Delighting in Denim - A Wonder Fabric

Delighting in Denim - a
wonder fabric
Denim
Washing
Introduction
Rugged cotton twill textile, in which the weft passes
under two (twi- "double") or more warp fibers,
producing the familiar diagonal ribbing identifiable
on the reverse of the fabric
Denim wash
Dry denim is a denim fabric that is not washed
after being dyed during its production. Fading is
affected by the body of the person and the
activities of daily life
Denim washing is the aesthetic finish given to the
denim fabric to enhance the appeal and to provide
strength.
Dry denim
Denim washes are of two types:

Mechanical washes
Chemical washes
Basic Mechanical washes

Stone wash
Micro Sanding
Basic Chemical
washes
Denim bleaching
Acid wash
Enzyme wash
Mechanical washes
1. Stone wash
Freshly dyed jeans are loaded into
large
tumbled
washing
with
machines
pumice
stones
and
to
achieve a soft hand and desirable

look.
Variations in composition, hardness,
size shape and porosity make these
stones multifunctional.
Contd
Expensive process.
Pumice stones gives the additional effect of a faded or
worn look.
Abrades the surface of the jeans like sandpaper, removing
some dye particles from the surfaces of the yarn.
Process cycle
Selection of stone
Stone should be selected of the proper hardness, shape , and
size for the particular end product
Large ,hard stones last longer and may be suited for heavy
weight fabrics
Smaller, softer stones would be used for light weight , more
delicate items.
Stone to fabric weight ratio should vary from .5 to

3.1
It depends on the degree of abrasion needed to
achieve the desired result.
Stones can be reused until they completely
disintegrate or washed down the drain.
Problems caused by stones:

Damage to wash machineries and garment due to
stone to machine and machine to stone abrasion
Increase in labor to remove dust from finished
garments.
Water pollution during disposal of used liquor.
Problems of back staining and re deposition.
Back staining or Re-deposition:

The dye removed from denim material after the treatment with
cellulose or by a conventional washing process may cause
"back staining or "redeposition
Re-coloration of blue threads and blue coloration of white
threads, resulting in less contrast between blue and white
threads.
Remedy
Adding dispersion/suspension agent to wash cycle.
Intermediate replacement of wash liqour.
Using alkaline detergent like sodium perborate
with optical brightner as afterwash.
Limitations of stone washing

Quality of the abrasion process is difficult
to control Outcome of a load of jeans is
never uniform, little percentage always
getting ruined by too much abrasion.
Process is also non-selective.
Metal buttons and rivets on the jeans in
the washing machines gets abraded.
This reduces quality of the products and
life of equipment, and increases
production costs.
Disadvantages of stonewashing
Process control is not easy because the change in size
and quality of stones impart different degree of
fading, strength, etc.
Stones may turn into powder during the process of
making the garment greyish in colour and rough too
Provides rougher feel than enzyme wash
Stone may lead the harm to the machine parts
Stone sometimes creates harm to the accessories of
garments.
Biostoning
Most economical and environmentally friendly
Reduced waste, pollution, quality variability, and
imperfections
Unlike pumice or acid, enzymes can be recycled.
Small dose of enzymes can replace several dozen pounds of
pumice stones.
Productivity can be increased by 30-50% as the room
formerly taken up by the pumice stones in the washing
machines can be filled with more jeans.
No need for the time-consuming and expensive task of
removing stone fragments from the jeans after the wash.
No pumice dust to endanger employee health or gritty
sediment to clog drains.
2. MICROSANDING
There are 3 ways for this technique:
Sandblasting
Machine sanding
Hand sanding or hand brushing
Used in various ways:
Flat surfaces (tables, ironing boards)
On the dummy (inflatable dummies,
sometimes standing, sometimes flat,
sometimes 'seated') and
Various templates can be used to create a 3D
effect.
2.1 Sand blasting

Sand blasting technique is based on blasting an abrasive
material in granular, powdered or other form through a
nozzle at very high speed and pressure onto specific areas
of the garment surface to be treated to give the desired
distressed/ abraded/used look.
It is purely mechanical process, not using any chemicals.

It is a water free process therefore no drying required.
Variety of distressed or abraded looks possible.
Any number of designs could be created by special
techniques.
Cond
Removes color from certain areas, either allover or
placed
Gives additional softness
Sand is actually shot at the garment with a powerful
spray gun.
Recent technology has introduced "automatic"
sandblasting, in which the jeans hang and rotate
continuously.
Sand blasting
Chemical washes
1. Denim bleaching
A strong oxidative bleaching agent such as sodium
hypochlorite or KMnO4 is added during the washing with or
without stone addition.
Discoloration is usually more apparent depending on strength
of the bleach liquor quantity, temperature and treatment
time.
A strong bleach with short treatment time is preferable .
Bleached goods should be adequately antichlored or after
washed with peroxide to minimize yellowing.
Materials should be carefully sorted before processing for
color uniformity.
Process cycle
Load garment
with/without stone
Desize
Rinse
Bleach with cold

