3M™ CoJet Sand (68411) 04/23/20

Safety Data Sheet

Copyright,2020, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 16-2874-2 Version Number: 8.01

Issue Date: 04/23/20 Supercedes Date: 06/27/18

SECTION 1: Identification
1.1. Product identifier
3M™ CoJet Sand (68411)

Product Identification Numbers

70-2011-0054-5
7000054650

1.2. Recommended use and restrictions on use

Recommended use
Dental Product, Restorative repair
Restrictions on use
For use only by dental professionals

1.3. Supplier’s details

MANUFACTURER: 3M
DIVISION: Oral Care Solutions Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which requires the
inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of the hazards
communicated in this document may vary depending on the potential for exposure.

2.1. Hazard classification

Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.

2.2. Label elements

Signal word
Not applicable.

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Symbols
Not applicable.

Pictograms
Not applicable.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
ALUMINUM OXIDE 1344-28-1 > 95 Trade Secret *
SYNTHETIC AMORPHOUS SILICA, FUMED, 112945-52-5 < 5 Trade Secret *
CRYSTALLINE FREE

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist,
get medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition
None known. During Combustion

5.3. Special protective actions for fire-fighters

Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
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bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Observe precautions from other sections.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container.
Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international
regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid prolonged or repeated skin contact. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
SILICA, AMORPHOUS 112945-52- OSHA TWA concentration:0.8
5 mg/m3;TWA:20 millions of
particles/cu. ft.
ALUMINUM OXIDE 1344-28-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 A4: Not class. as human
mg/m3 carcin
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use in a well-ventilated area.

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8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields

Skin/hand protection
See Section 7.1 for additional information on skin protection.

Respiratory protection
None required.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Solid
Color Light Gray

Specific Physical Form: Powder

Odor Odorless
Odor threshold No Data Available
pH Not Applicable
Melting point 3542 ºF
Boiling Point Not Applicable
Flash Point No flash point
Evaporation rate Not Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density No Data Available
Specific Gravity 3.96 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Volatile Organic Compounds No Data Available
Percent volatile No Data Available
VOC Less H2O & Exempt Solvents No Data Available

SECTION 10: Stability and reactivity

10.1. Reactivity
This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

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10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which
requires the inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of
the hazards communicated in this document may vary depending on the potential for exposure.
The information below represents toxicological information associated with the individual components of the uncured
product. Once properly mixed and/or cured, the product is safe for its intended use.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
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Name Route Species Value

Overall product Inhalation- No data available; calculated ATE >12.5 mg/l
Dust/Mist(4
hr)
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
ALUMINUM OXIDE Dermal LD50 estimated to be > 5,000 mg/kg
ALUMINUM OXIDE Inhalation- Rat LC50 > 2.3 mg/l
Dust/Mist
(4 hours)
ALUMINUM OXIDE Ingestion Rat LD50 > 5,000 mg/kg
SYNTHETIC AMORPHOUS SILICA, FUMED, Dermal Rabbit LD50 > 5,000 mg/kg
CRYSTALLINE FREE
SYNTHETIC AMORPHOUS SILICA, FUMED, Inhalation- Rat LC50 > 0.691 mg/l
CRYSTALLINE FREE Dust/Mist
(4 hours)
SYNTHETIC AMORPHOUS SILICA, FUMED, Ingestion Rat LD50 > 5,110 mg/kg
CRYSTALLINE FREE
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

ALUMINUM OXIDE Rabbit No significant irritation

SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

ALUMINUM OXIDE Rabbit No significant irritation

SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE Rabbit No significant irritation

Skin Sensitization
Name Species Value
SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE Human Not classified
and
animal

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

ALUMINUM OXIDE In Vitro Not mutagenic

SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE In Vitro Not mutagenic

Carcinogenicity
Name Route Species Value
ALUMINUM OXIDE Inhalation Rat Not carcinogenic
SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE Not Mouse Some positive data exist, but the data are not
FREE Specified sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure
Duration
SYNTHETIC AMORPHOUS SILICA, Ingestion Not classified for female reproduction Rat NOAEL 509 1 generation
FUMED, CRYSTALLINE FREE mg/kg/day
SYNTHETIC AMORPHOUS SILICA, Ingestion Not classified for male reproduction Rat NOAEL 497 1 generation
FUMED, CRYSTALLINE FREE mg/kg/day

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SYNTHETIC AMORPHOUS SILICA, Ingestion Not classified for development Rat NOAEL 1,350 during
FUMED, CRYSTALLINE FREE mg/kg/day organogenesi
s

Target Organ(s)

Specific Target Organ Toxicity - single exposure

For the component/components, either no data are currently available or the data are not sufficient for classification.

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
ALUMINUM OXIDE Inhalation pneumoconiosis Some positive data exist, but the Human NOAEL Not occupational
data are not sufficient for available exposure
classification
ALUMINUM OXIDE Inhalation pulmonary fibrosis Not classified Human NOAEL Not occupational
available exposure
SYNTHETIC Inhalation respiratory system | Not classified Human NOAEL Not occupational
AMORPHOUS SILICA, silicosis available exposure
FUMED, CRYSTALLINE
FREE

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. If no other
disposal options are available, waste product may be placed in a landfill properly designed for industrial waste.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

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15.1. US Federal Regulations

Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Not applicable

Health Hazards
Not applicable

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
ALUMINUM OXIDE 1344-28-1 Trade Secret > 95
ALUMINUM OXIDE (ALUMINUM OXIDE 1344-28-1 > 95
(FIBROUS FORMS ONLY))

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this product are in compliance with the new substance notification requirements of CEPA.

The components of this material are in compliance with the China "Measures on Environmental Management of New
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.

This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated
by the FDA.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 1 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 16-2874-2 Version Number: 8.01

Issue Date: 04/23/20 Supercedes Date: 06/27/18

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
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NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.

3M USA SDSs are available at www.3M.com

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