SCHOLAR SPECTRA

NEET MODEL
EXAMINATION
CODE-B
 SECTION – I (PHYSICS)
T2 9. (2) Every planet revolve around the sun in an elliptical
1. (2) ML2 T -3 = path and gravitational force acting on the planet is
b L
T2 directly proportional to the product of mass of the
b= = M −1L-3 T 5 planet (m) and mass of sun (M) and inversely
ML T −3  L
2

proportional to the square of distance (r) between sun

[a .b] = M−1L-3T5  T2 = [M−1L-3T7 ]
and planet.
 x  2x 
2. (4) g d = g 1 −  ; g h = g 1 −  Mm GMm
 R  R i.e. F  2  F = 2
r r
 g h = 2g d for same x
When a planet revolve around the sun, then centripetal
3. (2) (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii)
force acting on the planet is directed towards the sun.
L 
(i)  LC  =  RC  = T 2 Thus, statement C is incorrect.
R  According to Kepler's third law.
2
L  V  W 
(ii )  LC  =  R 2  = T [ R 2 ] = T   = T   T2  a3
R  I   QI 
2
 ML2T −2  3RT
W  10.
=T 2  =T 2 4 −5 −4
=M LT A  M = 3
I t  AT 
2 (3) rms =
 av 8RT 8
 Heat  ML2T −2 M
(iii )  H  =  = = L2T −2
 Mass  M
11. 1
(2) In isothermal process p 
−2
  ML T V
2
Heat
(iv)  s  =  2 −2
 = MK = L T K
−1

 Mass × temperature  Hence, graph between p and V is a hyperbola.

4. (2) With respect to an observer on the ground,
trajectory will be parabolic.
12. (1) On increasing temperature, the viscosity of liquid
5. (4)
decreases and that of gas increases.
In UCM, acceleration vector is directed towards the
centre 13. (1) t  ( H1 − H 2 )
6. (3) Friction force between block A and block B and
between block B and surface will oppose the F. H
 F = FAB + FBS H−
t1 2 = 2 −1
=
=  AB mA g +  BS (mA + mB ) g t2 H
− 0
= 0.2 100 10 + 0.3(100 + 200)10 2
= 200 + 900 = 1100 N 2T cos 
14. (1) h =
This is the required minimum force to move the block rg
B.
−GM (
7. (2) So, mg – T = mR … (i) (4) V = r  R)
As torque = T × R = mR2 … (ii) 15. R
From Eqs. (i) and (ii), we get I = 0(r  R)
a = g/2
−p
8. (3) p = 2mv cos  16. (3) As B =
V
V
1
= 2mv 
2 V p 105
 =− = = 8  10−7
V B 1.25  1011
= mv

2
 YA
(2) F = l
l
So energy required to remove second electron from
17. F = YA (strain)
22
the atom E = 13.6  = 54.4 eV
For a given strain F2  F1  A2  A1 1
1 − cos 2t  Total energy required = 24.6 + 54.4 = 79 eV
18. (4) y = sin 2 t = Ans: 1
2 28.
Sol: W = 8πT 2
R − R
2
= 8πT (2r)
2
− r
2
= 24πr
2  (
2 1 ) [ ]
T= =
2  29. (3) From eV0 = h –  and Kmax= h – . If  increases
I
(4) Intensity of light from first polariser = 0 keeping  constant, then V0 and Kmax both increase.
19. 2 If  decreases keeping  constant, then V0 and Kmax
From Malu’s law
increase.
I
I = 0 ( cos  )
2 2
If I increases more photoelectrons would be liberated,
2
hence saturation photocurrent increases.
2
I0 I  3  9I 0
 ( cos 30 ) = 0
2
=   =
2
If separation between cathode and anode is increased,
2 2 4 32 ,K
then there is no effect on 0 max or current.
p T sin i
20. (4) f = 30. (3) = sin r
2  
200 = p (40) As  v   R So rv  rR
P=5
1 1 1
  31. (3) For lens + =  v = 60 cm
5  = 1 v 30 20
2
Now, 20 + 2f = 60  f = 20 cm
1
= 100 = 20 cm fo
2 5 32. (1) = 12 ...(1)
fe
21. (3) As we know, temp = force
FL f o + f e = 39 ...(2)
or L (T) =
AY 12 f e + f e = 39

