Class -12 Holiday HomeWork

Subject -English
Reading Section (S.H.A.R.P Insights)
Homework and Assignment
1 to 10(passages)
Page no. 62 to 84
Homework Assignment 1 to 7(Notice)
Page no. 127 to 140
Editorial letter(1 to 10)
Page no. 218 to 235
Job Application
Page no. 252 to 261
Article writing
Page no. 286 to 291
Read and learn question and answer of these lessons from Literature Lexicon:
Flamingo(Prose)
1. The last lesson
2. Lost spring
3. Deep water
4. The Rattrap
Poem
1. My mother at Sixty Six
2. Keeping quiet
Vistas
1. The Third Level
2. The Tiger King
Subject - Maths

1 . Iff: R→R defined by f (x) = (3x - 2)/5 is inversible, find the inverse of f.
2. Show that the function f: R(x: x ∈ R, -1 < x < 1) given by f(x) = x / 1+ lxl one-one and onto. Hence, find
the inverse function of f.
3. Show that the relation R defined by (a, b) R (c, d) iff a + d = b + c on the set N × N is an equivalence
relation.
4. Show that the relation R defined by (a, b) R (c, d) iff ad= bc on the set N × N is an equivalence
relation. equivalence relation.
5. Show that the relation R defined by (a, b) R (c, d) iff ad (b+c) = bc ( a+d) on the set N × N is an
equivalence relation.
6. Show that the relation R in the set A = {x : x ∈ W, 0 ≤ x ≤ 12) given by R = {(a, b): la-bl is a multiple of
4) is an equivalence relation. Also find the set of all elements related to 2.
7.. Write the following functions in the simplest form :
(i) tan-1 [cosx / ( 1+ sinx). ]. (ii)tan-1 [cosx / ( 1- sinx) ]
8.Find A-1, Hence, solve the system of equations:
4x + 2y + 3z = 2, x + y + z = 1, 3x + y - 2z = 5.
9. Solve the following system of equations, using matrices :
2/x + 3/y + 10/z =4, 4/x - 6/y + 5/z = 1, 6/x + 9/y - 20/z = 2.

10.

2
11.

Subject - Physics
Chapter 1
1. Calculate the force between two charges 2 μC and 3 μC placed 2 cm apart in vacuum.
2. A charge of 1 nC is placed at the origin. Find the electric field at (1 m, 0, 0).
3. Calculate the electric field due to a point charge at a distance r.
4. A charge of 2 μC is placed in an electric field of intensity 3×10^5 N/C. Calculate the force on the charge.
5. Find the net force on a charge of 4 μC placed in the vicinity of two equal charges of 2 μC placed 10 cm apart.
6. Calculate electric flux through a surface of area 1 m² perpendicular to a uniform field of 5 N/C.
7. Two point charges +3 μC and -3 μC are placed 5 cm apart. Calculate the electric field at the midpoint.
8. Find the work done in moving a charge of 2 μC across two points having potential difference of 5 V.
9. Calculate the electric field at a distance of 0.2 m from a charge of 10 μC.
10. Three charges are placed at the vertices of an equilateral triangle. Find the net force on one charge.
11. Describe how electric field lines help to visualize the electric field.
12. Explain Coulomb’s law and its vector form.
13. State the principle of superposition of electric fields.
14. Give the dimensional formula of electric field.
15. Electric field due to a dipole at a point on equatorial line is 0. What does it indicate?
16. State and explain the significance of the permittivity of free space.
17. Can two field lines intersect? Justify your answer.
18. Explain the concept of electric dipole. Derive the expression for electric field at axial point.
19. Define electric flux. Write its SI unit.
20. Describe how to calculate electric field intensity using Gauss’s Law for a spherical shell.

Chapter 2
21. What is the potential energy of a system of three point charges placed at corners of a triangle?
22. A 5 μC charge is placed in an electric field and moves from a point with 10 V to 5 V. Find the work done.
23. A capacitor of 4 μF is connected to 50 V. Calculate the energy stored.
24. A 10 μF capacitor is charged to 100 V. It is then connected to an uncharged 10 μF capacitor. Final voltage?
25. A parallel plate capacitor has capacitance 5 μF. What charge is stored when connected to 12 V?
26. A capacitor of 8 μF is charged to 50 V. Find the energy stored in the capacitor.
27. A 3 μF and 6 μF capacitor are connected in parallel across 12 V. Find total energy stored.
28. A 2 μF and 3 μF capacitor are connected in series across 100 V. Find charge and potential across each.
29. Find the potential at a distance of 0.1 m from a 5 μC point charge.
30. Calculate the work done to charge a 2 μF capacitor to 100 V.
31. Derive the expression for potential energy of a capacitor.
32. What is the role of a dielectric in a capacitor?
33. What happens to capacitance when dielectric constant increases?
34. State the relation between electric field and potential.
35. Explain potential gradient. What is its physical significance?
36. Explain energy stored in a capacitor. Derive the expression.
37. Define electrostatic potential. Write its SI unit.
38. Derive the expression for energy density in a capacitor.
39. Why do electric field lines not pass through a conductor?
40. What will be the effect on capacitance if the area of the plates is doubled?
3
Chapter 3
41. A copper wire of length 10 m and cross-section 1 mm² has resistivity 1.7×10^-8 Ωm. Find resistance.
42. A cell of emf 1.5 V and internal resistance 1 Ω is connected to a 4 Ω resistor. Find current.
43. A wire of 1 mm diameter is replaced by another of 2 mm diameter, keeping material and length same. Ratio of
resistance?
44. A resistor of 10 Ω carries 3 A current for 5 min. Calculate total heat generated.
45. A potentiometer wire is 100 cm long. A cell gives balance at 40 cm. Find emf if standard cell is 2 V.
46. A battery of 12 V is connected to three resistors in series: 2Ω, 3Ω, and 5Ω. Find current and voltage drop.
47. Find equivalent resistance of a cube of resistors each of 1 Ω using symmetry.
48. Two resistors 5 Ω and 10 Ω are in parallel. Find total resistance and current through each if 15 V applied.
49. A resistor of 4 Ω is connected in parallel with another of 6 Ω. Find equivalent resistance.
50. A current of 2 A flows through a conductor. How many electrons pass per second?
51. Distinguish between emf and potential difference.
52. Define resistivity and its dependence on temperature.
53. Explain the concept of internal resistance of a cell.

