01-06-2025

4001CJA101001250006 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two small balls A and B are launched in the same vertical plane simultaneously, with same speed
of 20 m/s at t = 0. Ball A has an initial horizontal velocity and ball B has initial velocity at an angle θ
above the line joining A and B as shown. If the projectiles collide in mid-air at time t :

(A) θ = 45°
(B) θ = 60°
(C) θ = 30°
(D) θ = 37°

2) A ball is thrown at different angles with the speed u & from the same point such that it has the
same range in both cases. If h1 and h2 are the maximum heights in the two cases then h1 + h2 equals
to :-

(A)

(B)

(C)

(D)

3) There are two inclined planes AO and OB inclined at 45° and 60° respectively with the horizontal
as shown in figure. When a man moves on the inclined plane AO, he observes that the rain drops are
falling at 45° with the vertical. When the man moves on the inclined plane OB, he observes that the
rain drops are falling vertically downward. Then actual speed of rain w.r.t. ground is:
(A)
(B)
(C)
(D) None of these

4) A coin is released inside a lift at a height of 2 m from the floor of the lift. The height of the lift is
10 m. The lift is moving with an acceleration of 11 m/s2 downwards. The time after which the coin
will strike with the lift is :

(A) 4 s
(B) 2 s

(C)
s

(D)

5) If a particle moves in a straight line according to the law x = t3 – 6t2 – 15t, the time interval during
which velocity is negative and acceleration is positive, is

(A) t < 2 and t > 5

(B) 2 < t < 5
(C) –1 < t < 5
(D) –1 < t < 2

SECTION-I (ii)

1) A fixed re-coilless cannon fires a shell with a speed v0, at the same instant a man falls from point
O. The shell hits a point on the wall. Initially shell is aimed towards a point P as shown in figure.
Mark the correct option(s).

(A) The falling man sees the shell move along straight line directed along initial velocity.
Time taken to reach wall is
(B)

(C) For a stationary man shell will strike below P

(D)
Man falls through y = till the shell hits wall.

2) A projectile is thrown horizontal from height 'h' as shown in figure.

vx : Horizontal component of velocity.
vy : Vertical component of velocity.
x : horizontal position.
y : Vertical position.
in figure O is origin

Which of the following graphs are correct ?

(A)

(B)
(C)

(D)

3) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,

then

(A) Value of T is L/4 v

(B) Value of T is L/2 v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4

4) A particle starts moving with initial velocity 3 m/s, along X-axis (from x = 0). Its acceleration
displacement graph is a parabola as shown in figure. At (marked point P on the graph), the
tangent on the curve makes angle 60°, with displacement axis. At this position.

(A)
speed of particle is
(B) acceleration is 1.5 m/s2
(C) speed is m/s
(D) acceleration is 3 m/s2

5) In given three cases 1, 2 and 3, time of flight are T1, T2, T3 respectively then choose correct

relations :

(A) T1 = T2 + T3
(B) T2 = T1 + T3
(C) T1 > T2
(D) T1 > T3

6) River is flowing with a velocity . A boat is moving with a velocity ms–1

relative to river and width of river is 100 m along y direction then :-

(A) The time of crossing is 25 sec.

(B) Velocity of boat w.r.t. ground is ms–1.
(C) Drift of boat is 50 m.
(D) The boat can never cross the river.

7) Two particles are projected from the same point with the same speed, at different angles θ1 and θ2
to the horizontal. They have the same horizontal range. Their times of flights are t1 and t2
respectively then

(A) θ1 + θ2 = 90

(B)

(C)

(D)

8) A particle moves in a straight line with the velocity as shown in the figure. At t = 0, x = –16m.

(A) The maximum value of the position coordinate of the particle is 54m.
(B) The maximum value of the position coordinate of the particle is 36m.
(C) The particle is at the position 36 m at time 18 sec.
(D) The particle is at the position 36 m at time 30 sec.

