 + b2 + a = 3
a2 + 1 = 3 − a 65. (3)
a2 + 1 = a2 + 9 – 6a Observing carefully the system of equations, we
4 find
6a = 8 a = 1+ i 1− i 1
3 = =
2 2i 2 1+ i
16 5
Then, z = + 1 = +1 = Hence, there are infinite number of solutions
3 9 3
66. (2)
62. (2) 9!
7! = 24 32 5 7 Total number of permutations =
2!
Since the factor should be odd as well as of the
Number of those containing ‘HIN’ = 7!
form 3t + 1, the factor cannot be a multiple of
7!
either 2 or 3. So the factors may be 1, 5, 7and 35 Number of those containing ‘DUS’ =
of which only 1 and 7 are of the from 3t +1, 2!
whose sum is 8. Number of those containing ‘TAN’ = 7!
Number of those containing ‘HIN’ and ‘DUS’ =
63. (1) 5!
Number of those containing ‘HIN’ and ‘TAN’ =
u2 − 2u + 2 = 0 u = 1 i
5!
( x + ) − ( x + )
n n
Number of those containing ‘TAN’ and ‘DUS’ =
− 5!
Number of those containing ‘HIN’, ‘DUS’ and
( cot −1) + (1 + i ) − ( cot − 1) + (1 − i )
n n
= ‘TAN’ = 3!
2i 9! 7!
− 7!+ 7!+ + 3 5! –
( cot −1 = x ) Required number =
2! 2
=
( cos + i sin ) − ( cos − i sin )
n n 3! = 169194.
sin n 2i
67. (1)
2i sin n
= z1 = z2 = z3 (given)
sin n 2i
Now, z1 = 1 z1 = 1 z1z1 = 1
2
sin n
= n
sin
[8]
Similarly, z2 z2 = 1, z3 z3 = 1 2b2 + 2b + 2ia (1 + b )
=
1 1 1 2 (1 + b )
Now, + + =1
z1 z2 z3 = b + ia
z1 + z2 + z3 = 1 72. (2)
z1 + z2 + z3 = 1 3 + 2 −54 = 3 + 6 6i
z1 + z2 + z3 = 1 Let 3 +6 6i = a + ib
a2 − b2 = 3 and ab = 3 6
( a 2 − b2 )
68. (3) 2
Draw all ten lines y = x + r and other ten lines y = a 2 + b2 = + 4a 2b2 = 15
–x + r. We can observe that required squares are So, a = 3 and b = 6
82 = 64
(
3 + 6 6i = 3 + 6 i )
( )
69. (2)
Let, Similarly, 3 − 6 6i = 3 − 6i
sin + i cos = z
8 8
lm ( 3 +6 6i − 3 − 6 6i = 2 6 )
8
1 + sin 8 + i cos 8 73. (2)
3630 = 2 3 5 112
1 + sin − i cos Now a divisor will be of the form (4n + 1) if
8 8 divisor is formed with the help of (4n + 1) type
8
number or by (4n + 3) types number taken even
1+ z times.
= Hence divisors are 1, 5, 3 11, 112, 5 112, 5
1+ 1
z 3 11, i.e., 6.
= z8
74. (4)
8
= sin + i cos After expansion, no two terms will have the same
8 8 powers of x or the terms are non over lapping.
8 Therefore, the total number of terms
= cos − + i sin − = 2 2 2 . . . (n + 2) times = 2n + 2 as a
2 8 2 8 particular power of x can be chosen from each
3 3
8
bracket in 2 ways.
= cos + i sin
8 8
75. (4)
= cos3 = −1 Any three numbers x, y, z from {1, 2, 3, …} can
be chosen in nC3 ways and we get unique triplet
70. (4) (x, y, z), x < y < z. Again any two numbers x, z
(1 – x4) (1 + 9C1 x + 9C2 x2 + 9C3 x3………9C9 x9) can be chosen from {1, 2, 3, ..., n} in nC2 ways
Coefficient of x7 = 9C7 – 9C3 = – 48 and we get the triplet (x, x, z), x < z. Hence total
number of required triplets is nC2 + nC3.