54. State Ohm’s law and its limitations.

55. Explain why alloys are preferred for making standard resistors.

56. What is the significance of temperature coefficient of resistance?

57. State the condition for balance in a Wheatstone bridge

Subject-Biology

Chapter 1: Sexual Reproduction in Flowering Plants

1. 1. Describe the process of double fertilization in flowering plants. (Competency)
2. 2. Why is pollination crucial for seed formation? Describe types of pollination. (Competency)
3. 3. Explain the role of tapetum in pollen development. (Competency)
4. 4. What are the advantages of cross-pollination over self-pollination? (Competency)
5. 5. Differentiate between geitonogamy and xenogamy with examples. (KV School)
6. 6. Label a diagram of a mature ovule and mention the functions of its parts. (KV School)
7. 7. Why do angiosperms undergo double fertilization? What is its outcome? (PYQ, CBSE 2022)
8. 8. Define apomixis and its significance in agriculture. (PYQ, CBSE 2020)
9. 9. Describe post-fertilization changes in a flower. (PYQ, CBSE 2021)
10. 10. Explain how endosperm forms in angiosperms. (PYQ, CBSE 2019)

Chapter 2: Human Reproduction

11. 11. Describe the structure and functions of the human male reproductive system. (Competency)
12. 12. What is spermatogenesis? Describe the hormonal control involved. (Competency)
13. 13. Trace the path of an ovum from ovary to uterus in a human female. (Competency)
14. 14. Explain the role of hormones in the menstrual cycle. (Competency)
15. 15. What are Sertoli cells? State their function. (KV School)
16. 16. Describe the process of fertilization in humans. (KV School)
17. 17. Name the source and function of hCG and hPL hormones during pregnancy. (PYQ, CBSE 2023)
18. 18. What changes occur in the ovary and uterus during the luteal phase? (PYQ, CBSE 2022)
19. 19. Give a labeled diagram of a sperm. Mention the role of its parts. (PYQ, CBSE 2021)
20. 20. Describe the events that occur during implantation. (PYQ, CBSE 2020)

Chapter 3: Reproductive Health

21. 21. What is reproductive health? Mention its significance. (Competency)
22. 22. Explain the importance of sex education in schools. (Competency)
4
23. 23. Name any two STDs and write their symptoms and prevention. (Competency)
24. 24. How are contraceptive pills effective in preventing pregnancy? (Competency)
25. 25. What are the consequences of uncontrolled population growth? (KV School)
26. 26. Differentiate between medical termination of pregnancy (MTP) and contraception. (KV School)
27. 27. Mention two advantages of using condoms as a contraceptive method. (PYQ, CBSE 2023)
28. 28. What are test-tube babies? Explain the steps involved in IVF. ((PYQ, CBSE 2022)
29. 29. Describe any two surgical contraceptive methods. (PYQ, CBSE 2021)
30. 30. What is amniocentesis? Why is it banned in India? (PYQ, CBSE 2020)
CH-4 PRINCIPLE OF INHERITANCE AND VARIATION
31. A human male has one Y chromosome and one X chromosome. Explain how he determines the sex
of the child.(Competency)
32. Why is haemophilia more common in males than in females? Explain with the help of a cross.
Competency)
33. A couple with normal vision has a daughter who is colour blind. How is it possible? Give a genetic
explanation. Competency)
34. A cross between a red flower (RR) and white flower (rr) results in pink flower (Rr). Identify the pattern
of inheritance. Justify. Competency)
35. Differentiate between dominance, co-dominance, and incomplete dominance with suitable
examples. Competency)
36. Why did Mendel choose pea plants for his experiments? Mention any three advantages.(KV)
37. Write a dihybrid cross and explain the law of independent assortment. .(KV)
38. What are multiple alleles? Explain with reference to ABO blood grouping in humans. .(KV)
39. How do genetic disorders differ from chromosomal disorders? Explain with examples. .(KV)
40. A woman with blood group A marries a man with blood group O. Predict the possible blood groups of
their children. .(KV)
41. What is the inheritance pattern observed in the size of starch grains and seed shape of Pisum
sativum in F2 generation? Explain. (CBSE 2023)
42. . Differentiate between Mendel’s law of dominance and law of segregation with one example each.
(CBSE 2020)
43. Explain the mechanism of sex determination in humans. Also, give a genetic cross. (CBSE 2022)
44. Hemophilia is a sex-linked recessive disease. Why does it occur only in males? Explain. (CBSE
2021)
45. State the possible genotype of the parents if a daughter has a blood group O and son has blood
group AB. (CBSE 2022)
46. A test cross is performed between a pea plant with yellow round seeds and a plant with green
wrinkled seeds. Explain the result with the help of a cross. (CBSE 2023)
47. .How can you differentiate between Turner’s syndrome and Klinefelter’s syndrome on the basis of
genetic constitution and symptoms? (CBSE 2020)
48. Explain how sickle cell anaemia is caused. Why is it said to be advantageous in malaria-prone
areas? (CBSE 2022)
49. Why are pedigree charts prepared in the study of human genetics? Explain with one example.
(CBSE 2021)
50. State the conclusion drawn by Mendel in monohybrid cross. Represent the cross using a Punnett
square. (CBSE 2019).
Subject – Chemistry

UNIT : 1 : SOLUTIONS (7 MARKS)

1. Define: Molality, Molarity, Mass percentage, Volume percentage, Parts per million (ppm), Mole
fraction. Write their formulas also.

5
 2. How does a change in temperature influence values of molarity and molality.
3. State Henry law with its mathematical expressions. What is the significance of Henry’s Law constant
KH? Mention some of important applications Henry law.
4. Why do aquatic species remain more comfortable in lakes in winters than in summers?
5. State Raoults law for a solution of volatile liquids .Give its mathematical relationship.
6. What is an ideal solution? What type of solutions are likely to behave as ideal solutions? Draw the
plot of vapour pressure and mole fraction of an ideal solution at constant temperature.
7. Differentiate between Non ideal solutions exhibiting Positive deviations & Negative deviations
8. What are Azeotropes? Give one example each of minimum boiling and maximum boiling azeotropes.
9. Define.(a)osmosis (b)osmotic pressure (c) reverse osmosis & application(d)colligative properties
10. Measurement of osmotic pressure method is preferred for the determination of molecular masses
of macromolecules such as proteins and polymers.Give two reasons.
11. What will happen if RBC are placed in (i)0.5% NaCl Solution (ii)1% NaCl Solution?
12. Define abnormal molecular mass. What is Van’t Hoff’s factor? What is value of Van’t Hoff’s factor
when the solute undergoes (a) association (b) dissociation?
13. Calculate the molarity of a solution containing 5 g of NaOH in 450ml solution.
14. Concentrated nitric acid used in the laboratory work is 68% nitric acid by mass in aqueous solution.
What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g/ml?
15. Calculate molality of 2.5g of ethanoic acid (CH3COOH) in 75g of benzene.
16. An antifreeze solution is prepared from 222.6g of ethylene glycol. C2H4 (OH) 2 and 200g of water.
Calculate molality of solution. If the density of the solution is 1.072 g/ml then what shall be the molarity
of the solution?
17. A solution of glucose in water is labelled as 10% w/w. What should be the molality and mole fraction of
each component in the solution? If the density of solution is 1.2g/ml, then what shall be the molarity of
the solution?
18. If N2 gas is bubbled through water at 298 K, how many millimoles of N 2 gas would dissolve in 1 litre of
water .Assume that N2 exerts a partial pressure of 0.987 bar . Henry’s law constant for N2 at 293K is
76.48 bar.
19. Vapour pressure of chloroform (CHCl3) and dichloroform (CH2Cl2) at 298 K are 200 mm Hg and 415 mm
Hg respectively. (i) Calculate the vapour pressure of the solution prepared by mixing 25.5 g of CHCl3 and
40.0 g of CH2Cl2 at 298 K and (ii) mole fractions of each component in vapour phase.
20. Vapour pressure of water at 293K is 17.535 mm Hg .calculate vapour pressure of water at 293 K when 25
g of glucose is dissolved in 450 g of water.
21. A solution is prepared by dissolving 10 g of non volatile solute in 200 g of water .It has a vapour pressure
of 31.84 mm of Hg at 308 K.Calculate the molar mass of the solute.(Vapour pressure of pure water at
308K is 32 mm of Hg.)
22. 18 g glucose C6H12O6 is dissolved in 1 kg of water in a saucepan. At what temperature will solution boil?
Kb for water is 0.512 KKgmol-1.
23. A solution of glycerol(C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This
solution has a boiling point of 100.42°C. What mass of glycerol was dissolved to make this solution? (Kb
for water = 0.512 K kg mol–1)
24. 45g of ethylene glycol (C2H6O2)is mixed with 600g of water .calculate(a)Freezing point depression
(b)Freezing point of the solution. Kf for water = 1.86 K kg mol-1
25. What mass of ethylene glycol(molar mass =62) must be added to 5.50kg of water to lower the freezing
point from 00C to -100C?( Kf for water = 1.86 K kg mol-1
26. A 5% solution (by mass) of cane sugar in water has freezing point of 271.15 K. calculate the freezing
point of 5% glucose in water if freezing point of water is 273.15 K.
27. At 300 k, 36g of glucose present per litre in its solution has an osmotic pressure of 4.98 bar. If the
osmotic pressure of solution is 1.52 bars at the same temperature, what would be the concentration?
28. A 5 % solution of canesugar is isotonic with 0.877% of substance X.Find the molecular weight of X.
29. 100 mg of a protein is dissolved in enough water to make 10ml of a solution. If this solution has an