SECTION-II

1) A body falls freely from the top of a tower. During the last second of its motion, it falls through
9/25 part of the whole distance. Find the height of the tower in meters.

2) A man wishes to cross a river of width 120 m by a motorboat. His rowing speed in still water is 5
m/s. He takes t seconds to cross the river and reach to the point directly opposite to his starting
point. Speed of water is 3 m/s. Find t (in sec).

3) A piece of marble is projected from earth's surface with velocity of 25 m/s. 2 seconds later, it just
clears a wall 5 m high. What is the angle (in degree) of projection with horizontal? (g = 10 m/s2)

4) A body is projected with speed v m/s at angle θ with horizontal .The kinetic energy at the highest
point is half of the initial kinetic energy. The value of θ (in degree ) is :

5) It is raining vertically downwards with a velocity of 3 km h–1. A man walks in the rain with a
velocity of 4 kmh–1. The rain drops will fall on the man with a relative velocity (magnitude)(in kmh–1)
of ;

PART-2 : CHEMISTRY

SECTION-I (i)

1) The (e/m) ratio (charge to mass ratio) is maximum for (among the following) :

(A) Na+
(B) He2+
(C) Mg2+
(D) Ca2+

2) The correct order of energy of following spectral lines in H-atom:

(A) 1 > 3 > 2 > 5 > 4

(B) 3 > 1 > 2 > 4 > 5
(C) 3 > 2 > 1 > 4 > 5
(D) 5 > 4 > 3 > 2 > 1

3) An aqueous solution of acetic acid (CH3COOH) has density and it is 5.0 m. Molarity of
solution will be

(A) 2.25 M
(B) 5 M
(C) 1.41 M
(D) 4.167 M

4) Magnesium & Nitrogen react to give Magnesium Nitride as per the reaction

calculate mass of excess reactant remaining if 48 gm Magnesium is mixed with 48 gm of Nitrogen

gas
(At.wt of Mg = 24, N = 14)

(A) No excess reactant left

(B) 12.6 gm
(C) 29.3 gm
(D) 40.2 gm

5) The diagram below shows a part of the skeleton of the periodic table in which elements are
indicated by letters which are not their usual symbols.

Which one of the

following statement is correct ?

(A) H is alkaline earth metal.

(B) Element J is an inner transition element.
(C) Element R is a gas at room temperature.
(D) Element T is an inert gas with an electronic configuration 1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s2, 4p6.

SECTION-I (ii)

1) Which of the following sets of quantum numbers is/are not possible ?

(A)
n = 4, ℓ = 4, mℓ = –2, ms = +

(B)
n = 3, ℓ = 0, mℓ = 0, ms = –
(C)
n = 3, ℓ = 2, mℓ = –3, ms = –

(D)
n = 5, ℓ = 3, mℓ = 0, ms = +

2) Which of the following is/are true ?

(A) '3s' orbital is spherically symmetrical with two nodes.

(B) has lobes of electron density in xy–plane along x and y–axis.
(C) The radial probability curves of 1s, 3p and 5d have one, two and three peaks respectively.
(D) has zero electro density in xy–plane.

3) Which of the following is/are true for energy of e– in an orbit.

T.E. → Total energy
P.E. → Potential energy
K.E. → Kinetic energy

(A) 2T.E. = P.E.

(B) P.E. = T.E.
(C) Total energy of e– in 1st orbit of He+ ion is –54.4 eV
(D) As orbit number increases K.E. decreases.

4) Select the CORRECT order of first ionisation energy order :-

(A) Na < Mg
(B) N < O
(C) Li < Na
(D) Na < Na+

5) Which of the following is correct order of EA.

(A) N < C < O < F

(B) F > Cl > Br > I
(C) Cl > F > Br > I
(D) C < N < O < F

6) Which of the following oxides/hydroxides are amphoteric in nature.