=
F
=
F f e = 3 cm
AYT r 2YT
f o = 36 cm
Coefficient of volume expansion = 3,
hc hc
 = 3 =
3F 33. (4) eV =   min =
r 2YT  min eV
22. (3) Photoelectric emf is proportional to intensity of 34. (2) 1 sin30 =  sin (90 − C )
light falling on the cell.
1
23. (1) =  cos C
2
24. (3)
Both coulomb and nuclear forces acting inside the 1 2 − 1 1
nucleus. =  = 2 − 1
2  4
25. (3) E = mc2
5 5
= 110−6  (3 108 ) = 110−6  9 1016 = 9 1010 J
2
2 =  =
4 4
26.
Displacement 2R 35. (2) Ac generator works on principle of
(3) vav = =
Time t electromagnetic induction.
27. (1) After the removal of first electron remaining atom 36. (4) VA − 6 + 4 − 1.5 − 10 − 4.5 = VB
will be hydrogen like atom.
VA − VB = 18 volt

3
 M q 43. (2) Diffusion current is from p to n side due to flow of
37. (3) =
L 2m majority charge carriers
q qvR 44. (4) The barrier potential depends on type of
M=  mvR =
2m 2 semiconductor (for Si Vb = 0.7 volt & for Ge Vb = 0.3
volt), amount of doping and also on the temperature.
38. (2) Beyond Curie temperature, ferromagnetic
substance becomes paramagnetic. 45. (3)
Y = A.B . A + B = ( A . B ) + A + B = A ( B + 1) + B
Y = A+ B
V 2 (12 )
2

39. (3) P = = = 36 watt OR Gate.

Req 4

40. (2) W = 1.6 10−19 ( 40 − 10) = 48 10−19 J

41. Ans: 2
This time period is independent of pendulum
mass.
42. Ans:
2
π π
Δϕ = ϕ 2 − ϕ 1 ⇒ Δϕ = −
2 6
3π−π π
⇒ Δϕ = =
6 3
 CHEMISTRY

54. (1) iii is wrong as conjugate acid base pairs differ in proton only.
55. (3) DiH of Pb is higher than of Sn due to poor shielding effect
46. of intervening d and f orbitals which increases effective
nuclear charge.
56. (3)

IUPAC name of the above compound is

47. (4) Lead has no tendency for catenation. Butane-1, 2, 4-tricarboxylic acid
57. (3) The compounds which differ in the nature of carbon chain
are called chain isomers.
48. (2) Mabcd type of complexes show 2 cis and 1 trans isomers,
where a b c, and d are monodentate ligands. 58. (1) Complex is inner orbital and diamagnetic. So its magnetic
, , moment is zero.
49. (4) The structure of H 2 O is angular V-shape and has sp 3 - 59. (2)
hybridization and bond angle is 105°. Its dipole moment Specific resistance is resistivity and the inverse of resistivity
value is positive or more than zero. is called conductivity represented by symbol kappa (κ). So,
O statement (i) is incorrect.
180o
The electrical resistance of any object is directly proportional
H 104.5o F Be F
to its length and inversely proportional to its area of cross
H
section. So, statement (ii) is incorrect.
But in BeF 2, structure is linear due to sp-hybridization
Electronic conductance decreases with increase in temperature.
(m = 0). Thus, due to m > 0, H 2O is dipolar and due to
So, statement (iii) is also incorrect.
m = 0, BeF2 is non-polar.

50. (1) For endothermic reactions,

∆H = +ve and ∆G = ∆H ‒ T∆S 60. (3) The molecular orbital electronic configuration.
(σ1s ) 2 (σ
*
1s ) 2 (σ2 s) 2 (σ
*
2 s ) 2 ( σ2 p x ) 2
1 (p 2 p y ) 2 (p 2 pz ) 2 (p* 2 p y ) 2 (p* 2 pz )1
51. (1) (I) H2 (g) + O (g) ® H2O(l); DH = –285.77 kJ/mol
2 2 Total electrons =17
1 Hence, this configuration belongs to O2– (17 e–) ion.
(II) H2(g) + O2(g) ® H2O(g); DH = –241.84 kJ/mol 61. (1)
2
H2O(l) ® H2O(g); DH = ? 62. (2) According to Raoult’s law
ps − p nA
Subtract the Eqs. (I) from (II) =
ps n A + nB
H2O(l) ® H2O(g); DH = –241.84 – (–285.77)
= –241.84 + 285.77 19.8 − p 0.1
= or 198 – 10p = 19.8 × 0.1
DH = +43.93 kJ/mol 19.8 9.9 + 0.1
On solving, p = 19.602 mm

52. (3) Cr26+ + 6e– ® 2Cr3+

63. (4)
53. (2) Coordination number is equal to total number of ligands in
a complex.
 64. (2) For 1st order reaction,

72. (4) Aldehydes other than formaldehyde give secondary alcohols.

