Kelompok 17 - Reaksi Cepat

LOGO
Kinetics of the Bray-Liebhafsky Oscillatory

Reaction Perturbed by Polymer Supported
Cobalt Catalyst
Presented by Group 17:

Saima Mega Putri Manurung G44090028
Shinta Dewi Permata Sari G44090084
Andhika Gusti Heriyanto G44090085
JOURNAL
Kinetics of the Bray-Liebhafsky Oscillatory Reaction Perturbed by
Polymer Supported Cobalt Catalyst
J. P. Maksimovic, Z. D. Cupic, D. Loncarevic, N. Pejic,

D. Vasiljevic-Radovic, S. Anic
Science of Sintering 2011, 43: 55-62

doi: 10.2298/SOS1101055M
INTRODUCTION
Fast Reaction
Oscillation Reaction
Bray-Liebhafsky Reaction
Kinetics of the Bray-Liebhafsky Oscillatory Reaction Perturbed by Polymer Supported Cobalt Catalyst
INTRODUCTION
Fast Reaction
 The fast reaction is used to described the reaction followed

difficulty with conventional method .
 In generally, fast reaction have a big constanta value, low

activation energy, and occurs in liquid phase especially reactions
with involving ions and electrons in an aqueous solution.
 The fast reaction is a reaction with half-life less than few seconds
at room temperature using conventional reactant concentration.
INTRODUCTION
Oscillation Reaction
 Oscillation reaction is a type of chemical reaction in which the product and reactant
concentration changes periodically with time.
 The oscillation reaction can present with :

1. The changes in color (the oscillating species show different colors)
2. The changes in pH (or concentration variation of H + OH)
3. The changes in redox potential and so on.
 Some type of oscillation reaction:

1. Oscillation reaction of Bray-Liebhafsky (BL)
2. Oscillation reaction of Briggs-Rauscher (BR)
3. Belousov-Zhabotinsky (BZ) reaction
INTRODUCTION
Bray-Liebhafsky Reaction
 Bray-Liebhafsky reaction is the decomposition reaction of hydrogen peroxide to be
water and oxygen with the hydrogen and iodate ion.
 The oscillation of Bray-Liebhafsky can used for characterization copolymer of poly-
4-vinylpyridine with divinylbenzene (Co-PVPDVB) catalyzed.
 BL reaction is the decomposition reaction of hydrogen peroxide to be water and
oxygen with the hydrogen and iodate ion.
 The parameter used are catalyst (cobalt(II)-nitrate), polymer (PVPDVB), and Co-
polymer (Co-PVPDVB).
 Oscillatory reaction of Bray-Liebhafsky (BL) resulting in a batch reactor was
disturbed by the presence of cobalt(II)-nitrate, which is supported by a
macroreticular Co-PVPDVB.
 The kinetic data were analyzed by looking the influence of parameters on the
oscillation frequency, the activation energy, and kinetics parameter.
RESULTS & DISCUSSION
 Kinetics of reaction is analysed by perturbation by

Polymer Supported Cobalt Catalyst.
 Catalyst is prepared by wetness impregnation of
cobalt(II)-nitrate (Co(NO3)2.6H2O) on the
macroreticular copolymer of poly-4-vinylpyridine
with divinylbenzene (Co-PVPDVB).
 The experiments were carried out in the isothermal
(±0.1 oC) closed well-stirred (900 rpm) reactor at
different temperatures (62, 64, 66 and 68 oC) in dark.
The reaction volume was 52 mL.
 The initial concentrations the BL matrix species:

[KIO3] = 7.2x10-2 mol/dm3,
[H2SO4] = 4.8x10-2 mol/dm3, and
[H2O2] = 4.6x10-2 mol/dm3
 The catalyst was placed in the reactor prior to

components of the matrix.
 The evolution of the indicative BL reaction was

followed potentiometrically.
RESULT AND DISCUSSION
 Reactive species can be adsorbed from

matrics to polymer and lost from liquid
phase of reaction
 That species can react in adsorb form
 Cobalt ion from catalyst could be easily
desorbed by acid aqeous medium and
continuosly interact in homogenous system
Conclusion
 Kinetics oscillating Bray-Liebhafsky reaction is analysed by Co-
PVPDVB catalyst. The result showed that kinetics is depend to
catalyst and half to polymer
 Catalyst activity was identified against oxidation branch of the

complex reaction
 Cobalt ions from catalyst Co-PVPDVB are extracted in acidified

aqueous medium of the BL reaction and polymer support
 PVPDVB is strongly perturbing agent
References
 Anic SR. 1997. Relation between the number of oscillations and the activation energy of an oscillatory
process. Journal of the Serbian Chemical Society 62(1): 65-69.
 Coulson JM, Ricardson JF. 1983. Chemical Engineering Vol 6. New York: Pergamon Press.
 Daniel B. 2000. The potentiometric study on Bray – Liebhafsky Reaction at high temperatures.
Acta.Chem.Scand 23: 21-30.
 Katarina et al. 2001. Numerical simulations of the oxygen production in the oscillating Bray-Liebhafsky
reaction. Chemical Physics Letters 341 : 345-350.
 Kuzovkov VN, Kortluke O, Niessen WV. 2001. Comment on Surface Restructuring, Kinetic Oscillations, and
Chaos in Heterogeneous Catalytic Reactions. Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics
66: 135-147.
 Loncarevic et al. 2010. Cyclohexane oxidation and cyclohexyl hydroperoxide decomposition by poly(4-
vinylpyridine-co-divinylbenzene) supported cobalt and chromium complexes. Chemical Engineering Journal
152: 181–188.
 Luyten et al. 1998. Ordering in Supramolecular Elastomer-Amphiphile Systems. 4 Vinylpyridine-
Divinylbenzene Networks with Alkylphenols. Macromolecules 31: 160-170.
 Natasa D. 2002. Analytical applications of oscillatory chemical reactions: determination of some
pharmaceuticaly and biologically important compounds. Journal of the Serbian Chemical Society 44: 55-66.
 Rodika N. 2011. A study of the dynamic of iodine formation In the Mn(II) catalysed Bray-Liebhafsky
reaction. Academia Romana 56: 47-55.
 Scott et al. 2001. Oscillating Chemical Reaction. J.Am.Chem.Soc 43: 1-10.
 Seborg, D. 2004. Process Dynamic and Control 2nd ed. New York: John Wiley and Sons.
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LOGO

Kinetics of the Bray-Liebhafsky Oscillatory

Presented by Group 17:

J. P. Maksimovic, Z. D. Cupic, D. Loncarevic, N. Pejic,

Science of Sintering 2011, 43: 55-62

 The fast reaction is used to described the reaction followed

 In generally, fast reaction have a big constanta value, low

 The oscillation reaction can present with :

 Some type of oscillation reaction:

 Kinetics of reaction is analysed by perturbation by

 The initial concentrations the BL matrix species:

 The catalyst was placed in the reactor prior to

 The evolution of the indicative BL reaction was

 Reactive species can be adsorbed from

 Catalyst activity was identified against oxidation branch of the

 Cobalt ions from catalyst Co-PVPDVB are extracted in acidified

 PVPDVB is strongly perturbing agent

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