Solution
Solution
1103CJA101021250069 JA
PHYSICS
SECTION-I (i)
1) Consider a mass 'm' attached with a spring oscillating in gravity free region as shown. If the mass
is given a charge 'q' and another charge '–q' is placed at the origin then,
2) Calculate energy needed for moving a mass of 4kg from the centre of the earth to its surface. If
radius of the earth is 6400 km and acceleration due to gravity at the surface of the earth is g = 10
m/sec2
3) Diagram shows 6 identical air capacitors connected to an ideal battery (V). In this condition,
charge on capacitor C6 is Q1. Now a dielectric whose dielectric constant is 2, is put between the
plates of C4 so that it occupies the entire space between the plates. Now charge on C6 becomes Q2.
Then should be :-
(A)
(B)
(C)
(D)
4) In the given circuit find the magnitude of current flowing through arm 'AB' :
(A) 4.5A
(B) 1.5 A
(C) 3.5A
(D) 4 A
5)
An igloo, a hemispherical enclosure built of ice (k = 1.67 J/m-s°C), has an inner radius of 2.50 m. The
thickness of the ice is 0.5 m. At what rate must thermal energy be generated to maintain the air
inside the igloo at 5°C when the outside temperature is –40°C ? Ignore all thermal energy losses
through the ground or by air currents.
6) A semi circular loop is given in fig. with current I and having radius R. The value of magnetic field
at D, is :-
(A)
(B)
(C)
(D)
SECTION-I (ii)
(A)
Trajectory of particle is symmetric about x =
(B)
Equation of the trajectory (path) of the particle is y = x
(C)
Equation of the trajectory (path) of the particle is y = x
(D)
Trajectory of particle is symmetric about x =
3)
Consider an isolated sphere (as explained in paragraph). If is electric field at any point because of
sphere and if C is centre of sphere and S is surface of sphere find the value of
(A)
(B)
(C)
(D)
4) If a small dipole of dipole moment P is placed at point A which is at large distance x from centre of
sphere as shown in figure. The force exerted by dipole on sphere would be :
(A)
(B)
(C)
(D)
5)
(A)
(B)
(C)
(D)
6)
(A)
(B)
(C)
(D)
SECTION-I (iii)
1) In elliptical orbit of a planet, as the planet moves from apogee position to perigee position,
List-I List-II
(S) Angular momentum about centre of Sun (4) Can not say
(A) P → 3;Q → 2;R → 2;S → 1
(B) P → 2;Q → 2;R → 2;S → 1
(C) P → 3;Q → 3;R → 2;S → 1
(D) P → 1;Q → 2;R → 2;S → 3
2) All capacitors have capacitance of 1μF. Find equivalent capacitance between points A & B.
(Q) (2)
(R) (3)
(S) (4)
3) Entries in List-I consists of diagrams of thermal conductors. The type of conductor & direction of
heat flows are listed below. Entries in List-II consists of the magnitude of rate of heat flow belonging
to any of the entries in List-I. If temperature difference in all the cases is (T1 – T2), then match List
List-I List-II
(P) (1)
(Q) (2)
(S) (4)
4) In List-I, we have certain situations where a battery of variable voltage other than zero is
connected in a circuit. List-II has comments on current in element A on variation of voltage:-
List-I List-II
On increasing V (from a certain value to another certain
(P) (1)
value), i may/will increase in magnitude
Ammeter is ideal
Ammeter is ideal
A → 4Ω resistor
A → 4Ω resistor
5) As shown in List-I their are graphs of electric field (E) and potential (V) along the line joining
charges Q1 and Q2 are drawn against distance (r) on x–axis for charges Q1 and Q2. Take potential at
infinity equal to zero. [Take direction of E in rightward direction as positive]
List-I List-II
(P) (1) Q1 < 0, Q2 > 0
CHEMISTRY
SECTION-I (i)
1)
(A)
(B)
(C)
(D)
2) Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason
R.
(A) Both A and R are true but R is NOT the correct explanation of A.
(B) A is true but R is false.
(C) A is false but R is true.
(D) Both A and R are true and R is the correct explanation of A.
