18-05-2025

2401CJA101029250009 JA

PART-1 : PHYSICS

SECTION - I (i)

1) AB represents a segment of infinite uniformly charged wire of density λ. Now a charge q0 is taken
from point P to Q slowly as shown in fig. then work done by the external forces

(A)

(B)

(C)

(D)

2) The total charge contained within the cube (see figure), in which the electric field is given by

, where ε is the permittivity of free space, is :-

(A) 7Kε0
(B) 5Kε0
(C) 33Kε0
(D) Zero
3) In the figure shown an infinitely long wire of uniform linear charge density λ is kept perpendicular
to the plane of figure such that it extends upto infinity on both sides of the paper. Find the
electrostatic force on a semicircular ring kept such that its geometrical axis coincides with the wire.

The semicircular ring has a uniform linear charge density λ' :-

(A)

(B)

(C)

(D)

4) A rod of mass m and length L is hinged at its one end and carries a block of same mass m at its
lower end. Two springs of same force constant k are installed at distances a = L/2 and b = L/4
respectively as shown in the figure. If the whole arrangement lies in the vertical plane, the

frequency of small vibration is :-

(A)

(B)

(C)

(D)

SECTION - I (ii)

1) Two springs with negligible masses and force constant of K1 = 200 Nm–1 and K2 = 160 Nm–1 are
attached to the block of mass m = 10 kg as shown in the figure. Initially the block is at rest, at the
equilibrium position in which both springs are neither stretched nor compressed. At time t = 0, a
sharp impulse of 50 Ns is given to the block with a hammer.

(A)
Period of oscillations for the mass m is s.
(B) Maximum velocity of the mass m during its oscillation is 5 ms–1.
(C) Data are insufficient to determine maximum velocity.
(D) Amplitude of oscillation is 0.42 m.

2) An infinitely long thin non-conducting wire is parallel to the z-axis and carries a uniform line
charge density λ. It pierces a thin non-conducting spherical shell of radius R in such a way that the
arc PQ subtends an angle 120° at the centre O of the spherical shell, as shown in the figure. The
permittivity of free space is e0. Which of the following statements is (are) true ?

(A) The electric flux through the shell is Rλ/ε0.

(B) The z-component of the electric field is zero at all the points on the surface of the shell.
(C) The electric flux through the shell is Rλ/ε0.
(D) The electric field is normal to the surface of the shell at all points.

3) Which of the following is/are true for the figure showing electric lines of force? (E is electrical

field, V is potential)

(A) EA > EB
(B) EB > EA
(C) VA > VB
(D) VB > VA

SECTION - I (iii)

Common Content for Question No. 1 to 2

In a uniformly charged fixed nonconducting sphere, a very thin tunnel has been made along the
diameter as shown in figure. A charge particle –q having mass m is released from rest at t = 0 at one
end of the tunnel. Total charge Q of sphere is uniformly distributed in its volume. Charge particle

reaches at the centre of solid sphere first time at with speed .

1) The value of N is______

2) The value of α is ________

Common Content for Question No. 3 to 4

Given a square frame of diagonal length 2r made of insulating wires. There is a short dipole, having
dipole moment P, fixed in the plane of the figure lying at the center of the square, making an
angle as shown in figure. Four identical particles having charges of magnitude q each and
alternatively positive and negative sign are placed at the four corners of the square. Select the

correct alternative(s).

3) Electrostatic force on the system of four charges due to dipole is Then the value of n
is____.

4) Net torque on the system of four charges about the centre of the square due to dipole is ____.
 SECTION - II

1) The frequency of oscillation of the system shown in the figure is then the value of α +

β is, α & β are in minimum possible integral form :

2) A block of mass m is attached with spring of spring constant K. There is a wall at distance from
the natural length of spring. Block is displaced such that compression produced in spring is A.If

then find the time period of this motion. All collision are elastic and spring is ideal. If

your answer is where m & n are lowest possible integer, fill value of (m + n) ?

3) Mass ‘m’ is suspended from the smooth, massless pulley which itself is supported by two springs
connected to each other as shown. If the mass is slightly displaced from its equilibrium position, find
angular frequency of resulting SHM of mass ‘m’ (take k1 = 3 N/m, k2 = 6 N/m, m = 0.5kg).

4) A solid conducting sphere of radius 'a' having charge q is surrounded by a concentric conducting
spherical shell of inner radius 2a and outer radius 3a as shown in figure. If the amount of heat
produced when switch is closed is . Fill the value of α.

5) Find the gravitational force of interaction between the mass m and infinite rod of varying mass

density λ such that , where x is the distance from mass m. Given that mass m is placed at a

distance d from the end of the rod on its axis as shown in the figure. If force is , then find the

value of n.