6
 osomotic pressure of 13.3 mm Hg at 250C,what is the molar mass of protein?(R=0.0821Latmmol-1K-1 and
760mmHg=1atm)
30. Calculate the boiling points of solution when 2 gm of Na2SO4 (molecular mass 142 gm/mol) was
dissolved in 50 gm of water assuming Na2SO4 undergoes complete ionization. Kb for water = 0.512 K
Kg mol-1
31. Calculate the freezing point of an aqueous solution containing 10.5g of magnesium bromide in 200g of
water assuming complete dissociation of magnesium bromide .(Molar mass of magnesium bromide=
184 g/mol & Kf for water is 1.86 KKgmol-1.)
32. Calculate the boiling point of solution containing 15.0 g of NaCl in 250g of water.(Molar mass of NaCl
= 58.44 g/mol Kb for water = 0.512 K Kg mol-1.)
UNIT : 2: ELECTROCHEMISTRY(9 MARKS)
33. Define Electrochemical cell.What happens when applied external opposite potential becomes greater
than Eocell of electrochemical cell.
34. Write the Nernst equation and emf of the following cells at 298K:
a) Cu/Cu2+(2M)//Ag+(0.05M)/Ag ; Eo Cu2+ /Cu = +0.34V , EoAg+ /Ag = + 0.80V
b) Mg(s)/Mg2+(10-3M)//Cu2+(10-4M)/Cu(s); Eo Cu2+ /Cu = +0.34V, Eo Mg2+/Mg = -2.36
c) Sn/Sn2+(0.050M)//H+(0.020M)/H2(g)/Pt(s) Eo Sn2+ /Sn = - 0.14V
35. Calculate the emf of the cell at 25oC for the following :
a) Mg(s) + 2Ag+(0.0001M) Mg+2(0.130M) + 2Ag(s). if Eo cell =3.17V.
b) 2Cr(s) + 3Fe2+(0.1M)  2Cr3+(0.01M) + 3Fe(s) Eo Cr3+ /Cr = - 0.74V , EoFe2+/fe= - 0.44V
36. A voltaic cell is constructed at 25oC with the following half cell Ag+(0.001M)/Ag and Cu+2 (0.01M)/Cu
what would be the voltage of this cell? Given Eo Ag+ /Ag = + 0.80V, EoCu2+ /Cu = +0.34V).
37. Calculate ΔrG0 & value of equilibrium constant for the following :
a) Mg(s)/Mg2+//Cu2+/Cu(s); Eo 2+ = +0.34V, Eo 2+ = -2.36

7
 Cu /Cu Mg /Mg
b) Cu (s) + 2Ag  Cu + 2Ag(s) E
+ +2 o 2+
= +0.34V, Eo +
= + 0.80V
Cu /Cu Ag /Ag

c) 2Fe3+ + 2I-  2Fe2+ + I2 has Eocell =0.236 V

d) 2Cr(s) + 3Cd2+  2Cr3+ + 3Cd(s) EoCr3+/Cr= - 0.74V , EoCd2+/Cd= - 0.40V
38. Given the standard electrode potentials,:K+/K = –2.93V, Ag+/Ag = 0.80V, Hg2+/Hg =
0.79V Mg2+/Mg = –
2.37 V, Cr3+/Cr = – 0.74V.Arrange these metals in their increasing order of reducing
power
39. Define conductivity,molar conductivity &. limiting molar conductivity.
40. Express the relation among the cell constant ,the resistance of the solution in the
cell and the conductivity of the solution .How is the conductivity of a solution
related to its molar conductivity.
41. The conductivity of 0.20M solution of KCl at 298 K is 0.0248SCm-1.Calculate its molar
conductivity.
42. The Molar conductivity of a 1.5M solution of an electrolyte is found to be 138.9 SCm2
mol-1 . Calculate the conductivity of this solution.
43. The resistance of conductivity cell containing 0.001M KCl at 298K is 1500 ohm. What
is cell constant if conductivity of 0.001M KCl at 298K is 0.146X 10-3Scm-1.
44. State Kohlrausch law and its application. Limiting molar conductivity of NaCl, HCl and
NaAc are 126.4,
425.9 &91 SCm2 mol-1.Calculate Limiting molar conductivity of HAc.
45. Calculate the degree of dissociation of acetic at 298K,given that Λm(CH3COOH)=11.7 SCm2
mol-1 , Λ0m(CH3COO-
2 -1 0 + 2 -1
)=40.9 SCm mol , Λ m(H )=349.1 SCm mol

