NATS 101 Atmospheric Composition and Vertical Structure

NATS 101
Lecture 1
Atmospheric Composition
and Vertical Structure
100 km 100 km
C = 2a
 4.084 x 104 km a  6500 km
Ratio: Height/ Length is 100/(4.084 x 104)

 2.45 x 10-3
- height of the atmosphere is extremely
small compared with its length
 air motions are primarily horizontal.
 air motions are primarily horizontal
 very small vertical motions are very important,
e.g., they causing the development/inhibition of clouds.
Composition of the atmosphere
1. Permanent gases
2. Variable gases
3. Aerosols
1. Permanent gases
stable concentration in the atmosphere.
• account for about 99% of the atmospheric mass
• occur in a constant proportion in the lowest ~80 km of the
atmosphere.
• although individual molecules exchange between the

atmosphere and Earth, the total concentration remains the same
 chemical homogeneity
• Lowest 80 km is called the Homosphere and is sometimes

considered to be the entire atmosphere.
• The atmosphere above this is called the Heterosphere.

1. Permanent gases
N2 + O2 = 99% of atmospheric
volume below 80 km.
They are chemically active.
Ar, Ne, He, Xe < 1% and are

chemically inert.
** The residence time of a gas is the average time an individual molecule

remains in the atmosphere.
1. Permanent gases
Nitrogen:
• N2 is added and removed from the atmosphere very
slowly – long residence time** of ~42 million years.
• N2 is relatively unimportant for most meteorological and
climate processes
• some gases containing N are important to the Earth’s
climate such as NO2.
Oxygen:
• O2 is crucial to the existence of almost all forms of life
currently on the Earth. Its residence time is ~5000 years.
2. Variable gases
distributions vary both in time and space.
• account for < 1% of the atmosphere below 80 km.

• some of these gases impact the behavior of the
atmosphere considerably.
H2O + CO2 + O3 = 0.296% of atmospheric volume.

Water Vapor (0.25%)
• water vapor varies considerably in both

space and time.
• Continually cycled between atmosphere
and earth by evaporation, condensation
and precipitation. (hydrologic cycle)
• Stores and releases large amounts of heat via evaporation
and condensation.
• Water vapor has a residence time of only 10 days.

• WV density is greatest at the surface, and decreases rapidly
with height.
• WV is extremely important for clouds
• WV absorbs radiant energy emitted from the Earth’s surface.
(Greenhouse gas)
Carbon Dioxide (0.036%)
• (CO2) is supplied to the atmosphere through plant and animal

respiration, through decay of organic material, volcanic eruptions,
and both natural and anthropogenic (human caused)
combustion.
• It is removed through photosynthesis, the process by which
green plants convert light energy to chemical energy. Oxygen is
released into the atmosphere as a by-product.
• CO2 has a residence time of ~150 yrs.

• It is an effective absorber of longwave radiation emitted from
the Earth’s surface. (Greenhouse gas)
• Its concentration in the atmosphere has increased ~18% since
1958.
Ozone (0.01%)
• (O3) is an unusual molecule made up of 3 Oxygen atoms. It

forms when individual O atoms collide with an O2 molecule and
exists in very small concentrations in the stratosphere (we’ll
define this a little later).
• O3 is vital for absorbing lethal UV radiation from the sun. As it

does this, it breaks down into its constituent components O + O 2.
• Near the surface ozone is a pollutant, but exists there in

extremely small amounts.
3. Aerosols
• are small solid particles or liquid droplets (except water
particles) in the air.
• They are formed by both natural and anthropogenic means.

Aerosols typically have residence times of a few days to several
weeks.
• Apart from pollution, aerosols play an important role as

condensation nuclei, the core about which water can condense
in clouds.
• Formed from chemical reactions, wind-generated dust, volcanic

ejections, sea spray, and combustion (e.g., fine ash)
 removed from the atmosphere in precipitation.

Composition of the atmosphere - recap
1. Permanent gases
Name two permanent gases
2. Variable gases
Name two variable gases
3. Aerosols
Name two ways aerosols form
Weather Map Symbols
Ref:- Appendix C, Aguado and Burt
48 997
32
34 247

30 65 103
42
W E
S
TEXAS
Oregon/California
Vertical Structure of the atmosphere
1. Density
2. Pressure
3. Temperature
mass
______
Density:  = volume (kg/m3 or g/cm3)
Initial State    
Incompressible fluid
Initial State    
Compressible fluid
The density of the gases that make up the atmosphere is

constantly changing. In addition, the atmosphere is compressible.
Near sea level, air density ~ 1.2 kg m-3.
Sea-level
At Denver CO, (~1.6 km altitude – or 1 mile), air density is

approximately 85% of that at sea level, or 1.01 kg m–3.
Denver, CO
Pressure:
30
Higher elevation
Height Less air above
(km) Lower pressure
Can be thought of as 20
weight of air above you.
(Note that pressure acts in
all directions!) 10
So as elevation increases,
pressure decreases.
0
Lower elevation
More air above
Higher pressure
Density and Pressure Variation
Key Points:
1. Both decrease
rapidly with height
2. Air is compressible,
i.e. its density varies
Ahrens, Fig. 1.5

