Presentation 1
Presentation 1
Presentation 1
Retrieved from
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Central, https://ebookcentral.proquest.com/lib/sct/detail.action?docID=424087 .
In general, air pollutants, emitted from natural and
anthropogenic sources, can be broadly classified under two
categories —Primary and Secondary pollutants. The primary
pollutants are those that are emitted directly from the sources.
These are: Inorganic gases – SO2 , NO, CO, CO2 , H2 S. HF.
Olefinic and Aromatic hydrocarbons; Radioactive compounds.
The Secondary pollutants are those that are formed in the
atmosphere by chemical reactions among primary pollutants
and atmospheric constituents. Examples are: SO3 , NO2 , PAN
(Peroxyacyl nitrate), O3 , aldehydes, ketones, various nitrate
and sulphate salts.
• The five major primary pollutants are: Carbon
monoxide CO Nitrogen Oxides, NOx Sulphur
dioxide, SO2 Hydrocarbons, HC and Particulate
matter
Kothari, D., Singal, K. C., & Ranjan, R. (2016). Environmental science and engineering. Retrieved
from http://ebookcentral.proquest.com
• Carbon monoxide (CO) It is a colorless, odorless
and toxic gas produced when coal, wood and
natural gas do not burn completely due to
deficiency in oxygen supply. Burning of fossil fuel
in vehicles is the largest source of CO. It can be
minimized by providing catalytic convertors with
two wheelers and cars. CO is not a persistent
pollutant as natural processes convert it into
other compounds that are not harmful.
• Sulphur oxides The oxides of sulphur or SO2
and SO3 produced by burning fossil fuel (coal)
containing sulphur. Few industrial process like
production of paper and smelting of metals
release SO2. Even at low levels SO2 is known
to increase daily mortality and hospital
admissions.
prob
• It is estimated that during the 1952 London smog
episode 25,000 metric tons of coal, with an average
sulfur content of 4%, was burned. The mixing depth
(the height of the inversion layer or cap over the city
that prevented the escape of pollutants) was about 150
m over an area of about 1200 km 2. What was the
approximate SO2 concentration after the coal was
burned? Peirce, J. J., Vesilind, P. A., & Weiner, R. (1998).
Environmental pollution and control. Retrieved from
http://ebookcentral.proquest.com(page 248)
• Nitrogen oxides There are several oxides of nitrogen i.e.
N2O, NO, N2O3 and N2O5 which are collectively called as
NOx. These are released by motor vehicles and thermal
generation stations using fossil fuels like coal and oil.
Nitrogen oxides play significant role, being a source of
producing secondary air pollutants that are more
dangerous to all living organisms. Short-term exposure to
NO2 can cause respiratory and cardiovascular diseases.
• Expressing the Concentration of Gaseous Air
Pollutants Gaseous air pollutant
concentrations can be expressed in two ways:
as micrograms per cubic meter of air (ILtg/m
3) and as parts per million (ppm), where
• Particulate Small solid particles and liquid
droplets are collectively termed particulates.
They originate both from natural and man-
made sources. Every year natural sources
discharge 800–2,000 million tonnes and man-
made sources 200–500 million tonnes of
particulates. Among manmade sources, fly ash
from thermal power plants deserve mention
• Hydrocarbons and Photochemical Smog Natural processes, particularly
trees emit large quantities of hydrocarbons in air. Methane, CH4 is a
major hydrocarbon. It is generated in large quantities by bacteria
formed by anaerobic decomposition of organic matter in water
sediments and soil.
• Domestic animals (cattle, buffaloes, etc.) contribute about 85 million
tonnes of methane to the atmosphere each year. Automobiles are
significant sources of hydrocarbons.
• In presence of ozone, carbon monoxide, nitrogen oxides and
hydrocarbon participate in photochemical reactions (in presence of
sunlight).
• Photochemical smog occurs in coastal cities in winter climate e.g., in
Los Angeles, USA which have the heaviest vehicular traffic.
• Particulates range in size from 0.0002 µ (about
the size of a molecule) to 500 µ (1 µ = 10–6
metre). The number of particles in the
atmosphere vary from several hundred per
cm3 in clean air to more than 100,000 per
cm3 in highly polluted air (urban/industrial
area).
effects Kothari, D., Singal, K. C., & Ranjan, R. (2016). Environmental science and engineering. Retrieved from
http://ebookcentral.proquest.com