46. Conductivity of 0.00241M acetic acid is 7.896 X 10-6 S cm-1. Calculate its molar
conductivity. If Λ0 for acetic acid is 390.5 S cm2 mol-1. What is its dissociation constant?
47. The molar Conductivity of 0.025 molL-1 methanoic acid is 46.1 S cm2 mol-1. Calculate its
degree of
dissociation & dissociation constant. If λ0(H+) is 349.6 S cm2 mol-1 and λ0(HCOO-) = 54.6 S
cm2 mol-1.
48. Why does the conductivity of a solution decrease with dilution?
49. How do you account for molar conductivity of strong (CH3COONa or KCl ) and
weak electrolyte (CH3COOH)with concentration? Plot the graphs also.
50. Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times
while that of A
increases 25 times. Which of the two is a strong electrolyte? Justify your answer
51. How much charge is required for following : (i) 1 mol of Al3+ to Al (ii) 1 mol of MnO4- to
Mn2+
52. How much electricity is required (i)20g of Ca from molten CaCl2 (ii) 40g of Al from
molten AlCl3
53. How much electricity is required of (i) 1 mol of H2O to O2 (ii) 1 mol of FeO to Fe2O3
54. A current of 1.50 A was passed through an electrolytic cell containing AgNO3 solution
with inert electrodes.the Weight of silver deposited was 1.50g.How long did the
current flow? (Molar mass of Ag
= 108gmol-1)
55. Calculate the time to deposit 1.27g of copper at the cathode when a current of 2A
was passed through the solution of CuSO4. (Molar mass of Cu = 63.5gmol-1)
56. Three electrolytic cells A,B,C containing solutions ZnSO4,AgNO3,and CuSO4 respectively
are connected in series .A steady current of 1.5 amperes was passed though them until
1.45g of silver deposited at the cathode of cell B.How long did the current flow? What
mass of copper and zinc were deposited? (Molar mass of Zn = 65,Cu = 63.5, Ag = 108
gmol-1
57. Classify Primary Cell or Secondary cell: Dry Cell ,Mercury Cell ,Lead Storage Battery
Nickel cadmium cell
58. Write the name of the cell which is generally used in transistors. Write the reactions
taking place at the cathode and anode of this cell.
59. Write the name of the cell which is generally used in hearing aids. Write the
reactions taking place at the cathode and anode of this cell
60. Write the name of the cell which is generally used in automobiles & inverters?
61. Write the reaction involved in the Lead Storage Battery. What happens when Lead
Storage Battery is recharged?
62. What is Nickel-Cadmium cell.State its one advantage & disadvantage over Lead Storage
Battery.
63. Which cell was used in Apollo space programme.
64. What is Fuel Cell? Explain with diagram & reaction involved in the following cell.
65. Write two advantages of H2-O2 fuel cell over ordinary cell.
66. Suggest two materials other than hydrogen that can be used as fuels in fuel cells.
67. Define Corrosion. How it is prevented.

UNIT : 3. CHEMICAL KINETICS (7 MARKS)

68. Define the term rate of reaction. Explain the difference between average rate &
Instantaneous rate of reaction
69. For the reaction 2N2O5(g)4NO2 (g)+ O2 (g) the rate of formation of NO2(g) is 2.8 x
10-3Ms-1.Calcualte the rate of disappearance of N2O5(g)
70. Explain the term rate law. Define rate constant.
71. Define Order of reaction. Give the units of rate constant for zero, first & second order
reaction.
72. Identify the reaction order from of the following rate constants. (i) k = 2.3 x 10-5 L mol-
 1 -1
s
(ii) k = 3 x10-4 s-1
73. Calculate the overall order of a reaction which has the rate expression (a) Rate = k [A] 1/2
[B] 3/2
74. A reaction is first order in A and second order in B. (a)How is the rate affected when
concentration of B is tripled. (b)How is the rate affected when the concentration of
both A and B is doubled?
75. A reaction is second order with respect to a reactant. How is the rate of
reaction affected if the concentration of the reactant is(i) doubled (ii) reduced
to half ?

76. For the reaction A B the rate becomes 27 times when the concentration of A is
increased 3 times. What is the order of reaction?
77. For the reaction A  B , the rate of reaction becomes three times when the
concentration of A is increased nine times. What is the order of the reaction ?
78. The decomposition of NH3 on platinum surface is zero order reaction. What are the
rates of production of N2 and H2 if k = 2.5 x 10-4 mol L-1 S-1?
79. Explain the tem Molecularity with example.
80. Mention the factors that affect the rate of a chemical reaction.
81. For a certain chemical reaction 2A + B - C+D The following result has been obtained :
Experiment [A] mol L-1 [B] mol L-1 Initial rate mol L-1min-1
I 0.1 0.1 6.0 x 10-3
II 0.3 0.2 7.2 x 10-2
III 0.3 0.4 2.88 x 10-1
IV 0.4 0.1 2.40 x 10-2
Determine the rate law and rate constant for the reaction
82. What are pseudo first order reactions? Give one example of such reaction.
83. A first order reaction have a rate constant. k = 5.5 x 10-4 s-1 . Find the half-life of the
reaction.
84. Show that in a first order reaction, time required for completion of 99.9% is 10 times
of half-life (t1/2) of the reaction.
85. For a first order reaction, show that time required for 99% completion is twice the time
required for the completion of 90% of reaction.
86. The rate constant for a first order reaction is 60 s–1. How much time will it take to
reduce the initial concentration of the reactant to its 1/16th value?
87. A first order reaction takes 40 min for 30% decomposition. Calculate t1/2.
88. A reactant has a half life of 10 min.(i)Calculate the rate constant for the first order
reaction (ii) what fraction of the reactant will be left after an hour of the reaction has
occurred.
89. For the first order thermal decomposition C2H5Cl(g) C2H4(g) + HCl (g). Calculate the
rate constant.
Experiment Time Pressure (atm)
 1 0 0.30
2 300 0.50
90. What is the effect of temperature on the rate constant of a reaction? How can this
temperature effect on rate constant be represented quantitatively?
91. The rate of a reaction quadruples when the temperature changes from 293 K to
313 K. Calculate the energy of activation of the reaction assuming that it does not
change with temperature.
92. The rate constants of a reaction at 500K and 700K are 0.02s–1 and 0.07s–1
respectively. Calculate the values of Ea and A.

