Fuel Properties and Use of Hydrogen I.C.engines
Fuel Properties and Use of Hydrogen I.C.engines
3. Working cycle
Ottocycle
Diesel cycle
4. No. of cylinders
Single cylinder engine
Multi cylinder engine
Classification of I .C. Engines
5. Engine design
Vertical engine
Horizontal engine
V engine
Radial engine
6.Method of Ignition
Spark Ignition
Compression Ignition
7. Speed
Low speed
High speed
Medium speed
8. Cooling system
Air cooled engine
Water cooled engine
Classification of I .C. Engines
9. Valve location
Over head valve engine
Side valve engine
10. Lubrication
Wet pump lubrication
Dry pump lubrication
11.Application
Stationary engine
Marine engine
Locomotive engine
Automotive engine
Aircraft engine
Applications of I .C. Engines
Motorcycles
Mopeds
Scooters
Model airplanes
Buses
Trucks
Boats
I.C.Engine terminology
Bore
TDC ( Top Dead Centre )
BDC ( Top Dead Centre )
Stroke
Compression ratio
Max. cylinder volume
Clearance volume
Cylinder volume
Swept volume + clearance volume
Swept volume
Clearance volume
I.C.Engine terminology
Major parts
• Cylinder
• Cylinder head
• Piston
• Piston rings
• Connecting rod
• Crankshaft
• Cam shaft
• Crank case
• Flywheel
• Valves
• Water jackets
Moving Components
• Piston
– Acted on by combustion gases
– Lightweight but strong/durable
• Piston Rings
– Transfer heat from piston to
cylinder
– Seal cylinder & distribute lube
oil
• Piston Pin
– Pivot point connecting piston to
connecting rod
• Connecting Rod
– Connects piston & crankshaft
– reciprocating rotating
motion
Moving Components
• Crankshaft
– Combines work done by each piston
– Drives camshafts, generator, pumps, etc.
• Flywheel
– Absorbs and releases kinetic energy of
piston strokes -> smoothes rotation of
crankshaft
Moving Components
• Valves
– Intake: open to admit air
to cylinder (with fuel in
Otto cycle)
– Exhaust: open to allow
gases to be rejected
• Camshaft & Cams
– Used to time the addition
of intake and exhaust
valves
– Operates valves via
pushrods & rocker arms
CLASSIFICATION OF INTERNAL COMBUSTION
ENGINES
• Strokes
– Intake
– Compression
– Power
– Exhaust
Difference between 2 stroke & 4 stroke
Four Stroke Two Stroke
One power stroke in two One power stroke in one
revolutions of crankshaft revolution of crankshaft
Valves are provided Ports are provided
Engine is cooled by Engine is cooled by air
water
More space is required Less space is required
More Thermal efficiency Less Thermal efficiency
Less fuel consumption More fuel consumption
Requires more lubrication Not essential
Heavier engine Lighter engine
Petrol Engine Diesel Engine
Operates on the principle of Operates on the principle of
Otto cycle Diesel cycle
Fuel is ignited by spark plug Fuel is ignited by hot
compressed air
Low compression ratio High compression ratio
Operates at high speed Operates at low speed
Fuel used is petrol Fuel used is Diesel
Lighter in weight Heavier in weight
Fuel is sent through Fuel is sent through fuel
carburetor injector
Fuel consumption is more Less fuel consumption
Less vibration More vibration
Petrol is highly volatile. So Diesel is less volatile. So
handling is more risk handling is not risky
Types of CI Engines
Glow plug
Orifice
-plate
Mol.wt. ≈110 ≈195 32.04 46.07 ≈18.7 44.10 46.1 ≈ 300 2.015
LHV,
44.0 42.5 19.9 26.8 50.0 46.3 28.4 37.7 120
MJ/kg
Heat of 410
vaporizati 305 250 1110 904 509 426 at 20º
on ,kJ/kg C
Boiling
30-215 180- 65 78 -160 -43 -24.9 330- -253
point, ºC 370 340
Property Gasoli Diesel Methan Ethanol Natural Propane DME RME Hydrogen
ne ol gas
90-98 120-
RON - 112 111 130 112 - -
(MON) (80- (120- 106
90) (91) (92) 130) (97)
Stoichio
metric A/
F ratio,
mass
14.7 15.0 6.43 8.94 17.12 15.58 9.0 11.2 34.13
Lower heating value and Higher
heating value
• The lower heating value (also known as net calorific value) of a fuel
is defined as the amount of heat released by combusting a specified
quantity (initially at 25°C) and returning the temperature of the
combustion products to 150°C, which assumes the latent heat of
vaporization of water in the reaction products is not recovered.
• The higher heating value (also known gross calorific value or gross
energy) of a fuel is defined as the amount of heat released by a
specified quantity (initially at 25°C) once it is combusted and the
products have returned to a temperature of 25°C, which takes into
account the latent heat of vaporization of water in the combustion
products.