6) Find the magnitude of electric field (in N/C) due to a line charge of λ = nC/m at a point P

as shown.

PART-2 : CHEMISTRY

SECTION - I (i)

1) The order of the reaction A → products is 0.5. The time for complete reaction T and time for 50%
reaction, t1/2 will be related as

(A) T = 2 × t1/2
(B) T = 4 × t1/2
(C) t1/2 = 0.3 T
(D) t1/2 = 0.7 T

2) The value of (n2 + n1) and for He+ ion in atomic spectrum are 4 and 8 respectively. The
wavelength of emitted photon when electron jump from n2 to n1 is
(A)

(B)

(C)

(D)

3) Which of the following reaction will not produce given alkene as major product ?

(A)

(B)

(C)

(D)

4) Arrange the following compounds in decreasing order of electrophilic addition :

(A) P > Q > R

(B) P > R > Q
(C) R > P > Q
(D) R > Q > P

SECTION - I (ii)

1) The correct statement(s) regarding 3py orbitals is/are:

(A) Angular part of wave function is independent of angle θ and ϕ.

(B) Number of maxima in 4πr2R2(r) vs r curve is 2.
(C) XZ plane is the nodal plane.
(D) Magnetic qauntum number must be –1.

2) In the given reaction

C7H12 (X)
(X) can be :

(A)

(B)

(C)

(D)

3) Markovnikoff's rule is applicable on which of the following alkene :

(A)

(B)

(C)

(D)

SECTION - I (iii)

Common Content for Question No. 1 to 2

The first - order decomposition of di-tert-butyl peroxide (DTBP) to acetone is given by the following
equation : C8H15O2(g) → 2CH3COCH3(g) + C2H6(g) The reaction has a half - life 80 minutes at 147°C.
Starting with pure DTBP in flask of constant volume at a pressure of 800 torr,

1) What will be the total gas pressure (in torr), when the partial pressure of DTBP is 700 torr ?
2) In what time (in min), the partial pressure of DTBP is 100 torr ?

Common Content for Question No. 3 to 4

Dehydration of alcohol is an elemination reaction, proceeds via formation of carbocation
intermediate & carbocation rearrangement is also considered if required. Alkene is the product of
the reaction where usually more stable alkene is major product.

3) How many α-hydrogen present in product P1?

4) Find out total number of degree of unsaturation in P1 + P2

SECTION - II

1) Not considering the electronic spin, the degeneracy of the second excited state of H atom is n1,
while the degeneracy of the fourth excited state of H– is n2, then difference between n1 and n2 is
_________

2) A(g) → 2B(g) + C(g) + D(l)

Decomposition of A is a first order reaction as given. After 30 minutes from start of decomposition in
closed vessel total pressure developed is found to be 932 mmHg & after a very long time the total
pressure is found to be 1532 mm Hg. Find total pressure (in Torr) after 60 minutes in the vessel.
Given : Vapour pressure of D(l) = 32 mm Hg

3) Catalyst A reduces the activation energy for a reaction by 10 kJ mol–1 at 300 K. The ratio of rate

constants, is ex. The value of x is _______. [nearest integer] [Assume theat the pre-
exponential factor is same in both the cases. Given R = 8.31 J K–1 mol–1]

4) Identify numbers of alcohol those will show rearrangement during dehydration with concentrate
H2SO4.
5) Calculate the total number of stereoisomers for given compound and find b–a

Total stereoisomers = a

Total stereoisomers = b

6) Find the sum of (X + Y):

; X = Number of steps in given reaction

; Y = Number of steps in given reaction

PART-3 : MATHEMATICS

SECTION - I (i)

1) Let a1, a2, a3. ...an be n positive consecutive terms of an arithmetic progression. If d > 0 is its

common difference, then

(A) 1
(B)

(C)

(D) 0
2)

(A) is equal to 9
(B) is equal to 27
(C) does not exist

(D)
is equal to

3) If the smallest positive angle A, B & C satisfying equation

, then choose most appropriate interval in which A + B +

C lies -

(A) (135°, 180°)

(B) (180°, 225°)
(C) (225°, 300°)
(D) (315°, 345°)

4) Let g(x) = tan–1(cotx – 2cot2x), if , then value of λ + µ is equal to -

(A) 11
(B) 15
(C) 8
(D) 10

SECTION - I (ii)

1)

If , then which of the following statement(s) is/are correct ?