(A) Cl2O7
(B) Zn(OH)2
(C) Be(OH)2
(D) Li2O

7) Select the incorrect statement(s). Consider NA = 6.02 × 1023 particles/mole. (Assume gases to be
ideal)
 25
(A) Mass of 6.02 × 10 molecule of SO3 is 8 kg.
23
(B) Number of oxygen atoms in 4.8 gm of O3 are 18.06 × 10 .
(C) Mass of 22.7 ml of C2H6 at 1 bar pressure & 273 K is 30 gm.
(D) Volume of 51 mg of NH3 at 1 bar pressure & 273 K is 68.1 litre.

8) The density of a liquid 1.2 gm/mL. There are 25 drops in 2 mL. The number of molecules in one
drop is :
[Given molecular mass of liquid = 50 amu]

(A)

(B)

(C)

(D) 1.2 × 25 NA

SECTION-II

1) An atomic orbital of H atom has the following characteristics. Calculate sum of radial & angular
nodes.
Characteristics I → The graph of radial probability distribution looks like :

Characteristics II → The shape of the orbital is double dumb-bell.

2) A H–like species emitted a photon corresponding to the first line of Lyman series. The photon
+
liberated a photoelectron from He in ground state. The de–Broglie wavelength of the photoelectron
is 2 Å. Calculate of the atomic number of H–like specie.

3) How many of the following species have bigger size than N atom ?
Li, B, C–, O, F, P, As

4) In how many of the following changes ΔH = positive

(i)
(ii)
(iii)
(iv)
5) In a gaseous mixture 2 mol of CO2, 1 mol of H2 and 2 mol of He are present than determine mole
percentage of CO2.

PART-3 : MATHEMATICS

SECTION-I (i)

1) The value of is

(A) 1
(B) 2
(C) 3
(D) 5

2) The smallest value of x + y such that 23x – 32y = 431, where x, y ∈ I, is

(A) 0
(B) 1
(C) 5
(D) 10

3) Sum of twenty terms of the series 1 + (1 + 2) + (1 + 2 + 3) + .... is

(A) 1410
(B) 210
(C) 1305
(D) 1540

4) If the roots of cubic equation are in A.P. with positive integral common
difference, then the maximum value of , is :

(A) 17
(B) 18
(C) 19
(D) 20

5) The roots of quadratic equation x2 – 12x + t = 0 are positive and one of them is square of the
other, if roots are α and β with α > β then

(A) 3α + β – t = 5
(B) 2α + 3β – t = 0
(C) α + β – t = 4
(D) α + 2β – t = 0
 SECTION-I (ii)

1) If ƒ(x) = x2 + 5x + 7, then which of the following is/are correct

(A) ƒ(x) < 0 ∀ x∈ R

(B) ƒ(x) > 1 ∀ x∈ (–∞,–3) ∪ (–2,∞)
(C) ƒ(x) > 3 ∀ x∈ (–∞,–4) ∪ (–1,∞)
(D) ƒ(x) < 13 ∀ x ∈ (–6,1)

2) If α, β and γ are roots of equation x3 – x + 1 = 0, then choose the correct statement(s)

(A) (α + β)(β + γ)(γ + α) = –1

(B) (α - 1)(β - 1)(γ - 1) = –1
(C) (α + β)(β + γ)(γ + α) = 1
(D) (α - 1)(β - 1)(γ - 1) = 1

3) Which of the following statements are True :-

(A)
(B)
(C)
(D)

4) For |x – 1| + |x – 2| = k, we have

(A) infinite solutions for k = 1

(B) no solution for k > 1
(C) two solutions for k > 1
(D) no solution k < 1

5) If log3(a3 + b3 + c3) = 1 + log3abc, then which of the following can be correct :-

(A) a + b + c = 0
(B) a2 + b2 + c2 = ab + bc + ca

(C)

(D) a + b + c = 6, if a,b,c are distinct

6) Given an A.P. whose terms are all positive integers. The sum of its first nine terms is greater then
200 and less then 220. If second term in it is 12, then its

