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    Tetra Ammine Copper (II) Sulphate

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    Midde Sridhar
    The document describes the preparation of tetra ammine copper(II) sulphate complex. Crystalline copper sulfate is dissolved in water and sulfuric acid is added to clear the solution. Ammonia is added to form a deep blue precipitate which is dissolved by further addition of ammonia. Ethanol is added and allowed to slowly evaporate, forming long needle-shaped dark blue-violet crystals of the tetra ammine copper(II) sulfate complex. The complex has a square planar structure and is paramagnetic with a magnetic moment of 1.732 Bohr magnetons.

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    Tetra Ammine Copper (II) Sulphate

    Uploaded by

    Midde Sridhar
    939 views11 pages
    The document describes the preparation of tetra ammine copper(II) sulphate complex. Crystalline copper sulfate is dissolved in water and sulfuric acid is added to clear the solution. Ammonia is added to form a deep blue precipitate which is dissolved by further addition of ammonia. Ethanol is added and allowed to slowly evaporate, forming long needle-shaped dark blue-violet crystals of the tetra ammine copper(II) sulfate complex. The complex has a square planar structure and is paramagnetic with a magnetic moment of 1.732 Bohr magnetons.

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    Original Title

    Tetra Ammine Copper(II)Sulphate

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    The document describes the preparation of tetra ammine copper(II) sulphate complex. Crystalline copper sulfate is dissolved in water and sulfuric acid is added to clear the solution. Ammonia is added to form a deep blue precipitate which is dissolved by further addition of ammonia. Ethanol is added and allowed to slowly evaporate, forming long needle-shaped dark blue-violet crystals of the tetra ammine copper(II) sulfate complex. The complex has a square planar structure and is paramagnetic with a magnetic moment of 1.732 Bohr magnetons.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    939 views11 pages

    Tetra Ammine Copper (II) Sulphate

    Uploaded by

    Midde Sridhar
    The document describes the preparation of tetra ammine copper(II) sulphate complex. Crystalline copper sulfate is dissolved in water and sulfuric acid is added to clear the solution. Ammonia is added to form a deep blue precipitate which is dissolved by further addition of ammonia. Ethanol is added and allowed to slowly evaporate, forming long needle-shaped dark blue-violet crystals of the tetra ammine copper(II) sulfate complex. The complex has a square planar structure and is paramagnetic with a magnetic moment of 1.732 Bohr magnetons.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 11

    Preparation of

    Tetra ammine copper(II) sulphate


    complex [Cu(NH3)4]SO4
    Aim: To prepare the pure sample of Tetra
    amine copper(II) sulphate complex

    Apparatus: 1.Conical flask 2.Beakers


    3.Funnels 4.Glass rod 5.Measuring
    jars
    Chemicals :
    1.C2H5OH Ethylalcohol

    2.NH4OH Ammonium solution.

    3. CuSO4 Copper sulphate


    Principle: Copper sulphate reacts with
    Ammonia to form Tetra amine
    copper(II) sulphate complex.
    Ethyl alcohol

    CuSO4+4NH3 [Cu(NH3)4]SO4
    Procedure :
    The four steps involve during the formation of hydrated
    tetraammine cupric sulphate complex given as

    Step I Firstly dissolve 2.5 g of crystalline


    CuSO4.5H2O in minimum amount of H2O
    in 250 mL beaker. Now add few drop of
    conc. H2SO4 to clear up the solution if
    necessary.
    Step II Add liquor ammonia to copper
    sulphate solution from dropping funnel
    with constant stirring until the blue
    precipitate formed is dissolved to give a
    Stepsolution.
    deep III Now add 20 mL of ethyl alcohol
    slowly with constant stirring to the deep
    blue solution.
    Step IV Then allow it to stand to slow
    evaporation which gives long needle
    shaped brilliant dark blueviolet crystal
    of tetraamine cupric sulphate complex

    Step V Filter and wash it with ethyl


    alcohol and dry in a desiccator.
    [Cu(NH3)4]SO4 STRUCURE

    SQUARE PLANAR STRUCTURE


    [Cu(NH3)4]SO4 COMPLEX
    ELECTRONIC CONFIGURATION IN Cu ATOM

    3d10 4s1 4p0 4d0


    ELECTRONIC CONFIGURATION IN Cu +2 ION

    3d9 4s0 4p0 4d0


    ELECTRONIC CONFIGURATION IN [Cu(NH3)4] SO4COMPLEX

    XX XX XX XX

    3d10 4s2 4p5 4d0


    dsp2 Hybridisation
    NH3 NH3 NH3 NH3
    Magnetic Nature Of [Cu(NH3)4]SO4 COMPLEX

    Number Of Unpaired Electrons in [Cu(NH3)4]SO4 Complex = 1

    μ=√n(n+2) BM
    μ=√1(1+2) BM
    μ=√1(3) BM
    μ =√3 BM
    μ = 1.732 BM
    [Cu(NH3)4]SO4 Complex is a paramagnetic Substance and it’s
    Magnetic moment is 1.732 BM
    IUPAC Tetra ammine copper (II)sulphate
    name
    Hybridisatio dsp2
    n
    Magnetic Paramagnetic Nature
    Nature
    Oxidation
    State +2
    Geometry Square planar Structure

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