JEE Revision Practice Sheet

Redox [Dropper Adv.]

One or More Than One Correct Type Questions 6. One mole of KMnO4 is used for complete oxidation
1. White P reacts with caustic soda, the products are of FeSO4, FeC2O4 and H2C2O4 respectively and
PH3 and NaH2PO2. This reaction involves: separately. Pick up the correct statement:
(A) oxidation (B) disproportionation
(A) 5 mole of FeSO4 can be oxidized
(C) reduction (D) neutralization
(B) 3/5 mole of FeC2O4 can be oxidized
2. Which of the following are correct in case of 5
(C) mole of FeC2O4 can be oxidized
Mohr’s salt? 3
(A) It decolourises KMnO4 (D) 2.5 mole of H2C2O4 can be oxidized
(B) It is primary standard titrant
(C) It is a double salt
(D) Oxidation state of Fe is + 3 in the salt 7. Which reactions involves iodimetric titrations?
(A) 2Na 2S2O3 + I2 ⎯⎯
→Na 2S4O4 + 2NaI
3. Select the correct statements, when Cl2 gas reacts
with hot and concentrated sodium hydroxide (B) 2MnO−4 + 2I− + 16H+ ⎯⎯
→2Mn2+ + 8H2O + 5I2
solution:
(C) Na3AsO3 + I2 + H2O ⎯⎯
→Na2AsO4 + 2HI
(A) the oxidation number of Cl2 changes from zero
to –1 (D) Cr2O72− + 14H+ + 6I− ⎯⎯
→2Cr3+ + 7H2O + 3I2
(B) the oxidation number of Cl2 changed from
zero to +5
(C) the oxidation number of Cl2 changes from zero 8. Select the correct statements:
to +3 (A) n-factor forCrI3 when it oxidises to Cr2O72−
(D) the oxidation number of Cl2 changes from zero
to –3 and IO−4 is 27

4. which of the following correctly represents the (B) n-factor for As2S3 when it oxidises to AsO3−

and SO24− is 28
equivalent mass in a redox change
( NH4 )2 Cr2O7 ⎯⎯
→ N2 + Cr2O3 + 2H2O?
(C) n-factor for FeS2 when it is oxidised to Fe2O3
M
(A) E( NH ) Cr O
4 2 2 7
= and SO2 is 11
6
(D) n-factor for Bi2S3 when it is oxidised to Bi5+
M
(B) E N2 = and S is 10
6
M
(C) ECr2O3 =
6 9. Which are correct statements?
M (A) In strong alkaline solution I2 disproportionates
(D) E N2 =
3 to I– and IO–
(B) In strong acidic solution I– is oxidised by
5. 1 mole of FeC2O4 for complete oxidation requires:
dissolved oxygen of water
(A) 0.6 mole of acidified KMnO4
(B) 0.5 mole of acidified K2Cr2O7 (C) Starch is an indicator for iodometric and
(C) 2 mole of HNO3 iodimetric titrations
(D) 0.3 mole of acidified K2Cr2O7 (D) K3Fe (CN)6 is used as external indicator