water
Rinse
Bleach
Optical brightening
Softening
Limitations
Process is difficult to control
i.e. difficult to reach the
same level of bleaching in
repeated runs.
When
desired
level
of
bleaching reached the time
span available to stop the
bleaching is very narrow. Due
to harshness of chemical, it
may
cause
damage
to
cellulose resulting in severe
strength losses and/or breaks
or pinholes at the seam,
pocket, etc.
Contd
Harmful to human health and
causes corrosion to stainless
steel.
Required antichlor treatment.
Problem of yellowing is very
frequent due to residual
chlorine.
Chlorinated organic
substances occur as abundant
products in bleaching, and
pass into the effluent where
they cause severe
environmental pollution.
Some people have great results use chlorine bleach

such as a Clorox Bleach, and others prefer a
commercial color remover such as Rit or Tintex. This
reducing bleach must be used very carefully, as it
will easily fade colors in any fabric it touches.
2. Acid wash:
Done by tumbling the garments with pumice stones
presoaked in a solution of sodium hypochlorite or
potassium permanganate for localized bleaching resulting
in a non uniform sharp blue/white contrast. After that it is
washed with acid.
Color contrast can be enhanced by optical brightening.
Addition of water is not required.
Process cycle
Load garment
With pumice stone
Desize
Dry
Dry tumbler
Cool with adding

water
Antichlor
Optical brightening
Softening
Limitations
Acid washed , indigo dyed denim has a

tendency to yellow after wet processing.
The major cause is residual manganese
due to incomplete neutralization,
washing or rinsing.
Remedy
Manganese is effectively removed during
laundering with addition of ethelene-diaminetetra-acetic acid as chelating agent.
Acid washing jeans avoided some of problems of
stone wash , but came with added dangers,
expenses, and pollution.
3. ENZYME WASH
Environmentally friendly
Application of organic enzymes that eat away at the fabric,
i.e. the cellulase
When the desired colour is achieved, the enzymes can be
stopped by changing the alkalinity of the bath or its
temperature
A final rinsing and softening cycle is next
Use of cellulase making the seams, hems, and pockets more
noticeable
Salt pepper effect is color contrast effect. Faded garment with
acid cellulase enzyme provides less colour contrast in
proportion to garment washed with neutral cellulase enzymes
Enzyme wash
3.1. CELLULASE WASH

This is done to achieve a wash down appearance without
the use of stones or with reduced quantities of stones.
Cellulase enzymes are selective only to the cellulose and
will not degrade starch.
Under certain conditions, their ability to react with
cellulose (cotton) will result in surface fiber removal
(weight loss).
This will give the garments a washed appearance and soft
hand.
Factors influencing cellulase performance

pH
Temperature
Time
Dose
Mechanical action
CHEMICALS FOR
DENIMS
1. Bleach fast Indigo
Value addition to denim
Retains indigo on certain parts
Kind of resist effect
Chemical applied by brush, cured at 150C
Ex. Indigofix AXN
2. Anti-depositing agent
Prevents back staining of fabric by loose indigo
during washing
Improves contrast in denim
Used in stone wash step
3. Dye stuffs with softener

To carry dyeing and softening in one step
Soft and supple hand
Saves time, money and energy as added to
final rinse
Gives used and worn out effect
4. Anti creasing agent

Provides fabric to fabric lubrication
Prevents formation of crack marks and streaks
Minimizes abrasion and gives strength
5. Wrinkle formation
Creating smooth and permanent wrinkle
Cross linking concept
Ex. DMDHEU
6. White pigment
Can be applied by brush, spray or screen
Then cured at 150C
Washed and treated with softener
Latest developments
Quick wash denim

Aims at minimizing wash cycle time
Results in more economical washes and solving many
other washing problems faced by launderes during
fashion wash cycles
The yarns are ring dyed using indigo giving 25 to 30%
less fixed dye to obtain a given shade
During wash cycle,indigo dye can be removed
quickly,giving washed look
Advantages of quick wash denim

1. Streaks develop in garments after washing process
due to differences in dye concentration of denim
fabrics are avoided using a modified alkali-ph
controlled system giving uniformity of shade.
2. Amount of indigo dye required is less thus making it
an economical process
3. Time required for washing is 20-30% less than that
required for conventional denim.
4. Lesser enzymes and oxidising agent used

5. Environment friendly process
6. Back staining is minimised due to less concentration of
of indigo dye in the wash liqour.
CONCLUSION
Apart from the basic washes which are used many
innovations has been done in the field of denim.
Not only there are variations in the denim in the
weaving stage but also lot of experimentation has
been done to give denim more aesthetic appearance.
Thank you

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Delighting in Denim - a

Denim washes are of two types:

Basic Mechanical washes

achieve a soft hand and desirable

Stone to fabric weight ratio should vary from .5 to

Problems caused by stones:

Back staining or Re-deposition:

Limitations of stone washing

2.1 Sand blasting

It is purely mechanical process, not using any chemicals.

Bleach with cold

Some people have great results use chlorine bleach

Cool with adding

Acid washed , indigo dyed denim has a

3.1. CELLULASE WASH

Factors influencing cellulase performance

1. Bleach fast Indigo

Value addition to denim

Retains indigo on certain parts

Kind of resist effect

Chemical applied by brush, cured at 150C

Ex. Indigofix AXN

3. Dye stuffs with softener

4. Anti creasing agent

Quick wash denim

Advantages of quick wash denim

4. Lesser enzymes and oxidising agent used

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