93. The Rate constant for the first order reaction is given by
following equation Calculate Ea for this reaction and rate
constant k if its half period be 200 min.
94. The decomposition of hydrocarbon follows the equation k = (4.5 × 1011s–1) e-28000K/T
Calculate Ea.
95. Define the terms : (i) Threshold Energy (ii) Activated Complex (iii) Activation energy
96. What is the effect of adding a catalyst on (i)Activation energy (ii)Gibbs Energy
MCQ Chapter 3 ELECTROCHEMISTRY class 12 HASIN AHMED Dekho seekho jano 9425761832
S.N. Question ANS
1
Which cell will measure standard electrode potential of copper electrode?
(i)Pt(s) H2(g,0.1 bar) H+(aq.,1 M) Cu2+(aq.,1M)Cu (ii) Pt(s) H2 (g, 1 bar) H+ (aq.,1 M) Cu2+ (aq.,2 M) Cu
(iii)Pt(s) H2(g, 1 bar) H+(aq.,1 M) Cu2+(aq.,1 M)Cu (iv) Pt(s) H2 (g, 1 bar) H+(aq.,0.1 M) Cu2+ (aq.,1 M) Cu
2
Electrode potential for Mg electrode varies according to the equation
EMg2+/Mg = EᶱMg2+/Mg – 0.0591/2 log1/[Mg2+ ] . The graph of EMg2+/Mg Vs log [Mg2+] is

3
Which of the following statement is correct?
(i) ECell and ∆rG of cell reaction both are extensive properties.
(ii) ECell and ∆rG of cell reaction both are intensive properties.
(iii) ECell is an intensive property while ∆rG of cell reaction is an extensive property.
(iv) ECell is an extensive property while ∆rG of cell reaction is an intensive property.
4
The difference between the electrode potentials of two electrodes when no current is drawn
through the cell is called ___________.
(i) Cell potential (ii) Cell emf (iii) Potential difference (iv) Cell voltage
5
Which of the following statement is not correct about an inert electrode in a cell?
(i) It does not participate in the cell reaction. (ii) It provides surface for oxidation or for the reduction.
(iii) It provides a surface for conduction of electrons. (iv) It provides a surface for a redox reaction
6
An electrochemical cell can behave like an electrolytic cell when ____________.
(i) Ecell = 0 (ii) Ecell > Eext (iii) Eext > Ecell (iv) Ecell = Eext
7
Which of the statements about solutions of electrolytes is not correct?
(i) The conductivity of the solution depends upon the size of ions.
(ii) Conductivity depends upon the viscosity of the solution.
(iii) Conductivity does not depend upon solvation of ions present in solution.
(iv) The conductivity of the solution increases with temperature.
8
Using the data given below to find out the strongest reducing agent.
EᶱCr2O72-/Cr3+ = 1.33V EᶱMnO4–/Mn2+ = 1.51V EᶱCl2/Cl– = 1.36V EᶱCr3+/Cr = -0.74V
(i) Cl– (ii) Cr (iii) Cr3+ (iv) Mn
9
Use the data given in Q.8 and find out which of the following is the strongest oxidising agent.
(i) Cl– (ii) Mn2+ (iii) MnO4– (iv) Cr3+
10
Using the data given in Q.8 find out in which option the order of reducing power is correct.
(i) Cr3+ < Cl–< Mn2+ < Cr (ii) Mn2+ < Cl–< Cr3+ < Cr
(iii) Cr3+ < Cl–< Cr2O72– < MnO4– (iv) Mn2+ < Cr3+ < Cl–< Cr
11
Use the data given in Q.8 and find out the most stable ion in its reduced form.
(i) Cl– (ii) Cr3+ (iii) Cr (iv) Mn2+
12
Use the data of Q.8 and find out the most stable oxidised species.
(i) Cr3+ (ii) MnO4– (iii) Cr2O72 (iv) Mn2+
13
The quantity of charge required to obtain one mole of aluminium from Al2O3 is______.
(i) 1F (ii) 6F (iii) 3F (iv) 2F
14
The cell constant of a conductivity cell _____________.
(i) changes with the change of electrolyte. (ii) changes with change of concentration of electrolyte.
(iii) changes with the temperature of the electrolyte. (iv) remains constant for a cell.
15
While charging the lead storage battery ______________.
(i) PbSO4 anode is reduced to Pb. (ii) PbSO4 cathode is reduced to Pb.
(iii) PbSO4 cathode is oxidised to Pb. (iv) PbSO4 anode is oxidised to PbO2
16
˄0m(NH4OH) is equal to ______________.
(i) ˄0m(NH4OH) + ˄0m(NH4Cl) – ˄0(HCl) (ii) ˄0m(NH4Cl) + ˄0m(NaOH) – ˄0(NaCl)
(iii) ˄0m(NH4Cl) + ˄0m(NaCl) – ˄0(NaOH) (iv) ˄0m(NaOH) + ˄0m(NaCl) – ˄0(NH4Cl)
17
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will
occur at anode?
(i) Na+(aq) + e– → Na (s); E°Cell = –2.71V (ii)2H2O (l) → O2(g) + 4H+(aq) + 4e– : E°Cell = 1.23V
(iii) H+(aq) + e–→1/2H2 (g); E°Cell = 0.00V (iv) Cl–(aq) →1/2Cl2(g) + e– ; E°Cell = 1.36V
18
Multiple Choice Questions (Type-II)
Note: In the following questions two or more than two options may be correct.
18. The positive value of the standard electrode potential of Cu2+/Cu indicates that ________.
(i) this redox couple is a stronger reducing agent than the H+/H2 couple.
(ii) this redox couple is a stronger oxidising agent than H+/H2.
(iii) Cu can displace H2 from acid. (iv) Cu cannot displace H2 from acid.
19
E°Cell for some half cell reactions are given below. Based on these mark the correct answer.
(a) H+(aq) + e– →1/2H2(g) ; E°cell = 0.00V (b) 2H2O (l) → O2 (g) + 4H+(aq) + 4e–: E°cell = 1.23V
(c) 2SO42– (aq) → S2O82– (aq) + 2e– ; E°cell = 1.96V
(i) In dilute sulphuric acid solution, hydrogen will be reduced at the cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidised at the anode.
(iii) In dilute sulphuric acid solution, water will be oxidised at the anode.
(iv) In dilute sulphuric acid solution, SO42– ion will be oxidised to tetrathionate ion at the anode.
20
E°Cell = 1.1V for Daniel cell. Which of the following expressions are correct description of state
of equilibrium in ths cell?
(i) 1.1 = Kc (ii) 2.303RT/2F logKc = 1.1 (iii) log Kc = 2.2/0.059 (iv) log Kc = 1.1
21
Conductivity of an electrolytic solution depends on ____________.
(i) nature of electrolyte. (ii) the concentration of electrolyte.
(iii) power of AC source. (iv) distance between the electrodes.
22
˄0m(H2O) is equal to ______________.
(i) ˄0m(HCl) + ˄0m(NaOHl) – ˄0m(NaCl) (ii) ˄0m(HNO3) + ˄0m(NaNO3) – ˄0m(NaOH)
(iii) ˄0m(HNO3) + ˄0m(NaOH) – ˄0m(NaNO3) (iv) ˄0m(NH4OH) + ˄0m(HCl) – ˄0m(NH4Cl)
ANSWERS - solution
1 (IIi) 2(iI) 3 (iii) 4 (ii), 5 (iv) 6 (iii) 7 (iii) 8 (ii) 9 (iii) 10 (ii) 11 (iv)
12 (i) 13 (i) 14 (iv) 15 (i) 16 (ii) 17 (iv) 18 (ii) ,iv
(iii) 19 (i) (iii) 20 (ii) 21 (I) (ii) 22 (i) (III)
HASIN AHMED Dekho seekho jano 9425761832 KV 3 EME CENTRE BAIRAGARH
MCQ Chapter 3 CHEMICAL KINETICS class 12 HASIN AHMED Dekho seekho jano 9425761832
S.N. Question ANS
1
The role of a catalyst is to change ______________.
(i) gibbs energy of reaction. (ii)enthalpy of reaction. (iii)Ea of reaction. (iv) equilibrium contant
In the presence of a catalyst, the heat evolved or absorbed during the reaction ___________.
2
(i) increases. (ii) decreases. (iii) remains unchanged. (iv) may increase or decrease.
3
Activation energy of a chemical reaction can be determined by _____________.
(i) determining the rate constant at standard temperature. (ii) determining the rate constants at two temp.
(iii) determining the probability of collision. (iv) using catalyst.
4
Consider Fig. 4.1 and mark the correct option.
(i) The activation energy of forwarding reaction is E1 + E2 and the product is less stable than reactant.
(ii) The activation energy of forwarding reaction is E1+E2and product is more stable than reactant.
(iii) The activation energy of both forward and backward reaction is E1+E2 and reactant is more stable than
the product.
(iv) The activation energy of the backward reaction is E1 and the product is more stable than reactant.