(A) first term = 4

(B) first term = 8
(C) common difference = 4
(D) common difference = 6
7) Let a, b, c, d are all positive real numbers such that a + 2b + 3c + 4d = 10, then correct option(s)
is/are

(A) Maximum value of (a + 2b)(3c + 4d) is 21

(B) Maximum value of (a + 2b)(3c + 4d) is 25
(C) Maximum value of (a + c + 2d)(b + c + d) is 12
(D) Maximum value of (a + c + 2d)(b + c + d) is 12.5

8) If a1, a2, a3, a4, a5 are in H.P. then a1a2 + a2a3 + a3a4 + a4a5 is equal to

(A) 2a1a5
(B) 4a1a5
(C) a1a5
(D) –4

SECTION-II

1)

Sum of 12 terms of series 1.2.3 + 2.3.4 + .... is N, then the value of is :

2) If first terms of an A.P. is 5, last term is 45 and sum is 400, then number of terms in A.P. is :

3) If roots of equation x2 – 5x + 16 = 0 are α, β and roots of equation x2 + px + q = 0 are α2 + β2 and

, then 56p – q equal to

4) Let be the roots of the quadratic equation then value of

is

5) The value of + + is:

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5
A. C B C A B

SECTION-I (ii)

Q. 6 7 8 9 10 11 12 13
A. A,B,C A,C A,C,D A,B A,C,D A,B,C A,B,D A,C,D

SECTION-II

Q. 14 15 16 17 18
A. 125 30 30 45 5

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23
A. B B D C D

SECTION-I (ii)

Q. 24 25 26 27 28 29 30 31
A. A,C A,B,C A,C,D A,D A,C B,C B,C,D A,C

SECTION-II

Q. 32 33 34 35 36
A. 5 3 5 3 40

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41
A. A C D A B

SECTION-I (ii)

Q. 42 43 44 45 46 47 48 49
A. B,C,D B,C B,C A,C,D A,B,C B,C B,D B
 SECTION-II

Q. 50 51 52 53 54
A. 90 16 0 2 890
 SOLUTIONS

PART-1 : PHYSICS

1)

Component of velocity perpendicular to line AB must be equal.

2)

h1 + h2 =

3)

Case-2 :

Vertically so u = 10
So v = 10

4) Relative to lift initial velocity and acceleration of coin are 0 m/s and 1 m/s2 upwards

∴8= t2 or t = 4 second

5) =

⇒ required interval 2 < t < 5

6) For falling mass

 =0

Shell moves in straight line time taken

Due to gravity path is parabola, it strikes below P. Height fallen on by man

7)

vx = v0 = constant
at t = 0 ⇒ vy = 0
x = v0t
at t = 0, y = 0

8)

W.r.to Board

9)
a = Ax2 + Bx

.....(1)
From equ. (1)
10) Use formulas of projectile motion of (1) = motion of (2) + motion (3)

11) Time of crossing =

Absolute velocity of boat (i.e. w.r.t. ground)

Drift of the boat = (4.2) × 25 = 50 m

12)

13)

Area (0 – 24) =
xf – xi = 20 + 32 + 18
xf + 16 = 70
xf = 54
Area (0 – 18) = 20 + 32 = 52
= xf + 16 = 36

14)

But t > 1s so t = 5 s

15)

For shortest path

 120 = 5 cosθ. t
5 sinθ = 3

sinθ = ⇒ θ = 37°

120 = 5 × ×t
t = 30s

16)
in t = 2 sec
Sy = 5m
vy = 25 sinθ
ay = –g

5 = 25sinθ × 2 – × 10 × (2)2
5 = 50sinθ – 5 × 4
25 = 50 sinθ

sinθ = θ = 30°

17)

⇒ | vx | = | vy | ⇒ 45°

18)

VRH = = = 5 km/h Ans.

PART-2 : CHEMISTRY
19)

The charge/mass ratio is given by the formula =

(I) For Na+, =

(II) For He2+ =

(III) For mg2+ =

(IV) For Ca2+ =

Ans. - (B)

20) ΔE = 13.6 × z2

1.