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10. For the reaction: 16. Volume V1 mL of 0.1 MK2Cr2O7 is needed for
I− + ClO3− + H2SO4 ⎯⎯
→Cl− + HSO−4 + I2 complete oxidation of 0.678 g N2H4 in acidic
medium. The volume of 0.3 M KMnO4 needed for
The correct statements(s) in the balanced equation
same oxidation in acidic medium will be: -
is/are:
2
(A) V1
(A) Stoichiometric coefficient of HSO−4 is 6 5
(B) Iodide is oxidized 5
(B) V1
(C) Sulphur is reduced 2
(D) H2O is one of the products (C) 113 V1
(D) can’t say
11. Which of the following species are capable of
sharing disproportionation? 17. If 10 g of V2O5 is dissolved in acid and is reduced
(A) ClO– to V2+ by zinc metal, how many mole I2 could be
(B) ClO−2 reduced by the resulting solution if it is further
oxidised to VO2+ ions?
(C) ClO3−
[Assume no change in state of Zn2+ ions] (V = 51,
(D) ClO−4 O = 16, I = 127):
(A) 0.11 mole of I2
12. 25 mL of 0.50 M H2O2 solution is added to 50 mL (B) 0.22 mole of I2
of 0.20 M KMnO4 in acid solution. Which two of (C) 0.055 mole of I2
the following statements are true? (D) 0.44 mole of I2
(A) 0.010 mole of oxygen is liberated
(B) 0.005 mole of KMnO4 does not react with 18. In the reaction CrO5 + H2 SO4 → Cr2 (SO4)3 + H2O
H2O2 + O2 one mole of CrO5 will liberate how many
(C) 0.0125 gram-mole of oxygen gas is evolved moles of O2: -
(D) 0.0025 mole H2O2 does not react with KMnO4 (A) 5/2
(E) In the final solution there are only water (B) 5/4
molecule and Mn2+ ions (C) 9/2
(D) 7/2
Single Correct Type Questions
19. One gram of Na3AsO4 is boiled with excess of solid
13. 125 mL of 63% (w/v) H2C2O4. 2H2O is made to
Kl in presence of strong HCl. The iodine evolved
react with 125 mL of a 40% (w/v) NaOH solution.
is absorbed in Kl solution and titrated against 0.2 N
The resulting solution is: -
hyposolution. Assuming the reaction to be
(A) neutral (B) acidic
(C) strongly acidic (D) alkaline → AsO33− + H2O + I2 ,
AsO34− + 2H+ + 2I− ⎯⎯
calculate the volume of thiosulphate hypo
14. A certain weight of pure CaCO3 is made to react consumed. [Atomic weight of As = 75]
completely with 200 mL of HCl solution to give (A) 48.1 mL
224 mL of CO2 gas at STP. The normality of the (B) 38.4 mL
HCl is: - (C) 24.7 mL
(A) 0.05 N (B) 0.1 N (D) 30.3 mL
(C) 1.0 N (D) 0.2 N
20. 25 mL of 0.50 M H2O2 solution is added to 50 mL
15. The volume of 1.5 MH3PO4 solution required to of 0.20 M KMnO4 in acid solution. Which of the
following statement is/are true: -
neutralize exactly 90 mL of a 0.5 M Ba (OH)2
(A) 0.010 mole of oxygen is liberated
solution is: -
(B) 0.005 mole of KMnO4 are left
(A) 10 mL (B) 30 mL
(C) 0.030 g atom of oxygen gas is evolved
(C) 20 mL (D) 60 mL
(D) 0.0025 mole H2O2 does not react with KMnO4
Paragraph Type Questions 1
Passage-1
H2O2 (aq) ⎯→ H2O ( )+ O2 ( g )
2
Equivalent weight = H2O2 can acts as oxidising as well as reducing
Molecular weight / Atomic weight agent, as oxidizing agent H2O2 converted into H2O
n − factor and as reducing agent H2O2 converted into O2, in
n-factor is very important in redox as well as non- both cases it's n-factor is 2.
redox reactions. With the help of n-factor we can  Normality of H2O2 solution = 2 × Molarity of
predicts the molar ratio of the reactant species H2O2 solution
taking part in reactions. The reciprocal of n-factor's
ratio of the reactants is the molar ratio of the 23. 20 mL of H2O2 solution is reacted with 80 mL of
reactants. 0.05 M KMnO4 in acidic medium then what is the
In general n-factor of acid/base is number of moles volume strength of H2O2?
of H+/OH– furnished per mole of acid/base. n-factor (A) 2.8 (B) 5.6
of a reactant is no. of moles of electrons lost or (C) 11.2 (D) none of these
gained per mole of reactant.
Example 1: 24. 40 g Ba(MnO4)2 (mol. wt. = 375) sample
1. In acidic medium : KMnO4 (n = 5) ⎯→ Mn2+ containing some inert impurities in acidic medium
2. In basic medium : KMnO4 (n = 3) ⎯→ Mn2+ is completely reacted with 125 mL of "33.6 V" of
3. In neutral medium : KMnO4 (n = 1) ⎯→ Mn6+ H2O2. What is the percentage purity of the sample?
Example 2: (A) 28.12 % (B) 70.31 %
FeC2O4 ⎯→ Fe3+ + 2CO2 (C) 85 % (D) none of these
Total no. of moles of e– lost by 1 mole of FeC2O4 =
1+1×23 Matrix Match Type Questions
 n-factor of FeC2O4 = 3 25.
List-I List-II

21. n-factor of Ba(MnO4)2 in acidic medium is :

(A) P2H4 ⎯⎯
→PH3 + P4H2 (P)
E=
3M
4
(A) 2 (B) 6
(C) 10 (D) None of these
(B) → I− + IO3−
I2 ⎯⎯ (Q)
E=
3M
5

22. For the reaction, Fe0.95O (molar mass : M) ⎯⎯

→
(C) MnO−4 + Mn2+ + H2O (R)
E=
15M
26
Fe2O3. What is the eq. wt. of Fe0.95O? →Mn3O4 + H+
⎯⎯
M M
(A)
0.85
(B)
0.95
(D) H3PO2 ⎯⎯
→ (S)
E=
5M
6
(C)
M
(D) None of these
PH3 + H3PO3
0.8075 I II III IV
(A) S Q R P
Passage-2 (B) P Q S R
The strength of H2O2 is expressed in several ways (C) R P Q S
(D) S P R Q
like molarity, normality, % (w/V), volume
strength, etc. The strength of "10 V" means 1
volume of H2O2 on decomposition gives 10
volumes of oxygen at STP or 1 litre of H2O2 gives
10 litre of O2 at STP. The decomposition of H2O2
is shown as under:
 ANSWER KEY
1. (A, B, C) 14. (B)
2. (A, B, C) 15. (C)
3. (A, B) 16. (A)
4. (A, B, C) 17. (A)
5. (A, B) 18. (D)
6. (A, B, C) 19. (A)
7. (A, C) 20. (B)
8. (A, B, C, D) 21. (C)
9. (A, B, C, D) 22. (C)
10. (A, B, D) 23. (B)
11. (A, B, C) 24. (B)
12. (B, C) 25. (A)
13. (A)

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