5
Consider a first order gas phase decomposition reaction given: A(g) → B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of
the system increased by x units and became ‘pt The rate constant k for the reaction is given as _______.
(i) k = 2.303/t log Pi/Pi-x (ii) k = 2.303/t log Pi/2Pi-Pt
(iii) k = 2.303/t log Pi/2Pi-2Pt (iv) k = 2.303/t log Pi/Pi+x
6
According to Arrhenius equation rate constant k is equal to A e–E /RT a. Which of the following
options represents the graph of ln k vs 1/T

7
Consider the Arrhenius equation given below and mark the correct option. a–E /RT k = A e
(i) Rate constant increases exponentially with increasing activation energy and decreasing emperature.
(ii) Rate constant decreases exponentially with increasing activation energy and decreasing temperature.
(iii) Rate constant increases exponentially with decreasing activation energy and decreasing temperature.
(iv) Rate constant increases exponentially with decreasing activation energy and increasing temperature
8
A graph of volume of hydrogen released vs time for the reaction between zinc and dil.HCl is given in
Fig. 4.2. On the basis of this mark the correct option.

(i) Average rate up to 40s is V3-V2/40 (ii) Average rate up to 40s is V3-V2/40-30
(ii) Average rate up to 40 seconds is V3/40 (iv) Average rate up to 40 seconds is V3-V1/40-20
9
Which of the following statements is not correct about an order of a reaction.
(i) The order of a reaction can be a fractional number. (ii) Order of reaction is experimentally determined quantity.
(iii) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in the balanced
chemical equation for a reaction.
(iv) The order of a reaction is the sum of the powers of the molar concentration of the reactants in the rate law
expression.
10
Consider the graph given in Fig. 4.2. Which of the following options does not show the instantaneous rate of
reaction at 40th second? (i) V5-V2/50-30 (ii) V4-V2/50-30 (iii) V3-V2/40-30 (iv) V3-V1/40-20
11
Which of the following statements is correct?
(i) The rate of a reaction decreases over time as the concentration of reactants decreases.
(ii) The rate of a reaction is the same at any time during the reaction.
(iii) The rate of a reaction is independent of temperature change.
(iv) The rate of a reaction decreases with increase in the concentration of the reactant(s).
12
Which of the following expressions is correct for the rate of reaction given below?
5Br–(aq) + BrO3–(aq) + 6H+(aq) → 3Br2(aq) + 3H2O(l)

13
Which of the following graph represents the exothermic reaction?

(i) (a) only (ii) (b) only (iii) (c) only (iv) (a) and (b)
14
The rate law for the reaction A + 2B → C is found to be Rate = k [A][B] The concentration of reactant ‘B’ is
doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be______.
(i) the same (ii) doubled (iii) quadrupled (iv) halved
15
Which of the following statements is incorrect about the collision theory of chemical reaction?
(i) It considers reacting molecules or atoms to be hard spheres and ignores their structural features.
(ii) A number of effective collisions determine the rate of reaction.
(iii) The collision of atoms or molecules having sufficient threshold energy results into product formation.
(iv) Molecules collide with sufficient threshold energy and proper orientation for the collision to be effective.
16
A first-order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100% completion?
(i) 1.26 × 1015 s (ii) 2.52 × 1014 s (iii) 2.52 × 1028 s (iv) infinite
17
). Following results were obtained.
Choose the correct option for the rate equations for this reaction.
Experiment Initial Concentration of Initial concentration of Initial concentration of [C]/molL-1S-1
[A]/ molL-1 [B]/ molL-1

1 0.30 0.30 0.10

2 0.30 0.60 0.40
3 0.60 0.30 0.20

(i) Rate = k [A]2[B] (ii) Rate = k [A] [B]2 (iii) Rate = k [A] [B] (iv) Rate = k [A]2[B]0
18
Which of the following statement is not correct for the catalyst?
(i) It catalyses the forward and backward reaction to the same extent. (ii) It alters ∆G of the reaction.
(iii) It is a substance that does not change the equilibrium constant of a reaction.
(iv) It provides an alternate mechanism by reducing activation energy between reactants and products.
19
The value of rate constant of a pseudo first order reaction ____________.
(i) depends on the concentration of reactants present in a small amount.
(ii) depends on the concentration of reactants present in excess.
(iii) is independent of the concentration of reactants. (iv) depends only on temperature.Solution:
20
Consider the reaction A B. The concentration of both the reactants and the products varies exponentially
with time. Which of the following figures correctly describes the change in concentration of reactants and
products with time?