2.

3.

4.

5.

21) Mass of solvent = 1000 g

Mass of solute = 5×60 = 300g
Mass of solution = 1000 + 300 = 1300 g

Volume of solution =

M=

22) Balanced reaction

nMg = 2 mol, mol

∴ L.R. is Mg, hence N2 remaining =

23) Element T is Kr.

24) In option (A) ‘ℓ’ cannot be equal to ‘n’ because values of ‘ℓ’ lie between 0, 1, 2, 3,.....(n – 1)
In option (C) mℓ cannot be –3 for ℓ = 2 because
mℓ = –1, ——— 0 ——— + ℓ

25) Number of nodes = n – 1.

26) P.E. = 2.T.E.

28)

EA ⇒ Cl > F,
N<C

31) Molecules = Mole × NA

32) Radial + angular node = 3 + 2 = 5

33)

K.E. of photoelectron = 37.5 eV

∴ Amount of energy required to liberated electron = 54.5 eV
Total energy of photon = 54.4 + 37.5 = 91.9 eV
Also 10.2 z2 = 91.9 (as for H–atom energy of first line of Lyman series = 10.2 eV)
z=3

34) Li, B, C–, P, As

 35) Be(g) → Be–(g) ΔH = +ve
–
N(g) → N (g) ΔH = +ve
– 2–
O (g) → O (g) ΔH = +ve
F(g) → F–(g) ΔH = (–)ve

36) %CO2 =

PART-3 : MATHEMATICS

37)

x3 + 3x – 4 = 0
(x – 1)(x2 + x + 4) = 0
∴x=1

38) 8x – 9y = 431
9y = 8x – 431 put x = 3
9y = 512 – 431 = 81
y=2

39) Tn = 1 + 2 + 3 + ..... + n

Now

40) Suppose a – d, a , a + d are roots of the given equation

roots are 2 – d, 2, 2 + d are the roots and 2. (2 – d) + 2 . (2 + d) + 2 – d) (2 + d) = β1

and

Hence
when d = 1

41) x2 – 12x + t = 0 roots are α, β

α + β = 12 αβ = t
α+β=9+3 9×3=t
⇒ α = 9, β = 3 t = 27

42) A) ƒ(x) > 0 ∀ x ∈ R as D = 25 – 28 < 0

(B) ƒ(x) > 1 ⇒ x2 + 5x + 7 > 1 ;
x2 + 5x + 6 > 0 ; (x + 3)(x + 2)
⇒ x < –3 ; x > –2
(C) ƒ(x) > 3
x2 + 5x + 7 > 3
(x2 + 5x + 4) > 0
(x + 1)(x + 4) > 0
⇒ x < –4 ; x > –1
(D) Similarly

43) x3 – x + 1 = (x – α)(x – β)(x – γ)

Put x = 1 & x = –1
&α+β+γ=0

44) Obious

45)

46) By solving a3 + b3 + c3 = 3abc and only options A,B,C are correct.

47) 200 < Sq < 220

...(i)
and a + d = 12 ...(ii)
from (i) and (ii)

⇒ d = 4 (∵ all terms are integer)

∴a=8

48) a + 2b + 3c + 4d = 10
⇒ (a + 2b)(3c + 4d) ≤ 25 ...(1)

⇒ ...(2)

49) a1a2 + a2a3 + a3a4 + ... + an–1an = (n – 1)a1an

50) 1.2.3 + 2.3.4 + ........

Tn = n(n + 1) (n + 2)

S12 = 782 + 1950 + 156 = 8190

N = S12 = 8190,

51) a = 5, ℓ = 45
Let common difference = d
a + (n – 1)d = 45
Sn = 400

[a + ℓ] = 400

[5 + 45] = 400
n = 16

52) α + β = 5
αβ = 16
α2 + β2 = (α + β)2 – 2αβ = –7

54)

=
= 625 + 216 + 49 = 890.