Esters of formaldehyde also give secondary alcohol.
14
73. (2) Mass of 1 atom of 14C = = 2.32 × 10−23
6.022 × 1023
28
65. (4) Mass of 1 molecule of N2 = = 4.65 × 10−23 g
6.022 × 1023
18
Mass of 1 molecule of H2O = = 2.99 × 10−23 g
6.022 × 1023
∴ statement (i) is incorrect and statement (ii) is correct.
74. (3)
75. (4)
76. (2)
HNO
C2 H5 NH 2 
H 2O
2
→ C2 H5 OH PCl
 5
→
Ethyl amine Ethyl alcohol
(A)
NH
C2 H5 Cl 
3
→ C2 H5 NH 2
Ethyl chloride Ethyl amine
(B) (C)

Na CH – CH – I
77. (4) CH3 – C ≡ CH → CH3 – C ≡ C – Na+ 
3 2
→
SN 2
66. (2) CH3– C ≡ C – CH2 – CH3
78. (1) Given reactions are of type A + B Æ AB and are therefore
combination redox reactions.

79.

67. (3) CH3CHO gives red ppt with Fehling solution and forms
yellow ppt with I2/NaOH.
C6H5CHO does not show Fehling solution test and neither
gives yellow ppt with I2/NaOH.
CH 3 COCH 3 reacts with I 2 /NaOH to form yellow ppt. 80. (3)
CH3COOH shows brisk effervescence with NaHCO3 whereas 81. (1) For n = 3
CH3CHO does not.
Subshell ( ) = 0 to (3 – 1)
68. (3) +3 and +4 states are shown by Ce in aqueous solution.
= 0, 1, 2 = s, p, d
Thus, statement (3) is incorrect.
∴ subshell are 3s, 3p, 3d
69. (1)
No. of orbitals = n2 = (3)2 = 9
70. (4) Xe has maximum solubility among noble gases due to
82. (3) RNA (ribonucleic acid) has single stranded a-helix
dipole-induced dipole interactions.
structure with adenine and guanine as purine bases. DNA
71. (1) In SN2 reaction, nucleophile and alkyl halide react in one (deoxyribonucleic acid) has double stranded a-helix structure
step. with adenine and guanine as purine bases. r-RNA forms the
R site of protein synthesis while t-RNA acts as a carrier of
R R amino acid.
R
-
C Br + Nu Nu ...... C ...... Br 83. (4) CH3CH2MgBr + HCN Æ
H3O+
H—C==NMgBr CH3CH2CHO
R R
(Y)
Thus, tertiary carbon is under steric hindrance and thus reaction CH2CH3
does not take place until (C‒Br) bond breaks. (X)
 [Salt]
84. (4)  pH = pKa + log
[Acid]
[Salt]
or 5.8 = 4.8 + log
[Acid]
[Salt]
or log = 1.0
[Acid] 89. (1)
[Salt]
= anti log 1.0 = 10
[Acid]
[Acid] 1
90. (2) Specific conductance = conductance × cell constant
\ = = 0.1
[Salt] 10 1
1.3 S m–1 = S × cell constant
85. (4) CH4 + 2O2 → CO2 + 2H2O 50
\ Cell constant
1 mol    2 mol     1 mol    2 mol
= 1.3 × 50 m–1

16 g                  36 g
= 65 m–1 = (65/100) cm–1
∴ 16 g CH4 on combustion forms 36 g of H2O. 1000 × conductance × cell constant
16 Molar conductivity =
Moles of O2 = = 0.5 mol molarity
32
1000 1 65
1 = × × = 6.25 S cm2 mol–1
Moles of H2 = = 0.5 mol 0.4 260 100
2
14 = 6.25 × 10–4 S m2 mol–1
Moles of N2 = = 0.5 mol
28
Since the number of moles is the same, so 16 g of O2, 1.0 g

of H2, and 14 g of N2 have same number of molecules.
86. (2) (I) is staggered conformation in which hydrogen atoms are as
far apart as possible.
(II) is eclipsed conformation as the hydrogen atoms attached
to carbon atoms are as closed together as possible.
!
87. (4) CH2CHO is the most stable carbanion since it is stabilized
by resonance
O O–
|| |
–
CH2 – C – H « CH2 = C – H
88. (1) For first order reaction,
2.303 [ A]0
Rate constant (k) = log10
t [ A]t
At t = 40 min,

2.303 0.1 2.303
k= log10 = log10 4
40 0.025 40
2.303
= × 2 log10 2
40
2.303
= × 2 × 0.3010
40
–1
= 0.0347 min
At concentration of A = 0.01 M = [A]

dx
Rate, = k [A]
dt
dx
= 0.0347 × 0.01
dt
= 3.47 × 10–4 mol L–1 min–1