ANSWERS - solution
1 (iii) 2(iii) 3 (ii) 4 (i), 5 (ii) 6 (i) 7 (i) 8 (iii) 9 (ii) 10 (iii)
11 (iii) 12 (iii) 13 (i) 14 (i) 15 (iii) 16 (iv) 17 (ii) 18 (ii) 19 (ii) 20 (iii)
HASIN AHMED Dekho seekho jano 9425761832 KV 3 EME CENTRE BAIRAGARH
MCQ Chapter 2 solution class 12 HASIN AHMED Dekho seekho jano 9425761832
S.N. Question ANS
1 Which of the following units is useful in relating concentration of solution with its vapour pressure?
(i) mole fraction (ii) parts per million (iii) mass percentage (iv) molality
On dissolving sugar in water at room temperature solution feels cool to touch. Under which of the following
2 cases dissolution of sugar will be most rapid?
(i) Sugar crystals in cold water. (ii) Sugar crystals in hot water.
(iii) Powdered sugar in cold water. (iv) Powdered sugar in hot water.
3 At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is __________.
(i) less than the rate of crystallization (ii) greater than the rate of crystallisation
(iii) equal to the rate of crystallization (iv) zero
4 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount of ‘A’ is
added to the solution. The solution is _________.
(i) saturated (ii) supersaturated (iii) unsaturated (iv) concentrated
5 Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not
depend upon ____________.
(i) Temperature (ii) Nature of solute (iii) Pressure (iv) Nature of solvent
6 Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ____________.
(i) low temp (ii) low atmosp pressure (iii) high atmosp pressure (iv) both low temp & high atmosp pressure
7 Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show
a positive deviation from Raoult’s law?
(i) Methanol and acetone. (ii) Chloroform and acetone. (iii) Nitric acid and water. (iv) Phenol and aniline.
8 Colligative properties depend on ____________.
(i) the nature of the solute particles dissolved in solution. (ii) the number of solute particles in solution.
(iii) the physical properties of the solute particles dissolved in solution. (iv) the nature of solvent particles.
9 Which of the following aqueous solutions should have the highest boiling point?
(i) 1.0 M NaOH (ii) 1.0 M Na2SO4 (iii) 1.0 M NH4NO3 (iv) 1.0 M KNO3
10 The unit of ebulioscopic constant is _______________.
(i) K kg mol–1 (ii) mol kg K–1 (iii) kg mol–1 K (iv) K mol kg–1
11 In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is __
(i) the same (ii) about twice (iii) about three times (iv) about six times
12 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _____________.
(i) it gains water due to osmosis. (ii) it loses water due to reverse osmosis.
(iii) it gains water due to reverse osmosis. (iv) it loses water due to osmosis.
13 At a given temperature, osmotic pressure of a concentrated solution of a substance _____________.
(i) is higher than that at a dilute solution. (ii) is lower than that of a dilute solution.
(iii) is same as that of a dilute solution. (iv) cannot be compared with osmotic pressure of dilute solution.
14 14. Which of the following statements is false?
(i) Two different solutions of sucrose of same molality prepared in different solvents will have the same depression in
freezing point.
(ii) The osmotic pressure of a solution is given by the equation Π = CRT ( where C is the molarity of the solution).
(iii) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium chloride, acetic
acid and sucrose is BaCl2 > KCl > CH3COOH > sucrose.
(iv) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is directly proportional
to its mole fraction in the solution.
15 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are _____________.
(i) 2, 2 and 2 (ii) 2, 2 and 3 (iii) 1, 1 and 2 (iv) 1, 1 and 1
16 Which of the following statements is false?
(i) Units of atmospheric pressure and osmotic pressure are the same.
(ii) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower
concentration of solute to a region of higher concentration.
(iii) The value of molal depression constant depends on nature of solvent.
(iv) Relative lowering of vapour pressure, is a dimensionless quantity.
17 Value of Henry’s constant KH ____________.
(i) increases with increase in temperature. (ii) decreases with increase in temperature.
(iii) remains constant. (iv) first increases then decreases.
18 The value of Henry’s constant KH is _____________.
(i) greater for gases with higher solubility. (ii) greater for gases with lower solubility.
(iii) constant for all gases. (iv) not related to the solubility of gases.
19

Consider the Fig. 2.1 and mark the correct option. Side A side B

(i) water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on piston (B).
(ii) water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied on piston (B).
(iii) water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on piston (B).
(iv) water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston (A).
20 We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 0.01M and
0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the order______.
(i) i A< iB< iC (ii) iA> iB> iC (iii) iA= iB= iC (iv) iA< iB> iC
21 On the basis of information given below mark the correct option. Information:
(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B
type interactions.
(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type
(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type
(i) Solution (B) and (C) will follow Raoult’s law. (ii) Solution (A) will follow Raoult’s law.
(iii) Solution (B) show -ve deviation from Raoult’s law. (iv) Solution (C) show +ve deviation from Raoult’s law.
22 Two beakers of capacity 500 mL were taken. One of these beakers, labelled as “A”, was filled with 400 mL water
whereas the beaker labelled “B” was filled with 400 mL of 2 M solution of NaCl. At the same temperature both
the beakers were placed in closed containers of same material and same capacity as shown in Fig. 2.2.
At a given temperature, which of the following statement is correct about the vapour pressure of pure water and that
of NaCl solution.
(i) vapour pressure in container (A) is more than that in container (B).
(ii) vapour pressure in container (A) is less than that in container (B).
(iii) vapour pressure is equal in both the containers.
(iv) vapour pressure in container (B) is twice the vapour pressure in container (A).
23 If two liquids A and B form minimum boiling azeotrope at some specific composition then _______________.
(i) A–B interactions are stronger than those between A–A or B–B.
(ii) vapour pressure of solution increases because more number of molecules of liquids A and B can escape from the
solution
(iii) vapour pressure of solution decreases because less number of molecules of only one of the liquids escape from the
solution.
(iv) A–B interactions are weaker than those between A–A or B–B.
24 24. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the
resultant solution is _____________ (i) 0.004 (ii) 0.008 (iii) 0.012 (iv) 0.016
25 On the basis of information given below mark the correct option.
Information : On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.
(i) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show +ve deviation
(ii) At specific composition methanol-acetone mixture forms maximum boiling azeotrope and will show +ve deviation
(iii) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show -ve deviation
(iv) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show -ve deviation
26 KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83×10–5and 0.413 respectively.
Arrange these gases in the order of their increasing solubility.
(i) HCHO < CH4 < CO2< Ar (ii) HCHO < CO2 < CH4 < Ar (iii) Ar < CO2 < CH4 < HCHO (iv) Ar < CH4 < CO2 < CHO
27 II. Multiple Choice Questions (Type-II) Note : In the following questions two or more options may be correct.
Which of the following factor (s) affect the solubility of a gaseous solute in the fixed volume of liquid solvent?
(a) nature of solute (b) temperature (c) pressure
(i) (a) and (c) at constant T (ii) (a) and (b) at constant P
(iii) (b) and (c) only (iv) (c) only
28 Intermolecular forces between two benzene molecules are nearly of same strength as those between two
toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero (ii) ∆mix V = zero
(iii) These will form minimum boiling azeotrope. (iv) These will not form ideal solution.
29 Relative lowering of vapour pressure is a colligative property because _____________.
(i) It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of the
solute molecules.
 (ii) It depends on number of particles of electrolyte solute in solution and does not depend on the nature of the solute
particles.
(iii) It depends on the concentration of a non electrolyte solute in solution as well as on the nature of the solute
molecules.
(iv) It depends on the concentration of an electrolyte or nonelectrolyte solute in solution as well as on the nature of
solute molecules.
30 Van’t Hoff factor i is given by the expression _____________.
(i) I = Normal molar mass
Abnormal molar mass
(ii) I = Abnormal molar mass
Normal molar mass
(iii) I = Observed colligative property
Calculated colligative property
(iv) I = Calculated colligative property
Observed colligative property
31 Isotonic solutions must have the same _____________.
(i) solute (ii) density (iii) elevation in boiling point (iv) depression in freezing point
32 Which of the following binary mixtures will have same composition in liquid and vapour phase?
(i) Benzene – Toluene (ii) Water-Nitric acid (iii) Water-Ethanol (iv) n-Hexane - n-Heptane
33 In isotonic solutions ________________.
(i) solute and solvent both are same. (ii) osmotic pressure is same.
(iii) solute and solvent may or may not be same. (iv) solute is always same solvent may be different.
34 For a binary ideal liquid solution, the variation in total vapour pressure versus composition of solution is given by