Pressure Decreases Exponentially
with Height
Logarithmic Decrease
1 mb
48 km
• For each 16 km
increase in altitude,
10 mb
32 km
pressure drops by
factor of 10.
100 mb 16 km 48 km - 1 mb 32
km - 10 mb 16 km -
100 mb 0
km - 1000 mb
Equation for Pressure Variation
We can Quantify Pressure Change with Height

What is Pressure at 2.8 km?
(Summit of Mt. Lemmon)
Use Equation for Pressure Change:

p(at elevation Z in km) = pMSL x 10 -Z/(16 km)
Set Z = 2.8 km, pMSL = 1013 mb
p(2.8 km) = (1013 mb) x 10 –(2.8 km)/(16 km)
p(2.8 km) = (1013 mb) x 10 –(0.175)
p(2.8 km) = (1013 mb) x 0.668 = 677 mb

What is Pressure at Tucson?
Use Equation for Pressure Change:

p(at elevation Z in km) = pMSL x 10 -Z/(16 km)
Set Z = 800 m, pMSL = 1013 mb
Let’s get cocky…

How about Denver? Z=1,600 m
How about Mt. Everest? Z=8,700 m
You try these examples at home for practice
Temperature Stratification
Divide into several vertical layers based on electrical, temperature,
and chemical (homogeneous/heterogeneous), characteristics.
Together with the

change in density with
height, this gives the
atmosphere its
structure.
“Standard atmosphere”
is calculated based on
profiles at 30 latitude.
Contains 80% of
Layer of most interest
the atmospheric
to this course!!!
mass
Tropopause
Depth ranges from ~8 km
at the poles to ~16 km in
the tropics
Troposphere
The lapse rate is the

average decrease Majority of the
Rapid decrease in
in temperature with weather occurs
temperature with
height ~ 6.5°C/km here
height
Contains ~19.9% of Layer of some interest Stratopause
the atmospheric to this course!!!
mass
Temperature increases with

height from 20-~50 km
(Temperature inversion)
Stratosphere
Ozone layer
The ozone layer absorbs

much of the incoming
solar radiation, warming
the stratosphere, and Isothermal in Little weather
protecting us from harmful lowest 10 km occurs here
UV radiation Lapse rate is 0
Neither of these layers have much
Mesosphere
interest for the Meteorologist
Temperature once
again decreases
with height
Thermosphere
Temperature once
again increases
with height
Ionosphere
- extends from the upper mesosphere into the thermosphere.
Contains large numbers of charged particles called ions. Ions
are atoms or molecules that have gained an electron or lost an
electron so that they carry a charge. This occurs in the upper
atmosphere because the molecules are being constantly
bombarded by solar radiation.
Important for reflecting AM radio waves back to Earth.
Also responsible for the aurora borealis (northern lights) and

aurora australis (southern lights).
Summary:
Divide the atmosphere into several vertical layers based on
temperature characteristics. Together with the change in density
with height, this gives the atmosphere its structure.
Thermosphere
Mesosphere
Temperature
Inversion
Stratosphere Stable layer
Troposphere
T-profile
tropopause
Temperature
inversion

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NATS 101

Ratio: Height/ Length is 100/(4.084 x 104)

• although individual molecules exchange between the

• Lowest 80 km is called the Homosphere and is sometimes

• The atmosphere above this is called the Heterosphere.

Ar, Ne, He, Xe < 1% and are

** The residence time of a gas is the average time an individual molecule

• account for < 1% of the atmosphere below 80 km.

H2O + CO2 + O3 = 0.296% of atmospheric volume.

• water vapor varies considerably in both

• Water vapor has a residence time of only 10 days.

• (CO2) is supplied to the atmosphere through plant and animal

• CO2 has a residence time of ~150 yrs.

• (O3) is an unusual molecule made up of 3 Oxygen atoms. It

• O3 is vital for absorbing lethal UV radiation from the sun. As it

• Near the surface ozone is a pollutant, but exists there in

• They are formed by both natural and anthropogenic means.

• Apart from pollution, aerosols play an important role as

• Formed from chemical reactions, wind-generated dust, volcanic

 removed from the atmosphere in precipitation.

The density of the gases that make up the atmosphere is

At Denver CO, (~1.6 km altitude – or 1 mile), air density is

Ahrens, Fig. 1.5

We can Quantify Pressure Change with Height

Use Equation for Pressure Change:

p(2.8 km) = (1013 mb) x 10 –(2.8 km)/(16 km)

p(2.8 km) = (1013 mb) x 10 –(0.175)

p(2.8 km) = (1013 mb) x 0.668 = 677 mb

Use Equation for Pressure Change:

Let’s get cocky…

Together with the

The lapse rate is the

Temperature increases with

The ozone layer absorbs

Important for reflecting AM radio waves back to Earth.

Also responsible for the aurora borealis (northern lights) and

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