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TRICKLE BED

REACTOR
Chemical reaction engineering 2
Batch 3 (150140105034 to 150140105049)
Government engineering college, bharuch
INTRODUCTION

A trickle-bed reactor (TBR) is a chemical reactor that uses the


downward movement of a liquid and the downward (co-current)
or upward (counter-current) movement of gas over a packed bed
of (catalyst) particles.
It is considered to be the simplest reactor type for performing
catalytic reactions where a gas and liquid (normally both
reagents) are present in the reactor and accordingly it is
extensively used in processing plants.
Typical examples are liquid-
phase hydrogenation, hydrodesulfurization,
and hydrodenitrogenation in refineries (three phase hydrotreater)
and oxidation of harmful chemical compounds in wastewater
streams or of cumene in the cumene process.
Alsoin the treatment of waste water trickle bed reactors are used
where the required biomass resides on the packed bed surface.

Kinetics
Although the physical reactor is relatively simple,
the hydrodynamics in the reactor are extremely complex. It is
for this reason that TBRs have been extensively studied over the
past five decades and currently the amount of open literature
publications on TBRs is increasing, hinting that the
understanding of the hydrodynamics is still limited.
A good introduction to the hydrodynamics of TBR can be found
in the classic article by Satterfield.[Rate of reaction and mass
transfer equations are derived by Fogler.
EQUIPMENT DESIGN

 A typical trickle bed reactor consists of a tubular tank with a


sieve plate or wire mesh near its bottom to support the packed
bed, and inlets and outlets for the liquid stream at the top and
bottom of the reactor, respectively. The gas inlet can be located
at the top or bottom, depending on the process, with the outlet
located at the opposite end. A bubble cap, sieve plate
distributor, or fine layer of non-reacting particles are placed at
the top of the bed to ensure  a uniform liquid distribution
throughout the bed.
 A large factor in the overall performance of a trickle bed
reactor is the type of  packed bed used. The configuration of
the bed, whether it be random packing or structured packing,
as well as the shape of packing used, affect properties such
as pressure drop and the catalyst coating area.
 The animation below shows the basic operation of a trickle
bed reactor, which contains a fixed bed of catalyst. Liquid
reactants (green arrows) and gas phase reactants (yellow
arrows) continuously enter the reactor and flow through the
catalyst bed. The liquid and gas reactants react at the
catalyst, and the products are removed continuously.
 Depending on the application, alternatives to the standard
trickle bed reactor design might be necessary to attain
different reactor characteristics. For example:
 Monolith trickle bed reactors use a channeled slab of
ceramic or metallic material coated in a catalyst layer.
This design allows for a far lower pressure drop and
eliminates diffusion as a limiting factor to the reaction.
 Micro-trickle bed reactors use very small characteristic
length scales to allow better control of reaction parameters
and enhance process safety.
Advantages
 Can be used for three - phase reactions
 Lower total energy consumption since solids are stagnant, not
suspended in slurry
 Simple to operate under high temperatures and pressures

 Lower catalyst attrition


Disadvantages
 Hot spots may develop due to solvent evaporation
 Channeling may occur, leading to inefficiencies

 Difficult to control vessel parameters

 Lower performance when liquid not uniformly distributed

 Difficult to scale up due to dependence on fluid dynamics of


system
Thank you

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