3) How many coulombs of electricity are required for the reduction of 1 mol of
(A) 96500 C
(B)
(C)
(D)
5) A certain zero order reaction has k = 0.025 M s–1 for the disappearance of A. What will be the
concentration of A after 15 seconds if the initial concentration is 0.50 M ?
(A) 0.50 M
(B) 0.375 M
(C) 0.125 M
(D) 0.060 M
6) Calculate the Van't hoff factor when 0.1 mole of NH4Cl is dissolved in 1 liter water solution. The
degree of dissociation of NH4Cl is 0.8 and degree of hydrolysis of NH4+ ion is 0.1 :
(A) 0.8
(B) 1.4
(C) 1.88
(D) 2.68
SECTION-I (ii)
1) Which of the following represent correct energy profile diagram for the reaction given in
paragraph-
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
3) The solubility product (Ksp ; mol3 dm–9) of MX2 at 298 K based on the information available for the
given concentration cell is x × 10–15 (take 2.303 × R × 298/F = 0.059 V). The value of x is ?
(A) 1 × 10–15
(B) 4 × 10–15
(C) 1 × 10–12
(D) 4 × 10–12
4) The value of ΔG (kJ mol–1) for the given cell M(s) + M2+(aq) → M(s) + M2+ (aq) is (take F = 96500 C
mol–1)
(A) –5.7
(B) 5.7
(C) 11.4
(D) –11.4
Carbanion
Electrophilic addition
(B) (ii) intermediate (Q)
is involved
is involved
(A) P , i
(B) Q , iv
(C) R , iii
(D) S , ii
(A) R , iii
(B) Q , iv
(C) P , i
(D) S , ii
SECTION-I (iii)
1) Match the List-I with List-II and select correct code for your answer :-
List-I List-II
(Properties) (Decreasing order)
(5) F > Cl
(A) P → 1;Q → 3;R → 5;S → 2
(B) P → 2;Q → 4;R → 1;S → 1
(C) P → 3;Q → 4;R → 3;S → 2
(D) P → 1;Q → 2;R → 4;S → 5
2) Electrolysis of following aqueous solution proceed in electrolytic cell for small period of time.
3)
List-I List-II
4)
List-I List-II
5)
List-I List-II
(Substances) (Can be prepared by)
MATHEMATICS
SECTION-I (i)
1) Let a1, a2, a3,.... a100 be an arithmetic progression with a1 = 5 and . If is independent
of n where m = 5n then sum of possible values of a2 is
(A) 3
(B) 20
(C) 5
(D) 15
2) equals -
(A)
(B)
(C)
(D)
(A) 4
(B) 2
(C) 3
(D) 1
(A)
(B) (0, 2)
(C)
(D) None of these
5)
(A) P = 3Q
(B) P = 2Q
(C) 2P = Q
(D) 3P = Q
(A) 0
(B)
(C) 2
(D) 1
SECTION-I (ii)
List-I List-II
(Q) (2) 2
Number of solutions of is divisible by
Let in obtuse angled ΔABC, AB = BC, ,
(R) (in radian) then number of distinct real roots of mx2 + nx + r = 0 (3) 3
is less than
(A) P 2, 3, 4
(B) Q → 1,2
(C) R 1, 2, 3
(D) S 1, 2, 3, 4
(A) P 1, 4
(B) Q 2, 3
(C) R → 3, 4
(D) S 2, 4
(A) 3
(B) 5
(C) 7
(D) 9
(A)
(B)
(C)
(D)
5)
Inverse of ƒ(x) is
(A)
(B)
(C)
(D)
6)
Possible value of k is :-
(A) 1
(B) 2
(C) 3
(D) 6
SECTION-I (iii)
1) Consider the equation: ax2 + bx + c = x3 + l/x. (a, b, c R; a, b, c 0). If the equation has only
real solutions then match the values given in List II corresponding to the quantities given in List I.
List-I List-II
(5) –8
(A) P → 2;Q → 2;R → 3;S → 4
(B) P → 1;Q → 2;R → 3;S → 3
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 1;Q → 2;R → 3;S → 5
2)
Column-I Column-II
(P) (1) 1
If , then k is greater than
(Q) (2) 1
If , then ak is less than
(R) (3) 3
If , then k is less than
(S) (4) 4
If , then is greater than
(5) 2
3) Answer the following by appropriately matching the lists based on the information given
in the list.
