4 Dental Ceramic
4 Dental Ceramic
4 Dental Ceramic
Dr Lekshmy AR
First year pg
Contents
• Introduction
• History
• Classification
• Application in Dentistry
• Composition
• General Properties
Introduction
(GPT 9)
History
1728 : Proposed the use of porcelain in dentistry –
Pierre Fauchard
2001- Cerec3
• Dental ceramic : 69
• Dental porcelain teeth : 45
• Metal ceramic system : 38
CLASSIFICATIONS
According to Anusavice
Firing temperature
Predominantly
Particle filled Polycrystalline
glassy materials
glasses ceramics
Eg: feldspathic
Eg: Dicor Eg: procera
porcelain
New Classification System for All-ceramic and Ceramic-like Restorative Materials By
Gracis Et Al, The International Journal Of Prosthodontics Volume 28, Number 3, 2015
APPLICATIONS IN DENTISTRY
Esthetic laminates
Short span bridges
Single crown
Veneer for PFM
Artificial teeth
Orthodontic bracket
Basic structure
Ceramics : 2 phases
Glassy Phase
Provides translucency
Makes ceramic brittle
Crystalline Phase
Added to improve the mechanical properties
Newer ceramics (35-90%)
Composition
Feldspar
• Primary constituent
• Minerals composed of potash (K₂O),
soda(Na₂O) and silica (SiO₂)
• 75-85%
Kaolin
• Serves as a binder
• Consists of Al₂O₃ 2SiO₂ 2H₂O (Hydrated
Aluminium Silicate)
• Increases the moldability of the plastic
porcelain
• Give opacity to the mass
Quartz
• Present in concentrations of 13-14%
• Provide strength, firmness and improve
translucency of porcelain
• Serves as a framework for other
ingredients
Alumina
• Replaces some of the silica in the glass
network.
• Gives strength & Opacity.
• Alters the softening point and increase
the viscosity of porcelain during firing.
Glass modifiers
• Potassium, sodium and calcium oxides
• Lower the viscosity of glass
• Increase thermal expansion
Opacifying agents
Opacifiers are added to increase its opacity in order
to simulate color of natural teeth
• Zirconium oxide
• Titanium oxide
• Tin oxide
• Cerium oxide
Pigments
• To obtain various shades to mimic natural
tooth colour.
• Made by fusing metallic oxide with fine
glass and feldspar & regrinding to a powder.
Metallic oxide colour
Titanium • Iron or
Cobalt oxide oxide ⎼
yellowish nickel oxide
⎼ blue
brown ⎼ brown
Copper
Manganese
oxide
oxide lavender
green
General Properties
Strength
• Flexure strength
PFM -70 MPa
Stabilized Zr – 1200 Mpa
• Tensile strength
Low because of the unavoidable surface defects
When porcelain is placed under tension, stress
concentrates around these imperfections and
can result in brittle fractures
• Shear strength
Low due to lack of ductility
Methods of Strengthening Ceramics
1. Introduction of residual compressive stress by
• Ion exchange
• Thermal tempering
• Thermal expansion coefficient mismatch
2. Interruption of crack propagation by
• Dispersion strengthening
• Transformation toughening
3. Optimal design
Ion exchange/ Chemical tempering
• High stiffness
• Stiffness ranges from 69 to 210 GPa
Surface hardness
• Much harder than natural teeth (370-400 VHN)
Thermal properties
Thermal conductivity
• Low thermal conductivity
Coefficient of thermal expansion
• 6.4 to 7.8* 10-6 /0C
• Important property for layered restorations.
• CTE of various layers should be closely matched.
• Extreme difference can induce a lot of stresses in
the ceramic leading to immediate or subsequent
failures
Specific gravity
• Helps in bonding
Application of opaquer
• Types :
cover darkened teeth or post & core. • Slip casting is a complex technique
• Wear of opposing teeth is lesser • Considerable reduction of tooth
accumulation.
In- Ceram spinel
• Introduced due to the comparatively high opacity of
the alumina core.
• Incorporating magnesium aluminate (Mg Al2O4)
results in improved optical properties
Characterized by
• Increased translucency
Advantages
• Spinel renders greater strength
characteristics.
• Spinel has extended uses
(Inlay/Onlays , ceramic core material
and Veneers.)
Disadvantages
• Incapable to be etched by HF
• 25% reduction in flexural strength
In- Ceram zirconia
Disadvantages
• Poor esthetics due to increased opacity.
• Inability to etch
CASTABLE CERAMICS
• Casting at 1350˚C
• e.g. Dicor
DI-COR(Developed by Corning glass works and marketed by Dentsply)
Disadvantages:-
• Internal characterization not possible.
• Inadequate strength for posterior areas.
Pressable ceramics
Optical scanning
DESIGN
RESTORATION Milling Try In
Contact
scanner Shape on computer
Scanning screen
CAD CAM Copy milling
• Scans the preparation • Scans pattern
• Restoration designed virtually • Restoration designed manually
• Object milled from virtual • Restoration mills replica of
pattern pattern
YTZP- YTTRIUM STABILIZED ZIRCONIA CERAMICS
• In stress, the tetragonal crystal phase is transformed into the monoclinic crystal
phase.
• Can be used in long span FPDs both in anterior and posterior regions.
• More esthetic
PORCELAIN DENTURE TEETH