Heat of Vaporization
The enthalpy of vaporization also known as
the (latent) heat of vaporization or heat of
evaporation, is the amount of energy
(enthalpy) that must be added to a liquid
substance, to transform a quantity of that
substance into a gas. The enthalpy of
vaporization is a function of the pressure at
which that transformation takes place.
• Octane number is a value used to indicate
the resistance of a motor fuel to knock.
Octane numbers are based on a scale on
which isoocatane is 100 (minimal knock)
and heptane is 0 (bad knock).
For low cetane fuels the ignition delay is long and most of the fuel is injected
before autoignition and rapidly burns, under extreme cases this produces an
audible knocking sound referred to as “diesel knock”.
For high cetane fuels the ignition delay is short and very little fuel is injected
before autoignition, the heat release rate is controlled by the rate of fuel
injection and fuel-air mixing – smoother engine operation.
45
Cetane Number
The higher the CN the better the ignition quality, i.e., shorter ignition delay.
The properties that contribute to its use as a combustible fuel are its:
• wide range of flammability
• low ignition energy
• small quenching distance
• high auto ignition temperature
• high flame speed at stoichiometric ratios
• high diffusivity
• very low density
Brake Thermal Efficiency
Nox Emission
CO Emission
HC Emission
Combustion characteristics of hydrogen and its impact
on emissions are given below;
• Hydrogen octane rating is 106 RON making it more suitable for spark-ignited engines.
• The laminar flame speed of hydrogen is 3 m/s, about 10 times that of gasoline and
methane.
• Hydrogen has very wide flammability limits ranging from 5 to 75% by volume (f = 0.07
to 9), which may lead to pre-ignition and backfiring problems.
• If inducted along with intake air, the volume of hydrogen is nearly 30% of the
stoichiometric mixture decreasing maximum engine power.
• Hydrogen on combustion produces water and there are no emissions of carbon
containing pollutants such as HC, CO and CO2 and air toxics.
• Trace amounts of HC, CO and CO2 however, may be emitted as a result of
combustion of lubricating oil leaking into engine cylinder.
• NOx is the only pollutant of concern from hydrogen engines. Very low NOx emissions
can be obtained with extremely lean engine operation (f < 0.05) and/or injection of
water into intake manifold or exhaust gas recirculation which in this case consists
primarily of water vapours.
Liquid H2 Hydride Fe-Ti Compressed
Gasoline (1.2%) H2 (70MPa)
14 5 5 5
Fuel mass, kg
Inlet Plenum TB
Cylinder head
Gasoline Direct Injection (GDI)
Controller
Air in
SP Exhaust
gas out
Throttle Injector
Comparison between PFI and GDI
Property Gasoline Diesel Methan Ethanol Natural Propane DME RME Hydrogen
ol gas
Mol.wt. ≈110 ≈195 32.04 46.07 ≈18.7 44.10 46.1 ≈ 300 2.015
LHV,
44.0 42.5 19.9 26.8 50.0 46.3 28.4 37.7 120
MJ/kg
Heat of 410
vaporizati 305 250 1110 904 509 426 at 20º
on ,kJ/kg C
Boiling
30-215 180- 65 78 -160 -43 -24.9 330- -253
point, ºC 370 340
Property Gasoli Diesel Methan Ethanol Natural Propane DME RME Hydrogen
ne ol gas
90-98 120-
RON - 112 111 130 112 - -
(MON) (80- (120- 106
90) (91) (92) 130) (97)
Stoichio
metric A/
F ratio,
mass
14.7 15.0 6.43 8.94 17.12 15.58 9.0 11.2 34.13
Properties of Hydrogen
The properties that contribute to its use as a combustible fuel are its:
• wide range of flammability
• low ignition energy
• small quenching distance
• high auto ignition temperature
• high flame speed at stoichiometric ratios
• high diffusivity
• very low density
Brake Thermal Efficiency
Nox Emission
CO Emission
HC Emission
Combustion characteristics of hydrogen and its impact
on emissions are given below;
• Hydrogen octane rating is 106 RON making it more suitable for spark-ignited engines.
• The laminar flame speed of hydrogen is 3 m/s, about 10 times that of gasoline and
methane.
• Hydrogen has very wide flammability limits ranging from 5 to 75% by volume (f = 0.07
to 9), which may lead to pre-ignition and backfiring problems.
• If inducted along with intake air, the volume of hydrogen is nearly 30% of the
stoichiometric mixture decreasing maximum engine power.
• Hydrogen on combustion produces water and there are no emissions of carbon
containing pollutants such as HC, CO and CO2 and air toxics.
• Trace amounts of HC, CO and CO2 however, may be emitted as a result of
combustion of lubricating oil leaking into engine cylinder.
• NOx is the only pollutant of concern from hydrogen engines. Very low NOx emissions
can be obtained with extremely lean engine operation (f < 0.05) and/or injection of
water into intake manifold or exhaust gas recirculation which in this case consists
primarily of water vapours.
Liquid H2 Hydride Fe-Ti Compressed
Gasoline (1.2%) H2 (70MPa)
14 5 5 5
Fuel mass, kg