List-I List-II
the value of – b is
If is a
(S) decreasing function for every x (4) 4
≤ 0. Then the least value of p2
is
(5) 5
Correctly match among the following is :
(A) P → 5;Q → 3;R → 4;S → 2
(B) P → 5;Q → 2;R → 4;S → 1
(C) P → 5;Q → 3;R → 4;S → 1
(D) P → 4;Q → 3;R → 2;S → 2
4) Let E1 =
and
List-I List-II
P. The range of ƒ is 1.
S. The domain of g is 4.
5.
6.
5)
Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
ƒ : R → (0,∞)
(Q) (2) Surjective Mapping
(R) (3) Non injective mapping
ƒ(x) = x3 – 2x2 + 2x + log x
ƒ : [–3,0] → [cos3,1]
(S) (4) Non surjective mapping
ƒ(x) = cosx
PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6
A. D A A D A B
SECTION-I (ii)
Q. 7 8 9 10 11 12
A. B B A A D C
SECTION-I (iii)
Q. 13 14 15 16 17
A. A C A B B
CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21 22 23
A. B C C B C C
SECTION-I (ii)
Q. 24 25 26 27 28 29
A. C B B D D C
SECTION-I (iii)
Q. 30 31 32 33 34
A. A C C B A
MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38 39 40
A. B A D C B D
SECTION-I (ii)
Q. 41 42 43 44 45 46
A. B C C A B B
SECTION-I (iii)
Q. 47 48 49 50 51
A. A C C A C
SOLUTIONS
PHYSICS
2)
ΔE =
3)
Q initially =
Q finally =
Initially Qi =
Finally Qf =
Qi : Qf = 3 : 4
4)
Current in branch AB 4 A
5)
⇒ ×
6)
KA = CL = R
Magnetic field (B) at D due to straight current KA & CL is zero
and magnetic field due to a semi circular
7) (a)
Speed at t =
(c)
8) (A) Eliminating 't' from both equations
⇒t= ⇒y=
(C)
∴x=
9)
10)
we can assume, sphere is placed at equitorial position of dipole, F = Q (Eeq)
=
Q = ρ0pR3
11)
12)
13)
L = constant
14) (A)
By symmetry point C,D are at sum potential hence capacitacne between C & D has no charge.
Similarly E & F ane at same potential.
(B) By symmetry C & D are at same potential
(D)
No charge will flow to upper loop
0
15) (A) = = πRk (T1 – T2)
(B) =
= =
(C) = =
0
(D) = –πR2k · = –πR2k
∴ = = –πR2k
∴ =
16) For D :
Similar for C
A, B are Wheatstone so no change.
Near so Q2 is –ve
(S)
near Q1 is –ve
near Q2 Q2 is +ve
E = 0 is near Q1
CHEMISTRY
18)
21)
22) Suppose At
We know
(A0 – At) = kt for zeroth order
(0.50 – At) = 0.025 × t
0.50 – At = 0.025 × 15
At = 0.125 M
0.8C
0.8C – 0.08C 0.08C 0.08C
24) Energy profile diagram involves two 1,2 shifts & two product are forming. For major
product P1, 4 intermediates and 5 TS is formed.
25)
F > Cl
(Q) Radii
S>O
(R) Electronegativity
So
Mg > Na & [He] 2s2 2p4 > [He]2s22p3
Li+ > Li F > Cl
(S) Electron affinity
S > O (due to small size of oxygen
Li+ > Li (E.A. ∝ Zeff)
[He] 2s2 2p4 > [He] 2s2 2p3
(because half filled is more)
31)
(R) CuSO4 O2 Cu
32)
33)
MATHEMATICS
36)
Let
Ans.