(A)
can be equal to

(B)
sin(θ – 83°) can be equal to

(C)
sin(θ – 83°) can be equal to

(D)
tan(θ + 67°) can be equal to
2) Let f(x) = cos x & , then -

(A) H(x) is continuous & derivable in [0, 3 ]

(B)
H(x) is continuous but not derivable at
H(x) is neither continuous nor derivable at
(C)

(D) Maximum value of H(x) in [0, 3 ] is 1

3) If then which of the following is/are correct ?

ƒ(x) is continuous at
(A)

(B) ƒ(x) is not differentiable at x = 0

(C) ƒ(x) is differentiable at x = 1

(D)
ƒ(x) is differentiable at

SECTION - I (iii)

Common Content for Question No. 1 to 2

Consider ƒ(x) = x4 – 3x3 + 2 and h(x) = be a rational function.

(i) infinite

(ii)
(iii) h(x) is continuous ∀ x ∈ R – {1, 2}
(iv) g(x) does not have any repeated factors.

1) Number of solutions of equation |g(|x|)| = is -

2) Number of points where P(x) = sgn(g(x)) is non differentiable in R is (where sgn(x) denotes
signum function of x)

Common Content for Question No. 3 to 4

Consider a function y = ƒ(x) = sinx + cosx + |sinx – cosx|, x ∈ [0, 2π].
3) The value of is -

4) Number of points in [0,2π] where ƒ(x) is non differentiable is -

SECTION - II

1)

Let f(x) = x +
Compute the value of f(100).f'(100).

2)

Suppose a differentiable function f(x) satisfies the identity f(x + y) = f(x) + f(y) + xy2 + x2y, for all

real x and y. If , then f '(3) is equal to ________.

3) Let f : R → R and g : R → R be respectively given by f(x) = –1 + |x| and g(x) = x3 – 1. Define h : R

→ R by number of points at which h(x) is not differentiable is k

then is

4) If f(x) = , g(x) = . If h(x) = f(x) –g(x) is a continuous

function then is :

5) Let f(x) =
If f(x) is continuous and derivable at x = 0, then (20b + 13k) is :

6) Let P(x) = x10 + a2x8 + a3 x6 + a4x4 + a2x2 be a polynomial with real coefficients. If P(1) = 1 and
P(2) = – 5, then the minimum number of distinct real zeroes of P(x) is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I (i)

Q. 1 2 3 4
A. A A D D

SECTION - I (ii)

Q. 5 6 7
A. A,B A,B A,D

SECTION - I (iii)

Q. 8 9 10 11
A. 4.00 1.00 6.00 0.00

SECTION - II

Q. 12 13 14 15 16 17
A. 7.00 5.00 4.00 6.00 2.00 3.00

PART-2 : CHEMISTRY

SECTION - I (i)

Q. 18 19 20 21
A. C C B B

SECTION - I (ii)

Q. 22 23 24
A. B,C A,B,C A,B,D

SECTION - I (iii)

Q. 25 26 27 28
A. 1000.00 240.00 7.00 4.00

SECTION - II

Q. 29 30 31 32 33 34
A. 6.00 1172.00 4.00 6.00 2.00 5.00

PART-3 : MATHEMATICS
 SECTION - I (i)

Q. 35 36 37 38
A. A B B D

SECTION - I (ii)

Q. 39 40 41
A. A,B,C,D A,D A,B,C,D

SECTION - I (iii)

Q. 42 43 44 45
A. 6.00 2.00 0.00 2.00

SECTION - II

Q. 46 47 48 49 50 51
A. 100.00 10.00 0.00 1.00 79.00 5.00
 SOLUTIONS

PART-1 : PHYSICS

1) W = q ΔV = q0(VQ – VP)

0 0
= – q (VP – VQ) = – q 2Kλ ℓn

0
= 2Kλq ℓn

2) (i) x = 1, ,

So,
(ii) x = 0, ,

So,
(iii) y = 1, ,

So,
(iv) y = 0, ,

So,
(v) z = 1, ,

So,
(vi) z = 0, ,

So,

Thus

3) The electrostatic field intensity at a point on the ring is

The force on the elementary charge dq is

The sine component of dF will get cancelled and cosine component will get added.
Net force on the ring

4)
Restoring force at P = k·(bθ)
Restoring force at Q = k·(aθ)
Torque abt Pt. x

I.α = (kb·θ)b + (kaθ) a + (mg) · Lθ + (mg) · θ

Given a = b=

α=θ·

frequency =

6)
Field due to straight wire is perpendicular to the wire and radially outward.
Hence Ez = 0
Length, PQ = 2R sin 60 = According to Gauss's law

Total flux = =

7) E ∝ density of E. F. lines
Potential decreases while moving along (in direction of E.F. lines).