71. (3)
Given that a2 + b2 = 1 . Therefore, 76. (4)
1 + b + ia (1 + b + ia )(1 + b + ia ) 1
11
= All the terms in the expansion of x + will
1 + b − ia (1 + b − ia )(1 + b + ia ) x
=
(1 + b ) − a 2 + 2ia (1 + b )
2 have odd powers of x. So required sum = 0.
1 + b2 + 2b + a 2 77. (2)
=
(1− a2 ) + 2b + b2 + 2ia (1 + b) First, 6 distinct digits can be selected in 10C6
2 (1 + b ) ways. Now the position of smallest digit in them
is fixed i.e. position 4. Of the remaining 5 digits,
[9]
two digits can be selected in 5C2 ways. These two
4
digits can be placed to the right of 4th position in cos 2 + i sin 2
=
one way only. The remaining three digits to the
left of 4th position are in the required order cos − i sin
automatically.
2 2
4
So, n(S) = 10C6 5C2 = 210 10 = 2100.
2
= cos + i sin
78. (1) 2 2
–(6 + i)³ = x + iy
= cos8 + i sin8 = cos 4 + i sin 4 n = 4
–[216 + i3 + 18 i (6 + i)] = x + iy 2 2
–216 + i – 108i + 18 = x + iy
– 198 – 107 i = x + iy 82. (6)
x = – 198, y = – 107 Let z = x + iy
y – x = – 107 + 198 = 91 E = z z + ( z − 3)( z − 3) + ( z − 6i )( z + 6i )
4
1 + cos + i sin 85. (16)
=i 4
16 10!
i sin + i (1 + cos )
2
2 REC students can choose their places in 8 ways
2
4
such that between them exactly 3 chairs are
2cos 2 + i 2sin 2 cos 2 vacant. Now 2 REC and 10 IIT students can
=
permute among themselves in 2! And 10! Ways
2cos2 − i 2sin cos respectively. Hence total no. of ways = 8 2!
2 2 2
10! = 16 10!.
[10]
86. (24) 89. (31)
Case I: The number is made of 0, 1, 2 and 3. 4
1 2
0 1 + x + x + x =
4
1 4
x (1 − x )
3 ways 1 ways
= 4 (1 − x ) (1 − x )
2 ways , number of numbers = 3 1 4 4 −4
21=6 1− x x
2
Constant term in the expansion of
4
2 ways 1 ways 1 2
1 + x + x + x = coefficient x in expansion
4
2 ways , number of numbers = 2 2
=4
of (1 – x4)4 (1 – x)–4 = 7C4 – 4C1 = 31.
Case II: The number is made of 0, 2, 3 and 4.
number of numbers = 3(3!) – 2 2 = 14
90. (5)
3 T2 = nC1 abn – 1 = 135 ...(1)
Substracting the case T3 = nC2 a2 bn – 2 = 30 ...(2)
2 ways 1 way T4 = nC3 a3bn – 3 = 10/3 ...(3)
2 ways
Dividing (1) by (2)
So, total numbers divisible by 6 = 6 + 4 + 14 = n
C1abn −1 135
=
24. n
C2 a 2b n−2 30
n b 9
87. (735) =
n
We have to calculate number of solution of ( n −1) 2
a
a + b + c 9, 1 a 9, 0 b, c 9 2
b 9
a + b + c + d = 9, d 0 = ( n −1) ... (5)
Number of solution is co−efficient of t9 in a 4
(t + t2 + ... + t9) (1 + t + t2 + ... + t9)2 (1 + t + t2 + Dividing (2) by (3)
…) n ( n − 1)
= coefficient of t8 in (1 − t9) (1 − t10)2 (1 − t)−4 2 b
. =9
= coefficient of t8 in (1 − t)−4 is 8 + 4 − 1C4 − 1 = 11C3 n ( n − 1)( n − 2) a
= 165 3.2
so, required number of natural number is 900 − b
165 = 735. = 3 ( n − 2) ...(6)
a
Eliminating a and b from (5) and (6)
88. (60)
n = 5.
(1 + x2)5 (1 + x)4
= (1 + 5x2 + 10x4 + ….) (1 + x)4
Coefficient of x5 will be
= 5 4C3 + 10 4C1
= 5 4 + 10 4
= 60.
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[11]