38)
Now,
39)
Now as
∴ P = 2Q
apply limit x → y
|ƒ'(y)| < 0 ⇒ ƒ'(y) = 0 ⇒ ƒ(y) = c ⇒ ƒ(x) = 1
41) (P)
From graph number of solutions = 3
(Q)
Number of solutions = 2
(R) > π/2, =r<
⇒ n > 2m = 2r ⇒ n2 > 4mr
⇒ D = n2 – 4mr > 0
⇒ Number of distinct real roots = 2
(S)
||x + 2| + |x – 3| – 5| £ 0
⇒ ||x + 2| + |x – 3| – 5| = 0
⇒ |x + 2| + |x – 3| = 5
⇒ x ∈ [–2, 3]
Sum of integral solutions
= –2 – 1 + 0 + 1 + 2 + 3 = 3
42) (P)
From graph number of solutions = 3
(Q)
Number of solutions = 2
(R) > π/2, =r<
2
⇒ n > 2m = 2r ⇒ n > 4mr
⇒ D = n2 – 4mr > 0
⇒ Number of distinct real roots = 2
(S)
||x + 2| + |x – 3| – 5| £ 0
⇒ ||x + 2| + |x – 3| – 5| = 0
⇒ |x + 2| + |x – 3| = 5
⇒ x ∈ [–2, 3]
Sum of integral solutions
= –2 – 1 + 0 + 1 + 2 + 3 = 3
43) Sn = 8 × 32 + 11 × 33 + 14 × 34 + ...... Tn
3Sn = 8 × 33 + 11 × 34 – 1 ....... 3Tn
–2Sn = 8 × 32 + 34 + 35 + ....... n terms – 3Tn.
⇒
⇒ 4Sn – 6Tn + 3n+3 + 63 = 0
⇒ a = 4, d = 3.
44)
Let = S∞ =
45)
So, x ≠ 2, –2
,
⇒ x – 4 = xy – 2y
⇒ 2y – 4 = x(y – 1)
46)
So, x ≠ 2, –2
,
⇒ x – 4 = xy – 2y
⇒ 2y – 4 = x(y – 1)
⇒
∴
(P)
(Q) When a = –4, AM = GM. So, = –1. In this case
f(x) will be the expansion of (x + l)4. So, b = –6 & c = –4.
(R) . As product of roots = =1,
48) (P)
let 2x = t
(Q)
(R)
k=2
(S)
49)
⇒ = 3x2 – 4x + c
at x = 1, =0 ⇒c=1
∴ = 3x2 – 4x + 1
⇒ y = x3 – 2x2 + x + d
at x = 1, y = 5
⇒ 5=1–2+1+d ⇒ d=5
∴ f(x) = x3 – 2x2 + x + 5
f(0) = 5
(Q) = 2ax + b
= 2a + b
⇒ 2=a+b+
⇒ .....(1)
y = x2 + 6x + 10
= 2x + 6
∴ .....(2)
From (1) and (2)
a = 1, b =
⇒ at A = A : (0, 2)
Equation of normal at A is
y – 2 = 2(x – 0)
⇒ y = 2x + 2
Let normal meets the curve at B.
⇒ 5α2x3 + 10αx2 + x + 4x + 4 – 4 = 0
⇒ 5x (αx + 1)2 = 0
⇒x=
∴B:
Slope of tangent at B
∴ Equation of tangent is
y+ –2=2
⇒
(S) f(x) =
f '(x) = –px e–x + pe–x – x + 1
f '(x) = pe–x (–x + 1) + (–x + 1)
= (pe–x + 1) (1 – x) ≤ 0, ∀ x < 0
⇒ p ≤ –1
50) E1 :
⇒ E1 : x ∈ (–∞, 0) ∪ (1, ∞)
E2 : –1 ≤
Now
⇒ x∈
also –e≤0
≥0
⇒ x ∈ (–∞, 1) ∪
So E2 :
as Range of is R+ – {1}
⇒ Range of f is R – {0} or (–∞, 0) ∪ (0, ∞)
Range of g is – {0} or
Now P → 4, Q → 2, R → 1, S → 1
Hence A is correct
51)
⇒ f'(x) > 0
∴ Always +ve
∴ f(x) is increasing ⇒ one one
Also Range of f(x) is R
∴ f(x) is one one onto
(S) f : [–3, 0] → [cos3, 1]
f(x) = cos x
one one onto