35 Colligative properties are observed when _____________.

(i) a non volatile solid is dissolved in a volatile liquid. (ii) a non volatile liquid is dissolved in another volatile liquid.
(iii) a gas is dissolved in non volatile liquid. (iv) a volatile liquid is dissolved in another volatile liquid.
Note : In the following questions a statement of assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices.
(i) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(ii) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
(iii) Assertion is correct statement but reason is wrong statement.
(iv) Assertion and reason both are incorrect statements.
(v) Assertion is wrong statement but reason is correct statement.
36 Assertion : Molarity of a solution in liquid state changes with temperature.
Reason : The volume of a solution changes with change in temperature.
37 Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.
38 Assertion : When NaCl is added to water a depression in freezing point is observed.
Reason : The lowering of vapour pressure of a solution causes depression in the freezing point.
39 Assertion : When a solution is separated from the pure solvent by a semipermeable membrane, the solvent
molecules pass through it from pure solvent side to the solution side.
Reason : Diffusion of solvent occurs from a region of high concentration solN to a region of low concentration solution.
40 Assertion : osmosis is colligative property.
Reason : Reverse osmosis is used for desalination of water.
Q 27 to 35 are for learning as in CBSE only one correct answer will be correct.
ANSWERS - solution
1 (i) 2(iv) 3 (iii) 4 (ii), 5 (iii) 6 (ii) 7 (i) 8 (ii) 9 (ii) 10 (i)
11 (iii) 12 (iv) 13 (i) 14 (i) 15 (ii) 16 (ii) 17 (i) 18 (ii) 19 (ii) 20 (iii)
21 (ii) 22 (i) 23 (i) 24 (iv) 25 (ii) 26 (iii) 27 (i), (ii) 28 (iii), (iv) 29 (i), (ii) 30 (i), (iii)
31(ii), (iii) 32 (ii), (iii) 33 (ii), (iii) 34 (i), (iv) 35 (i), (ii) 36 (i) 37 (iv) 38 (i) 39 (ii) 40 (V)
HASIN AHMED Dekho seekho jano 9425761832 KV 3 EME CENTRE BAIRAGARH
 Class – XII
Computer Science (083)
Note:- Execute the following question in an SQL application. Copy the question along with the output
and your answer into a Word document. Then, print out the document and bring a hard copy.

1
AIM: To write Queries for the following Questions based on the given table.

Rollno Name Gender Age Dept DOA Fees

1 Arun M 24 COMPUTER 1997-01-10 120
2 Ankit M 21 HISTORY 1998-03-24 200
3 Anu F 20 HINDI 1996-12-12 300
4 Bala M 19 NULL 1999-07-01 400
5 Charan M 18 HINDI 1997-09-05 250
6 Deepa F 19 HISTORY 1997-06-27 300
7 Dinesh M 22 COMPUTER 1997-02-25 210
8 Usha F 23 NULL 1997-07-31 200

(a) Write a Query to Create a new database in the name of "STUDENTS".

(b) Write a Query to Open the database "STUDENTS".

(c) Write a Query to create the above table called: "STU"

(d) Write a Query to list all the existing database names.

2. To write Queries for the following Questions based on the given table:

Rollno Name Gender Age Dept DOA Fees

1 Arun M 24 COMPUTER 1997-01-10 120
2 Ankit M 21 HISTORY 1998-03-24 200
3 Anu F 20 HINDI 1996-12-12 300
4 Bala M 19 NULL 1999-07-01 400
5 Charan M 18 HINDI 1997-09-05 250
6 Deepa F 19 HISTORY 1997-06-27 300
7 Dinesh M 22 COMPUTER 1997-02-25 210
8 Usha F 23 NULL 1997-07-31 200

(a) Write a Query to insert all the rows of above table into Info table.

(b) Write a Query to display all the details of the Employees from the above table
'STU'.

(c) Write a query to Rollno, Name and Department of the students from STU table.
 (d) Write a Query to select distinct Department from STU table.

(e) To show all information about students of History department.

3. To write Queries for the following Questions based on the given table:
Rollno Name Gender Age Dept DOA Fees
1 Arun M 24 COMPUTER 1997-01-10 120
2 Ankit M 21 HISTORY 1998-03-24 200
3 Anu F 20 HINDI 1996-12-12 300
4 Bala M 19 NULL 1999-07-01 400
5 Charan M 18 HINDI 1997-09-05 250
6 Deepa F 19 HISTORY 1997-06-27 300
7 Dinesh M 22 COMPUTER 1997-02-25 210
8 Usha F 23 NULL 1997-07-31 200

(a) Write a Query to list name of female students in Hindi Department.

(b) Write a Query to list name of the students whose ages are between 18 to 20.
(c) Write a Query to display the name of the students whose name is starting with
'A'.

(d) Write a query to list the names of those students whose name have second
alphabet 'n' in theirnames.
4. To write Queries for the following Questions based on the given table:

Rollno Name Gender Age Dept DOA Fees

1 Arun M 24 COMPUTER 1997-01-10 120
2 Ankit M 21 HISTORY 1998-03-24 200
3 Anu F 20 HINDI 1996-12-12 300
4 Bala M 19 NULL 1999-07-01 400
5 Charan M 18 HINDI 1997-09-05 250
6 Deepa F 19 HISTORY 1997-06-27 300
7 Dinesh M 22 COMPUTER 1997-02-25 210
8 Usha F 23 NULL 1997-07-31 200

(a) Write a Query to delete the details of Roll number is 8.

(b) Write a Query to change the fess of Student to 170 whose Roll number is 1,
if the existing fessis less than 130.
(c) Write a Query to add a new column Area of type varchar in table STU.

(d) Write a Query to Display Name of all students whose Area Contains NULL.
(e) Write a Query to delete Area Column from the table STU.
(f) Write a Query to delete table from Database.
5. To write Queries for the following Questions based on the given table:
 TABLE: UNIFORM

Ucode Uname Ucolor StockDate

1 Shirt White 2021-03-31
2 Pant Black 2020-01-01
3 Skirt Grey 2021-02-18
4 Tie Blue 2019-01-01
5 Socks Blue 2019-03-19
6 Belt Black 2017-12-09

TABLE: COST

Ucode Size Price Company

1 M 500 Raymond
1 L 580 Mattex
2 XL 620 Mattex
2 M 810 Yasin
2 L 940 Raymond
3 M 770 Yasin
3 L 830 Galin
4 S 150 Mattex

(a)To Display the average price of all the Uniform of Raymond Company from table COST.

(b) To display details of all the Uniform in the Uniform table in descending order of Stock
date.
( c) To Display max price and min price of each company.

(d) To display the company where the number of uniforms size is more than 2.
(e ) To display the Ucode, Uname, Ucolor, Size and Company of tables uniform and cost.