8)

⇒ SHM with MP at the centre of sphere

v = vmax = Aω =

9)

⇒ SHM with MP at the centre of sphere

v = vmax = Aω =

10)

11) Conceptual.

12)
= k + k + 3k = 5k

13) From phaser diagram the total angle covered by block is 90° + 30° +30° + 90° = 240°
time taken = =
m=2,n=3

14) Let mass m be displaced by a distance of x from its equilibrium position so that the
additional elongation in spring 1 & 2 are x1 & x2 respectively, then
2x = x1 + x2 ............(1)
Also since tension in both springs are same.
T = k1x1 = k2x2

from (1), 2x = x1

∴ T = k1x1 = = .

T' = 2T =
T & T′ are additional tension, over and above the tension already present at equilibrium
hence, for the mass m,

– =

⇒ = = 4 Hz

15)

So, Ui – Uf = H =

16)

17)
 E|| =

E=

PART-2 : CHEMISTRY

18) For nth order reaction (n ≠ 1)

and

19) n2 + n1 = 4
(n2 – n1) (n2 + n1) = 8
n2 – n1 = 2
∵ n2 = 3 and n1 = 1

21) Reactivity of alkene for electrophilic addition reaction ∝ nucleophilicity of Alkene

Nu– of Alkene :

25)

C8H15O2 → 2CH3COCH3 + C2H6

800 – –
700 200 100
PTotal = 700 + 200 + 100
PTotal = 1000 bar
26)

C8H15O → 2CH3COCH3 + C2H6

800 – –
800 – x 2x x
100 1400 700

= 240 min.

29) H atom, degeneracy (n = 3) is 9(n1)H–, degeneracy 3p (fourth excited state) is 3(n2).

30)
t=0 P0 0 0 0
t = 30 P0–x 2x x 32

t = ∞ 0 2P0 P0 32
1532 3P0 + 32
P0 = 500 x = 200
t = 60
Here,

= 500 + 2 × 320 + 32
= 1172 mon Hg

31)

32) Ans : (6)

 33) a = 8, b = 10
b-a=2

PART-3 : MATHEMATICS

35) On rationalising each term

=1

36)

37) A is just less than 30°

B is just less than 90°.
C is just greater than 90°.
⇒ A + B + C ∈ (180°, 225°)

38) g(x) = tan–1(tanx)

∴ = tan–1tan1 + tan–1tan2
+ tan tan3 + tan–1tan4 + tan–1tan5
–1

= 1 + 2 – π + 3 – π + 4 – π + 5 – 2π
= 15 – 5π ⇒ λ + m = 10

39) ⇒

⇒
40) H(x)
as cos x is decreasing

H′(x)
H(x) is continous & derivable in [0, 3].

41) ,

ƒ′(0–) = 0, ƒ′(0+) = 1 ∴ not differentiable at x = 0

ƒ′(1–) = 1, ƒ′(1+) = 1 ∴ differentiable at x = 1

as

ƒ′(x) = sinx which is differentiable at x =

42) graph of |g(|x|)|

6 solutions

43) by (i) degree of g(x) must be less than 4

by (iii) g(x) must have x – 1 and x – 2 in its factors
by (iv) No other factor of g(x) will be possible as it can not be a linear factor or a repeated
fector
∴ Let g(x) = a(x – 1)(x – 2)
∴

h(x) =

⇒ a=2
∴ g(x) = 2(x – 1)(x – 2)
= 2x2 – 6x + 4

44) ƒ(x) = sinx + cosx + |sinx – cosx|

= 2max(sinx, cosx)

= ƒ'(π).2.(2ƒ(π)) = 0

45)

46)

f(x) = x +

f(x) =
let y = f(x) ⇒ (y – x) (y + x) = 1
y2 = x2 + 1

⇒ f(x) f'(x) = 2
47)

Since, exist ⇒ ƒ(0) = 0

Now,

(take y = h)

⇒ ƒ'(x) = 1 + 0 + x2
⇒ ƒ'(3) = 10

48)

h(x) =
∴ Number of points at which h(x) is not differentiable is 0.

49) g(x) is continuous at x = 1

f(x) shouls also be
so, 1 – 3 = 1+ a
a = –3
and
f(x) is continuous at x = 2 but g(x) should also be, so
0=1–b
⇒b=1
so |a – b| = | –3 –1|
=4

50) For continuity

0+0+2=b=2 ⇒ b=2
For derivability

=
2 = –1 + k ⇒ k = 3
∴ b+k=5
51) P(x) is an even function.
So, it is symmetrical about y-axis.
P(–1) = P(1) = 1 and P(–2) = P(2) = –5